THE STUDY OF THE NON-STEADY KINETICS OF THE OXYDEHYDROGENATION OF ETHANE TO ETHYLENE OVER THE CATALYST OF Mo-V-Nb/Al_2O_3 BY THE TECHNIQUE OF TEMPERATURE PROGRAMMED TRANSIENT RESPONSE AND ELECTRIC CONDUCTIVITY

In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer(FTIR) a new technique of Temperature Programmed Transient Response(TP-TR) has been used with gas chromatography. Therefore, the TP-TR will be applied more widespreadly than ever before. With the technique of TP-TR and electric conductivity, the study is on the reaction mechanism and the adsorption behavior of the reactants and products to the present catalyst Mo-V-Nb/Al_2O_3 in the reaction from ethane through oxydehydrogenation to ethylene as the product. By Range-Kutta-Gill and Margarat methods, the kinetic parameters of the reaction elementary steps (i.e. rate constants, active energies and frequency factors) have been evaluated. The mathematical treatment coincides with the experimental results.

A NEW METHOD FOR PREDICTION OF PRODUCTIVITY OF FRACTURED HORIZONTAL WELLS BASED ON NON-STEADY FLOW

Hydraulic fracturing technologies of horizontal well are important ways to develop oil-gas field with low permeability. Productivity forecast of fractured horizontal wells is a difficult problem of hydraulic fracturing technologies. Basing on non-steady flow of fractures fluid during production, applying potential function principles, superposition principle and mathematical method for solving, coupling of seepage flow in the formation and pipe flow in the well bore, a new model on multi-fracture interference productivity forecast of fractured horizofltal well is established in this article. The results indicate the coincidence rate between this model and practice is high. The pressure loss in the horizontal well bore has definite influence on the production status of fractured horizontal wells. The productions of different fractures in horizontal well bore are unequal, the productions of outer fractures are higher than middle fractures; the pressure in the well bore shows an uneven distribution, the pressure declines gradually from finger tip to heel end. Asymmetry of fractures may make productivity of fractured horizontal wells decline. The conclusions are instructive in designing fractured horizontal well for low permeability reservoir.

General kinetic model of imperfect living polymerization(Ⅳ)——Non-steady state analysis for reaction systems with two active species

The living ionic polymerization with two active species was theoretically studied, presenting the expressions of the number- and weight-average degrees of polymerization and the polydispersity index. The numerical calculation shows that both steady state and non-steady state approaches result in the essentially same outcomes when the exchange rate between the two active species is larger than the rates of chain propagation; however, the steady state method leads to a larger error and only the non-steady state approach is valid if the exchange rate between the two active species is comparable to or smaller than propagation rates. In addition, the molecular weight distribution of the resulting polymer becomes narrower with the value of k_p approaching to k_p~’ and with increasing M_o/l_o.

Numerical Simulation of Dieless Drawing Process with Non-steady Processing Parameters

Since processing parameters have always been assumed to be stable in the current finite element numerical simulation of dieless drawing process, the simulation results for the product dimension tend to stabilize gradually. In fact, the dimension fluctuation exists in the forming process all the while. A mathematical model of Gauss distribution for processing parameters was employed and a finite element numerical model of dieless drawing process with non-steady processing parameters was established. Dieless drawing processing of Ni-Ti alloy wire was conducted for verifying the proposed model. The results indicated that the non-steady processing parameters model had higher simulation accuracy of the wire diameter than that given by the steady parameters model. Furthermore, the model could also be used to analyze the fluctuation characteristics in the whole dieless drawing process.

ADAPTIVE RIGID-PLASTIC MESHLESS GALERKIN METHOD AND ITS APPLICATION IN ANALYSIS OF EXTRUSION PROCESSES

Under the hypothesis of the rigid-plastic material, specific efforts are placed on the developments of the key simulation techniques of the meshless Galerkin method because of the complexity of the deformation process as well as the generality and atomization of the simulation procedures for non-steady state large deformation plastic processes, therefore, an adaptive rigid meshless Galerkin method is developed. The influence domain control method is used in the least square approximation by dynamic evaluation of the magnitude of the influence domain and the effective control of the amount and the positions of the points in the least square approximation in order to improve approximation precision. The amount of the Gauss integration points in the discrete domain is maintained in a considerable magnitude in order to ensure the integration precision in the discrete domain. The length of the frictional boundary of the plastic deformation process may be getting longer when its deforma- tion is getting severe. Thus, the densities of the boundary points of some places get lower. The adaptive boundary points setting method is employed to improve the approximation precision of the boundary points and enhance the constraint of the boundary condition by adaptive control of boundary point density. Some typical extrusion processes are analyzed, detail simulation results such as the deformation field, velocity field, effective strain field, effective strain rate field, the volume loss curve and load-stroke curve are obtained. The effectiveness of the method developed is demonstrated and the precision of the meshless simulation is proved by overall comparison with the results obtained by using the commercial software deform.

Region Division and Stress Analysis for Plate Roller Leveling Process

The flatness of leveled plate is settled by residual stress. According to stress distribution simulated by FEM software ANSYS/LS-DYNA, the plate can be divided into non-steady region and steady region. The nonsteady region is composed of four zones, two of which are about half of leveling roller pitch at leading and end edges and other two are about 10% of the width at lateral edges. The steady region is the rest part enclosed by the non-steady regions. It is helpful to improve the leveling process by analyzing forming mechanism of each region and selecting suitable processes settings.