The deamination reaction of \Cl 2 was studied by using the non-isothermal TG method. The data from the non-isothermal experiments were analyzed by means of ACHAR and COATS-REDFERN methods. It was found that the integr...The deamination reaction of \Cl 2 was studied by using the non-isothermal TG method. The data from the non-isothermal experiments were analyzed by means of ACHAR and COATS-REDFERN methods. It was found that the integral kinetic equation and differential coefficient kinetic eqution for the deamination of \l 2 were f（α）=\ -1, g（α）=α+（1-α）ln （1-α）, activation energies were E 1=81.223 6 kJ/mol, E 2=189.634 2 kJ/mol; pre-exponential factor A 1=4.10×10 9/s, A2=7.02×10 22/s, and kinetic compensation effect equation ln A1=3.519 6E 1+5.378 2; ln A 2=3.457 3E 2+4.804 5.展开更多
文摘The deamination reaction of \Cl 2 was studied by using the non-isothermal TG method. The data from the non-isothermal experiments were analyzed by means of ACHAR and COATS-REDFERN methods. It was found that the integral kinetic equation and differential coefficient kinetic eqution for the deamination of \l 2 were f（α）=\ -1, g（α）=α+（1-α）ln （1-α）, activation energies were E 1=81.223 6 kJ/mol, E 2=189.634 2 kJ/mol; pre-exponential factor A 1=4.10×10 9/s, A2=7.02×10 22/s, and kinetic compensation effect equation ln A1=3.519 6E 1+5.378 2; ln A 2=3.457 3E 2+4.804 5.
