STUDIES ON ORGANOPHOSPHORUS COMPOUNDS 69.A NOVEL SYNTHESIS OF 5-SUBSTITUTED 3-(1'-DIETHOXYPHOSPHORYLALKYL)-2-ISOXAZOLINES

Additions of diethyl phosphite to α-nitroalkenes followed by the introduction of trimethylchlorosilane and an activated alkene, gave the corresponding title compounds via regioselective 1,3-dipolar cycloaddition in moderate yield.

NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS

It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnishing each end ofpolymer blocks with a reactive functional group, one can only prepare heteropolymer chains with few long blocks, such asdiblock and triblock copolymers. The most plausible result so far was a pentablock copolymer. Recently, using a combinationof polymer physics and synthetic chemistry, we have invented self-assembly assisted polycondensation (SAAP). Thiscommunication reports the results of using this novel. method to connect 10-100 triblock polymer chains together to formlong multi-block heteropolymer chains with an ordered sequence and controllable block lengths.

SYNTHESIS AND CHARACTERIZATION OF NOVEL MULTIFUNCTIONAL HOST COMPOUNDS.1.β-CYCLODEXTRIN DERIVATIVE BEARING DIETHANOLAMINE MOIETY

A novel β-cyclodextrin(β-CD)derivative bearing diethanolamine moiety was synthesized by a convenient method with 63% yield,and the new host compound was characterized by (13)~C-NMR,FT-IR spectra etc,

Synthesis of Novel Polypyridine Ligands

Some novel polypyridine ligands containing adsorbing groups were synthesized with the purpose of developing new ruthenium(II) polypyridine complexes to be used in solar cell based on dye-sensitized nanocrystilline TiO2 film electrode.

THE REGIOSELECTIVE SYNTHESIS OF NOVEL PHENYLSULFONES BEARING ISOPRENE UNITS

The facile and regioselective synthesis of some novel phenylsulfones bearing isoprene units were accomplished by using the corresponding terpenoid compounds as the starting material through ene-chlorination and phenylsulfonyl group substritution steps. The yields are excellent and the experimental conditions are very mild.

SYNTHESIS OF NOVEL TRLACETAL OXA-CAGECOMPOUNDS

Ozonolysis of compounds 3a-3e and 6 in dichlormethane at -78℃ followed by reduction with dimethylsulfide gave the novel triacetal oxa-cage compounds 5a-5e and 7 in moderate yields respectively.

SYNTHESIS AND CHARACTERIZATION OF NOVEL MICROPOROUS ALUMINOPHOSPHATES.

A series of novel aluminophosphates,named AlPO_4-CJ_n(n=2-5),has been synthesized hydrothermally from R-Al_2O_3-P_2O_5-H_2O systems(R= organic amine molecules),and characterized by means of X-ray powder diffraction,infrared,SEM,XPS,composition and thermal analyses.

SYNTHESIS OF A NOVEL AMPHIPHILE, 4-[4-(4-DECYLOXYPHENYLAZO) NAPHTHYLOXY] BUTYL TRIMETHYLAMMONIUM BROMIDE, AND ITS SELF-ASSEMBLING BEHAVIOR IN DILUTE AQUEOUS SOLUTION

A novel amphiphile of 4-[4-(4-decyloxyphenylazo) naphthyloxy] butyl trimethylammonium bromide has been synthesized. It can form the stable bilayer in dilute aqueous solution.

Novel Phosphonoacetic Acid Derivatives.Synthesis of N-(Ethoxycarbonylmethylphosphonyl)-α-Amino Esters and-α-Amino Phosphonic Acid Esters and Their Bioactivities

A series of novel phosphonoacetic acid derivatives, N-(ethoxycarbonylmethy-ethoxyphosphonyl)-α-amino acid esters and α-amino phosphonates, were synthesized via the reaction of the corresponding phosphonyl chloride with amino acid ester hydrochlorides or amino phosphonates in the presence of a base. The preliminary bioassay shows that some compounds show significant anti-viral activity against tobacco mosaic virus (TMV)

SYNTHESIS AND CHARACTERIZATION OF A NOVEL BONDING TRINUCLEAR(Mo/Fe/Mo) COMPLEX (MoCl_4)_2·dppf

By the reaction of bidentate ligand 1,1'-bis(diphenylphosphino)-ferrocene (dppf) with MoCl_4(CH_3CN)_2, a novel bonding type complex (MoCl_4)2_· (dppf) was synthesized and characterized by elemental analyses, ^(31)p-NMR, IR and electronic spectra, TG and ICP-AES. Structure of the title complex was proposed.

SYNTHESIS AND CHARACTERIZATION OF FOUR NOVEL TYPES OF MICROPOROUS BERYLLOPHOSPHATE(Ⅱ)

Four new types of microporous beryllophosphates were hydrothermally synthesized using BeO - P_2O_5- R - MCl (or MCl_2) - H_20, R being HMDA (1, b-hexanediamine), EDA (ethylenediamine), or TBAOH (tetrabutytamine hydroxide), M alkali or alkali earth cation. By means of X-ray diffraction patterns (XRD), infrared (IR), TG-DT and elemental analyses we show that the crystalline beryllopbospbates have novel, unique framework structures, composed from basic units of tetrahedral P0_4 and Be0_4. These materials exhibit zeolite-like adsorption and ion-exchange properties.

Synthesis of a Novel Copper Phthalocyanine-Fullerene Dyad

A new copper phthalocyanine-fullerene dyad (CuPc-C-60) was synthesized by Diels-Alder adduct of corresponding CuPc and C-60. The chemical structure of this compound was characterized by elemental analysis, MS, IR, UV-VIS and NMR.