It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. se...It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. self-condensation in aprotic polar solvent occurs to give symmnetrical disubstituted diphenyl ethers. However. when it is substituted with moderate electron withdrawing groups, no diphenyl ethers are obtained under the same conditions, instead, corresponding carboxylates are yielded. As a result. the applicability of this reaction is distinctly clarified展开更多
文摘It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. self-condensation in aprotic polar solvent occurs to give symmnetrical disubstituted diphenyl ethers. However. when it is substituted with moderate electron withdrawing groups, no diphenyl ethers are obtained under the same conditions, instead, corresponding carboxylates are yielded. As a result. the applicability of this reaction is distinctly clarified
