Reversible solid-liquid conversion enabled by self-capture effect for stable non-flow zinc-bromine batteries

Non-flow aqueous zinc-bromine batteries without auxiliary components(e.g.,pumps,pipes,storage tanks)and ion-selective membranes represent a cost-effective and promising technology for large-scale energy storage.Unfortunately,they generally suffer from serious diffusion and shuttle of polybromide(Br^(-),Br^(3-))due to the weak physical adsorption between soluble polybromide and host carbon materials,which results in low energy efficiency and poor cycling stability.Here,we develop a novel self-capture organic bromine material(1,10-bis[3-(trimethylammonio)propyl]-4,4'-bipyridinium bromine,NVBr4)to successfully realize reversible solid complexation of bromide components for stable non-flow zinc-bromine battery applications.The quaternary ammonium groups(NV^(4+)ions)can effectively capture the soluble polybromide species based on strong chemical interaction and realize reversible solid complexation confined within the porous electrodes,which transforms the conventional“liquid-liquid”conversion of soluble bromide components into“liquid-solid”model and effectively suppresses the shuttle effect.Thereby,the developed non-flow zinc-bromide battery provides an outstanding voltage platform at 1.7 V with a notable specific capacity of 325 mAh g^(-1)NVBr4(1 A g^(-1)),excellent rate capability(200 mAh g^(-1)NVBr4 at 20 A g^(-1)),outstanding energy density of 469.6 Wh kg^(-1)and super-stable cycle life(20,000 cycles with 100%Coulombic efficiency),which outperforms most of reported zinc-halogen batteries.Further mechanism analysis and DFT calculations demonstrate that the chemical interaction of quaternary ammonium groups and bromide species is the main reason for suppressing the shuttle effect.The developed strategy can be extended to other halogen batteries to obtain stable charge storage.

Seasonal Variability of Rainfall and Thunderstorm Patterns in Kenya

This paper presents an analysis of spatial and temporal variation of rainfall and thunderstorm occurrence over Ken-ya from January 1987 to December 2017.The meteorological data used were obtained from the Kenya Meteorological Department(KMD)for the same period.This included the monthly thunderstorm occurrences and rainfall amounts of 26 synoptic stations across the country.The characteristics of monthly,seasonal and annual frequency results were presented on spatial maps while Time series graphs were used to display the pattern for annual cycle,seasonal varia-tions and the inter-annual variability of rainfall amounts and thunderstorm occurrences.A well-known non-parametric statistical method Mann Kendall(MK)trend test was used to determine and compare the statistical significance of the trends.Thunderstorm frequencies over the Eastern,Central and Coast regions of the country showed a bimodal pattern with high frequencies coinciding with March-April-May(MAM)and October-November-December(OND)rainy sea-sons.Very few thunderstorm days were detected over June-July-August(JJA)season.The areas to the western part of the country,near Lake Victoria,had the highest thunderstorm frequencies in the country over the three seasons:MAM,JJAS and OND.The annual frequency showed a quasi-unimodal pattern.These places near Lake Victoria showed sig-nificantly increasing thunderstorm trends during the MAM and OND seasons irrespective of the rainfall trends.This shows the effects of Lake Victoria over these areas,and it acts as a continuous source of moisture for thunderstorm for-mation.However,most stations across the country showed a reducing trend of thunderstorm frequency during MAM and JJA seasons.The importance of these findings is that they could support various policy makers,and users of cli-mate information,especially in the agriculture and aviation industries.

Case Studies of Sprite-producing and Non-sprite-producing Summer Thunderstorms

Three summer thunderstorms in the eastern region of China were analyzed in detail using multiple data, including Doppler radar, lightning location network, TRMM （Tropical Rainfall Measuring Mission）, MT- SAT （Multi-Function Transport Satellite） images, NCEP （National Centers for Environmental Prediction） Reanalysis, and radiosonde. Two of the three storms were sprite-producing and the other was non-sprite- producing. The two sprite-producing storms occurred on 1 2 August and 2~28 July 2007, producing 16 and one sprite, respectively. The non-sprite-producing storm occurred on 29-30 July 2007. The major ob- jective of the study was to try to find possible differences between sprite-producing and non-sprite producing storms using the multiple datasets. The results showed that the convection in the 1-2 August storm was the strongest compared with the other storms, and it produced the largest number of sprites. Precipitation ice, cloud ice and cloud water content in the convective regions in the 1-2 August storm were larger than in the other two storms, but the opposite was true in the weak convective regions. The storm microphysical prop- erties along lines through parent CG （cloud-to-ground lightning） locations showed no special characteristics related to sprites. The flash rate evolution in the 1-2 August storm provided additional confirmation that major sprite activity coincides with a rapid decrease in the negative CG flash rate. However, the evolution curve of the CG flash rate was erratic in the sprite-producing storm on 27-28 July, which was significantly different from that in the 1 2 August storm. The average positive CG peak current in sprite-producing storms was larger than that in the non-sprite-producing one.

Novel ternary metals-based telluride electrocatalyst with synergistic effects of high valence non-3d metal and oxophilic Te for pH-universal hydrogen evolution reaction

Electrocatalyst designs based on oxophilic foreign atoms are considered a promising approach for developing efficient pH-universal hydrogen evolution reaction(HER)electrocatalysts by overcoming the sluggish alkaline HER kinetics.Here,we design ternary transition metals-based nickel telluride(Mo WNi Te)catalysts consisting of high valence non-3d Mo and W metals and oxophilic Te as a first demonstration of non-precious heterogeneous electrocatalysts following the bifunctional mechanism.The Mo WNi Te showed excellent HER catalytic performance with overpotentials of 72,125,and 182 mV to reach the current densities of 10,100,and 1000 mA cm^(-2),respectively,and the corresponding Tafel slope of 47,52,and 58 mV dec-1in alkaline media,which is much superior to commercial Pt/C.Additionally,the HER performance of Mo WNi Te is well maintained up to 3000 h at the current density of 100 mA cm^(-2).It is further demonstrated that the Mo WNi Te exhibits remarkable HER activities with an overpotential of 45 mV(31 mV)and Tafel slope of 60 mV dec-1(34 mV dec-1)at 10 mA cm^(-2)in neutral(acid)media.The superior HER performance of Mo WNi Te is attributed to the electronic structure modulation,inducing highly active low valence states by the incorporation of high valence non-3d transition metals.It is also attributed to the oxophilic effect of Te,accelerating water dissociation kinetics through a bifunctional catalytic mechanism in alkaline media.Density functional theory calculations further reveal that such synergistic effects lead to reduced free energy for an efficient water dissociation process,resulting in remarkable HER catalytic performances within universal pH environments.

Thunderstorm and Lightning Activities over Western Pacific,Northern Indian Ocean and South China Sea Along with Their Adjacent Lands

The Lightning Imaging Sensor(LIS)and Radar Precipitation Feature(RPF)data are used to investigate the activities and properties of lightning and thunderstorms over a region including the Western Pacific,northern Indian Ocean and the South China Sea along with their adjacent lands.The lands feature significantly more frequent lightning flashes and thunderstorms than the oceans,especially the open oceans.The highest densities of lightning and thunderstorm occur over the Strait of Malacca and the southern foothills of the Himalayas.Over the ocean regions,the Bay of Bengal and the South China Sea are characterized by relatively frequent lightning and thunderstorm activities.Larger average spatiotemporal size and optical radiance of flashes can be found over the oceans;specifically,the offshore area features the most significant flash duration,and the open ocean area is characterized by the greatest flash length and optical radiance.The smallest average values of flash properties can be found over and around the Tibetan Plateau(TP).The oceanic thunderstorms tend to have a significantly larger horizontal extent than the continental thunderstorms,with the former and latter having the average area of the regions with radar reflectivity larger than 20 dBZ,generally over 7000 km^(2) and commonly below 6000 km^(2),respectively.The TP thunderstorms show the smallest horizontal extent.Meanwhile,the oceanic thunderstorms exhibit greater 20 dBZ but smaller 40 dBZ top heights than the continental thunderstorms.The average flash frequency and density of the oceanic thunderstorms are typically less than 5 fl min^(-1) and 0.3 fl 100 km^(-2) min^(-1),respectively;in contrast,the corresponding values of continental thunderstorms are greater.It is explored that the regions associated with strong convective thunderstorms are more likely to feature small-horizontal-extent and low-radiance flashes.

Radio-Acoustic Study of Thunderstorms

The observation, in the past, that a thunderstorm perturbed the transmissions of an old vacuum tubes radio with noise discharges in correspondence with lightnings, suggested the possibility of radio-acoustic study of thunderstorms. The noise discharges appeared to convey not only information about lightnings, but also about any other thunderstorm electromagnetic phenomena generating noise discharges. The low-cost instrumentation involved in the radio-acoustic study, comprised a radio Telefunken mod. T33B, a 15 m long indoor wire antenna, a mobile telephone Samsung Galaxy S20 FE 5G provided with the recorder App Enregistreur vocal, a computer HP Pavillion dv5-1254eg and the s/w audio analyser Audacity. A first thunderstorm on 20 June 2023 and a second thunderstorm on 22 June 2023, both above Munich, were radio-acoustic studied. The second thunderstorm was more active than the first and released much more energy.

Prediction-Based Thunderstorm Path Recovery Method Using CNN-BiLSTM

The loss of three-dimensional atmospheric electric field(3DAEF)data has a negative impact on thunderstorm detection.This paper proposes a method for thunderstorm point charge path recovery.Based on the relation-ship between a point charge and 3DAEF,we derive corresponding localization formulae by establishing a point charge localization model.Generally,point charge movement paths are obtained after fitting time series localization results.However,AEF data losses make it difficult to fit and visualize paths.Therefore,using available AEF data without loss as input,we design a hybrid model combining the convolutional neural network(CNN)and bi-directional long short-term memory(BiLSTM)to predict and recover the lost AEF.As paths are not present during sunny weather,we propose an extreme gradient boosting(XGBoost)model combined with a stacked autoencoder(SAE)to further determine the weather conditions of the recovered AEF.Specifically,historical AEF data of known weathers are input into SAE-XGBoost to obtain the distribution of predicted values(PVs).With threshold adjustments to reduce the negative effects of invalid PVs on SAE-XGBoost,PV intervals corresponding to different weathers are acquired.The recovered AEF is then input into the fixed SAE-XGBoost model.Whether paths need to be fitted is determined by the interval to which the output PV belongs.The results confirm that the proposed method can effectively recover point charge paths,with a maximum path deviation of approximately 0.018 km and a determination coefficient of 94.17%.This method provides a valid reference for visual thunderstorm monitoring.

Analysis of Continuous Thunderstorm in One Week at Qingdao Airport Based on Sounding Data

Continuous thunderstorm occurring at Qingdao Airport in China from August 7 to 13,2022 was analyzed based on sounding data.The weather was divided into thunderstorm gale,thunderstorm and heavy precipitation,and some physical quantities and time variables which can effectively identify severe convective weather types were preliminarily obtained.The results show that CAPE was sensitive to different types of weather,but the uncertainty was relatively large.Convective temperature T_(CON),temperature difference between 500 and 850 hPa,and vertical wind shear can distinguish thunderstorm gale,thunderstorm and heavy precipitation weather obviously.Besides,K index,Showalter index,θ_(se) difference between 500 and 850 hPa were also important basis to distinguish thunderstorm and heavy precipitation weather.Thunderstorm gale can be distinguished by the 24-hour variations of K index,and the difference of dew point between 500 and 850 hPa.The 24-hour variations of(T-T_(d))_(500) and vertical wind shear can be used to distinguish between heavy precipitation and thunderstorm weather;the 24-hour variation of stratification stability Δθ_(se) can distinguish the three kinds of weather well.For the wind field,the existence of vertical wind shear was required for strong convective weather,and the 24-hour increment of thunderstorm gale and thunderstorm was larger than that of heavy precipitation.

Assessment of the Impacts of Thunderstorm on Flight Operations at Murtala Mohammed International Airport,Ikeja,Lagos State,Nigeria

The inefficiency of the aviation industry and the persistent rise in aviation hazards have been linked to weather phenomena.As a result,researchers are looking for better solutions to the problem.The study examined the impact of thunderstorms on flight operations at Murtala Mohammed International Airport,Lagos.The data on thunderstorms and flight operations were sourced from Nigerian Meteorological Agency(NiMet)and Nigerian Airspace Management Agency(NAMA)respectively.In order to meet the research target,descriptive statistics(mean,standard deviation,and charts)and inferential statistics(Pearson’s Product Moment Correlation(PPMC)and Regression)were used.The significance level for all inferential analyses was set at 5%(0.05).The study revealed that 77.4%of thunderstorms occurred during the rainy season(April-October)while 22.6%occurred during the dry season(November-March).It also revealed some fluctuating movements of a thunderstorm in the study area.According to the findings,thunderstorms occur most frequently at the airport in June and less frequently in January and December.The study also discovered that thunderstorms at the airport are positively and significantly related to flight delays and cancellations,while the association between flight diversions and thunderstorm occurrence is positive but statistically insignificant.Furthermore,flight delays,flight diversions,and flight cancellations interact positively among themselves.The regression result of the study revealed that a 1%increase in thunderstorm occurrence leads to a 19.4%increase in flight delay,a 7.1%increase in flight cancellation,and a 4.3%increase in flight diversion.As a result,the study presented various regression models that may be utilized to make predictions.The study proposes consistent thunderstorm observation at the airport and steady forecasts using the regression models,based on the findings.However,it further recommends that pilots,air traffic controllers,and meteorologists be trained and retrained so that they can provide better and more efficient services.

我国大气电学研究的最新进展

大气电学主要研究地球大气和近地空间发生的电学过程及其机理和影响,其核心研究内容是雷电物理和雷暴电学。自1980年代以来,中国大气电学研究不断取得新的进展,特别是近年来,得益于高时间分辨率雷电探测技术的进步,大气电学研究不仅在雷电物理学和雷暴云电荷结构方面取得了重要成果,也在雷电和雷暴对近地空间的影响、强对流天气的雷电特征、以及雷电资料同化和预警预报等方面取得了重要进展。本文从六个方面对近五年来大气电学的主要研究进展进行回顾,包括高精度雷电探测和定位技术、雷电物理过程和机制、雷暴对中上层大气的影响、雷暴云电荷结构的观测和数值模拟、强对流天气的雷电特征与预报、雷电对气候变化的影响与响应等,最后对大气电学未来发展进行展望。

湖北冷季高架雷暴天气分类及环境参数特征分析

利用常规观测资料、加密地面自动站、闪电定位仪和ERA5再分析资料,将2011—2020年湖北冷季91次高架雷暴事件,按照形成机制分为雷雨型、强对流型和雷打雪型3类,并细致归纳了3类事件的时空分布特征、大气环流背景及关键环境参数等特征。(1)湖北冷季高架雷暴雷雨型最多,强对流型次之,雷打雪型最少。3类型存在明显的时空分布差异,雷雨型主要发生在秋末冬初(11月)和冬末初春(1—2月),强对流型及雷打雪型常出现在早春2月,3月基本以强对流型为主。(2)低槽冷锋、850 hPa切变线及低空西南急流是冷季高架雷暴发生的有利环流背景,近地面为稳定的冷气团控制,逆温明显,西南低空急流沿着锋面逆温层以上的850 hPa附近触发抬升,水汽、上升运动及不稳定层结均出现在850 hPa以上。雷雨型和雷打雪型距离冷锋超过100 km以上,强对流型不足100 km。(3)850 hPa是风场转换的重要层次。强对流型850 hPa露点温度(T_(d850))、K指数、850 hPa与500 hPa温差(ΔT_(85))、850 hPa假相当位温(θ_(se850))、西南急流厚度和强度(I700)、切变线强度(S_(850))最大,中低层(850~700 hPa)垂直风切变(SL78)最小;雷打雪型对水汽和不稳定能量的要求最低,SL78最大。

《雷雨》复数故事系统的生成及意义指向

话剧《雷雨》中有一个在时间和空间上层层叠叠的故事系统。其生成涉及从“五四”到20世纪30年代社会文化生活的多个层面,如个性解放、阶级斗争、文化时尚、旧家庭的恶习残留和人性错乱等。这些故事源头复杂,既涉及中西文化传统,也涉及时代语境。作家曹禺在讲述这些故事的时候,运用三角恋爱叙事、家庭戏、法庭审判叙事、戏剧巧合、人物身份背景模糊化、年龄漏洞和互文等方式,将本来散乱在不同历史阶段和当时社会各个层面的文化现象,在“家庭”格局下,收集、整理、剪辑、连缀、凝聚为一个以双重乱伦故事为树干,以其他故事为枝杈的层次丰富的故事树。这个复杂的故事树及其折叠艺术,所体现的伦理指向是复杂暧昧的,并远远逸出创作主体的把控。

播撒碘化银人工消雹对冰雹云微物理过程和起放电过程影响的数值模拟研究

为了全面了解人工消雹对云中冰相粒子的浓度和时空变化以及冰雹云微物理过程和起放电的影响,本文利用包含了AgI催化方案的三维强风暴动力电耦合数值模式,以AgI播撒量为唯一变化量进行了多组模拟实验。结果表明,催化过后,整体上,-40~0℃范围内的冰晶、雪花和霰粒子数浓度和比含水量增多。播撒AgI使霰的平均尺度减小,向雹的转化比例大为降低,因此冰雹的比含水量和浓度都减小。随着AgI播撒剂量的增加,冰晶、雪花和霰粒子的数浓度和比含量整体变化趋势不变,增大与减小区域相对应,但变化更明显;消雹效果会更好,但降雨量呈先增加后减小。播撒AgI会使冰雹云前期正的非感应起电率区出现时间提前,中心增强,上界高度抬升,后期负的非感应起电率区中心增强。所以,播撒后前期主要使底部次正电荷区增强,后期主要使上方主正电荷区和中部负电荷区增强。随着催化剂量增多,这些变化越明显。播撒AgI对地闪有一定的抑制作用,而使云闪和总闪少量增多,首次放电和云闪的峰值时间提前,放电持续性更强,闪电频发时段的闪电频率略有降低。

廊坊市雷暴大风多普勒雷达特征指标预警应用分析

利用北京、天津和沧州多普勒天气雷达对2010—2019年廊坊市发生的29次雷暴大风天气过程中的阵风锋、径向速度大值区、垂直累积液态水含量(VIL)≥40 kg·m^(-2)等预警指标进行验证分析,结果表明:51.9%的站次出现了阵风锋,其中61.0%的雷暴大风出现在主体回波移动前方中部到右侧;17 m·s^(-1)以上大风速区作为预警指标,预警的平均提前量达47.2 min。100%的弓形回波雷暴大风出现前上游及可能影响区域存在≥17 m·s^(-1)的大风速区,以此发布预警可提前37.1 min;71.4%的雷暴大风站点上空或10 km范围内VIL≥40 kg·m^(-2),平均预警提前量最高,达到52.7 min;依据带状回波前侧或右前侧出现阵风锋发布预警的平均提前量为60.6 min。73.7%的块状回波雷暴大风天气上游及可能影响区域有≥17 m·s^(-1)的大风速区。结合上游及可能影响区域≥17 m·s^(-1)和≥20 m·s^(-1)大风速区、阵风锋、VIL≥40 kg·m^(-2)出现位置可以提前30~60 min发布雷暴大风预警信号,且可更加精准地预测灾害性大风的落区、出现时间和强度。

河南一次伴有龙卷的多阶段强对流天气形成机制分析

利用常规观测资料以及区域自动站、卫星、新一代天气雷达和ERA5再分析等高时空分辨率资料,对2022年6月13日河南一次伴有局地龙卷的多阶段强对流过程(以下简称“6.13”过程)的环流形势、中尺度系统演变特征进行了分析,并探讨了该过程不同阶段对流触发维持机制以及濮阳局地龙卷的雷达监测特征。结果表明:(1)这次东北冷涡槽后西北气流形势下大范围强对流天气具有影响范围广、持续时间长、灾害天气种类多的特点。(2)雷达监测到该过程强对流系统分3个阶段相继经过河南,各阶段强回波均持续8~9 h,移速30~50 km·h^(-1),强对流系统以多单体为主,受西北气流引导自西北向东南方向移动且落区有重叠。(3)河南上空始终维持强条件不稳定层结和中等到强的垂直风切变是“6.13”过程多阶段强对流天气长时间维持的重要原因。第一阶段河南本地强对流主要是由风场日变化、局地冷空气活动和地形分布共同作用形成的边界层辐合线或辐合中心触发;第二、三阶段强对流则由前期或同期周边区域强烈发展的地面中尺度雷暴高压伴随的阵风锋(出流边界)触发。(4)濮阳县局地龙卷由发展迅速的超级单体产生,该单体回波生成后12 min出现钩状回波和中尺度气旋性涡旋、18 min出现龙卷涡旋特征(TVS),且钩状回波和中尺度气旋性涡旋较龙卷发生有6 min的提前量。

雷暴电场对LHAASO观测面宇宙线次级光子的影响

LHAASO实验利用到达探测器的宇宙线次级粒子来获取原初宇宙线信息,而次级粒子中成分最多的是光子.雷暴期间,大气电场会影响次级带电粒子,进而改变地面光子信息.本文利用Monte Carlo方法,模拟研究了近地雷暴电场对LHAASO观测面次级光子的影响.模拟中使用了一个厚度均匀、方向垂直于地面的电场模型.结果表明,雷暴电场中光子的数目和能量变化显著,且依赖于电场强度.当电场为-1000 V/cm时,光子数目增加23%,能谱变软,当能量小于2 MeV时,数目增加超过29%.当电场为1700 V/cm时,光子数目呈指数增长,达到279%,能谱相较于-1000 V/cm变得更软,当能量小于2 MeV时,数目增加超过361%,符合相对论电子逃逸雪崩机理.这些变化主要源于电子被大气电场加速,数目增加(-1000 V/cm中增加65%,17000 V/cm中增加992%),能谱变软.同时,高能自由电子通过轫致辐射产生光子,导致光子的数目和能量也发生变化,且变化趋势与电子的一致.本模拟结果有助于理解雷暴期间LHAASO实验数据变化特点,并为大气电场加速宇宙线次级带电粒子的物理机制提供信息.

冷涡影响下杭州湾一次区域性极端大风的演变和机制分析

利用常规气象探空观测、地面自动气象站逐分钟观测、风廓线雷达以及多普勒天气雷达等多源观测资料,分析了2021年4月30日傍晚到夜间浙江北部和杭州湾沿海地区一次区域性极端大风的天气特征,重点探讨了对流系统移入杭州湾后的中尺度演变特征和大风增强的原因。结果表明,此次过程是典型的多尺度相互作用的结果,在高空深厚的东北冷涡影响下,配合中层西北急流和较强的地面暖低压促使飑线后部对流系统发展,形成雷暴大风天气。对流单体在经过杭州湾水系后明显增强,其阵风锋前侧有西南暖湿入流,后部冷池发展强盛,气压涌升,叠加地面环境风场和杭州湾水面的热动力条件,从而触发不稳定能量促使单体发展。系统经过杭州湾后辐散下沉出流明显增强,将中高层的动量更快地下传至地面,对于杭州湾南部风力增强效应显著。杭州湾光滑下垫面、喇叭口等特殊地形也是造成极端大风出现的原因之一。同时,逐分钟变温相比于极大风出现时间提前了约7~10 min,对于局地极端大风监测预警有一定的指示意义。

一种场磨式三维大气电场传感器

针对市面上电场传感器只能探测一维电场垂直分量且电场测量结果存在一定的误差,为了更加精确地测量大气电场强度,提高雷暴云预警的准确率,提出一种场磨式三维大气电场传感器,传感器主要结构由屏蔽罩、感应电极、光电开关、叶片和电机组成,电路设计主要包括I-V转换电路、差分放大电路、峰值检测电路和滤波电路等,进行传感器实地电场测量实验并整理实验数据;实验结果表明,该传感器能够对环境电场进行水平和垂直分量测量,有效反映了环境电场特征,验证了场磨式三维大气电场传感器结构设计和电路设计的有效性。

东北冷涡背景下三类区域性强对流天气过程时空分布和环境特征对比分析

东北冷涡是造成中国暖季强对流的重要天气尺度系统之一。为对比东北冷涡与不同类型强对流过程的时空关系及其环境特征差异,基于欧洲中期天气预报中心第5代大气再分析数据和中国国家气象信息中心提供的逐时大风、降水观测资料,筛选了2017—2021年4—9月东北冷涡背景下9例雷暴大风型、9例强降水型以及8例混合型强对流天气过程,通过动态合成开展了分析研究。结果表明:(1)三类强天气过程相对于冷涡的时空分布差异明显:雷暴大风型过程,超过70%的雷暴大风出现在冷涡中心的西南部或南部;而混合型过程,超过70%的大风出现在冷涡中心的东南部或南部;混合型和强降水型过程中,短时强降水均主要出现在冷涡中心南部或东南部,但后者发生在冷涡东南部的比例更高;雷暴大风型和强降水型过程主要出现在东北冷涡的发展和成熟阶段,而混合型过程主要发生在东北冷涡的成熟阶段。(2)三类强天气过程的环流形势和环境条件差异显著。雷暴大风型过程多出现在5—6月,一般对应的东北冷涡更深厚,等温线更密集,大气环境偏干,存在气温垂直递减率大和强风垂直切变条件,雷暴大风多发生在冷涡南侧的锋区附近,对流层中、高层受干冷空气控制,叠加在低层比较浅薄的暖湿空气之上有利于大气层结条件不稳定的增强,降水粒子蒸发降温形成的下沉气流和地面冷池,叠加锋区辐合更有利于形成区域性地面强风;而强降水型过程多集中在7—8月,对应的东北冷涡强度较弱,等温线较稀疏,强降水一般出现在锋前靠近暖区一侧的强层结不稳定区域内,对应水汽充沛、整层暖湿的环境条件,中低层温差较小,风垂直切变较弱。混合型过程对应的月份和冷涡强度与强降水型过程更接近,水汽、高低层温差以及风垂直切变等环境条件介于上述两类过程之间,但下沉对流有效位能在三类过程中表现为最大。总体来看,相较于中国中、低海拔地区雷暴大风和短时强降水的环境特征而言,东北冷涡背景下的强天气过程对应更强的深层风垂直切变,具有更强的天气尺度动力强迫。

Evolution Mechanism of a Severe Squall Line Triggered by the Coupling of a Sea Breeze Front and a Gust Front

In the present study, a severe squall line(SL) was analyzed by using intensive observational surface data and radar monitoring products. In this process, mesoscale convergence lines, such as the sea breeze front(SBF), gust front and dry line, served as the main triggering and strengthening factors. The transition from convection triggering to the formation of the initial shape was mainly affected by the convergence line of the SBF, which combined with thermal convection to form the main parts of the SL. In the later stage, the convergence line of the gust front merged with other convergence lines to form a series of strong convective cells. The SBF had good indicative significance in terms of severe convective weather warnings. The suitable conditions of heat, water vapor and vertical wind shear on the Shandong Peninsula were beneficial to the maintenance of the SL. Before SL occurrence, tropopause folding strengthened, which consequently enhanced the baroclinic property in the middle and upper troposphere. The high sensible heat flux at the surface easily produced a positive potential vorticity anomaly in the low layer, resulting in convective instability, which was conducive to the maintenance of these processes. In the system, when precipitation particles passed through the unsaturated air layer, they underwent strong evaporation, melting or sublimation, and the cooling effect formed negative buoyancy, which accelerated the sinking of the air and promoted the sustained development of the surface gale. Together with the development of lowlevel mesocyclones, the air pressure decreased rapidly, which was conducive to gale initiation.