The combination of a 4-node quadrilateral mixed interpolation of tensorial components element(MITC4)and the cell-based smoothed finite element method(CSFEM)was formulated and implemented in this work for the analysis ...The combination of a 4-node quadrilateral mixed interpolation of tensorial components element(MITC4)and the cell-based smoothed finite element method(CSFEM)was formulated and implemented in this work for the analysis of free vibration and unidirectional buckling of shell structures.This formulation was applied to numerous numerical examples of non-woven fabrics.As CSFEM schemes do not require coordinate transformation,spurious modes and numerical instabilities are prevented using bilinear quadrilateral element subdivided into two,three and four smoothing cells.An improvement of the original CSFEM formulation was made regarding the calculation of outward unit normal vectors,which allowed to remove the integral operator in the strain smoothing operation.This procedure conducted both to the simplification of the developed formulation and the reduction of computational cost.A wide range of values for the thickness-to-length ratio and edge boundary conditions were analysed.The developed numerical model proved to overcome the shear locking phenomenon with success,revealing both reduced implementation effort and computational cost in comparison to the conventional FEM approach.The cell-based strain smoothing technique used in this work yields accurate results and generally attains higher convergence rate in energy at low computational cost.展开更多
Situated in the Shilong Industrial District of Mentougou, Beijing, the Beijing Dayuan Non-woven Fabric Co. Ltd is a Sino-foreign joint venture producing non-woven fabrics, set up in 1991.
Nano-silver and waterborne polyurethane(WPU)composite emulsion was synthesized.The average diameter of silver nanoparticles(SNPs)was about 20 nm,and the average diameter of WPU was 101.32 nm.The anti-bacteria finishin...Nano-silver and waterborne polyurethane(WPU)composite emulsion was synthesized.The average diameter of silver nanoparticles(SNPs)was about 20 nm,and the average diameter of WPU was 101.32 nm.The anti-bacteria finishing of a polypropylene non-woven fabric(NWF)was carried out by ultraviolet finishing technology and the double dipping twin-roll method.The standard AATCC100 was used to test the antimicrobial activity of the samples.The results showed that the antimicrobial rates of Klebsiella pneumoniae(K.pneumoniae)and Staphylococcus aureus(S.aureus)were above 90%,which indicated that the NWF finishing had good antimicrobial activity.In addition,the thermal stability,mechanical properties,whiteness and contact angle of antimicrobial finishing nonwovens were characterized.The results showed that the performance of antimicrobial nonwovens was stable at 300℃.The breaking strength was better than that of untreated nonwovens,and the contact angle reached 119.1°.展开更多
The relationship between light scattering intensity and basis weight of nonwoven fabrics is studied by using the theory of electromagnetic wave propagation and scatter-ing in random media.The theoretical analysis show...The relationship between light scattering intensity and basis weight of nonwoven fabrics is studied by using the theory of electromagnetic wave propagation and scatter-ing in random media.The theoretical analysis shows that the backscattering intensity of nonwoven fabric is closely related to its basis weight,and 2 series nonwoven samples manufactured by spun-bonded and thermal-bounded processing methods are tested for checking the theoretical expression.The study shows that the scattering intensity increases with increasing basis weight of nonwoven fabrics in exponential equation,and theoretical expression is consistent with the experimental data.展开更多
The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. The effects of parameters such as the concentration of TiO2 solution, pH valu...The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. The effects of parameters such as the concentration of TiO2 solution, pH value, and drying temperature on the photocatalytic degradation of the formaldehyde gas were also studied. The results showed that the photodegradation efficiency of the formaldehyde gas increased rapidly with the increasing of the concentration of TiO2 solution up to 15g/L, but when the concentration was in excess of 15 g/L, the photodegradation efficiency decreased gradually and fluctuated due to light obstruction and disperse state of TiO2. Adjusting the pH value in the solution, the efficiency of photocatalytic degradation of the formaldehyde gas could be improved. The mechanisms of the reaction and the role of the additives were also investigated. After 42hours, TiO2/polyester non-woven fabric showed no significant loss of the photocatalytic activity.展开更多
Carbon nanotube(CNT)fibers have great promise for constructing multifunctional fabrics with high electrical conductivity,good electro-heating ability,excellent flexibility,and a low density.However,the inter-fiber con...Carbon nanotube(CNT)fibers have great promise for constructing multifunctional fabrics with high electrical conductivity,good electro-heating ability,excellent flexibility,and a low density.However,the inter-fiber contacts in the fabric greatly reduce these advantages and limit their application.Herein,a simple pressure-fusing method to fabricate single-wall CNT(SWCNT)fiber non-woven fabrics(NWFs)that are composed of interconnected SWCNT fibers with fused joints is reported,which have good flexibility,a low density of 0.46 g/cm^(3),a high electrical conductivity of 3.7×10^(5)S/m,and a record high specific electrical conductivity of 803(S·m^(2))/kg.They also showed excellent electrical heating ability,so that a temperature of~160℃was rapidly reached at a low voltage of 2 V.Combined with their low density,the SWCNT fiber NWFs are promising for use as a heating unit for low temperature battery protection and de-icing applications.展开更多
With the exponential development in wearable electronics,a significant paradigm shift is observed from rigid electronics to flexible wearable devices.Polyaniline(PANI)is considered as a dominant material in this secto...With the exponential development in wearable electronics,a significant paradigm shift is observed from rigid electronics to flexible wearable devices.Polyaniline(PANI)is considered as a dominant material in this sector,as it is endowed with the optical properties of both metal and semiconductors.However,its widespread application got delineated because of its irregular rigid form,level of conductivity,and precise choice of solvents.Incorporating PANI in textile materials can generate promising functionality for wearable applications.This research work employed a straightforward in-situ chemical oxidative polymerization to synthesize PANI on Cotton fabric surfaces with varying dopant(HCl)concentrations.Pre-treatment using NaOH is implemented to improve the conductivity of the fabric surface by increasing the monomer absorption.This research explores the morphological and structural analysis employing SEM,FTIR and EDX.The surface resistivity was measured using a digital multimeter,and thermal stability is measured using TGA.Upon successful polymerization,a homogenous coating layer is observed.It is revealed that the simple pre-treatment technique significantly reduces the surface resistivity of Cotton fabric to 1.27 kΩ/cm with increasing acid concentration and thermal stability.The electro-thermal energy can also reach up to 38.2°C within 50 s with a deployed voltage of 15 V.The modified fabric is anticipated to be used in thermal regulation,supercapacitor,sensor,UV shielding,antimicrobial and other prospective functional applications.展开更多
In surface-enhanced Raman scattering(SERS),flexible substrate plays an important role in target molecular collection from various shape surfaces and increases the analytical sensitivity.In this study,silver nanopartic...In surface-enhanced Raman scattering(SERS),flexible substrate plays an important role in target molecular collection from various shape surfaces and increases the analytical sensitivity.In this study,silver nanoparticles(Ag NPs)were deposited on a non-woven fabric used as an SERS substrate by self-assembly,in situ growing or the self-assembly/in situ growing combination method.4-Aminothiophenol was selected as a model molecular for the evaluation of the SERS performance using the substrates.The Ag NPs substrate prepared by self-assembly/in situ growing method presented the best Raman enhancement effect and its enhancement factor was estimated as high as 3.59106.The substrate was applied to the determination of four pesticide residues on the surfaces of fruit samples through wipe sampling,and the results revealed the good reproducibility of SERS responses and high detection sensitivity.The prepared flexible substrate was simple to fabricate and environmentally friendly.It could be expected to be a useful tool in rapid on-site test of pesticide residues on fruit surfaces because of its high sensitivity,convenience and non-destructive characteristics.展开更多
As an alternative to short fibers,non-woven fabrics(NWFs)were made using different types of long fibers to optimize the performance of paper-based friction materials and their technology.In this investigation,the fill...As an alternative to short fibers,non-woven fabrics(NWFs)were made using different types of long fibers to optimize the performance of paper-based friction materials and their technology.In this investigation,the fillers and resin were impregnated into these NWFs to prepare three kinds of wet friction material.The tribological,mechanical,and thermal properties of the new wet friction material were studied.The results indicate that the dynamic friction coefficient of the new friction material is approximately 0.12 and the static friction coefficient is approximately 0.15;the better wear rate is 0.81334×10^(-14)m^(3)·(N·m)^(-1).In addition,the temperature for 10%mass loss yielded 100°C enhancement and the tensile strength was improved by 200%,compared to previously reported values.Most importantly,the advantages include a simple preparation flow,low cost,and resource conservation.This is a promising approach for the future development of paper-based friction materials.展开更多
Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatil...Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatile strategy to prepare a non-woven fabric photodetector.The blue non-woven fabric photodetector has been prepared by coating photo-thermochromic ink(including crystal violet lactone(CVL)as the thermo-sensitive dye,polypyrrole(PPy)nanospheres as the photothermal component and hydroxyethyl cellulose(HEC)as the polymer matrix)on white non-woven fabric.When the blue fabric photodetector is irradiated by NIR(808-nm as model,0.75 W cm^(−2))laser,the discoloration occurs in 35 s,and higher laser intensity confers more rapid discoloration.This discoloration results from the photothermal effect of PPy which confers the elevation of temperature(>50℃)and then converts CVL to its leuco form(colorless).When the laser is turned off,the temperature drops to below the transition temperature(<43℃),and then CVL reverts to its initial blue color.Moreover,different figures and images can be easily printed on the fabric photodetector by 808 nm laser,and then they can be erased automatically under ambient conditions,with excellent cycling stability.Therefore,this fabric photodetector may act as a new platform for rapid NIR light detection and writing.展开更多
The outbreak of coronavirus has led to an increase in the demand for facemasks globally. Unavailability of appropriate polypropylene non-woven fabrics face masks as a result of inadequate supply to satisfy the growing...The outbreak of coronavirus has led to an increase in the demand for facemasks globally. Unavailability of appropriate polypropylene non-woven fabrics face masks as a result of inadequate supply to satisfy the growing population has brought about the manufacturing of locally fabrics masks to augment or substitute standard medical class facemasks. The study aims at analyzing airflow of these locally manufactured fabrics to determine possible means of transmitting the virus as well as establish comfort of the user of these masks. Standard polypropylene non-woven, woven and knitted fabrics were considered for the study. Air permeability test was conducted on these fabrics using Frazier Air permeability tester. Depending on the property significant variation in the textile fabrics, polypropylene non-woven is widely accepted for facial masks. Nevertheless, this study illustrates that woven and knitted fabrics have more open structures, which allow a high rate of air penetration and so may require two or three layers to prevent antimicrobial or antiviral potential.展开更多
Poly(vinylidene fluoride-co-hexafluoropropyle- ne) (PVDF-HFP) is one of the most popular polymers for polymer electrolyte membranes because of its excellent oper- ating characteristics and superior electrochemical pro...Poly(vinylidene fluoride-co-hexafluoropropyle- ne) (PVDF-HFP) is one of the most popular polymers for polymer electrolyte membranes because of its excellent oper- ating characteristics and superior electrochemical properties. The electrochemical performances of polymer electrolyte membrane can be enhanced by evenly dispersing nano-meter SiO2 particles in the polymer. In this paper, non-woven fab- rics were immersed in the mixed solution of PVDF-HFP/ SiO2/butanone/butanol/plasticizer, and then dried in a vac- uum oven to remove the solvents and the plasticizer and to make porous composite polymer electrolyte membranes. The prepared composite membranes supported by non-woven fabrics boast good mechanical strength and excellent elec- trochemical properties: the electrochemical stability window is 4.8 V vs. Li+/Li, and the ionic conductivity is 3.35×10?4 S/cm (around 60% of that of a common PE membrane) at room temperature. The lithium-ion polymer battery assem- bled by the composite membrane exhibits high rate capabil- ity and excellent cycling performance.展开更多
Over the last decade,remarkable progress has been made in metal halide perovskite solar cells(PSCs),which have been a focus of emerging photovoltaic techniques and show great potential for commercialization.However,th...Over the last decade,remarkable progress has been made in metal halide perovskite solar cells(PSCs),which have been a focus of emerging photovoltaic techniques and show great potential for commercialization.However,the upscaling of small-area PSCs to large-area solar modules to meet the demands of practical applications remains a significant challenge.The scalable production of high-quality perovskite films by a simple,reproducible process is crucial for resolving this issue.Furthermore,the crystallization behavior in the solution-processed fabrication of perovskite films can be strongly influenced by the physicochemical properties of the precursor inks,which are significantly affected by the employed solvents and their interactions with the solutes.Thus,a comprehensive understanding of solvent engineering for fabricating perovskite films over large areas is urgently required.In this paper,we first analyze the role of solvents in the solution-processed fabrication of large-area perovskite films based on the classical crystal nucleation and growth mechanism.Recent efforts in solvent engineering to improve the quality of perovskite films for solar modules are discussed.Finally,the basic principles and future challenges of solvent system design for scalable fabrication of high-quality perovskite films for efficient solar modules are proposed.展开更多
基金supported by the Portuguese Foundation for Science and Technology(FCT)through project UID/CTM/00264/2019 of 2C2T—Centro de Ciência e Tecnologia Têxtil,hold by National Founds of FCT/MCTES,and project UID/EEA/04436/2013,COMPETE 2020 with the code POCI-01-0145-FEDER-006941.
文摘The combination of a 4-node quadrilateral mixed interpolation of tensorial components element(MITC4)and the cell-based smoothed finite element method(CSFEM)was formulated and implemented in this work for the analysis of free vibration and unidirectional buckling of shell structures.This formulation was applied to numerous numerical examples of non-woven fabrics.As CSFEM schemes do not require coordinate transformation,spurious modes and numerical instabilities are prevented using bilinear quadrilateral element subdivided into two,three and four smoothing cells.An improvement of the original CSFEM formulation was made regarding the calculation of outward unit normal vectors,which allowed to remove the integral operator in the strain smoothing operation.This procedure conducted both to the simplification of the developed formulation and the reduction of computational cost.A wide range of values for the thickness-to-length ratio and edge boundary conditions were analysed.The developed numerical model proved to overcome the shear locking phenomenon with success,revealing both reduced implementation effort and computational cost in comparison to the conventional FEM approach.The cell-based strain smoothing technique used in this work yields accurate results and generally attains higher convergence rate in energy at low computational cost.
文摘Situated in the Shilong Industrial District of Mentougou, Beijing, the Beijing Dayuan Non-woven Fabric Co. Ltd is a Sino-foreign joint venture producing non-woven fabrics, set up in 1991.
基金National Natural Science Foundation of China(Regional Fund)(No.51863020)
文摘Nano-silver and waterborne polyurethane(WPU)composite emulsion was synthesized.The average diameter of silver nanoparticles(SNPs)was about 20 nm,and the average diameter of WPU was 101.32 nm.The anti-bacteria finishing of a polypropylene non-woven fabric(NWF)was carried out by ultraviolet finishing technology and the double dipping twin-roll method.The standard AATCC100 was used to test the antimicrobial activity of the samples.The results showed that the antimicrobial rates of Klebsiella pneumoniae(K.pneumoniae)and Staphylococcus aureus(S.aureus)were above 90%,which indicated that the NWF finishing had good antimicrobial activity.In addition,the thermal stability,mechanical properties,whiteness and contact angle of antimicrobial finishing nonwovens were characterized.The results showed that the performance of antimicrobial nonwovens was stable at 300℃.The breaking strength was better than that of untreated nonwovens,and the contact angle reached 119.1°.
基金This project is aupported by key subject foundstion of Shanghai Educational Committee
文摘The relationship between light scattering intensity and basis weight of nonwoven fabrics is studied by using the theory of electromagnetic wave propagation and scatter-ing in random media.The theoretical analysis shows that the backscattering intensity of nonwoven fabric is closely related to its basis weight,and 2 series nonwoven samples manufactured by spun-bonded and thermal-bounded processing methods are tested for checking the theoretical expression.The study shows that the scattering intensity increases with increasing basis weight of nonwoven fabrics in exponential equation,and theoretical expression is consistent with the experimental data.
文摘The feasibility of photocatalytic degradation of the formaldehyde gas by titanium dioxide (TiO2)/polyester non-woven fabrics was studied. The effects of parameters such as the concentration of TiO2 solution, pH value, and drying temperature on the photocatalytic degradation of the formaldehyde gas were also studied. The results showed that the photodegradation efficiency of the formaldehyde gas increased rapidly with the increasing of the concentration of TiO2 solution up to 15g/L, but when the concentration was in excess of 15 g/L, the photodegradation efficiency decreased gradually and fluctuated due to light obstruction and disperse state of TiO2. Adjusting the pH value in the solution, the efficiency of photocatalytic degradation of the formaldehyde gas could be improved. The mechanisms of the reaction and the role of the additives were also investigated. After 42hours, TiO2/polyester non-woven fabric showed no significant loss of the photocatalytic activity.
基金the National Key R&D Program of China(No.2022YFA1203302)the National Natural Science Foundation of China(Nos.52130209,52188101,and 52072375)+1 种基金Liaoning Revitalization Talents Program(No.XLYC2002037)Basic Research Project of Natural Science Foundation of Shandong Province,China(No.ZR2019ZD49).
文摘Carbon nanotube(CNT)fibers have great promise for constructing multifunctional fabrics with high electrical conductivity,good electro-heating ability,excellent flexibility,and a low density.However,the inter-fiber contacts in the fabric greatly reduce these advantages and limit their application.Herein,a simple pressure-fusing method to fabricate single-wall CNT(SWCNT)fiber non-woven fabrics(NWFs)that are composed of interconnected SWCNT fibers with fused joints is reported,which have good flexibility,a low density of 0.46 g/cm^(3),a high electrical conductivity of 3.7×10^(5)S/m,and a record high specific electrical conductivity of 803(S·m^(2))/kg.They also showed excellent electrical heating ability,so that a temperature of~160℃was rapidly reached at a low voltage of 2 V.Combined with their low density,the SWCNT fiber NWFs are promising for use as a heating unit for low temperature battery protection and de-icing applications.
基金This work is supported by the International Publication Research Grant No.RDU223301 and Postgraduate Research Grant Scheme,UMP,Malaysia(PGRS210370).
文摘With the exponential development in wearable electronics,a significant paradigm shift is observed from rigid electronics to flexible wearable devices.Polyaniline(PANI)is considered as a dominant material in this sector,as it is endowed with the optical properties of both metal and semiconductors.However,its widespread application got delineated because of its irregular rigid form,level of conductivity,and precise choice of solvents.Incorporating PANI in textile materials can generate promising functionality for wearable applications.This research work employed a straightforward in-situ chemical oxidative polymerization to synthesize PANI on Cotton fabric surfaces with varying dopant(HCl)concentrations.Pre-treatment using NaOH is implemented to improve the conductivity of the fabric surface by increasing the monomer absorption.This research explores the morphological and structural analysis employing SEM,FTIR and EDX.The surface resistivity was measured using a digital multimeter,and thermal stability is measured using TGA.Upon successful polymerization,a homogenous coating layer is observed.It is revealed that the simple pre-treatment technique significantly reduces the surface resistivity of Cotton fabric to 1.27 kΩ/cm with increasing acid concentration and thermal stability.The electro-thermal energy can also reach up to 38.2°C within 50 s with a deployed voltage of 15 V.The modified fabric is anticipated to be used in thermal regulation,supercapacitor,sensor,UV shielding,antimicrobial and other prospective functional applications.
基金Natural Science Foundation of Fujian Province(No.2015J01058)and NFFTBS(No.J1310024)which are gratefully acknowledged.
文摘In surface-enhanced Raman scattering(SERS),flexible substrate plays an important role in target molecular collection from various shape surfaces and increases the analytical sensitivity.In this study,silver nanoparticles(Ag NPs)were deposited on a non-woven fabric used as an SERS substrate by self-assembly,in situ growing or the self-assembly/in situ growing combination method.4-Aminothiophenol was selected as a model molecular for the evaluation of the SERS performance using the substrates.The Ag NPs substrate prepared by self-assembly/in situ growing method presented the best Raman enhancement effect and its enhancement factor was estimated as high as 3.59106.The substrate was applied to the determination of four pesticide residues on the surfaces of fruit samples through wipe sampling,and the results revealed the good reproducibility of SERS responses and high detection sensitivity.The prepared flexible substrate was simple to fabricate and environmentally friendly.It could be expected to be a useful tool in rapid on-site test of pesticide residues on fruit surfaces because of its high sensitivity,convenience and non-destructive characteristics.
基金supported by the National Key R&D Program of China(Grant No.2017YFB0308303)Shaanxi Province Technology Innovation Guide Special Project(Grant No.2017CGZH-RGGJ-01)+1 种基金Shaanxi Provincial Key Research(Grant No.2018ZDCXL-GY09-05)the Analytical&Testing Center of Northwestern Polytechnical University,and the seed Foundation of Innovation and Creation for Graduate Students in Northwestern Polytechnical University(ZZ2019082)。
文摘As an alternative to short fibers,non-woven fabrics(NWFs)were made using different types of long fibers to optimize the performance of paper-based friction materials and their technology.In this investigation,the fillers and resin were impregnated into these NWFs to prepare three kinds of wet friction material.The tribological,mechanical,and thermal properties of the new wet friction material were studied.The results indicate that the dynamic friction coefficient of the new friction material is approximately 0.12 and the static friction coefficient is approximately 0.15;the better wear rate is 0.81334×10^(-14)m^(3)·(N·m)^(-1).In addition,the temperature for 10%mass loss yielded 100°C enhancement and the tensile strength was improved by 200%,compared to previously reported values.Most importantly,the advantages include a simple preparation flow,low cost,and resource conservation.This is a promising approach for the future development of paper-based friction materials.
基金This work was financially supported by the National Natural Science Foundation of China(51773036 and 51972056)Shanghai Shuguang Program(18SG29)+3 种基金Natural Science Foundation of Shanghai(18ZR1401700)Innovation Program of Shanghai Municipal Education Commission(2017-01-07-00-03-E00055)the Fundamental Research Funds for the Central UniversitiesDHU Distinguished Young Professor Program.
文摘Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatile strategy to prepare a non-woven fabric photodetector.The blue non-woven fabric photodetector has been prepared by coating photo-thermochromic ink(including crystal violet lactone(CVL)as the thermo-sensitive dye,polypyrrole(PPy)nanospheres as the photothermal component and hydroxyethyl cellulose(HEC)as the polymer matrix)on white non-woven fabric.When the blue fabric photodetector is irradiated by NIR(808-nm as model,0.75 W cm^(−2))laser,the discoloration occurs in 35 s,and higher laser intensity confers more rapid discoloration.This discoloration results from the photothermal effect of PPy which confers the elevation of temperature(>50℃)and then converts CVL to its leuco form(colorless).When the laser is turned off,the temperature drops to below the transition temperature(<43℃),and then CVL reverts to its initial blue color.Moreover,different figures and images can be easily printed on the fabric photodetector by 808 nm laser,and then they can be erased automatically under ambient conditions,with excellent cycling stability.Therefore,this fabric photodetector may act as a new platform for rapid NIR light detection and writing.
文摘The outbreak of coronavirus has led to an increase in the demand for facemasks globally. Unavailability of appropriate polypropylene non-woven fabrics face masks as a result of inadequate supply to satisfy the growing population has brought about the manufacturing of locally fabrics masks to augment or substitute standard medical class facemasks. The study aims at analyzing airflow of these locally manufactured fabrics to determine possible means of transmitting the virus as well as establish comfort of the user of these masks. Standard polypropylene non-woven, woven and knitted fabrics were considered for the study. Air permeability test was conducted on these fabrics using Frazier Air permeability tester. Depending on the property significant variation in the textile fabrics, polypropylene non-woven is widely accepted for facial masks. Nevertheless, this study illustrates that woven and knitted fabrics have more open structures, which allow a high rate of air penetration and so may require two or three layers to prevent antimicrobial or antiviral potential.
文摘Poly(vinylidene fluoride-co-hexafluoropropyle- ne) (PVDF-HFP) is one of the most popular polymers for polymer electrolyte membranes because of its excellent oper- ating characteristics and superior electrochemical properties. The electrochemical performances of polymer electrolyte membrane can be enhanced by evenly dispersing nano-meter SiO2 particles in the polymer. In this paper, non-woven fab- rics were immersed in the mixed solution of PVDF-HFP/ SiO2/butanone/butanol/plasticizer, and then dried in a vac- uum oven to remove the solvents and the plasticizer and to make porous composite polymer electrolyte membranes. The prepared composite membranes supported by non-woven fabrics boast good mechanical strength and excellent elec- trochemical properties: the electrochemical stability window is 4.8 V vs. Li+/Li, and the ionic conductivity is 3.35×10?4 S/cm (around 60% of that of a common PE membrane) at room temperature. The lithium-ion polymer battery assem- bled by the composite membrane exhibits high rate capabil- ity and excellent cycling performance.
基金financially supported by the National Key Research and Development Project funding from the Ministry of Science and Technology of China(2021YFB3800104)the National Natural Science Foundation of China(51822203,52002140,U20A20252,51861145404,62105293,62205187)+4 种基金the Young Elite Scientists Sponsorship Program by CAST,the Self-determined and Innovative Research Funds of HUST(2020KFYXJJS008)the Natural Science Foundation of Hubei Province(ZRJQ2022000408)the Shenzhen Science and Technology Innovation Committee(JCYJ20180507182257563)Fundamental Research Program of Shanxi Province(202103021223032)the Innovation Project of Optics Valley Laboratory of China(OVL2021BG008)。
文摘Over the last decade,remarkable progress has been made in metal halide perovskite solar cells(PSCs),which have been a focus of emerging photovoltaic techniques and show great potential for commercialization.However,the upscaling of small-area PSCs to large-area solar modules to meet the demands of practical applications remains a significant challenge.The scalable production of high-quality perovskite films by a simple,reproducible process is crucial for resolving this issue.Furthermore,the crystallization behavior in the solution-processed fabrication of perovskite films can be strongly influenced by the physicochemical properties of the precursor inks,which are significantly affected by the employed solvents and their interactions with the solutes.Thus,a comprehensive understanding of solvent engineering for fabricating perovskite films over large areas is urgently required.In this paper,we first analyze the role of solvents in the solution-processed fabrication of large-area perovskite films based on the classical crystal nucleation and growth mechanism.Recent efforts in solvent engineering to improve the quality of perovskite films for solar modules are discussed.Finally,the basic principles and future challenges of solvent system design for scalable fabrication of high-quality perovskite films for efficient solar modules are proposed.