A novel tolane 4-methoxy-4'-nitro-diphenyl-acetylene (MONA) has been prepared quantitatively by reacting cuprous p-methoxy phenyl-acetylene with p-iodonitrobenzene. A single crystal of the Moan was grown by soluti...A novel tolane 4-methoxy-4'-nitro-diphenyl-acetylene (MONA) has been prepared quantitatively by reacting cuprous p-methoxy phenyl-acetylene with p-iodonitrobenzene. A single crystal of the Moan was grown by solution growth method. The crystal was then characterized by X-ray diffraction structure analysis and second-harmonic generation(SHG)investigation. Polymorphous crystal forms of the MONA were grown from different solvents having different nonlinear optical properties depending on their different crystal structures. The relationship between the crystal growth and crystal structure is discusse.展开更多
zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is character...zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.展开更多
A new semi-organic nonlinear optical thiosemicarbazide cadmium acetate (TSCA) material has been synthesized. TSCA single crystals were grown from aqueous solution by slow evaporation method. The solubility of TSCA has...A new semi-organic nonlinear optical thiosemicarbazide cadmium acetate (TSCA) material has been synthesized. TSCA single crystals were grown from aqueous solution by slow evaporation method. The solubility of TSCA has been determined for various temperatures. The grown crystals were characterized by single crystal X-ray diffraction (XRD), FTIR, UV-Vis., thermal and second harmonic generation (SHG) analysis. Single crystal XRD study has been carried out to identify the lattice parameters. FTIR studies confirm the functional groups present in the grown crystal. Optical transmission studies have confirmed that the grown crystal is highly transparent. Thermogravimetric and differential thermal analyses reveal the good thermal stability of the material. The SHG conversion efficiency of TSCA was determined using Kurtz powder technique and found two times that of potassium dihydrogen orthophosphate (KDP).展开更多
Organic nonlinear optical material of 4-bromo-4’-methyl benzylidene aniline (BMBA) was synthesized and single crystal of BMBA was grown by solvent evaporation method at room temperature using ethanol as solvent. The ...Organic nonlinear optical material of 4-bromo-4’-methyl benzylidene aniline (BMBA) was synthesized and single crystal of BMBA was grown by solvent evaporation method at room temperature using ethanol as solvent. The crystalline nature of the grown crystals was confirmed using powder X-ray diffraction studies. The crystals were also characterized by single crystal X-ray diffraction method and their lattice parameters were determined. Thermal properties of BMBA were evaluated with thermogravimetric, differential thermal and differential scanning calorimetric analyses. Fourier transform infrared and FT-Raman spectral studies were carried out on the BMBA material to confirm the synthesized compound. 1H and 13C-nuclear magnetic resonance spectral studies were recorded to elucidate the structure of the grown crystals. Fluorescence spectrum recorded shows a peak at 485 nm. UV-Vis-NIR spectral analysis shows transmittance of ~92% in the visible region. The mechanical stability was analyzed by Vickers microhardness tester and the work hardening coefficient of the grown crystal was calculated. Second harmonic generation efficiency of the grown crystal measured by Kurtz powder technique is ~1.8 times that of potassium dihydrogen orthophosphate.展开更多
A triphenylamine-containing Schiff base ligand(L), namely, N-(4-(1 H-imidazol-1-yl)benzylidene)-N,N-diphenylbenzene-1,4-diamine, was synthesized and characterized. By coordination of the ligand with CdI2, a complex Cd...A triphenylamine-containing Schiff base ligand(L), namely, N-(4-(1 H-imidazol-1-yl)benzylidene)-N,N-diphenylbenzene-1,4-diamine, was synthesized and characterized. By coordination of the ligand with CdI2, a complex CdI2 L2 was obtained. The structure of the complex was analyzed through single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/c with a = 25.277(5), b = 11.176(5), c = 17.912(5) ?, β = 106.056(5)°, V = 4863(3) ?3, Z = 4, Dc =1.633 Mg/m3, F(000) = 2360, Μr = 1195.19, μ = 1.766 mm-1, the final R = 0.0323 and wR = 0.0758 for 33414 observed reflections with I > 2?(I). The linear absorption spectra of the complex were experimentally and theoretically studied. And the third-order nonlinear optical(NLO) property of the complex was also measured through Z-scan technique.展开更多
Large crystal NPP-OTs has been obtained by growth from solution,its powder SHG efficiency is 1/3 of urea.It shows it is a new convenient approach to obtain organic second-order NLO crystal:the dipole-dipole interactio...Large crystal NPP-OTs has been obtained by growth from solution,its powder SHG efficiency is 1/3 of urea.It shows it is a new convenient approach to obtain organic second-order NLO crystal:the dipole-dipole interaction is oppos- ed by introducing a large side group.展开更多
The structure of ZnL2Cl2 (L=4-methoxybenzaldehyde thiosemicarbazone) has beenobtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cellof dimensions, a=9.08909(10), b=22. l420(...The structure of ZnL2Cl2 (L=4-methoxybenzaldehyde thiosemicarbazone) has beenobtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cellof dimensions, a=9.08909(10), b=22. l420(10), c=11 .7890(l0)A,β=90.050(10)°, v=2374.6(12)A3,Dc=1 .552gcm-3. H=1 .463mm-1. R=0.0338. and Rw=0.0418. The structure contains individualZnL2Cl2 distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metalions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex arealso presented in this letter.展开更多
Dependence of the periodically poled nonlinear-optical lithium niobate (PPLN) crystal temperature on laser power in the course of laser frequency conversion was measured using piezoelectric resonance. Crystal’s tempe...Dependence of the periodically poled nonlinear-optical lithium niobate (PPLN) crystal temperature on laser power in the course of laser frequency conversion was measured using piezoelectric resonance. Crystal’s temperature tuning curves are precisely measured using concept of the equivalent temperature. Both optical absorption and heat transfer coefficients of the crystal are measured employing kinetics of the crystal equivalent temperature.展开更多
The crystal structUre of the title ligand and its copper (Ⅱ) complex was determined bysingle crystal X-ray diffraction. The electrochendcal properties and the third-order nonlinearoptical response of the ligand and i...The crystal structUre of the title ligand and its copper (Ⅱ) complex was determined bysingle crystal X-ray diffraction. The electrochendcal properties and the third-order nonlinearoptical response of the ligand and its copper (Ⅱ) complex were also studied.展开更多
The geometric structure,electronic structure,and optical properties of CdHg(SCN)4 crystal are calculated by using the density functional perturbation theory and Green function screening Coulomb interaction approxima...The geometric structure,electronic structure,and optical properties of CdHg(SCN)4 crystal are calculated by using the density functional perturbation theory and Green function screening Coulomb interaction approximation.The band gap of CdHg(SCN)4 crystal is calculated to be 3.198 eV,which is in good agreement with the experimental value 3.265 eV.The calculated second-order nonlinear optical coefficients are d14 = 1.2906 pm/V and d15 = 5.0928 pm/V,which are in agreement with the experimental results(d14=(1.4 ±0.6) pm/V and d15=(6.0 ±0.9) pm/V).Moreover,it is found that the contribution to the valence band mainly comes from Cd-4d,Hg-5d states,and the contributions to the valence band top and the conduction band bottom predominantly come from C-2p,N-2p,and S-3p states.The second-order nonlinear optical effect of CdHg(SCN)_4 crystal results mainly from the internal electronic transition of(SCN)^-.展开更多
In the current investigation,L-proline cadmium chloride monohydrate(LPCC) single crystal is grown by a slow solvent evaporation technique to identify its credibility for nonlinear optical device applications.The con...In the current investigation,L-proline cadmium chloride monohydrate(LPCC) single crystal is grown by a slow solvent evaporation technique to identify its credibility for nonlinear optical device applications.The constituent elements of LPCC crystal are determined by the energy dispersive spectroscopic(EDS) technique.The single crystal x-ray diffraction technique is used to determine the structural dimensions of LPCC crystal.The UV-visible studies are carried out within a wavelength range of 200 nm–1100 nm to determine the optical transmittance of LPCC crystal.The linear optical parameters of LPCC crystal are evaluated using the transmittance data to discuss its importance for distinct optical devices.The Nd:YAG laser assisted Kurtz–Perry test is carried out to determine the enhancement in second harmonic generation efficiency of LPCC crystal with reference to KDP crystal.The Z-scan technique is employed to assess the third order nonlinear optical(TONLO) properties of LPCC crystal at 632.8 nm.The Z-scan data are utilized to evaluate the TONLO refraction,absorption and susceptibility of LPCC crystal.The color oriented luminescence behavior of LPCC crystal is investigated within a spectral range of 350 nm–700 nm.The dependence of dielectric constant and dielectric loss on temperature and frequency is evaluated through the dielectric measurement studies.展开更多
Single crystals of pure and Li+ doped L-citrulline oxalate (LCO) crystals are grown successfully by slow evaporation technique. The effect of lithium doping on crystal properties has been studied. The samples are char...Single crystals of pure and Li+ doped L-citrulline oxalate (LCO) crystals are grown successfully by slow evaporation technique. The effect of lithium doping on crystal properties has been studied. The samples are characterized by X-ray powder diffraction, TGA, FTIR, Raman and UV-Vis spectroscopic techniques. The presence of lithium in Li+ doped LCO crystals is estimated using AES. The thermal stability and the optical transparency region are found to be enhanced for the doped samples. The second harmonic generation efficiency of the doped crystal has improved considerably compared to pure L-citrulline oxalate. Lithium doping can hence be considered as a simple and advantageous technique to improve the thermal, optical and non linear optical (NLO) properties of the LCO single crystals.展开更多
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of ethanolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystallizes in orthorhombic, space group ...The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of ethanolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystallizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7) A^°, C9H11N3O7, Mr = 273.21, Z = 4, V= 1214.3(7) , A^°3, Dc = 1.494 g/cm^3, F(000) = 568,μ(MoKα) = 0.131 mm^-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure.展开更多
Benzoyl glycine (BG) is a promising organic nonlinear optical (NLO) crystal, whose second harmonic generation (SHG) efficiency is much higher than that of KDP (potassium dihydrogen phosphate). Single crystals ...Benzoyl glycine (BG) is a promising organic nonlinear optical (NLO) crystal, whose second harmonic generation (SHG) efficiency is much higher than that of KDP (potassium dihydrogen phosphate). Single crystals of pure, Cu2+ and Cd2+ doped BG were grown by slow evaporation technique. Optically transparent and defect free single crystals of size up to 10 mm×15 mm×10 mm were harvested in a period of 40-60 days. The growth conditions of pure and doped crystals of BG were optimized and the grown crystals were confirmed by single crystal XRD (X-ray diffraction). The grown crystals were characterized by FTIR (Fourier transform infrared spectroscopy), optical absorption and microhardness studies. The microhardness studies confirm that BG has a moderate VHN (Vickers hardness number) value in comparison to the.other organic NLO crystals. The efficiency of frequency doubling was measured for the using Nd:YAG laser and the results were discussed.展开更多
In the work, there have been investigated the optical power limiting effects which occur in the nonlinear photonic crys-tals possessing saturable Kerr nonlinearity. The method is proposed which allows exact determinat...In the work, there have been investigated the optical power limiting effects which occur in the nonlinear photonic crys-tals possessing saturable Kerr nonlinearity. The method is proposed which allows exact determination of the parame-ters of the structure as well as the radiation parameters which provide the limiting effect.展开更多
A cluster compound V2S6O2Cu6(3-MePy)6(3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-raydiffraction: space group P1, Z = 1, a = 9.7278(4...A cluster compound V2S6O2Cu6(3-MePy)6(3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-raydiffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) , α = 108.240(3), β = 98.120(2), γ = 99.500(2)o, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability(α2 = 1.7 × 10–10 m·W–1) and effective self-focusing performance(n2 = 1.27×10–18 m2·W–1) in a 1.58 × 10–4 mol·dm–3 DMF solution.展开更多
A new pentagon polarization maintaining photonic crystal fibre with low nonlinearity is introduced. The full vector finite element method was used to investigate the distribution and the effective area of modal field,...A new pentagon polarization maintaining photonic crystal fibre with low nonlinearity is introduced. The full vector finite element method was used to investigate the distribution and the effective area of modal field, the nonlinear properties, the effective indices of two orthogonal polarization modes and the birefringence of the new PM-PCF effectively. It is found that the birefringence of the new polarization maintaining photonic crystal fibre can easily achieve the order of 10-4, and it can obtain higher birefringence, larger effectively mode-field area and lower nonlinearity than traditional hexagonal polarization maintaining photonic crystal fibre with the same hole pitch, same hole diameter, and same ring number. It is important for sensing and communication applications, especially has potential application for fibre optical gyroscope.展开更多
Density functional theory and finite field FF method were employed to investigate the fluoroalkyl chain containing biphenylester liquid crystal molecules,and the results showed that the lowest-energy excitation was ob...Density functional theory and finite field FF method were employed to investigate the fluoroalkyl chain containing biphenylester liquid crystal molecules,and the results showed that the lowest-energy excitation was obtained from HOMO to LUMO with π → π* transition,and the absorption wavelength was obtained at around 390 nm,belonging to the near UV absorption area.It is found that the title compound molecules display good nonlinear optical properties,and the values of the second-and third-non-linear optical properties are 35 × 10-30 and 32 × 10-35 esu,respectively.展开更多
文摘A novel tolane 4-methoxy-4'-nitro-diphenyl-acetylene (MONA) has been prepared quantitatively by reacting cuprous p-methoxy phenyl-acetylene with p-iodonitrobenzene. A single crystal of the Moan was grown by solution growth method. The crystal was then characterized by X-ray diffraction structure analysis and second-harmonic generation(SHG)investigation. Polymorphous crystal forms of the MONA were grown from different solvents having different nonlinear optical properties depending on their different crystal structures. The relationship between the crystal growth and crystal structure is discusse.
文摘zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.
文摘A new semi-organic nonlinear optical thiosemicarbazide cadmium acetate (TSCA) material has been synthesized. TSCA single crystals were grown from aqueous solution by slow evaporation method. The solubility of TSCA has been determined for various temperatures. The grown crystals were characterized by single crystal X-ray diffraction (XRD), FTIR, UV-Vis., thermal and second harmonic generation (SHG) analysis. Single crystal XRD study has been carried out to identify the lattice parameters. FTIR studies confirm the functional groups present in the grown crystal. Optical transmission studies have confirmed that the grown crystal is highly transparent. Thermogravimetric and differential thermal analyses reveal the good thermal stability of the material. The SHG conversion efficiency of TSCA was determined using Kurtz powder technique and found two times that of potassium dihydrogen orthophosphate (KDP).
文摘Organic nonlinear optical material of 4-bromo-4’-methyl benzylidene aniline (BMBA) was synthesized and single crystal of BMBA was grown by solvent evaporation method at room temperature using ethanol as solvent. The crystalline nature of the grown crystals was confirmed using powder X-ray diffraction studies. The crystals were also characterized by single crystal X-ray diffraction method and their lattice parameters were determined. Thermal properties of BMBA were evaluated with thermogravimetric, differential thermal and differential scanning calorimetric analyses. Fourier transform infrared and FT-Raman spectral studies were carried out on the BMBA material to confirm the synthesized compound. 1H and 13C-nuclear magnetic resonance spectral studies were recorded to elucidate the structure of the grown crystals. Fluorescence spectrum recorded shows a peak at 485 nm. UV-Vis-NIR spectral analysis shows transmittance of ~92% in the visible region. The mechanical stability was analyzed by Vickers microhardness tester and the work hardening coefficient of the grown crystal was calculated. Second harmonic generation efficiency of the grown crystal measured by Kurtz powder technique is ~1.8 times that of potassium dihydrogen orthophosphate.
基金supported by the Major Project of Natural Science Research in Universities of Anhui Province(KJ2018ZD037,KJ2018A0333)Key Project of Youth Talents in Universities of Anhui Province(gxyqZD2017067)+4 种基金National Natural Science Foundation of China(21401024)Natural Science Foundation of Anhui Province(1508085MB21)National Students Research Training Program(201710371099,201710371019)Research Innovation Team of Fuyang Normal University(kytd201710)Horizontal Cooperation Project of Fuyang Municipal Government and Fuyang Normal University(XDHX2016011,XDHX2016004)
文摘A triphenylamine-containing Schiff base ligand(L), namely, N-(4-(1 H-imidazol-1-yl)benzylidene)-N,N-diphenylbenzene-1,4-diamine, was synthesized and characterized. By coordination of the ligand with CdI2, a complex CdI2 L2 was obtained. The structure of the complex was analyzed through single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/c with a = 25.277(5), b = 11.176(5), c = 17.912(5) ?, β = 106.056(5)°, V = 4863(3) ?3, Z = 4, Dc =1.633 Mg/m3, F(000) = 2360, Μr = 1195.19, μ = 1.766 mm-1, the final R = 0.0323 and wR = 0.0758 for 33414 observed reflections with I > 2?(I). The linear absorption spectra of the complex were experimentally and theoretically studied. And the third-order nonlinear optical(NLO) property of the complex was also measured through Z-scan technique.
文摘Large crystal NPP-OTs has been obtained by growth from solution,its powder SHG efficiency is 1/3 of urea.It shows it is a new convenient approach to obtain organic second-order NLO crystal:the dipole-dipole interaction is oppos- ed by introducing a large side group.
文摘The structure of ZnL2Cl2 (L=4-methoxybenzaldehyde thiosemicarbazone) has beenobtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cellof dimensions, a=9.08909(10), b=22. l420(10), c=11 .7890(l0)A,β=90.050(10)°, v=2374.6(12)A3,Dc=1 .552gcm-3. H=1 .463mm-1. R=0.0338. and Rw=0.0418. The structure contains individualZnL2Cl2 distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metalions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex arealso presented in this letter.
文摘Dependence of the periodically poled nonlinear-optical lithium niobate (PPLN) crystal temperature on laser power in the course of laser frequency conversion was measured using piezoelectric resonance. Crystal’s temperature tuning curves are precisely measured using concept of the equivalent temperature. Both optical absorption and heat transfer coefficients of the crystal are measured employing kinetics of the crystal equivalent temperature.
文摘The crystal structUre of the title ligand and its copper (Ⅱ) complex was determined bysingle crystal X-ray diffraction. The electrochendcal properties and the third-order nonlinearoptical response of the ligand and its copper (Ⅱ) complex were also studied.
基金supported by the National Natural Science Foundation of China(Grant No.51372140)the Youth Scientist Fund of Shandong Province,China(Grant No.BS2011CL025)the Basic Discipline Research Fund of China University of Petroleum,Beijing,China(Grant No.01JB0169)
文摘The geometric structure,electronic structure,and optical properties of CdHg(SCN)4 crystal are calculated by using the density functional perturbation theory and Green function screening Coulomb interaction approximation.The band gap of CdHg(SCN)4 crystal is calculated to be 3.198 eV,which is in good agreement with the experimental value 3.265 eV.The calculated second-order nonlinear optical coefficients are d14 = 1.2906 pm/V and d15 = 5.0928 pm/V,which are in agreement with the experimental results(d14=(1.4 ±0.6) pm/V and d15=(6.0 ±0.9) pm/V).Moreover,it is found that the contribution to the valence band mainly comes from Cd-4d,Hg-5d states,and the contributions to the valence band top and the conduction band bottom predominantly come from C-2p,N-2p,and S-3p states.The second-order nonlinear optical effect of CdHg(SCN)_4 crystal results mainly from the internal electronic transition of(SCN)^-.
基金UGC,New Delhi,India for awarding Maulana Azad National Fellowship(Grant No.F1-17.1/2015-16/MANF-2015-17-MAH-68193)RCAMSKing Khalid University,Saudi Arabia for support
文摘In the current investigation,L-proline cadmium chloride monohydrate(LPCC) single crystal is grown by a slow solvent evaporation technique to identify its credibility for nonlinear optical device applications.The constituent elements of LPCC crystal are determined by the energy dispersive spectroscopic(EDS) technique.The single crystal x-ray diffraction technique is used to determine the structural dimensions of LPCC crystal.The UV-visible studies are carried out within a wavelength range of 200 nm–1100 nm to determine the optical transmittance of LPCC crystal.The linear optical parameters of LPCC crystal are evaluated using the transmittance data to discuss its importance for distinct optical devices.The Nd:YAG laser assisted Kurtz–Perry test is carried out to determine the enhancement in second harmonic generation efficiency of LPCC crystal with reference to KDP crystal.The Z-scan technique is employed to assess the third order nonlinear optical(TONLO) properties of LPCC crystal at 632.8 nm.The Z-scan data are utilized to evaluate the TONLO refraction,absorption and susceptibility of LPCC crystal.The color oriented luminescence behavior of LPCC crystal is investigated within a spectral range of 350 nm–700 nm.The dependence of dielectric constant and dielectric loss on temperature and frequency is evaluated through the dielectric measurement studies.
文摘Single crystals of pure and Li+ doped L-citrulline oxalate (LCO) crystals are grown successfully by slow evaporation technique. The effect of lithium doping on crystal properties has been studied. The samples are characterized by X-ray powder diffraction, TGA, FTIR, Raman and UV-Vis spectroscopic techniques. The presence of lithium in Li+ doped LCO crystals is estimated using AES. The thermal stability and the optical transparency region are found to be enhanced for the doped samples. The second harmonic generation efficiency of the doped crystal has improved considerably compared to pure L-citrulline oxalate. Lithium doping can hence be considered as a simple and advantageous technique to improve the thermal, optical and non linear optical (NLO) properties of the LCO single crystals.
基金This project was supported by the Innovation Foundation for College Students of Nankai University
文摘The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of ethanolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystallizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7) A^°, C9H11N3O7, Mr = 273.21, Z = 4, V= 1214.3(7) , A^°3, Dc = 1.494 g/cm^3, F(000) = 568,μ(MoKα) = 0.131 mm^-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure.
文摘Benzoyl glycine (BG) is a promising organic nonlinear optical (NLO) crystal, whose second harmonic generation (SHG) efficiency is much higher than that of KDP (potassium dihydrogen phosphate). Single crystals of pure, Cu2+ and Cd2+ doped BG were grown by slow evaporation technique. Optically transparent and defect free single crystals of size up to 10 mm×15 mm×10 mm were harvested in a period of 40-60 days. The growth conditions of pure and doped crystals of BG were optimized and the grown crystals were confirmed by single crystal XRD (X-ray diffraction). The grown crystals were characterized by FTIR (Fourier transform infrared spectroscopy), optical absorption and microhardness studies. The microhardness studies confirm that BG has a moderate VHN (Vickers hardness number) value in comparison to the.other organic NLO crystals. The efficiency of frequency doubling was measured for the using Nd:YAG laser and the results were discussed.
文摘In the work, there have been investigated the optical power limiting effects which occur in the nonlinear photonic crys-tals possessing saturable Kerr nonlinearity. The method is proposed which allows exact determination of the parame-ters of the structure as well as the radiation parameters which provide the limiting effect.
基金supported by Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials Foundation(No.JSKC12110)the funds of high-grade scientific research project from Huaiyin Normal University+1 种基金the National Science Foundation of Educational Commission of Jiangsu Province(No.12KJA150004)Huaian Key Laboratory for Photoelectric Conversion and Energy Storage Materials(No.HAP201205)
文摘A cluster compound V2S6O2Cu6(3-MePy)6(3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-raydiffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) , α = 108.240(3), β = 98.120(2), γ = 99.500(2)o, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability(α2 = 1.7 × 10–10 m·W–1) and effective self-focusing performance(n2 = 1.27×10–18 m2·W–1) in a 1.58 × 10–4 mol·dm–3 DMF solution.
基金supported by the Specific Scientific and Technological Cooperation between China and Russia (Grant No.2010DFR80140)
文摘A new pentagon polarization maintaining photonic crystal fibre with low nonlinearity is introduced. The full vector finite element method was used to investigate the distribution and the effective area of modal field, the nonlinear properties, the effective indices of two orthogonal polarization modes and the birefringence of the new PM-PCF effectively. It is found that the birefringence of the new polarization maintaining photonic crystal fibre can easily achieve the order of 10-4, and it can obtain higher birefringence, larger effectively mode-field area and lower nonlinearity than traditional hexagonal polarization maintaining photonic crystal fibre with the same hole pitch, same hole diameter, and same ring number. It is important for sensing and communication applications, especially has potential application for fibre optical gyroscope.
基金supported by the National Natural Science Foundation of China (No. 50811140156)Science and Technology Plan of Sichuan Province (No. 2010JY0041)Science Research Fund of Sichuan Normal University (No. 09ZDL03)
文摘Density functional theory and finite field FF method were employed to investigate the fluoroalkyl chain containing biphenylester liquid crystal molecules,and the results showed that the lowest-energy excitation was obtained from HOMO to LUMO with π → π* transition,and the absorption wavelength was obtained at around 390 nm,belonging to the near UV absorption area.It is found that the title compound molecules display good nonlinear optical properties,and the values of the second-and third-non-linear optical properties are 35 × 10-30 and 32 × 10-35 esu,respectively.