Herein,we report the victorious synthesis of metal-organic frameworks(MOFs) on TiO_2 nanotubes(NTs)using a layer-by-layer(LbL) approach.Highly crystalline and homogenous thin films of MOFs were grown and characterized...Herein,we report the victorious synthesis of metal-organic frameworks(MOFs) on TiO_2 nanotubes(NTs)using a layer-by-layer(LbL) approach.Highly crystalline and homogenous thin films of MOFs were grown and characterized using XRD,SEM,FT-IR and UV/Vis spectroscopy.Moreover,the utilization of the MOF films as sensitizers was probed in bespoke Graetzel type liquid junction solar cells.The constructed cell performance revealed an I_(sc) of 1.16 mA cm^(–2),Vocof 0.63 V,FF of 0.33,and E_(ff) of 0.42%.Further,pumpprobe transient laser spectroscopy was performed to investigate the energy and charge transfer dynamics of the MOFs/TiO_2 NTs interface.The results indicated 86% injection efficiency.The ultrafast pump-probe spectroscopy allows the investigation of this process and the differences between MOFs.It also showed that the relaxation of the MOF chromophores is in competition with electron injection in the Ti O2 motif.Thus this study provides a new insight into electron transfer from photoexcited metal-organic frameworks(MOFs) into titanium dioxide.展开更多
The maximum power conversion efficiencies of the top-emitting,oxide-confined,two-dimensional integrated 2×2 and4×4 vertical-cavity surface-emitting laser（VCSEL） arrays with the oxide-apertures of 6 μm,16 ...The maximum power conversion efficiencies of the top-emitting,oxide-confined,two-dimensional integrated 2×2 and4×4 vertical-cavity surface-emitting laser（VCSEL） arrays with the oxide-apertures of 6 μm,16 μm,19 μm,26 μm,29 μm,36 μm,39 μm,and 46 urn are fabricated and characterized,respectively.The maximum power conversion efficiencies increase rapidly with the augment of oxide-aperture at the beginning and then decrease slowly.A maximum value of27.91%at an oxide-aperture of 18.6 μm is achieved by simulation.The experimental data are well consistent with the simulation results,which are analyzed by utilizing an empirical model.展开更多
In this paper,we present our efforts on simulating and analyzing the effect of two-dimensional nano-sphere surface array on the characteristic of GaAs solar cells.Based on the scattering and diffraction theory of the ...In this paper,we present our efforts on simulating and analyzing the effect of two-dimensional nano-sphere surface array on the characteristic of GaAs solar cells.Based on the scattering and diffraction theory of the photonic crystals,the simulation results show that the distance of adjacent nano-spheres(D)has the pronounced influence on the conversion efficiency and exhibits much poor tolerance,the absolutely conversion efficiency is reduced by exceeding of 2%as the D varies from 0 to 1μm,in addition,the lower conversion efficiency(<18%)is exhibited and almost remains unaltered when the D is of>2μm.The radius(R)of nano-spheres demonstrates much great tolerance.For D=0,the solar cells exhibit high conversion efficiency(>20%)and the efficiency is only varied by less than 1%when R is varied in a very wide region of 0.3-1.2μm.One can also find out that there is good tolerance for efficiency around the optimal value of refractive index and there is only about 0.2%decrease in final cell efficiency for around±24%variation in the optimal values,which implys that it does not demand high precision processing equipment and the whole nano-sphere array could be fully complemented using self-assembled chemical methods.展开更多
为了减小低快拍数和低信噪比下采样协方差矩阵误差,并降低其运算复杂度,提出了一种基于实数化的均匀圆阵采样协方差矩阵重构方法。针对均匀圆阵的特点,通过组建特殊的基向量,构成特殊的重构矩阵。通过将采样协方差矩阵实数化,进一步降...为了减小低快拍数和低信噪比下采样协方差矩阵误差,并降低其运算复杂度,提出了一种基于实数化的均匀圆阵采样协方差矩阵重构方法。针对均匀圆阵的特点,通过组建特殊的基向量,构成特殊的重构矩阵。通过将采样协方差矩阵实数化,进一步降低了重构矩阵的复杂度。考虑到多通道不一致性对重构矩阵的影响,引入0位校正算法,提高了重构方法的稳健性。最后应用重构后的协方差矩阵进行子空间类波达方向估计(direction of arrival,DOA)。实验仿真证明,该特殊重构矩阵在实数化下与原矩阵重构能力相同;当快拍数为100、信噪比为0 dB时,双信源分辨力较重构前由74%提高到95%以上;理论重构运算复杂度降低到原来的53.99%。展开更多
The advancement of cost-effective and selective electrocatalyst towards CO_(2) to CO conversion is crucial for renewable energy conversion and storage,thus to achieve carbon-neutral cycle in a sustainable manner.In th...The advancement of cost-effective and selective electrocatalyst towards CO_(2) to CO conversion is crucial for renewable energy conversion and storage,thus to achieve carbon-neutral cycle in a sustainable manner.In this communication,we report that CujSb decorated Cu nanowire arrays on Cu foil act as a highly active and selective electrocatalyst for CO_(2) to CO conversion.In CO_(2)-saturated 0.1 M KHCO_(3),it achieves a high Faraday efficiency(FE)of 86.5%for CO,at-0.90 V vs.reversible hydrogen electrode(RHE).The H_(2)/CO ratio is tunable from 0.08:1 to 5.9:1 by adjusting the potential.It is worth noting that HCOO-product was totally suppressed on such catalyst,compared with Sb counterpart.The improving selectivity for CO could be attributed to the bimetallic effect and nanowire arrays structure.展开更多
A novel method for converting an array of out-of-phase lasers into one of in-phase lasers that can be tightly focused is presented.The method exploits second-harmonic generation and can be adapted for different laser ...A novel method for converting an array of out-of-phase lasers into one of in-phase lasers that can be tightly focused is presented.The method exploits second-harmonic generation and can be adapted for different laser arrays geometries.Experimental and calculated results,presented for negatively coupled lasers formed in a square,honeycomb,and triangular geometries are in good agreement.展开更多
We prepared highly-ordered titanium dioxide nanotube arrays (TNAs) by anodizing Ti foils in F-containing electrolytes.The crystalline nature and morphology of the TNAs were studied using X-ray diffraction patterns and...We prepared highly-ordered titanium dioxide nanotube arrays (TNAs) by anodizing Ti foils in F-containing electrolytes.The crystalline nature and morphology of the TNAs were studied using X-ray diffraction patterns and scanning electron microscopy.We found the morphology of TNAs affects the light-to-electricity conversion efficiency (η) of dye-sensitized solar cells (DSSCs).The efficiency of DSSCs reached 5.95% under the condition of light illuminated from the counter electrode.The high efficiency of TNA-based DSSCs was attributed to the neat top surface of TNAs,which allows more dye molecule loading on the surface of the TiO 2 nanotubes,and fewer electron recombination centers and a low interface resistance of integrated TNAs.展开更多
组合型振荡浮子式波浪发电装置由能量俘获系统与能量转换系统构成,其中能量转换系统直接决定整个装置的能量转换效率和发电功率。基于前期10 k W波浪发电装置的海试结果,对装置中的直驱型液压式能量转换系统进行结构优化,设计一种应用于...组合型振荡浮子式波浪发电装置由能量俘获系统与能量转换系统构成,其中能量转换系统直接决定整个装置的能量转换效率和发电功率。基于前期10 k W波浪发电装置的海试结果,对装置中的直驱型液压式能量转换系统进行结构优化,设计一种应用于100 k W波浪发电装置的蓄能型液压式能量转换系统,并研制"液压自调整控制系统",实现能量转换系统蓄能与放能过程的解耦控制。通过现场试验,验证优化后的能量转换系统在提高能量转换效率和维持过程平稳性上的有效性。基于该能量转换系统的能量输出特性,提出发电机带纯阻性负载时的"最大功率点跟踪"匹配负载计算方法,以及后续并网电力变换系统的拓扑结构设计,并通过Simulink仿真,验证方案的可靠性。展开更多
基金funded by the Science and Technology Development Fund in Egypt (STDF),project number 12323
文摘Herein,we report the victorious synthesis of metal-organic frameworks(MOFs) on TiO_2 nanotubes(NTs)using a layer-by-layer(LbL) approach.Highly crystalline and homogenous thin films of MOFs were grown and characterized using XRD,SEM,FT-IR and UV/Vis spectroscopy.Moreover,the utilization of the MOF films as sensitizers was probed in bespoke Graetzel type liquid junction solar cells.The constructed cell performance revealed an I_(sc) of 1.16 mA cm^(–2),Vocof 0.63 V,FF of 0.33,and E_(ff) of 0.42%.Further,pumpprobe transient laser spectroscopy was performed to investigate the energy and charge transfer dynamics of the MOFs/TiO_2 NTs interface.The results indicated 86% injection efficiency.The ultrafast pump-probe spectroscopy allows the investigation of this process and the differences between MOFs.It also showed that the relaxation of the MOF chromophores is in competition with electron injection in the Ti O2 motif.Thus this study provides a new insight into electron transfer from photoexcited metal-organic frameworks(MOFs) into titanium dioxide.
基金supported by the National Natural Science Foundation of China(Grant Nos.61222501 and 61335004)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20111103110019)
文摘The maximum power conversion efficiencies of the top-emitting,oxide-confined,two-dimensional integrated 2×2 and4×4 vertical-cavity surface-emitting laser（VCSEL） arrays with the oxide-apertures of 6 μm,16 μm,19 μm,26 μm,29 μm,36 μm,39 μm,and 46 urn are fabricated and characterized,respectively.The maximum power conversion efficiencies increase rapidly with the augment of oxide-aperture at the beginning and then decrease slowly.A maximum value of27.91%at an oxide-aperture of 18.6 μm is achieved by simulation.The experimental data are well consistent with the simulation results,which are analyzed by utilizing an empirical model.
基金National Nature Science Foundation of China(Grant No.61871350)Zhejiang Provincial Department of Education for their financial support of this research(Grant Nos.Y201121882 and Y201225406)
文摘In this paper,we present our efforts on simulating and analyzing the effect of two-dimensional nano-sphere surface array on the characteristic of GaAs solar cells.Based on the scattering and diffraction theory of the photonic crystals,the simulation results show that the distance of adjacent nano-spheres(D)has the pronounced influence on the conversion efficiency and exhibits much poor tolerance,the absolutely conversion efficiency is reduced by exceeding of 2%as the D varies from 0 to 1μm,in addition,the lower conversion efficiency(<18%)is exhibited and almost remains unaltered when the D is of>2μm.The radius(R)of nano-spheres demonstrates much great tolerance.For D=0,the solar cells exhibit high conversion efficiency(>20%)and the efficiency is only varied by less than 1%when R is varied in a very wide region of 0.3-1.2μm.One can also find out that there is good tolerance for efficiency around the optimal value of refractive index and there is only about 0.2%decrease in final cell efficiency for around±24%variation in the optimal values,which implys that it does not demand high precision processing equipment and the whole nano-sphere array could be fully complemented using self-assembled chemical methods.
文摘为了减小低快拍数和低信噪比下采样协方差矩阵误差,并降低其运算复杂度,提出了一种基于实数化的均匀圆阵采样协方差矩阵重构方法。针对均匀圆阵的特点,通过组建特殊的基向量,构成特殊的重构矩阵。通过将采样协方差矩阵实数化,进一步降低了重构矩阵的复杂度。考虑到多通道不一致性对重构矩阵的影响,引入0位校正算法,提高了重构方法的稳健性。最后应用重构后的协方差矩阵进行子空间类波达方向估计(direction of arrival,DOA)。实验仿真证明,该特殊重构矩阵在实数化下与原矩阵重构能力相同;当快拍数为100、信噪比为0 dB时,双信源分辨力较重构前由74%提高到95%以上;理论重构运算复杂度降低到原来的53.99%。
基金supported by the National Natural Science Foundation of China(No.22072015)the Foundation of Sichuan Department of Science and Technology(No.2017FZ0079).
文摘The advancement of cost-effective and selective electrocatalyst towards CO_(2) to CO conversion is crucial for renewable energy conversion and storage,thus to achieve carbon-neutral cycle in a sustainable manner.In this communication,we report that CujSb decorated Cu nanowire arrays on Cu foil act as a highly active and selective electrocatalyst for CO_(2) to CO conversion.In CO_(2)-saturated 0.1 M KHCO_(3),it achieves a high Faraday efficiency(FE)of 86.5%for CO,at-0.90 V vs.reversible hydrogen electrode(RHE).The H_(2)/CO ratio is tunable from 0.08:1 to 5.9:1 by adjusting the potential.It is worth noting that HCOO-product was totally suppressed on such catalyst,compared with Sb counterpart.The improving selectivity for CO could be attributed to the bimetallic effect and nanowire arrays structure.
基金supported in part by the Minerva FoundationIsrael Science Foundation (ISF) Bikura foundation
文摘A novel method for converting an array of out-of-phase lasers into one of in-phase lasers that can be tightly focused is presented.The method exploits second-harmonic generation and can be adapted for different laser arrays geometries.Experimental and calculated results,presented for negatively coupled lasers formed in a square,honeycomb,and triangular geometries are in good agreement.
基金supported by the National High Technology Research and Development Program of China (2007AA05Z439)the National Basic Research Program of China (2006CB202605)+1 种基金the National Natural Science Foundation of China (20973183)the Foundation of Chinese Academy of Sciences (KJCX2-YW-386-2)
文摘We prepared highly-ordered titanium dioxide nanotube arrays (TNAs) by anodizing Ti foils in F-containing electrolytes.The crystalline nature and morphology of the TNAs were studied using X-ray diffraction patterns and scanning electron microscopy.We found the morphology of TNAs affects the light-to-electricity conversion efficiency (η) of dye-sensitized solar cells (DSSCs).The efficiency of DSSCs reached 5.95% under the condition of light illuminated from the counter electrode.The high efficiency of TNA-based DSSCs was attributed to the neat top surface of TNAs,which allows more dye molecule loading on the surface of the TiO 2 nanotubes,and fewer electron recombination centers and a low interface resistance of integrated TNAs.
文摘组合型振荡浮子式波浪发电装置由能量俘获系统与能量转换系统构成,其中能量转换系统直接决定整个装置的能量转换效率和发电功率。基于前期10 k W波浪发电装置的海试结果,对装置中的直驱型液压式能量转换系统进行结构优化,设计一种应用于100 k W波浪发电装置的蓄能型液压式能量转换系统,并研制"液压自调整控制系统",实现能量转换系统蓄能与放能过程的解耦控制。通过现场试验,验证优化后的能量转换系统在提高能量转换效率和维持过程平稳性上的有效性。基于该能量转换系统的能量输出特性,提出发电机带纯阻性负载时的"最大功率点跟踪"匹配负载计算方法,以及后续并网电力变换系统的拓扑结构设计,并通过Simulink仿真,验证方案的可靠性。
