Decoupled water electrolysis:Flexible strategy for pure hydrogen production with small voltage inputs

Hydrogen gas is widely regarded as an ideal green energy carrier and a potential alternative to fossil fuels for coping with the aggravating energy crisis and environmental pollution.Currently,the vast majority of the world's hydrogen is produced by reforming fossil fuels;however,this hydrogen-making technology is not sustainable or environmentally friendly because ofits high energy consumption and large carbon emissions.Renewables-driven water splitting(2H_(2)0-2H_(2)+0_(2))becomes an extensively studied scheme for sustain-able hydrogen production.Conventional water electrolysis requires an input voltage higher than 1.23 V and forms a gas mixture of H_(2)/O_(2),which results in high electricity consumption,potential safety hazards,and harmful reactive oxygen species.By virtue of the auxiliary redox mediators(RMs)as the robust H^(+)/e^(-)reservoir,decoupled electrolysis splits water at a much lower potential and evolves O_(2)(H_(2)O+RMS_(ox)-O_(2)+H-RMS_(red))and H_(2)(H-RMS_(red)-H_(2)+RMS_(ox))at separate times,rates,and spaces,thus pro-ducing the puretarget hydrogen gas safely.Decoupled electrolysis has accelerated the development ofwater electrolysis technology for H_(2) production.However,itis still lack of a comprehensive and in-depth review in this field based on different types of RMs.This review highlights the basic principles and critical progress of this emerging water electrolysis mode over the past decade.Several representative examples are then dis-played in detail according to the differences in the RMs.The rational choice and design of RMs have also been emphasized.Subsequently,novel applications of decoupled water splitting are briefly discussed,including the manufacture of valuable chemicals,Cl_(2) production,pollutant degradation,and other half-reactions in artificial photosynthesis.Finally,thekey characteristics and disadvantages of each type of mediator are sum-marized in depth.In addition,we present an outlook for future directions in decoupled water splitting.Thus,the flexibility in the design of mediators provides huge space for improving this electrochemical technology.@2024 Science Press and Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by ELSEVIER B.V.and Science Press.All rights reserved.

HetNets Under Decoupled Uplink and Downlink Access with UE Random Discontinuous Transmission: Local Delay and Energy Efficiency

Due to the limited uplink capability in heterogeneousnetworks (HetNets), the decoupled uplinkand downlink access (DUDA) mode has recently beenproposed to improve the uplink performance. In thispaper, the random discontinuous transmission (DTX)at user equipment (UE) is adopted to reduce the interferencecorrelation across different time slots. By utilizingstochastic geometry, we analytically derive themean local delay and energy efficiency (EE) of an uplinkHetNet with UE random DTX scheme under theDUDA mode. These expressions are further approximatedas closed forms under reasonable assumptions.Our results reveal that under the DUDA mode, there isan optimal EE with respect to mute probability underthe finite local delay constraint. In addition, with thesame finite mean local delay as under the coupled uplinkand downlink access (CUDA) mode, the HetNetsunder the DUDA mode can achieve a higher EE witha lower mute probability.

Comparative Analysis of Characteristics of the Coupled and Decoupled Parallel Mechanisms

The existence of coupling makes the parallel mechanism possess some special advantages over the serial mechanism, while it is just the coupling that brings about the parallel mechanism some limitations, such as complex workspace, high nonlinear relationship between input and output, difficulties in static and dynamic analysis, and the development of control system, which restricts its application fields. The decoupled parallel mechanism is currently one of the research focuses of the mechanism fields, while the study on the different characteristics between the deeoupled and coupled parallel mechanisms has not been reported. Therefore, this paper performs the systematic comparative analysis of the 3-RPUR and the 3-CPR parallel mechanisms. The features of the two mechanisms are described and their movement forms are analyzed with screw theory. The inverse and forward displacement solutions are solved and the Jacobian matrices are obtained. According to the Jacobian matrices and by using the theory of physical model of the solution space, the workspace, dexterity, velocity, payload capability, and stiffness of the mechanisms are analyzed with plotting the indices atlases. The research results prove that the effects of the coupling on the parallel mechanism are double-side, and then the adoption of the decoupled parallel mechanism should be determined by the requirements of the concrete application situation. The contents of this paper should be useful for the type synthesis and practical application of the parallel mechanism.

Type Synthesis and Characteristic Analysis of a Family of 2-DOF Rotational Decoupled Parallel Mechanisms

It is widely used for the rotational parallel mechanism in the field of spatial orientation. While owing to the existence of coupling, the forward kinematic solution and the control of the general rotational parallel mechanism are especially difficult. If decoupling can be realized, the kinematic analysis of the mechanism will be very simple. Presently, the research of the parallel mechanism is focused on the inverse solution and structure optimization, and there is a lack of rotation decoupled parallel mechanisms （DPMs）. So this paper proposes a family of 2 degree of freedom （DOF） rotational DPMs based on the four-bar linkage mechanism, and performs a characteristic analysis. This family of DPMs is composed of a moving platform, a fixed base and three limbs. Taking U_RRU SPU DPM as an example, the motion feature of this DPM is analyzed with the constraint screw method, and its mobility is calculated by using the Modified Kutzbach-Grtibler criterion. The inverse and forward displacement problems of the proposed parallel mechanism are solved. The decoupled feature of the proposed parallel mechanism is validated by the deduction of the expression of the Jaeobian matrix. Three kinds of singularity conditions of this DPM are discussed, and the atlases of the output parameter concerning different geometric parameters are plotted with the theory of the physical model of the solution space. The proposition and characteristic analysis of the novel rotational DPMs in this paper should be useful for further research and application of the parallel mechanisms.

Type Synthesis Method for the Translational Decoupled Parallel Mechanism Based on Screw Theory

Coupling is the significant characteristic of parallel mechanism,while it is just the coupling that brings about much difficulty for the configuration design,theoretical analysis and the development of the control system of the parallel mechanism. And recently,the research on the decoupled parallel mechanism becomes one of the research hot points in the mechanism fields. In this paper,a type synthesis method for the translational decoupled parallel mechanism( TDPM) is proposed based on the screw theory. To achieve the decoupling characteristics of the translational parallel mechanism,the translational decoupled criterion for type synthesis of the branches are presented in this paper. According to this criterion and the realization conditions of rotational degree of freedom of the mechanism proposed former,a large number of branches for the TDPM are obtained. Taking the three degrees of freedom( DOFs) TDPM as an example,the process of type synthesis is discussed in detail. Using this proposed type synthesis method,a serial of translational decoupled parallel mechanisms, including but not limited to all the existing typical 3-DOF TDPMs, are obtained, which identifies the correctness and effective of the method. The contents of this paper provide a reference and possess significant theoretical meanings for the synthesis and development of the novel decoupled parallel mechanisms.

Design and Dynamic Modeling of a 2-DOF Decoupled Flexure-Based Mechanism

Flexure mechanisms with decoupled characteristics have been widely utilized in precision positioning applications.However,these mechanisms suffer from either slow response or low load capability.Furthermore,asymmetric design always leads to thermal error.In order to solve these issues,a novel 2-DOF decoupled mechanism is developed by monolithically manufacturing sets of statically indeterminate symmetric（SIS） flexure structures in parallel.Symmetric design helps to eliminate the thermal error and Finite Element Analysis（FEA） results show that the maximum coupling ratio between X and Y axes is below 0.25% when a maximum pretension force of 200 N is applied.By ignoring the mass effect,all the SIS flexure structures are simplified to ＂spring-damper＂ components,from which the static and dynamics model are derived.The relation between the first resonant frequency of the mechanism and the load is investigated by incorporating the load mass into the proposed dynamics model.Analytical results show that even with a load of 0.5 kg,the first resonant frequency is still higher than 300 Hz,indicating a high load capability.The mechanism＇s static and dynamic performances are experimentally examined.The linear stiffnesses of the mechanism at the working platform and at the driving point are measured to be 3.563 0 N·μm-1 and 3.362 1 N·μm-1,respectively.The corresponding estimation values from analytical models are 3.405 7 N·μm-1 and 3.381 7 N·μm-1,which correspond to estimation errors of-4.41% and 0.6%,respectively.With an additional load of 0.16 kg,the measured and estimated first resonant frequencies are 362 Hz and 365 Hz,respectively.The estimation error is only 0.55%.The analytical and experimental results show that the developed mechanism has good performances in both decoupling ability and load capability;its static and dynamic performance can be precisely estimated from corresponding analytical models.The proposed mechanism has wide potentials in precision positioning applications.

Energy-efficient data transmission with non-ideal circuit power for downlink cellular networks

The downlink energy-efficient transmission schedule with non-ideal circuit power over Wreless networks involving a single transmitter and multiple receivers was investigated. According to the special structure of the problem, a novel algorithm called OOSCPMR （the optimal offine scheduling with non-ideal circuit power for multi-receivers） is proposed, and the optimal offine solutions to optimize the energy- efficient transmission policy are found. The packets to be transmitted can be divided into two types where one type of packet is determined to be transmitted using the enrgy- efficient tansmission time, and the other type of packet is determined by the ID moveright algorithm. Finally, an energy-efficient online schedule is developed based on te proposed OOSCPMR algoriAm. Simulation results show that the optima offline transmission schedule provides te lower bound performance for the online tansmission schedule. The proposed optimal offline and online policy is more energy efficient than the existing schemes tat assume ideal circuit power.

Decoupled Delay and Bandwidth Centralized Queue-Based QoS Scheme in OpenFlow Networks

There are an increasing of scenarios that require the independent bandwidth and delay demands. For instance, in a data center, the interactive message would not occupy much bandwidth, but it requires the rigorous demands for the delay. However, the existing QoS approaches are mainly bandwidth based, which are inappropriate for these scenarios. Hence, we propose the decoupled scheme in the OpenFlow networks to provide the centralized differential bandwidth and delay control. We leverage the mature HTB to manage the bandwidth. And we design the Queue Delay Management Scheme (QDMS) for queuing delay arrangement, as well as the Comprehensive Parameters based Dijkstra Route algorithm (CPDR) for the propagation delay control. The evaluation results verify the decoupling effectiveness. And the decoupled scheme can reduce the delay for high priority flows.

A Non-linear Non-ideal Model of Simulated Moving Bed Chromatography for Chiral Separations

A non-linear non-ideal model, taking into account non-linear competitive isotherms, axial dispersion, film mass transfer, intraparticle diffusion, and port periodic switching, was developed to simulate the dynamics of simulated moving bed chromatography (SMBC). The model equations were solved by a new efficient numerical technique of orthogonal collocation on finite elements with periodical movement of concentration vector. The simulated SMBC performance is in accordance with the experimental results reported in the literature for separation of l,1'-bi-2-naphthol enantiomers using SMBC. This model is useful for design, operation, optimization and scale-up of non-linear SMBC for chiral separations with significant non-ideal effects, especially for high solute concentration and small intraparticle diffusion coefficient or large chiral stationary phase particle.

Numerical modelling of non-ideal detonation in ANFO explosives applying Wood-Kirkwood theory coupled with EXPLO5 thermochemical code

Ammonium nitrate and fuel oil(ANFO)based explosive is a classic example of non-ideal high explosives.Its detonation is characterized by a strong dependence of detonation parameters on explosive charge diameter,presence and characteristics of confinement,as well as incomplete consumption of explosive at the sonic point.In this work we propose a detonation model based on the Wood-Kirkwood(WK)theory coupled with the thermochemical code EXPLO5 and supplemented with reaction rate models.Our objective is to analyze the validity of the model for highly non-ideal ANFO explosives,with emphasis on effect of reaction rate models.It was found that both single-step and two-step pressure-based models can be calibrated to reproduce experimental detonation velocity-charge radius data of ANFO at radii significantly above the failure radius(i.e.for D/D_(id)>~0.6).Single-step pressure-based model,with the pressure exponent equal to 1.4,proved to be the most accurate,even in the vicinity of the failure radius.The impact of the rate models is most evident on temporal(and spatial)distribution of flow parameters in detonation driving zone,especially when it comes to the conversion and width of detonation driving zone.

Design and Fabrication of MEMS Gyroscopes on the Silicon-on-insulator Substrate with Decoupled Oscillation Modes

The mode coupling is a major factor to affect the precision of the micro electromechanical systems（MEMS） gyroscope. Currently, many MEMS gyroscopes with separate oscillation modes for drive and detection have been developed to decrease the mode coupling, but the gyroscope accuracy can not satisfy the high-precision demand well. Therefore, high performance decoupled MEMS gyroscopes is still a hot topic at present. An innovative design scheme for a MEMS gyroscope is designed, and in this design, the inertial mass is divided into three parts including the inner mass, the outer mass and the main frame mass. The masses are supported and separated by a set of mutually orthogonal beams to decouple their movements. Moreover, the design is modelled by multi-port-element network（MuPEN） method and the simulation results show that the mode coupling of the gyroscope between driving and sensing mode was eliminated effectively. Furthermore, we proposed a new silicon-on-insulator（SOI） process to fabricate the gyroscope. The scale factor of the fabricated gyroscope is 8.9 mV/（（~）os） and the quality factor（Q-factor） is as high as 600 at atmosphere pressure, and then, the resonant frequency, scale factor and bias drift has been test. Process and test results show that the proposed MEMS gyroscope are effective for decrease mode coupling, furthermore, it can achieve a high performance at atmosphere pressure. Furthermore, the MEMS gyroscope can achieve a high performance at atmosphere pressure. The research can be taken as good advice for the design and fabrication of MEMS gyroscope, meanwhile, it also provides technical support for speeding up of MEMS gyroscope industrialization.

Study on Multi-variables Decoupled Fuzzy Controller for Confined Pig House in Northern China

In winter, the confined pig house of northern China is severe. The environment variables are nonlinear, time-varying and coupled, which seriously affect the health of pigs and the qualities of the meat. In order to solve the problem multi-variables coupling, a multi-variables decoupled fuzzy logic control method was proposed. Two fuzzy logic controllers were designed based on fuzzy logic theory. The fans, heaters and humidifiers were used to control temperature, humidity and ammonia. The reductions of temperature and humidity caused by ventilating were compensated by heaters and humidifiers respectively which realized the multivariables decoupling. The proposed methods were validated through theoretical, experimental and simulation analysis. The results suggested that the methods were able to regulate the confined pig house environment effectively. In addition, comparing to the manual regulation, the proposed methods could reduce 19% power consumption as well.

Decoupled estimation of frequency-dependent IQI and channel for OFDM systems with direct-conversion transceivers

The in-phase and quadrature-phase imbalance (IQI) is one of the major radio frequency impairments existing in orthogonal frequency division multiplexing (OFDM) systems with direct-conversion transceivers. During the transmission of the communication signal, the impact of IQI is coupled with channel impulse responses (CIR), which makes the traditional channel estimation schemes ineffective. A decoupled estimation scheme is proposed to separately estimate the frequency-dependent IQI and wireless channel. Firstly, the generalized channel model is built to separate the parameters of IQI and wireless channel. Then an iterative estimation scheme of frequency-dependent IQI is designed at the initial stage of communication. Finally, based on the estimation result of IQI, the least square algorithm is utilized to estimate the channel-related parameters at each time of channel variation. Compared with the joint estimation schemes of IQI and channel, the proposed decoupled estimation scheme requires much lower training overhead at each time of channel variation. Simulation results demonstrate the good estimation performance of the proposed scheme.

Decoupled Wiener state fuser for descriptor systems

By the modem time series analysis method, based on the autoregressive moving average （ARMA） innovation models and white noise estimation theory, using the optimal fusion rule weighted by diagonal matrices, a distributed descriptor Wiener state fuser is presented by weighting the local Wiener state estimators for the linear discrete stochastic descriptor systems with multisensor. It realizes a decoupled fusion estimation for state components. In order to compute the optimal weights, the formulas of computing the cross-covariances among local estimation errors are presented based on cross-covariances among the local innovation processes, input white noise, and measurement white noises. It can handle the fused filtering, smoothing, and prediction problems in a unified framework. Its accuracy is higher than that of each local estimator. A Monte Carlo simulation example shows its effectiveness and correctness.

Experimental study of partially decoupled oxidation of ethane for producing ethylene and acetylene

With increasing amount of unconventional natural gas,the production of ethane,propane and other low alkanes continues to increase.In our previous works,a partially decoupled process(PDP) was proposed for conversion of ethane based on numerical simulations,which showed higher acetylene and ethylene selectivities than the original partial oxidation process.In the current work,the PDP of ethane for producing acetylene and ethylene was studied experimentally to verify the PDP concept.In the PDP of ethane,coke-oven gas or other cheap gas combusts with stoichiometric oxygen as heat carrier,and ethane is mixed with the heat carrier and undergoes pyrolysis at high temperatures.The jet-in-cross-flow(JICF) reactor was designed and manufactured to realize the PDP.A positioning device of 0.1 mm accuracy and a mass spectrometer were used to measure the spatial profiles of the species concentrations.The maximum combined yield(52.7%) of acetylene and ethylene was obtained even at the condition of heat loss,confirming that the PDP of ethane was advantageous over the partial oxidation process and at least comparable to the steam cracking process.

A novel digital control strategy of three-phase shunt active power filter under non-ideal mains voltages

A novel control strategy for three-phase shunt active power filter (SAPF) was proposed to improve its performance under non-ideal mains voltages. The approach was inspired by our finding that the classic instantaneous reactive power theory based algorithm was unsatisfactory in terms of isolating positive sequence fundamental active components exactly under non-ideal mains voltages. So, a modified ip-iq reference current calculation method was presented. With usage of the new method, not only the positive sequence but also the fundamental active current components can be accurately isolated from load current. A deadbeat closed-loop control model is built in order to eliminate both delay error and tracking error between reference voltages and compensation voltages under unbalanced and distorted mains voltages. Computer simulation results show that the proposed strategy is effective with better tracking ability and lower total harmonic distortion (THD). The strategy is also applied to a 10 kV substation with a local electrolysis manganese plant injecting a large amount of harmonics into the power system, and is proved to be more practical and efficient.

Decoupled thermal–hydraulic analysis of an air-cooled separated heat pipe for spent fuel pools under natural convection

An investigation of the decoupled thermal–hydraulic analysis of a separated heat pipe spent fuel pool passive cooling system(SFS)is essential for practical engineering applications.Based on the principles of thermal and mass balance,this study decoupled the heat transfer processes in the SFS.In accordance with the decoupling conditions,we modeled the spent fuel pool of the CAP1400 pressurized water reactor in Weihai and used computational fluid dynamics to explore the heat dissipation capacity of the SFS under different air temperatures and wind speeds.The results show that the air-cooled separated heat pipe radiator achieved optimal performance at an air temperature of 10℃ or wind speed of 8 m/s.Fitted equations for the equivalent thermal conductivity of the separated heat pipes with the wind speed and air temperature we obtained according to the thermal resistance network model.This study is instructive for the actual operation of an SFS.

Development of the Decoupled Discreet-Time Jacobian Eigenvalue Approximation for Situational Awareness Utilizing Open PDC

With the increased number of PMUs in the power grid, effective high speed, realtime methods to ascertain relevant data for situational awareness are needed. Several techniques have used data from PMUs in conjunction with state estimation to assess system stability and event detection. However, these techniques require system topology and a large computational time. This paper presents a novel approach that uses real-time PMU data streams without the need of system connectivity or additional state estimation. The new development is based on the approximation of the eigenvalues related to the decoupled discreet-time power flow Jacobian matrix using direct openPDC data in real-time. Results are compared with other methods, such as Prony’s method, which can be too slow to handle big data. The newly developed Discreet-Time Jacobian Eigenvalue Approximation (DDJEA) method not only proves its accuracy, but also shows its effectiveness with minimal computational time: an essential element when considering situational awareness.

DESIGN OF DISTURBANCE DECOUPLED FILTER AND ITSAPPLICATION TO MANEUVERING TARGETS TRACKING

A novel disturbance decoupled filter (DDF) design scheme is presented. Firstly, the system with unknown input is translated into an equivalent system without unknown imputs by a simple algebraic transformation. Then, a new DDF design scheme, which is very simple, is proposed via innovations theorem. At last, the application of DDF to Maneuvering Targets Tracking is simulated and the simulation results show that DDF is suitable for high maneuvering cases.

Can environmental sustainability be decoupled from economic growth? Empirical evidence from Eastern Europe using the common correlated effect mean group test

The European Union(EU) and Organisation for Economic Co-operation and Development(OECD) aim to develop long-term policies for their respective member countries. Having observed increasing dangers to the environment posed by rising economic growth, they are seeking pathways to enable policy action on economic growth and environmental sustainability. Given the facts in theoretical and empirical studies, this study assessed the validity of the decoupling hypothesis by investigating asymmetricity in the relationship between environmental sustainability and economic growth in nine Eastern European countries from 1998 to 2017 using the cross-section augmented Dickey-Fuller(CADF) unit root, panel corrected standard error(PCSE), common correlated effect mean group(CCEMG), and Dumitrescu Hurlin causality approaches. Both population growth and drinking water are used as controlled variables. The outcomes establish strong cointegration among all the variables of interest. According to the results of CCEMG test, economic growth exerts short-term environmental degradation but has long-term environmental benefits in Eastern Europe;and population growth and drinking water exert a positive effect on environmental sustainability in both the short-and long-run. The results of Dumitrescu Hurlin causality test indicate that environmental sustainability is unidirectionally affected by economic growth. Based on these outcomes, we suggest the following policies:(1) the EU and OECD should implement member-targeted policies on economic growth and fossil-fuel use towards regulating industrial pollution, water use, and population control;and(2) the EU and OECD member countries should invest in environmental technologies through green research and development(R&D) to transform their dirty industrial processes and ensure productive energy use.