CO2 flooding is considered not only one of the most effective enhanced oil recovery (EOR) methods, but also an important alternative for geological CO2 storage. In this paper, the visualization of CO2 flooding was s...CO2 flooding is considered not only one of the most effective enhanced oil recovery (EOR) methods, but also an important alternative for geological CO2 storage. In this paper, the visualization of CO2 flooding was studied using a 400 MHz NMR micro-imaging system. For gaseous CO2 immiscible displacement, it was found that CO2 channeling or fingering occurred due to the difference of fluid viscosity and density. Thus, the sweep efficiency was small and the final residual oil saturation was 53.1%. For supercritical CO2 miscible displacement, the results showed that piston-like displacement occurred, viscous fingering and the gravity override caused by the low viscosity and density of the gas was effectively restrained, and the velocity of CO2 front was uniform. The sweep efficiency was so high that the final residual oil saturation was 33.9%, which indicated CO2 miscible displacement could enhance oil recovery more than CO2 immiscible displacement. In addition, the average velocity of CO2 front was evaluated through analyzing the oil saturation profile. A special core analysis method has been applied to in-situ oil saturation data to directly evaluate the local Darcy phase velocities and capillary dispersion rate.展开更多
The green algae Botryococcus braunii is widely recognized as a source of oil, including hydrocarbons. However, the slow rate of growth B. braunii hampers its commercial development. This stu- dy addresses this by exam...The green algae Botryococcus braunii is widely recognized as a source of oil, including hydrocarbons. However, the slow rate of growth B. braunii hampers its commercial development. This stu- dy addresses this by examining the effects of three growth media on biomass and oil production in two B. braunii Race B strains, Kossou-4 and Overjuyo-3. Growth of B. braunii strains in BG11 medium resulted in significantly higher growth (2.3 - 4.2 and 2.9 - 6.0 fold increases in Kossou-4 and Overjuyo-3 respectively) compared to the JM and BBM-3N media after 15 days. A similar trend was obtained when biomass was measured indirectly using optical density (OD) and chlorophyll fluo-rescence. Oil production was also significantly higher in BG11 whether measured as oil weight or absorbance (ODs at 680 and 750 nm). However, the presence of extracellular oil was shown to in-crease absorbance values making OD measurements less reliable than dry weight assays. Maximum recovery of oil was recorded when hexane was used as solvent compared to hexane-isopro- panol and heptane. These results suggest that BG11 is the best growth medium for these two strains under the conditions of this experiment.展开更多
The relationship between NaCl concentration and the phase change behavior of microemulsion of anionic surfactant was characterized by the salinity scan experiments.The wettability of WinsorⅠtype surfactant solution(W...The relationship between NaCl concentration and the phase change behavior of microemulsion of anionic surfactant was characterized by the salinity scan experiments.The wettability of WinsorⅠtype surfactant solution(WⅠsolution)and the effect of NaCL concentration on phase change behavior of WⅠsolution and imbibition in oil-wet porous media were investigated by microfluidic experiments in this study.The WⅠsolution and WinsorⅠtype microemulsion are similar in wetting phase with stronger wettability than other phases.Two main mechanisms of WⅠsolution enhancing imbibitions recovery in oil wet porous media are the wetting phase drive and residual oil solubilization.Under the salinity condition of WinsorⅠtype microemulsion,the NaCl concentration has strong impact on the imbibition mechanism of WⅠsolution,the higher the NaCl concentration,the complex the imbibition process and the higher the imbibition efficiency will be.The NaCl concentration has strong impact on the solubilization ability to oil of the WⅠsolution,the higher the NaCl concentration,the stronger the solubility of the WⅠsolution to residual oil will be.展开更多
Fracture systems in nature are complicated. Normally vertical fractures develop in an isotropic background. However, the presence of horizontal fine layering or horizontal fractures in reservoirs makes the vertical fr...Fracture systems in nature are complicated. Normally vertical fractures develop in an isotropic background. However, the presence of horizontal fine layering or horizontal fractures in reservoirs makes the vertical fractures develop in a VTI(a transversely isotropic media with a vertical symmetry axis) background. In this case, reservoirs can be described better by using an orthorhombic medium instead of a traditional HTI(a transversely isotropic media with a horizontal symmetry axis) medium. In this paper, we focus on the fracture prediction study within an orthorhombic medium for oil-bearing reservoirs. Firstly, we simplify the reflection coefficient approximation in an orthorhombic medium. Secondly, the impact of horizontal fracturing on the reflection coefficient approximation is analyzed theoretically. Then based on that approximation, we compare and analyze the relative impact of vertical fracturing, horizontal fracturing and fluid indicative factor on traditional ellipse fitting results and the scaled B attributes. We find that scaled B attributes are more sensitive to vertical fractures, so scaled B attributes are proposed to predict vertical fractures. Finally, a test is developed to predict the fracture development intensity of an oil-bearing reservoir. The fracture development observed in cores is used to validate the study method. The findings of both theoretical analyses and practical application reveal that compared with traditional methods, this new approach has improved the prediction of fracture development intensity in oil-bearing reservoirs.展开更多
Foam is widely used in the petroleum industry thanks to its unique properties and performance. Its application to water control in oil wells has received more and more attention. The stability of nitrogen foam was inv...Foam is widely used in the petroleum industry thanks to its unique properties and performance. Its application to water control in oil wells has received more and more attention. The stability of nitrogen foam was investigated in pressurized equipment and sand pack. The result indicated that with increasing pressure (0-2 MPa) the stability of foam in the pressurized equipment increased linearly. Increased nitrogen injection pressure caused better dispersion of nitrogen-foaming solution in porous media. The initial residual resistance factor to gas was an exponential function of injection pressure, but the residual resistance factor (to gas and liquid) decreased exponentially with time. The halflife of foam in porous media (expressed in residual resistance factor) was much longer than that in bulk phase (expressed in foam height). Pore model analysis indicated that good dispersion in porous media and the presence of thick liquid film during dispersion were the main reasons for high stability. Field test indicated that effective residence of foam in the formation not only resulted in much better heat insulation, but also improved steam stimulation by enhancing steam heating.展开更多
This is the second paper of a series where we introduce a control volume based finite element method (CVFEM) to simulate multiphase flow in porous media. This is a fully conservative method able to deal with unstruc...This is the second paper of a series where we introduce a control volume based finite element method (CVFEM) to simulate multiphase flow in porous media. This is a fully conservative method able to deal with unstructured grids which can be used for representing any complexity of reservoir geometry and its geological objects in an accurate and efficient manner. In order to deal with the inherent heterogeneity of the reservoirs, all operations related to discretization are performed at the element level in a manner similar to classical finite element method (FEM). Moreover, the proposed method can effectively reduce the so-called grid orientation effects. In the first paper of this series, we presented this method and its application for incompressible and immiscible two-phase flow simulation in homogeneous and heterogeneous porous media. In this paper, we evaluate the capability of the method in the solution of highly nonlinear and coupled partial differential equations by simulating hydrocarbon reservoirs using the black-oil model. Furthermore, the effect of grid orientation is investigated by simulating a benchmark waterflooding problem. The numerical results show that the formulation presented here is efficient and accurate for solving the bubble point and three-phase coning problems.展开更多
The purpose of this article is to show the role and influence of fluid injection, porosity on two-phase flows in porous media for the purpose of improving and increasing recovery efficiency assisted by oil. An experim...The purpose of this article is to show the role and influence of fluid injection, porosity on two-phase flows in porous media for the purpose of improving and increasing recovery efficiency assisted by oil. An experimental study was carried out in porous media, it is a plexiglass cylinder filled with sands saturated with crude oil. Pressure drop and data processing for two-phase flow are measured and processed using a differential pressure sensor connected to an acquisition computer. It thus makes it possible to determine the pressure difference between the inlet and the outlet of the porous medium over time. In this experiment, the flow rates at the inlet and the outlet of the porous medium were measured as a function of time using a flow rate and a pump. To describe these flows we will use Darcy’s model.展开更多
The propagation of electromagnetic waves in the annular region of oil wells was studied. The present study aims to analyse the propagation attenuation along the well, as well as the input impedance determined by a sou...The propagation of electromagnetic waves in the annular region of oil wells was studied. The present study aims to analyse the propagation attenuation along the well, as well as the input impedance determined by a source placed near the wellhead. A coaxial waveguide model was adopted with heterogeneous dielectrics and losses. First, a wave equation solution for the waveguide is presented, assuming a homogeneous medium with losses, by solving the equation in cylindrical coordinates using the vector potential technique. An uncertainty analysis model is then developed to model the heterogeneous characteristics of the medium. Monte Carlo simulations were performed with the created model using data gathered from the literature. The results of the simulations indicate that propagation in the transverse electromagnetic mode has the smallest attenuation and that for depths of up to 4000 m, there is an attenuation of less than 52 dB. Furthermore, the input impedance ranges from 10 Ω to 10 kΩ because of the uncertainties involved in the problem in question.展开更多
基金support from the National High Technology Reseatch and Development Program of China(863 Program,Grant No.2008AA062303 and No.2009AA063402)National Basic Research Program of China(973 Program,Grant No.2006CB705804)the National Natural Science Foundation of China (Key Program,Grant No.50736001)
文摘CO2 flooding is considered not only one of the most effective enhanced oil recovery (EOR) methods, but also an important alternative for geological CO2 storage. In this paper, the visualization of CO2 flooding was studied using a 400 MHz NMR micro-imaging system. For gaseous CO2 immiscible displacement, it was found that CO2 channeling or fingering occurred due to the difference of fluid viscosity and density. Thus, the sweep efficiency was small and the final residual oil saturation was 53.1%. For supercritical CO2 miscible displacement, the results showed that piston-like displacement occurred, viscous fingering and the gravity override caused by the low viscosity and density of the gas was effectively restrained, and the velocity of CO2 front was uniform. The sweep efficiency was so high that the final residual oil saturation was 33.9%, which indicated CO2 miscible displacement could enhance oil recovery more than CO2 immiscible displacement. In addition, the average velocity of CO2 front was evaluated through analyzing the oil saturation profile. A special core analysis method has been applied to in-situ oil saturation data to directly evaluate the local Darcy phase velocities and capillary dispersion rate.
文摘The green algae Botryococcus braunii is widely recognized as a source of oil, including hydrocarbons. However, the slow rate of growth B. braunii hampers its commercial development. This stu- dy addresses this by examining the effects of three growth media on biomass and oil production in two B. braunii Race B strains, Kossou-4 and Overjuyo-3. Growth of B. braunii strains in BG11 medium resulted in significantly higher growth (2.3 - 4.2 and 2.9 - 6.0 fold increases in Kossou-4 and Overjuyo-3 respectively) compared to the JM and BBM-3N media after 15 days. A similar trend was obtained when biomass was measured indirectly using optical density (OD) and chlorophyll fluo-rescence. Oil production was also significantly higher in BG11 whether measured as oil weight or absorbance (ODs at 680 and 750 nm). However, the presence of extracellular oil was shown to in-crease absorbance values making OD measurements less reliable than dry weight assays. Maximum recovery of oil was recorded when hexane was used as solvent compared to hexane-isopro- panol and heptane. These results suggest that BG11 is the best growth medium for these two strains under the conditions of this experiment.
基金Supported by China National Science and Technology Major Project(2017ZX05009-005-003).
文摘The relationship between NaCl concentration and the phase change behavior of microemulsion of anionic surfactant was characterized by the salinity scan experiments.The wettability of WinsorⅠtype surfactant solution(WⅠsolution)and the effect of NaCL concentration on phase change behavior of WⅠsolution and imbibition in oil-wet porous media were investigated by microfluidic experiments in this study.The WⅠsolution and WinsorⅠtype microemulsion are similar in wetting phase with stronger wettability than other phases.Two main mechanisms of WⅠsolution enhancing imbibitions recovery in oil wet porous media are the wetting phase drive and residual oil solubilization.Under the salinity condition of WinsorⅠtype microemulsion,the NaCl concentration has strong impact on the imbibition mechanism of WⅠsolution,the higher the NaCl concentration,the complex the imbibition process and the higher the imbibition efficiency will be.The NaCl concentration has strong impact on the solubilization ability to oil of the WⅠsolution,the higher the NaCl concentration,the stronger the solubility of the WⅠsolution to residual oil will be.
基金financially supported by 973 Program (No. 2014CB239104)NSFC and Sinopec Joint Key Project (U1663207)National Key Science and Technology Project (2017ZX05049002)
文摘Fracture systems in nature are complicated. Normally vertical fractures develop in an isotropic background. However, the presence of horizontal fine layering or horizontal fractures in reservoirs makes the vertical fractures develop in a VTI(a transversely isotropic media with a vertical symmetry axis) background. In this case, reservoirs can be described better by using an orthorhombic medium instead of a traditional HTI(a transversely isotropic media with a horizontal symmetry axis) medium. In this paper, we focus on the fracture prediction study within an orthorhombic medium for oil-bearing reservoirs. Firstly, we simplify the reflection coefficient approximation in an orthorhombic medium. Secondly, the impact of horizontal fracturing on the reflection coefficient approximation is analyzed theoretically. Then based on that approximation, we compare and analyze the relative impact of vertical fracturing, horizontal fracturing and fluid indicative factor on traditional ellipse fitting results and the scaled B attributes. We find that scaled B attributes are more sensitive to vertical fractures, so scaled B attributes are proposed to predict vertical fractures. Finally, a test is developed to predict the fracture development intensity of an oil-bearing reservoir. The fracture development observed in cores is used to validate the study method. The findings of both theoretical analyses and practical application reveal that compared with traditional methods, this new approach has improved the prediction of fracture development intensity in oil-bearing reservoirs.
文摘Foam is widely used in the petroleum industry thanks to its unique properties and performance. Its application to water control in oil wells has received more and more attention. The stability of nitrogen foam was investigated in pressurized equipment and sand pack. The result indicated that with increasing pressure (0-2 MPa) the stability of foam in the pressurized equipment increased linearly. Increased nitrogen injection pressure caused better dispersion of nitrogen-foaming solution in porous media. The initial residual resistance factor to gas was an exponential function of injection pressure, but the residual resistance factor (to gas and liquid) decreased exponentially with time. The halflife of foam in porous media (expressed in residual resistance factor) was much longer than that in bulk phase (expressed in foam height). Pore model analysis indicated that good dispersion in porous media and the presence of thick liquid film during dispersion were the main reasons for high stability. Field test indicated that effective residence of foam in the formation not only resulted in much better heat insulation, but also improved steam stimulation by enhancing steam heating.
基金Iranian Offshore OilCompany (IOOC) for financial support of this work
文摘This is the second paper of a series where we introduce a control volume based finite element method (CVFEM) to simulate multiphase flow in porous media. This is a fully conservative method able to deal with unstructured grids which can be used for representing any complexity of reservoir geometry and its geological objects in an accurate and efficient manner. In order to deal with the inherent heterogeneity of the reservoirs, all operations related to discretization are performed at the element level in a manner similar to classical finite element method (FEM). Moreover, the proposed method can effectively reduce the so-called grid orientation effects. In the first paper of this series, we presented this method and its application for incompressible and immiscible two-phase flow simulation in homogeneous and heterogeneous porous media. In this paper, we evaluate the capability of the method in the solution of highly nonlinear and coupled partial differential equations by simulating hydrocarbon reservoirs using the black-oil model. Furthermore, the effect of grid orientation is investigated by simulating a benchmark waterflooding problem. The numerical results show that the formulation presented here is efficient and accurate for solving the bubble point and three-phase coning problems.
文摘The purpose of this article is to show the role and influence of fluid injection, porosity on two-phase flows in porous media for the purpose of improving and increasing recovery efficiency assisted by oil. An experimental study was carried out in porous media, it is a plexiglass cylinder filled with sands saturated with crude oil. Pressure drop and data processing for two-phase flow are measured and processed using a differential pressure sensor connected to an acquisition computer. It thus makes it possible to determine the pressure difference between the inlet and the outlet of the porous medium over time. In this experiment, the flow rates at the inlet and the outlet of the porous medium were measured as a function of time using a flow rate and a pump. To describe these flows we will use Darcy’s model.
文摘The propagation of electromagnetic waves in the annular region of oil wells was studied. The present study aims to analyse the propagation attenuation along the well, as well as the input impedance determined by a source placed near the wellhead. A coaxial waveguide model was adopted with heterogeneous dielectrics and losses. First, a wave equation solution for the waveguide is presented, assuming a homogeneous medium with losses, by solving the equation in cylindrical coordinates using the vector potential technique. An uncertainty analysis model is then developed to model the heterogeneous characteristics of the medium. Monte Carlo simulations were performed with the created model using data gathered from the literature. The results of the simulations indicate that propagation in the transverse electromagnetic mode has the smallest attenuation and that for depths of up to 4000 m, there is an attenuation of less than 52 dB. Furthermore, the input impedance ranges from 10 Ω to 10 kΩ because of the uncertainties involved in the problem in question.