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The(1+1)-dimensional nonlinear ion acoustic waves in multicomponent plasma containing kappa electrons
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作者 林麦麦 蒋蕾 王明月 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第12期416-421,共6页
Large amplitude (1+1)-dimensional nonlinear ion acoustic waves are theoretically studied in multicomponent plasma consisting of positively charged ions and negatively charged ions, ion beam, kappa-distributed electron... Large amplitude (1+1)-dimensional nonlinear ion acoustic waves are theoretically studied in multicomponent plasma consisting of positively charged ions and negatively charged ions, ion beam, kappa-distributed electrons, and dust grains,respectively. By using the Sagdeev potential method, the dynamical system and the Sagdeev potential function are obtained.The important influences of system parameters on the phase diagram of this system are investigated. It is found that the linear waves, the nonlinear waves and the solitary waves are coexistent in the multicomponent plasma system. Meanwhile,the variations of Sagdeev potential with parameter can also be obtained. Finally, it seems that the propagating characteristics of (1+1)-dimensional nonlinear ion acoustic solitary waves and ion acoustic nonlinear shock wave can be influenced by different parameters of this system. 展开更多
关键词 multicomponent plasma nonlinear ion acoustic waves Sagdeev potential method
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Multi-ion Mach–Zehnder interferometer with artificial nonlinear interactions
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作者 胡艳敏 杨万里 +2 位作者 肖兴 冯芒 李朝红 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第3期278-283,共6页
We propose a method to implement a Mach-Zehnder interferometry based upon a string of trapped ions with artificial nonlinear interactions. By manipulating the coupling strength between two involved internal states of ... We propose a method to implement a Mach-Zehnder interferometry based upon a string of trapped ions with artificial nonlinear interactions. By manipulating the coupling strength between two involved internal states of the ions, we could achieve the beam splitting/recombination with NOON states. Using current techniques for manipulating trapped ions, we discuss the experimental feasibility of our scheme and analyze some undesired uncertainty under realistic experimental environment. 展开更多
关键词 Mach-Zehnder interferometer trapped ions nonlinear interactions
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Differential nonlinear photocarrier radiometry for characterizing ultra-low energy boron implantation in silicon
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作者 Xiao-Ke Lei Bin-Cheng Li +3 位作者 Qi-Ming Sun Jing Wang Chun-Ming Gao Ya-Fei Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第3期575-580,共6页
The measuring of the depth profile and electrical activity of implantation impurity in the top nanometer range of silicon encounters various difficulties and limitations, though it is known to be critical in fabricati... The measuring of the depth profile and electrical activity of implantation impurity in the top nanometer range of silicon encounters various difficulties and limitations, though it is known to be critical in fabrication of silicon complementary metal–oxide–semiconductor(CMOS) devices. In the present work, SRIM program and photocarrier radiometry(PCR)are employed to monitor the boron implantation in industrial-grade silicon in an ultra-low implantation energy range from 0.5 keV to 5 keV. The differential PCR technique, which is improved by greatly shortening the measurement time through the simplification of reference sample, is used to investigate the effects of implantation energy on the frequency behavior of the PCR signal for ultra-shallow junction. The transport parameters and thickness of shallow junction, extracted via multi-parameter fitting the dependence of differential PCR signal on modulation frequency to the corresponding theoretical model, well explain the energy dependence of PCR signal and further quantitatively characterize the recovery degree of structure damage induced by ion implantation and the electrical activation degree of impurities. The monitoring of nmlevel thickness and electronic properties exhibits high sensitivity and apparent monotonicity over the industrially relevant implantation energy range. The depth profiles of implantation boron in silicon with the typical electrical damage threshold(YED) of 5.3×10^(15)cm^(-3) are evaluated by the SRIM program, and the determined thickness values are consistent well with those extracted by the differential PCR. It is demonstrated that the SRIM and the PCR are both effective tools to characterize ultra-low energy ion implantation in silicon. 展开更多
关键词 ultra-low energy ion implantation differential nonlinear photocarrier radiometry junction depth electronic transport parameters
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About Nonlinear Mechanism of Energy Transformation at Ion Implantation
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作者 S.G.Psakhie, K.P.Zolnikov, R.I.Kadyrov, G.E.Rudenskii, S.A.Vassiliev and Yu.P.Shatheev (Institute of Strength Physics and Materials Science, Russian Academy of Sciences, Siberian Branch, Tomsk, Russia) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1999年第6期581-582,共2页
The peculiarities of energy dissipation transferred by solitary waves on defects such as freesurface, grain boundary, region with high concentration of vacancies are studied. One of theways of description of the long ... The peculiarities of energy dissipation transferred by solitary waves on defects such as freesurface, grain boundary, region with high concentration of vacancies are studied. One of theways of description of the long range effect taking place at ion implantation in metallic materialsis suggested. 展开更多
关键词 About nonlinear Mechanism of Energy Transformation at ion Implantation
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Nonlinear parametric interactions in ion-implanted semiconductor plasmas having strain-dependent dielectric constants
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作者 N Yadav S Ghosh P S Malviya 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第1期304-309,共6页
We report nonlinear parametric interactions using a hydrodynamic model of ion-implanted semiconductor plasmas having strain-dependent dielectric constants(SDDC). High-dielectric-constant materials are technologicall... We report nonlinear parametric interactions using a hydrodynamic model of ion-implanted semiconductor plasmas having strain-dependent dielectric constants(SDDC). High-dielectric-constant materials are technologically important because of their nonlinear properties. We find that the third-order susceptibility varies in the range 10^-14--10^-12m^2·V^-2 for ion-implanted semiconductor plasmas, which is in good agreement with previous results. It is found that the presence of SDDC in ion-implanted semiconductor plasma modifies the characteristic properties of the material. 展开更多
关键词 nonlinear parametric interactions ion-implanted semiconductor plasmas strain-dependent dielectric constant
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含有非热电子和陷俘离子的复杂等离子体中非线性尘埃声波的传播特征
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作者 林麦麦 宋晨光 +1 位作者 王明月 陈富艳 《物理学报》 SCIE EI CAS CSCD 北大核心 2024年第7期252-261,共10页
本文研究了同时含有非热(nonthermal)电子和陷俘(trapped)离子分布的复杂等离子体系统中非线性尘埃声波的传播特征.首先,利用线性化方法推导得到非线性尘埃声波的色散关系.接着,借助Sagdeev势方法推导得到表征非线性尘埃声波运动的二维... 本文研究了同时含有非热(nonthermal)电子和陷俘(trapped)离子分布的复杂等离子体系统中非线性尘埃声波的传播特征.首先,利用线性化方法推导得到非线性尘埃声波的色散关系.接着,借助Sagdeev势方法推导得到表征非线性尘埃声波运动的二维自治系统、Sagdeev势方程和Sagdeev势函数的具体表达式.然后,依据数值模拟的方法分析了多种系统因素对二维自治系统相图的重要影响.结果表明:含有nonthermal电子和trapped离子的复杂等离子体系统中同时存在线性周期波、非线性周期波和孤立波.接下来,通过讨论Sagdeev势函数随系统参数的变化规律发现:该复杂等离子体系统中仅存在振幅大于零的压缩型孤立波.最后,探讨多种系统因素对非线性尘埃声孤波的振幅、宽度和波形等传播特征的重要影响.结果显示:马赫数、nonthermal电子和trapped离子以及尘埃颗粒未扰动的数密度、温度及荷电量等参数对该复杂等离子体系统中非线性尘埃声孤波的振幅、宽度和波形等传播特性均具有显著影响,且该结果与Sagdeev势函数的分析结果保持一致. 展开更多
关键词 非线性尘埃声孤波 Sagdeev势方法 非热电子分布 陷俘离子分布
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基于平均电压快速识别锂离子电池老化模式
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作者 刘秀兰 张倩 +3 位作者 王瑾瑜 陈熙 陈慧敏 关宇 《电源技术》 CAS 北大核心 2024年第2期263-268,共6页
锂离子电池在老化过程中表现为非线性衰退,这会危及新能源汽车或储能系统的安全。提出了一种基于实车使用或储能系统使用的原位快速识别老化模式的方法,该方法仅需要80%放电深度(DOD)区间的电压、电流数据。通过建立的老化模型模拟了27... 锂离子电池在老化过程中表现为非线性衰退,这会危及新能源汽车或储能系统的安全。提出了一种基于实车使用或储能系统使用的原位快速识别老化模式的方法,该方法仅需要80%放电深度(DOD)区间的电压、电流数据。通过建立的老化模型模拟了27种老化模式,该模型可通过扩展平均电压与容量衰退的轨迹快速识别非线性衰退的老化模式。证明了电池的非线性衰退与负极材料损失或锂离子损失增加有关,并且扩展平均电压的轨迹可判断正极材料损失是否加速衰退。采用正负极匹配的无损老化模式诊断验证了方法的准确性。 展开更多
关键词 锂离子电池 平均电压 非线性衰退 老化机理
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Modeling the dynamic behavior of a lithium-ion battery for electric vehicles using numerical optimization 被引量:2
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作者 胡晓松 孙逢春 邹渊 《Journal of Beijing Institute of Technology》 EI CAS 2011年第1期60-64,共5页
In order to simulate the dynamical behavior of a lithium ion traction battery used in elec tric vehicles, an equivalent circuit based battery model was established. The methodology in the guide document of the ADVISO... In order to simulate the dynamical behavior of a lithium ion traction battery used in elec tric vehicles, an equivalent circuit based battery model was established. The methodology in the guide document of the ADVISOR software was used to determine the initial parameters of the model as a function of state of charge ( SoC ) over an experimental data set of the battery. A numerically nonlinear least squares algorithm in SIMULINK design optimization toolbox was applied to further op timize the model parameters. Validation results showed that the battery model could well describe the dynamic behavior of the lithinm ion battery in two different battery loading situations. 展开更多
关键词 battery modeling nonlinear least squares algorithm lithium ion battery
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Ion stopping in dense plasmas: A basic physics approach 被引量:4
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作者 Claude Deutsch Gilles Maynard 《Matter and Radiation at Extremes》 SCIE EI CAS 2016年第6期277-307,共31页
We survey quite extensively the present research status of ion-stopping in dense plasmas of potential importance for initial confinement fusion(ICF)drivenby intense and heavy ion beams,and alsofor warm dense matter(WD... We survey quite extensively the present research status of ion-stopping in dense plasmas of potential importance for initial confinement fusion(ICF)drivenby intense and heavy ion beams,and alsofor warm dense matter(WDM).First,we putemphasis on every possible mechanism involved in the shaping of the ion projectile effective charge,while losing energy in a target plasma with classical ions and partially degenerate electrons.Then,we switch to ion stopping by target bound electrons,taking detailed account of mean excitation energies.Free electron stopping has already been given a lot of attention in former works[C.Deutsch et al.,Recent Res.Devel.Plasma 1(2000)1-23;Open Plasma Phys.J.3(2010)88-115].Then,we extend the usual standard stopping model(SSM)framework to nonlinear stopping including a treatment of the Z 3 Barkas effect and a confronting comparison of Bloch and Bohr Coulomb logarithms.Finally,we document low velocity ion slowing down(LVISD)in single ion plasmas as well as in binary ionic mixtures(BIM),in connection with specific ICF fuels. 展开更多
关键词 ion projectile effective charge Mean excited energies nonlinear stopping Binary ionic mixture
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Synthesis of Poly[(3-octanoylpyrrole-2,5-diyl)-p-(N,N-dimethylamino)benzylidene] and Its Properties by Nitrogen Ion Implantation 被引量:1
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作者 ZHANGZhi-gang WUHong-cai +1 位作者 LIUXiao-zeng YIWen-hui 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第2期166-168,共3页
A novel soluble π-conjugated polymer, poly[(3-octanoylpyrrole-2,5-diyl)-p-(N,N-dimethylamino)benzylidene](POPDMABE), was synthesized firstly by the condensation of 3-octanoylpyrrole with para-dimethylaminobenzaldehyd... A novel soluble π-conjugated polymer, poly[(3-octanoylpyrrole-2,5-diyl)-p-(N,N-dimethylamino)benzylidene](POPDMABE), was synthesized firstly by the condensation of 3-octanoylpyrrole with para-dimethylaminobenzaldehyde. The chemical structure of the polymer was characterized by FTIR and 1H NMR spectrometries. The polymer is a potential nonlinear optical(NLO) material. According to the function of optical forbidden band gap(E_g) and photon energy(hν), the optical forbidden band gaps of the polymer before and after ion implantation were calculated. The resonant third-order nonlinear optical properties of POPDMABE before and after ion implantation were also studied by using the degenerate four-wave mixing(DFWM) technique at 532 nm. When the energy is 25 keV and the dose is 2.2×10 17 ions/cm 2, the {polymer′s} optical forbidden band gap is about 1.63 eV which is smaller than that of the non-implanted sample(1.98 eV) and the resonant third-order NLO susceptibility of POPDMABE is about 4.3×10 -7 esu, 1 order of magnitude higher than that of the non-implanted sample(4.1×10 -8 esu). The results show that nitrogen ion implantation is an effective method to improve the resonant third-order NLO property of the polymer. 展开更多
关键词 Poly[(3-octanoylpyrrole-2 5-diyl)-p-(N N-dimethylamino)benzylidene] ion implantation Optical forbidden band gap Resonant third-order nonlinear optical property Degenerate four-wave mixing technique
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Influences of Temperature and Solvent Ions in Solution on States and Properties of Deoxyribonucleic Acid (DNA)
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作者 PANGXiao-Feng FENGYuan-Ying +2 位作者 ZHANGHuai-Wu A.F.Jalbout DONGRui-Xin 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第6期1141-1152,共12页
We here study the influences of the temperature and solvent ions in solution on the states and properties of DNA by a new dynamical model. This model admits three degrees of freedom per base-pair: two displacement var... We here study the influences of the temperature and solvent ions in solution on the states and properties of DNA by a new dynamical model. This model admits three degrees of freedom per base-pair: two displacement variables related to the vibrations of the hydrogen atom in the hydrogen bonds and base (nucleotide), respectively, and an angular variable related to the rotation of each base, which delineate different forms of motion of the hydrogen atom and bases and the relations among them. In this -model we stress specially the important role of the hydrogen atom in the hydrogen bonds of the bases in the dynamics of DNA. According to their properties of motion we give the Hamiltonian of the system and the corresponding equations of motion, and End out their soliton solutions. The solitons formed by the displacements of the hydrogen atoms and bases and their rotations are the excitation states arising from the energy absorbed by the DNA working at the biological temperature. We give further the free energy of the thermal excitation state in DNA system by transfer integral way and End out the corresponding specific heat. The specific heat increases with the increasing of the temperature and concentration of the solvent ions in the solution, but is not linear changes in the region of high temperature. If compared with experimental data, they are approximately consistent. Meanwhile we End that the solvent ion conceptration influences seriously on the stability, states, and configurations of DNA. 展开更多
关键词 dynamical property DNA nonlinearITY SOLITON solvent ion specific heat
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锂离子电池快速寿命评价技术与方法 被引量:2
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作者 晏莉琴 马尚德 +3 位作者 罗英 吕桃林 潘延林 解晶莹 《上海航天(中英文)》 CSCD 2023年第1期123-135,共13页
随着锂离子电池寿命特性的提升,以及电力储能、电动汽车和航空航天等应用领域对长期运行可靠性的需求,迫切需要在较短时间内完成锂离子电池的高精度全周期寿命评价。近年来,针对锂离子电池剩余寿命的研究较多,但对以锂离子电池寿命特性... 随着锂离子电池寿命特性的提升,以及电力储能、电动汽车和航空航天等应用领域对长期运行可靠性的需求,迫切需要在较短时间内完成锂离子电池的高精度全周期寿命评价。近年来,针对锂离子电池剩余寿命的研究较多,但对以锂离子电池寿命特性验证与鉴定为目的的快速寿命评价技术和方法缺乏系统梳理。本文分析了锂离子电池寿命评价的快速、高精度、强适用性等特点,归纳了锂离子电池寿命预测的通用技术和加速寿命试验设计流程,总结了4种可操作性强的快速寿命评价方法实例,为锂离子电池设计、制造和应用提供参考和借鉴。 展开更多
关键词 锂离子电池 快速寿命评价 加速寿命试验 非线性衰退 早期寿命预测
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Nonlinear Optieal Properties of Ag Nanopartieles/Glass Composites Measured on a Femtosecond Time Scale
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作者 杨修春 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第B12期850-852,共3页
Ag nanoparticles embedded in soda-lime silicate glass were fabricated by ion-exchange and subsequently annealing method. Effects of annealing duration on the optical nonlinearity and ultrafast dynamics of Ag nanoparti... Ag nanoparticles embedded in soda-lime silicate glass were fabricated by ion-exchange and subsequently annealing method. Effects of annealing duration on the optical nonlinearity and ultrafast dynamics of Ag nanoparticles in glass were investigated by z-scan technique and pump-probe technique. The results indicate that the third-order optical nonlinearity increases with extending the annealing time, the fast decay process with lifetime of a few picoseconds is attributed to thermal equilibrium process of hot electrons and the energy transfer to lattices by interaction with phonons in the formed Ag nanoparticles, while the slow decay in more than one hundred picoseconds corresponds to the subsequent cooling process by a thermal diffusion from the Ag nanoparticle to the host matrix via the phonon-medium interaction. The fast decay process is accelerated with extending the annealing time. 展开更多
关键词 ion-exchange Ag nanoparticles/glass composites third-order optical nonlinearity
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暴时等离子体层顶密度不规则结构对SAR弧的调制
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作者 向溢民 袁志刚 +2 位作者 薛祖祥 余雄东 黄政 《地球物理学报》 SCIE EI CAS CSCD 北大核心 2023年第11期4413-4428,共16页
SAR弧的磁层源区对应环电流与等离子体层顶重叠区域,而等离子体层顶常常观测到密度不规则结构.之前还没有暴时等离子体层顶密度不规则结构对SAR弧调制的观测报道.本文报道了地基成像和磁层、电离层卫星对2013年10月9日磁暴恢复相期间发... SAR弧的磁层源区对应环电流与等离子体层顶重叠区域,而等离子体层顶常常观测到密度不规则结构.之前还没有暴时等离子体层顶密度不规则结构对SAR弧调制的观测报道.本文报道了地基成像和磁层、电离层卫星对2013年10月9日磁暴恢复相期间发生的SAR弧的联合观测事件.在SAR弧的磁层源区,Van Allen Probe B卫星观测到了密度不规则结构,其中存在EMIC波、环电流离子分布和非线性电场结构.联合观测表明:该区域中的环电流离子分布通过库伦碰撞产生的热流通量足以驱动SAR弧,热流通量受到密度不规则结构的调制,形成空间上的小尺度分布,环电流离子中几keV的质子和几十keV的氧离子对这个过程起主导作用;此外,位于等离子体层顶密度不规则结构的低密度区的非线性结构电场引起的低能电子沉降可能是造成这次SAR弧非常明亮的原因. 展开更多
关键词 SAR弧 密度不规则结构 库伦碰撞 非线性电场结构 等离子体层电子 环电流离子
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软包装锂离子电池表面划痕的检测方法
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作者 谷峰 王正家 +1 位作者 昝傲 权佳怡 《电池》 CAS 北大核心 2023年第5期514-518,共5页
表面缺陷是判断软包装锂离子电池质量的重要指标之一。针对软包装锂离子电池表面凹凸不平且存在反光,导致划痕自动化检测检出率低的问题,提出一种表面划痕检测方法。采用电荷耦合元件(CCD)相机及远心镜头,从3个方向拍照,通过光度立体法... 表面缺陷是判断软包装锂离子电池质量的重要指标之一。针对软包装锂离子电池表面凹凸不平且存在反光,导致划痕自动化检测检出率低的问题,提出一种表面划痕检测方法。采用电荷耦合元件(CCD)相机及远心镜头,从3个方向拍照,通过光度立体法融合图像,生成电池表面反照率图像;通过二阶高斯卷积进行图像平滑,并提取划痕边缘特征信息;采用非线性灰度变换增强划痕细节;通过阈值分割对划痕进行提取。划痕的检测准确率为97.5%,满足检测精度需求。 展开更多
关键词 划痕检测 反照率图像 非线性灰度变换 软包装锂离子电池 表面划痕 光度立体法 高斯卷积
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径向电场对离子温度梯度模稳定性的影响
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作者 陈凝飞 魏广宇 仇志勇 《物理学报》 SCIE EI CAS CSCD 北大核心 2023年第21期167-176,共10页
为了理解托卡马克装置中给定径向电场对离子温度梯度模(ITG)稳定性的影响,基于非线性回旋动理学理论和气球模表象推导了环位形下包含径向电场引起的极向流和密度扰动影响的ITG的本征模方程,并分别在长/短波长极限下研究了高能量粒子诱... 为了理解托卡马克装置中给定径向电场对离子温度梯度模(ITG)稳定性的影响,基于非线性回旋动理学理论和气球模表象推导了环位形下包含径向电场引起的极向流和密度扰动影响的ITG的本征模方程,并分别在长/短波长极限下研究了高能量粒子诱发测地声模(EGAM)所伴随的径向电场对ITG的本征频率、增长率和平行模结构的影响.不仅对该本征模方程进行了理论研究,还使用本征矩阵法对其进行数值求解,以便对理论结果进行验证.研究发现EGAM伴随的电场引起的极向转动会大幅降低ITG的增长率,而极向模数m=1的密度扰动对ITG的线性稳定性影响很小.这一结果与一般认为的带状流通过极向流剪切抑制湍流的结果是一致的.除此之外,使用本文发展的一般性方法也可以研究高能量粒子激发的阿尔芬不稳定性与漂移波湍流通过阿尔芬不稳定性激发带状结构发生的间接非线性相互作用,即带状结构所伴随的径向电场通过极向转动和密度扰动影响ITG的稳定性.该间接非线性通道可以作为对主导背景等离子体输运的微观湍流和主导高能量粒子输运的阿尔芬不稳定性之间的直接相互作用通道的补充. 展开更多
关键词 离子温度梯度模 径向电场 高能量粒子诱发测地声模 非线性回旋动理学理论
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基于反馈线性化的EMS型磁浮列车非线性悬浮控制器设计 被引量:24
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作者 刘德生 李杰 张锟 《国防科技大学学报》 EI CAS CSCD 北大核心 2005年第2期96-101,共6页
悬浮系统控制技术是EMS型磁浮列车的关键技术之一。针对悬浮系统的非线性特征,设计了一种非线性悬浮控制器。在合理假设的基础上,建立了EMS型磁浮列车悬浮系统的非线性数学模型;通过反馈线性化将该非线性模型精确线性化,得到等价的线性... 悬浮系统控制技术是EMS型磁浮列车的关键技术之一。针对悬浮系统的非线性特征,设计了一种非线性悬浮控制器。在合理假设的基础上,建立了EMS型磁浮列车悬浮系统的非线性数学模型;通过反馈线性化将该非线性模型精确线性化,得到等价的线性模型,采用状态反馈的方法设计了非线性控制器。仿真结果表明,该非线性控制器的控制性能明显优于传统的局部近似线性化方法设计的控制器,对间隙干扰和负载干扰具有鲁棒性。 展开更多
关键词 非线性 悬浮控制器 反馈线性化 仿真
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金属酞菁配合物的合成及其三阶非线性光学性能研究 被引量:16
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作者 夏雪伟 徐庆锋 +4 位作者 路建美 姚社春 王丽华 陈飞 朱秀林 《高校化学工程学报》 EI CAS CSCD 北大核心 2007年第1期131-135,共5页
合成了酞菁铝(AlClPc)、酞菁亚铁(II)(FePc)、酞菁钴(II)(CoPc)、酞菁镍(II)(NiPc)以及酞菁铜(II)(CuPc)等金属酞菁配合物。使用四波混频技术测量了它们在硫酸溶液中的三阶非线性光学系数χ(3)值,发现四种过渡金属酞菁配合物的χ(3)值... 合成了酞菁铝(AlClPc)、酞菁亚铁(II)(FePc)、酞菁钴(II)(CoPc)、酞菁镍(II)(NiPc)以及酞菁铜(II)(CuPc)等金属酞菁配合物。使用四波混频技术测量了它们在硫酸溶液中的三阶非线性光学系数χ(3)值,发现四种过渡金属酞菁配合物的χ(3)值随着金属的原子系数的增加而上升。而酞菁铝的χ(3)值则大于酞菁亚铁(II)和酞菁钴(II)的χ(3)值、小于酞菁镍(II)和酞菁铜(II)的χ(3)值。文中初步讨论了金属离子的d电子以及与酞菁构成的空间结构对紫外吸收和三阶非线性光学性质的影响机理。 展开更多
关键词 金属离子 酞菁 三阶非线性光学性质 四波混频
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从铜离子的作用研究Orbán振荡体系中的动力学特征 被引量:2
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作者 高庆宇 孙康 +2 位作者 李兰萍 蔡遵生 赵学庄 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第6期1025-1027,共3页
In the H 2O 2 KSCN CuSO 4 NaOH reaction system, cupric ion plays an essential role for batch and CSTR oscillation . Since Cu 2+(or Cu+) can be precipitated as CuOH, CuSCN and Cu(OH) 2 , its concentration has a complex... In the H 2O 2 KSCN CuSO 4 NaOH reaction system, cupric ion plays an essential role for batch and CSTR oscillation . Since Cu 2+(or Cu+) can be precipitated as CuOH, CuSCN and Cu(OH) 2 , its concentration has a complex influence on the amplitude and initial high flowrate of oscillation. The pH drop resulted from the oxidation of KSCN by hydrogen peroxide inhibited the oscillation. The kinetic nature of oscillation should be the H 2O 2 decomposition catalyzed by cupric and thiocyanate. 展开更多
关键词 铜离子 非线性反应 Orban振荡体系 动力学 振荡 反应机理 PH值
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锂离子电池荷电状态估计:非线性观测器方法 被引量:11
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作者 张云 张承慧 崔纳新 《控制理论与应用》 EI CAS CSCD 北大核心 2012年第12期1639-1644,共6页
电池荷电状态(state of charge,SOC)的准确估计是电动汽车有效实施能量管理的基本前提和安全高效运行的重要保障.为降低电池系统因迟滞效应和非线性因素对SOC估计产生的不利影响,本文基于Lipschitz非线性系统观测器设计理论,提出了一类... 电池荷电状态(state of charge,SOC)的准确估计是电动汽车有效实施能量管理的基本前提和安全高效运行的重要保障.为降低电池系统因迟滞效应和非线性因素对SOC估计产生的不利影响,本文基于Lipschitz非线性系统观测器设计理论,提出了一类电池SOC估计新方法.基于该新方法设计的观测器具有结构简单,估计性能好等优点.首先根据电池等价电路模型给出电池系统的数学描述,进而利用脉冲放电实验数据计算出电池系统各参数值,然后利用线性矩阵不等式方法求解出观测器增益矩阵,最后利用城市道路循环(urban dynamometer driving schedule,UDDS)工况测试验证了观测器系统具有良好的跟踪性能. 展开更多
关键词 锂离子电池 状态估计 非线性观测器 电池模型
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