The marine non\|carbonate sediment is exposed at the southwestern flank of the Zhepure Syncline where it lies about 4 km east to the typical cross\|section, Gongzha cross\|section (Hao and Wan, 1985; Willems et al., 1...The marine non\|carbonate sediment is exposed at the southwestern flank of the Zhepure Syncline where it lies about 4 km east to the typical cross\|section, Gongzha cross\|section (Hao and Wan, 1985; Willems et al., 1993, 1996) and ca.75km north to the Qomolangma. There are few people who can approach the place of the cross\|section, even so are endemic Tibetan. The cross\|section is named of the Qumiba cross\|section in this abstract. The new discovery, conformed on the massive Zhepure Formation limestone, here is named of Qumiba Formation. It is composed of two series of terrigenous sediments: Enba Member—lower gray shales intercalating with sandstones, and Zhaguo Member—upper reddish shales interbedding with sandstones. Abundant nannofossils with chronological meanings are first found out.Enba Member Common calcareous nannofossils in the Lutetian such as Chiastozygus barbatus, Chiasmolithus sp., Discoaster barbadiensis, Helicosphaera compacta, Reticulofenstra bisecta, Sphenolithus radians are processed in sample S12W1\|S17W1, in which the Helicosphaera compacta and Sphenolithus radians are part of the indicators of the nannofossil zone NP15. So it is proposed that Units S12\|17, 110 m in thickness, could have been deposited during Middle\|Late Lutetian.展开更多
In this paper, by using concentration and carbon stable isotope the CO2 sources of soil profiles developed on limestone, dolostone and claystone basements in Central Guizhou, China are comparatively studied. The resul...In this paper, by using concentration and carbon stable isotope the CO2 sources of soil profiles developed on limestone, dolostone and claystone basements in Central Guizhou, China are comparatively studied. The results show that CO2 concentration of soil profiles developed on different basements is different, having the following sequence: limestone>dolostone>claystone. Below the soil depth of 20 cm from the surface the δ13C value of CO2 in soil profile developed on limestone ranges from -12.811‰--13.492‰(PDB), that in soil profile developed on dolostone varys from -13.212‰--14.271‰(PDB) and that in soil profile developed on claystone is about -20.234‰- -21.485‰(PDB). Taking the carbon isotope of soil organic matter and carbonate rock as two isotopic endmembers, the proportion of soil CO2 generated by dissolution of carbonate rock is calculated, about 21%-25% for soil profile developed on limestone basement, 19%-21% for soil profile developed on dolostone basement. There is almost no influx of CO2 generated by the dissolution of carbonate rock in soil profile developed on claystone basement.展开更多
Supercapacitors(SCs) with high power density and long cycling span life are demanding energy storage devices that will be an attractive power solution to modern electronic and electrical applications. Numerous theoret...Supercapacitors(SCs) with high power density and long cycling span life are demanding energy storage devices that will be an attractive power solution to modern electronic and electrical applications. Numerous theoretical and experimental works have been devoted to exploring various possibilities to increase the functionality and the specific capacitance of electrodes for SCs. Non-carbon two-dimensional(2D)materials have been considered as encouraging electrode candidates for their chemical and physical advantages such as tunable surface chemistry, high electronic conductivity, large mechanical strength, more active sites, and dual non-faradaic and faradaic electrochemical performances. Besides, these 2D materials also play particular roles in constructing highway channels for fast ion diffusion. This concise review summarizes cutting-edge progress of some representative 2D non-carbon materials for the aqueous electrolyte-based SCs, including transition metal oxides(TMOs), transition metal hydroxides(TMHs), transition metal chalcogenides(TMCs), MXenes, metal-organic frameworks(MOFs) and some emerging materials. Different synthetic methods, effective structural designs and corresponding electrochemical performances are reviewed in detail. And we finally present a detailed discussion of the current intractable challenges and technical bottlenecks, and highlight future directions and opportunities for the development of next-generation high-performance energy storage devices.展开更多
文摘The marine non\|carbonate sediment is exposed at the southwestern flank of the Zhepure Syncline where it lies about 4 km east to the typical cross\|section, Gongzha cross\|section (Hao and Wan, 1985; Willems et al., 1993, 1996) and ca.75km north to the Qomolangma. There are few people who can approach the place of the cross\|section, even so are endemic Tibetan. The cross\|section is named of the Qumiba cross\|section in this abstract. The new discovery, conformed on the massive Zhepure Formation limestone, here is named of Qumiba Formation. It is composed of two series of terrigenous sediments: Enba Member—lower gray shales intercalating with sandstones, and Zhaguo Member—upper reddish shales interbedding with sandstones. Abundant nannofossils with chronological meanings are first found out.Enba Member Common calcareous nannofossils in the Lutetian such as Chiastozygus barbatus, Chiasmolithus sp., Discoaster barbadiensis, Helicosphaera compacta, Reticulofenstra bisecta, Sphenolithus radians are processed in sample S12W1\|S17W1, in which the Helicosphaera compacta and Sphenolithus radians are part of the indicators of the nannofossil zone NP15. So it is proposed that Units S12\|17, 110 m in thickness, could have been deposited during Middle\|Late Lutetian.
基金This work was supported by the National Natural Science Foundation of China(Grant No.49833002)National Climbing Project(Grant No.95-per-39)
文摘In this paper, by using concentration and carbon stable isotope the CO2 sources of soil profiles developed on limestone, dolostone and claystone basements in Central Guizhou, China are comparatively studied. The results show that CO2 concentration of soil profiles developed on different basements is different, having the following sequence: limestone>dolostone>claystone. Below the soil depth of 20 cm from the surface the δ13C value of CO2 in soil profile developed on limestone ranges from -12.811‰--13.492‰(PDB), that in soil profile developed on dolostone varys from -13.212‰--14.271‰(PDB) and that in soil profile developed on claystone is about -20.234‰- -21.485‰(PDB). Taking the carbon isotope of soil organic matter and carbonate rock as two isotopic endmembers, the proportion of soil CO2 generated by dissolution of carbonate rock is calculated, about 21%-25% for soil profile developed on limestone basement, 19%-21% for soil profile developed on dolostone basement. There is almost no influx of CO2 generated by the dissolution of carbonate rock in soil profile developed on claystone basement.
基金financial support from National Natural Science Foundation of China (No. 21671173)the Independent Designing Scientific Research Project of Zhejiang Normal University (No. 2020ZS03)Zhejiang Provincial Ten Thousand Talent Program (No. 2017R52043)。
文摘Supercapacitors(SCs) with high power density and long cycling span life are demanding energy storage devices that will be an attractive power solution to modern electronic and electrical applications. Numerous theoretical and experimental works have been devoted to exploring various possibilities to increase the functionality and the specific capacitance of electrodes for SCs. Non-carbon two-dimensional(2D)materials have been considered as encouraging electrode candidates for their chemical and physical advantages such as tunable surface chemistry, high electronic conductivity, large mechanical strength, more active sites, and dual non-faradaic and faradaic electrochemical performances. Besides, these 2D materials also play particular roles in constructing highway channels for fast ion diffusion. This concise review summarizes cutting-edge progress of some representative 2D non-carbon materials for the aqueous electrolyte-based SCs, including transition metal oxides(TMOs), transition metal hydroxides(TMHs), transition metal chalcogenides(TMCs), MXenes, metal-organic frameworks(MOFs) and some emerging materials. Different synthetic methods, effective structural designs and corresponding electrochemical performances are reviewed in detail. And we finally present a detailed discussion of the current intractable challenges and technical bottlenecks, and highlight future directions and opportunities for the development of next-generation high-performance energy storage devices.