The Tongyu volcanic-hosted massive sulfide(VHMS) copper deposit is located in the west part of the North Qinling(NQL),Shaanxi Province.Here we report geological features and trace elemental characteristics of ores,min...The Tongyu volcanic-hosted massive sulfide(VHMS) copper deposit is located in the west part of the North Qinling(NQL),Shaanxi Province.Here we report geological features and trace elemental characteristics of ores,mineralized rocks,and volcanic host rocks of this deposit.We also conducted in situ zircon U-Pb and Lu-Hf LA-ICP-MS dating and lithogeochemical study of the Meigou granodiorite,which is intruded in the south of the Tongyu mining district.It is inferred that the volcanic host rocks of the Tongyu Cu deposit belong to calc-alkaline island arc volcanic rocks,and the volcanic host rocks and the ore-forming materials share common material sources.During subduction of the Paleo-Qinling oceanic slab at around 472 Ma,high oxygen-fugacity aqueous fluid released by dehydration reaction of the subducting slab rose into the mantle wedge,leached Cu and other metal elements,and triggered partial melting of the mantle wedge.Associated with the ore-forming materials,the arc calc-alkaline magmas erupted and formed the Tongyu VHMS deposit.The weighted average zircon U-Pb age of the Meigou granodiorite is 439.3±3 Ma,suggesting its genesis is associated with the subduction event of the Paleo-Qinling oceanic plate around 440 Ma.In terms of the granitoid’s geochemical characteristics,the Mg#,Ni,and Cr contents are high.REE show strongly fractionated patterns with unobvious Eu anomalies.Sr contents are high while Y contents are low,resulting in high Sr/Y ratios.Two-stage zircon Hf model ages mostly range between 908 and 723 Ma,with εHf(t)】0.Therefore,we classify Meigou granodiorite as island arc granite with adakitic geochemical features.It was generated by interaction between mantle wedge and melt produced by partial melting of the subducted basaltic slab of the Paleo-Qinling Ocean.The Tongyu VHMS deposit was formed in the island arc tectonic setting during Ordovician-Silurian between 439.3±3 Ma and 472±11 Ma.The volcanic exhalation-sedimentation,which was contemporaneous with the submarine volcanics,produced the primary mineralization of the Tongyu Cu deposit.Afterward,the ore bodies and host rocks were reworked and overprinted intensively by structures corresponding with the overall collisional orogenic process of the Qinling Orogenic Belt during the Indosinian period.In contrast to classic VHMS deposits such as the Kuroko deposit in Japan,the Tongyu Cu deposit possesses the dual characteristics of island arc volcanic exhalation and sedimentation as well as structural reworking and overprinting.Therefore,the Tongyu VHMS Cu deposit is a volcanic exhalation and sedimentation-structural reworking and overprinting type deposit.展开更多
Tectonic movements formed several unconfor- mities in the north-west margin of the Junggar basin. Based on data of outcrop, core, and samples, the unconformity is a structural body whose formation associates with weat...Tectonic movements formed several unconfor- mities in the north-west margin of the Junggar basin. Based on data of outcrop, core, and samples, the unconformity is a structural body whose formation associates with weath- ering, leaching, and onlap. At the same time, the structural body may be divided into three layers, including upper layer, mid layer, and lower layer. The upper layer with good primary porosity serves as the hydrocarbon migration system, and also accumulates the hydrocarbon. The mid layer with compactness and ductility can play a role as cap rock, the strength of which increases with depth. The lower layer with good secondary porosity due to weathering and leaching can form the stratigraphic truncation traps. A typical stratigraphie reservoir lying in the unconformity between the Jurassic and Triassic in the north-west margin of the Junggar basin was meticulously analyzed in order to reveal the key controlling factors. The results showed that the hydrocarbon distribution in the stratigraphic onlap reservoirs was controlled by the onlap line, the hydro- carbon distribution in the stratigraphic truncation reser- voirs was confined by the truncation line, and the mid layer acted as the key sealing rock. So a conclusion was drawn that "two lines (onlap line and truncation line) and a body (unconformity structural body)" control the formation and distribution of stratigraphic reservoirs.展开更多
In estimating emissions reductions brought about by renewables in China, much of existing research assumes that renewables displace coal power. In this paper, this assumption is challenged and the potential environmen...In estimating emissions reductions brought about by renewables in China, much of existing research assumes that renewables displace coal power. In this paper, this assumption is challenged and the potential environmental effects of photovoltaic (PV) power in North-west China are reevaluated when the marginal generator actually being displaced is taken into account. The annual PV power generation in the North-west Grid is estimated, in this paper, to be as high as 17900GW.h in 2015, roughly equaling to the output of 1.5 nuclear power plants in the US today. The total associated emission reduction in 2015 will at most be 0.36 percent of SO2 and 0.25 percent of NOx emissions from their 2010 levels in China. Further, PV power may render no emissions reduction at all if it displaces hydropower, which is often used to meet peak demand in the North-west Grid in China. These results imply that a more cost-effective area of focus in the short- term may be on desulfurization and denitrification technologies for coal plants.展开更多
基金supported by National Basic Research Program of China (Grant No.2006CB403502)National Natural Science Foundation of China (Grant No.40872071)+3 种基金Program of Chinese Ministry of Science and Technology for State Key Laboratory of Continental Dynamics (Grant No.BJ091349)Foundation of the State Key Laboratory for Mineral Deposits Research,Nanjing University (Grant No.14-08-1)Foundation of the Educational Bureau of Shaanxi Province Foundation (Grant No.07JK414)Graduate Innovation and Creativity Funds of Northwest University,China (Grant No.08YZZ53)
文摘The Tongyu volcanic-hosted massive sulfide(VHMS) copper deposit is located in the west part of the North Qinling(NQL),Shaanxi Province.Here we report geological features and trace elemental characteristics of ores,mineralized rocks,and volcanic host rocks of this deposit.We also conducted in situ zircon U-Pb and Lu-Hf LA-ICP-MS dating and lithogeochemical study of the Meigou granodiorite,which is intruded in the south of the Tongyu mining district.It is inferred that the volcanic host rocks of the Tongyu Cu deposit belong to calc-alkaline island arc volcanic rocks,and the volcanic host rocks and the ore-forming materials share common material sources.During subduction of the Paleo-Qinling oceanic slab at around 472 Ma,high oxygen-fugacity aqueous fluid released by dehydration reaction of the subducting slab rose into the mantle wedge,leached Cu and other metal elements,and triggered partial melting of the mantle wedge.Associated with the ore-forming materials,the arc calc-alkaline magmas erupted and formed the Tongyu VHMS deposit.The weighted average zircon U-Pb age of the Meigou granodiorite is 439.3±3 Ma,suggesting its genesis is associated with the subduction event of the Paleo-Qinling oceanic plate around 440 Ma.In terms of the granitoid’s geochemical characteristics,the Mg#,Ni,and Cr contents are high.REE show strongly fractionated patterns with unobvious Eu anomalies.Sr contents are high while Y contents are low,resulting in high Sr/Y ratios.Two-stage zircon Hf model ages mostly range between 908 and 723 Ma,with εHf(t)】0.Therefore,we classify Meigou granodiorite as island arc granite with adakitic geochemical features.It was generated by interaction between mantle wedge and melt produced by partial melting of the subducted basaltic slab of the Paleo-Qinling Ocean.The Tongyu VHMS deposit was formed in the island arc tectonic setting during Ordovician-Silurian between 439.3±3 Ma and 472±11 Ma.The volcanic exhalation-sedimentation,which was contemporaneous with the submarine volcanics,produced the primary mineralization of the Tongyu Cu deposit.Afterward,the ore bodies and host rocks were reworked and overprinted intensively by structures corresponding with the overall collisional orogenic process of the Qinling Orogenic Belt during the Indosinian period.In contrast to classic VHMS deposits such as the Kuroko deposit in Japan,the Tongyu Cu deposit possesses the dual characteristics of island arc volcanic exhalation and sedimentation as well as structural reworking and overprinting.Therefore,the Tongyu VHMS Cu deposit is a volcanic exhalation and sedimentation-structural reworking and overprinting type deposit.
文摘Tectonic movements formed several unconfor- mities in the north-west margin of the Junggar basin. Based on data of outcrop, core, and samples, the unconformity is a structural body whose formation associates with weath- ering, leaching, and onlap. At the same time, the structural body may be divided into three layers, including upper layer, mid layer, and lower layer. The upper layer with good primary porosity serves as the hydrocarbon migration system, and also accumulates the hydrocarbon. The mid layer with compactness and ductility can play a role as cap rock, the strength of which increases with depth. The lower layer with good secondary porosity due to weathering and leaching can form the stratigraphic truncation traps. A typical stratigraphie reservoir lying in the unconformity between the Jurassic and Triassic in the north-west margin of the Junggar basin was meticulously analyzed in order to reveal the key controlling factors. The results showed that the hydrocarbon distribution in the stratigraphic onlap reservoirs was controlled by the onlap line, the hydro- carbon distribution in the stratigraphic truncation reser- voirs was confined by the truncation line, and the mid layer acted as the key sealing rock. So a conclusion was drawn that "two lines (onlap line and truncation line) and a body (unconformity structural body)" control the formation and distribution of stratigraphic reservoirs.
文摘In estimating emissions reductions brought about by renewables in China, much of existing research assumes that renewables displace coal power. In this paper, this assumption is challenged and the potential environmental effects of photovoltaic (PV) power in North-west China are reevaluated when the marginal generator actually being displaced is taken into account. The annual PV power generation in the North-west Grid is estimated, in this paper, to be as high as 17900GW.h in 2015, roughly equaling to the output of 1.5 nuclear power plants in the US today. The total associated emission reduction in 2015 will at most be 0.36 percent of SO2 and 0.25 percent of NOx emissions from their 2010 levels in China. Further, PV power may render no emissions reduction at all if it displaces hydropower, which is often used to meet peak demand in the North-west Grid in China. These results imply that a more cost-effective area of focus in the short- term may be on desulfurization and denitrification technologies for coal plants.