This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker...This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.展开更多
With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors an...With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors and the number of side defects have restricted the practical applications of small sized micro-LEDs.Recently,quantum dot(QD)and nonradiative energy transfer(NRET)have been proposed to solve existing problems.QDs possess nanoscale dimensions and high luminous efficiency,and they are suitable for NRET because they are able to nearly contact the micro-LED chip.The NRET between QDs and micro-LED chip further improves the color conversion efficiency(CCE)and effective quantum yield(EQY)of full-color micro-LED devices.In this review,we discuss the NRET mechanism for QD micro-LED devices,and then nano-pillar LED,nano-hole LED,and nano-ring LED are introduced in detail.These structures are beneficial to the NRET between QD and micro-LED,especially nano-ring LED.Finally,the challenges and future envisions have also been described.展开更多
Inverted perovskite solar cells(PSCs) have attracted broad research and industrial interest owing to their suppressed hysteresis,cost-effectiveness,and easy-fabrication.However,the issue of non-radiative recombination...Inverted perovskite solar cells(PSCs) have attracted broad research and industrial interest owing to their suppressed hysteresis,cost-effectiveness,and easy-fabrication.However,the issue of non-radiative recombination losses at the n-type interface between the perovskite and fullerene has impeded further improvement of photovoltaic performance.Here,we modify the n-type interface of FAPbI_(3) perovskite films by constructing a stereochemical two-dimensional(2D) perovskite interlayer,in which the organic cations comprise both pyridine and ammonium groups.The pyridine N donor can create stable bonding with the surface-uncoordinated Pb on the perovskite,thereby passivating the shallow-level defects and enhancing the air stability of the film.Furthermore,the pyridine N donor also offers a positive polar interface to decrease the surface work function of the perovskite film,enabling n-type modification.Ultimately,we employ a p-i-n photovoltaic(PV) device with the positive dipole interlayer at perovskite/fullerene contact and achieve remarkable photoelectric conversion efficiency(PCE) of 22.0%.展开更多
Colonoscopy is considered to be the most effective tool for reducing colorectal cancer(CRC) morbidity and mortality. As a result, certifying trainee competence in the performance of colonoscopy is critical to maximizi...Colonoscopy is considered to be the most effective tool for reducing colorectal cancer(CRC) morbidity and mortality. As a result, certifying trainee competence in the performance of colonoscopy is critical to maximizing CRC screening and prevention efforts. Guidelines on training and accreditation around the world have been revised to emphasize the attainment of milestones in the technical and cognitive skills necessary to perform the procedure. To meet this challenge, new evaluation systems have been developed to measure trainee competence through all aspects of colonoscopy training. These changes stem from increased recognition that procedural numbers alone do not necessarily guarantee trainees' proficiency in the performance of colonoscopy. Variability in endoscopic practice and in CRC screening outcomes also point to deficiencies in the current approach towards colonoscopy instruction. However, technological innovations hold great promise in training endoscopists to perform high quality colonoscopy. Furthermore, potential advances in the use of feedback as a training tool provide new avenues for research. This review summarizes the latest evidence on the effort to define, evaluate and promote the achievement of competence in colonoscopy among trainees.展开更多
This paper analyzes the current situation of industrial land supply,use and structure and industry pattern in Chizhou Economic and Technological Development Zone,and selects 83 typical enterprises which can reflect th...This paper analyzes the current situation of industrial land supply,use and structure and industry pattern in Chizhou Economic and Technological Development Zone,and selects 83 typical enterprises which can reflect the comprehensive industrial land utilization within this zone and the problems in economical and intensive utilization,to carry out the evaluation of economical and intensive utilization of industrial land. Based on the evaluation results,we find the problems in industrial land use and set forth corresponding recommendations in order to provide a reference for the future sustained land use in the development zone.展开更多
Analytical expressions are given for computing the magnetic potential and charac-teristic functions produced by the non-radial deflectors.These expressions are useful for designingthe defiectors such as those used in ...Analytical expressions are given for computing the magnetic potential and charac-teristic functions produced by the non-radial deflectors.These expressions are useful for designingthe defiectors such as those used in the color picture tubes and the electron beam lithographysystem.The computing results are in agreement with the measured values.展开更多
Radiation protection programs aims to reduce the radiation dose to the lowest possible level under the Dose Limit (DL) limit by the national or international laws, while the dose monitoring programs working as scale u...Radiation protection programs aims to reduce the radiation dose to the lowest possible level under the Dose Limit (DL) limit by the national or international laws, while the dose monitoring programs working as scale used to evaluating the efficiency of these programs and tools. In this study, the average of the annual Eff dose for the intensive care units at Hamad General Hospital (HGH) is less than the 50% of DL. It was aiming also to evaluate the efficiency of the radiation safety requirements (especially the shielding Adequacy) for the non radiation workers at oncology centers, hence several monitors were installed in chosen locations outside the radiation treatment machine from 2007 to 2011.展开更多
Interfacial imperfections between the perovskite layer and the electron transport layer(ETL)in perovskite solar cells(PSCs)can lead to performance loss and negatively influence long-term operational stability.Here,we ...Interfacial imperfections between the perovskite layer and the electron transport layer(ETL)in perovskite solar cells(PSCs)can lead to performance loss and negatively influence long-term operational stability.Here,we introduce an interface engineering method to modify the interface between perovskite and ETL by using multifunctional carbon dots(CDs).C=O in the CDs can chelate with the uncoordinated Pb2+in the perovskite material,inhibit interfacial recombination,and enhance the performance and stability of device.In addition,–OH in CDs forms hydrogen bonds with I-and organic cation in perovskite,inhibiting light-induced I2release and organic cation volatilization,causing irreversible degradation of perovskite films,thereby enhancing the long-term operational stability of PSCs.Consequently,we achieve the champion inverted device with an efficiency of 24.02%.The CDs-treated PSCs exhibit high operational stability,and the maximum power point tracking only attenuates by 12.5%after 1000 h.Interfacial modification engineering supported by multifunctional quantum dots can accelerate the road to stable PSCs.展开更多
We study sufficient conditions on radial and non-radial weight functions on the upper half-plane that guarantee norm approximation of functions in weighted Bergman,weighted Dirichlet,and weighted Besov spaces on the u...We study sufficient conditions on radial and non-radial weight functions on the upper half-plane that guarantee norm approximation of functions in weighted Bergman,weighted Dirichlet,and weighted Besov spaces on the upper half-plane by dilatations and eventually by analytic polynomials.展开更多
基金supported by the National Natural Science Foundation of China(U21A20331,81903743,22005322,22279151,and 22275004)National Science Fund for Distinguished Young Scholars(21925506).
文摘This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.
基金supports from the National Natural Science Foundation of China(11904302,61921005)Major Project of the Science and Technology in Fujian Province of China(2019HZ020013)Major Science and Technology Projects in Xiamen of China(3502Z20191015).
文摘With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors and the number of side defects have restricted the practical applications of small sized micro-LEDs.Recently,quantum dot(QD)and nonradiative energy transfer(NRET)have been proposed to solve existing problems.QDs possess nanoscale dimensions and high luminous efficiency,and they are suitable for NRET because they are able to nearly contact the micro-LED chip.The NRET between QDs and micro-LED chip further improves the color conversion efficiency(CCE)and effective quantum yield(EQY)of full-color micro-LED devices.In this review,we discuss the NRET mechanism for QD micro-LED devices,and then nano-pillar LED,nano-hole LED,and nano-ring LED are introduced in detail.These structures are beneficial to the NRET between QD and micro-LED,especially nano-ring LED.Finally,the challenges and future envisions have also been described.
基金financially supported by the National Ten Thousand Talent Program for Young Top-notch Talent,China,the National Natural Science Fund for Excellent Young Scholars,China(52022030)the National Natural Science Foundation of China,China(51972111,52203330)+7 种基金the Shanghai Pilot Program for Basic Research,China(22TQ1400100-5)the “Dawn”Program of Shanghai Education Commission,China(22SG28)the Shanghai Municipal Natural Science Foundation,China(22ZR1418000)the Science and Technology Innovation Plan of Shanghai Science and Technology Commission,China(22YF1410000)the Postdoctoral Research Foundation of China,China(2021M701190)the Fundamental Research Funds for the Central Universities,China(JKD01231632,JKVD1231041)the Major Science and Technology Projects of Inner Mongolia Autonomous Region,China(2021ZD0042)the Shanghai Engineering Research Center of Hierarchical Nanomaterials,China(18DZ2252400)。
文摘Inverted perovskite solar cells(PSCs) have attracted broad research and industrial interest owing to their suppressed hysteresis,cost-effectiveness,and easy-fabrication.However,the issue of non-radiative recombination losses at the n-type interface between the perovskite and fullerene has impeded further improvement of photovoltaic performance.Here,we modify the n-type interface of FAPbI_(3) perovskite films by constructing a stereochemical two-dimensional(2D) perovskite interlayer,in which the organic cations comprise both pyridine and ammonium groups.The pyridine N donor can create stable bonding with the surface-uncoordinated Pb on the perovskite,thereby passivating the shallow-level defects and enhancing the air stability of the film.Furthermore,the pyridine N donor also offers a positive polar interface to decrease the surface work function of the perovskite film,enabling n-type modification.Ultimately,we employ a p-i-n photovoltaic(PV) device with the positive dipole interlayer at perovskite/fullerene contact and achieve remarkable photoelectric conversion efficiency(PCE) of 22.0%.
文摘Colonoscopy is considered to be the most effective tool for reducing colorectal cancer(CRC) morbidity and mortality. As a result, certifying trainee competence in the performance of colonoscopy is critical to maximizing CRC screening and prevention efforts. Guidelines on training and accreditation around the world have been revised to emphasize the attainment of milestones in the technical and cognitive skills necessary to perform the procedure. To meet this challenge, new evaluation systems have been developed to measure trainee competence through all aspects of colonoscopy training. These changes stem from increased recognition that procedural numbers alone do not necessarily guarantee trainees' proficiency in the performance of colonoscopy. Variability in endoscopic practice and in CRC screening outcomes also point to deficiencies in the current approach towards colonoscopy instruction. However, technological innovations hold great promise in training endoscopists to perform high quality colonoscopy. Furthermore, potential advances in the use of feedback as a training tool provide new avenues for research. This review summarizes the latest evidence on the effort to define, evaluate and promote the achievement of competence in colonoscopy among trainees.
基金Supported by Special Research Fund for Nonprofit Industry,the Ministry of Land and Resources(201111010-03)
文摘This paper analyzes the current situation of industrial land supply,use and structure and industry pattern in Chizhou Economic and Technological Development Zone,and selects 83 typical enterprises which can reflect the comprehensive industrial land utilization within this zone and the problems in economical and intensive utilization,to carry out the evaluation of economical and intensive utilization of industrial land. Based on the evaluation results,we find the problems in industrial land use and set forth corresponding recommendations in order to provide a reference for the future sustained land use in the development zone.
文摘Analytical expressions are given for computing the magnetic potential and charac-teristic functions produced by the non-radial deflectors.These expressions are useful for designingthe defiectors such as those used in the color picture tubes and the electron beam lithographysystem.The computing results are in agreement with the measured values.
文摘Radiation protection programs aims to reduce the radiation dose to the lowest possible level under the Dose Limit (DL) limit by the national or international laws, while the dose monitoring programs working as scale used to evaluating the efficiency of these programs and tools. In this study, the average of the annual Eff dose for the intensive care units at Hamad General Hospital (HGH) is less than the 50% of DL. It was aiming also to evaluate the efficiency of the radiation safety requirements (especially the shielding Adequacy) for the non radiation workers at oncology centers, hence several monitors were installed in chosen locations outside the radiation treatment machine from 2007 to 2011.
基金supported by the National Natural Science Foundation of China(52172237,22261142666)the Shaanxi International Cooperation Project(2020KWZ-018)+3 种基金the Shaanxi Science Fund for Distinguished Young Scholars(2022JC-21)the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(2021-QZ-02)the Fundamental Research Funds for the Central Universities(D5000220033)the Hong Kong Scholars Program(XJ2022025)。
文摘Interfacial imperfections between the perovskite layer and the electron transport layer(ETL)in perovskite solar cells(PSCs)can lead to performance loss and negatively influence long-term operational stability.Here,we introduce an interface engineering method to modify the interface between perovskite and ETL by using multifunctional carbon dots(CDs).C=O in the CDs can chelate with the uncoordinated Pb2+in the perovskite material,inhibit interfacial recombination,and enhance the performance and stability of device.In addition,–OH in CDs forms hydrogen bonds with I-and organic cation in perovskite,inhibiting light-induced I2release and organic cation volatilization,causing irreversible degradation of perovskite films,thereby enhancing the long-term operational stability of PSCs.Consequently,we achieve the champion inverted device with an efficiency of 24.02%.The CDs-treated PSCs exhibit high operational stability,and the maximum power point tracking only attenuates by 12.5%after 1000 h.Interfacial modification engineering supported by multifunctional quantum dots can accelerate the road to stable PSCs.
文摘We study sufficient conditions on radial and non-radial weight functions on the upper half-plane that guarantee norm approximation of functions in weighted Bergman,weighted Dirichlet,and weighted Besov spaces on the upper half-plane by dilatations and eventually by analytic polynomials.
