Tight sandstone reservoirs are widely developed in the Mesozoic Yanchang Formation of the Ordos Basin,China.There is a lack of understanding on the sedimentary setting,source-reservoir relationship and oil accumulatio...Tight sandstone reservoirs are widely developed in the Mesozoic Yanchang Formation of the Ordos Basin,China.There is a lack of understanding on the sedimentary setting,source-reservoir relationship and oil accumulation conditions in this area.In this study,through the comprehensive analysis of the distri-bution of tight oil,we evaluated the properties and petrological features of reservoir,geochemical characteristics of source rocks,the source-reservoir relationship,as well as the trapping,preservation and accumulation conditions of tight oil in the Chang 7 Member,and predicted the sweet spots of tight oil in the study area.The results show that the Chang 7 Member is a typical low-porosity and ultra-low permeability reservoir with great tightness,small pore throat and high capillary pressure,and must have been of near-source accumulation.The source rocks are mainly developed in the Chang 7_(3) submember,and the reservoirs mainly occur in the Chang 7_(1) and Chang 7_(2) submembers,forming a combination mode of“lower source rock and upper reservoir”.Sandbodies with good connectivity and fractures being well developed in local areas are the main hydrocarbon transport systems.The abnormal high pressure caused by hydrocarbon generation and pressurization is the main driving force of tight oil accumulation.The mode of hydrocarbon transportation is dominated by the vertical or lateral migration from under-lying source rocks or adjacent source rocks to reservoirs within a short distance.Following the integrated evaluation of lithology,physical properties and oil saturation of reservoirs and geochemical character-istics of source rocks,we grouped the sweet spots of Chang 7 Member into three types:Type I,Type II and Type III.Among others,the Type I sweet spots are the best in terms of porosity,permeability and source rock thickness and hydrocarbon enrichment which should be the focus of oilfield development.This study lays an important foundation for the economic and efficient development of tight oil in the Chang 7 Member of Heshui area,and has important implications on tight sandstone reservoirs in other regions of Ordos Basin in China.展开更多
Successful breakthroughs have been made in shale oil exploration in several lacustrine basins in China,indicating a promising future for shale oil exploration and production.Current exploration results have revealed t...Successful breakthroughs have been made in shale oil exploration in several lacustrine basins in China,indicating a promising future for shale oil exploration and production.Current exploration results have revealed the following major conditions of lacustrine shale oil accumulation:(1)stable and widely distributed shale with a high organic abundance and appropriate thermal maturity acts as a fundamental basis for shale oil retention.This shale exhibits several critical parameters,such as total organic carbon content greater than 2%,with optimal values ranging from 3% to 4%,kerogen Ⅰ and Ⅱ_(1) as the dominant organic matter types,and vitrinite reflectance(R_(o))values greater than 0.9%(0.8% for brackish water environments).(2)Various types of reservoirs exhibiting brittleness and a certain volume of micro-nanoscale pores are critical conditions for shale oil accumulation,and these reservoirs have porosities greater than 3% to 6%.Moreover,when diagenesis is incipient,pure shales are not favorable for medium-to-high maturity shale oil enrichment,whereas tight sandstone and hybrid rocks with clay content less than 20% are favorable;however,for medium-to-late-stage diagenesis,pure shales with a clay content of 40% are favorable.(3)The retention of a large amount of high-quality hydrocarbons is the factor that best guarantees shale oil accumulation with good mobility.Free hydrocarbon content exceeding a threshold value of 2 mg/g is generally required,and the optimum value is 4 mg/g to 6 mg/g.Moreover,a gas-oil ratio exceeding a threshold value of 80 m^(3)/m^(3) is required,with the optimal value ranging from 150 m^(3)/m^(3) to 300 m^(3)/m^(3).(4)High-quality roof and floor sealing conditions are essential for the shale oil enrichment interval to maintain the overpressure and retain a sufficient amount of hydrocarbons with good quality.Lacustrine shale oil distributions exhibit the following characteristics:(1)major enrichment areas of shale oil are located in semi-deep to deep lacustrine depositional areas with external materials,such as volcanic ash fallout,hydrothermal solutions,and radioactive substances with catalytic action,as inputs;(2)intervals with“four high values and one preservation condition”govern the distribution of shale oil enrichment intervals;and(3)favorable assemblages of lithofacies/lithologies determine the distribution of enrichment area.According to preliminary estimates,China has 131×10^(8) to 163×10^(8) t of total shale oil resources with medium-to-high thermal maturity,among which 67×10^(8) to 84×10^(8) t is commercial.These resources are primarily located in the Chang 7^(1+2) interval in the Ordos Basin,Qing 1+2 members in Gulong sag in the Songliao Basin,Kongdian and Shahejie formations of Cangdong sag,Qikou sag and the Jiyang depression in the Bohai Bay Basin,and Lucaogou Formation in the Junggar Basin.展开更多
This article deals with the biochemical characteristics of varieties of Saint Mary’s Thistle such as Panacea, Debut and Samaryanka. Based on the studies, it was found that the highest oil content was found in the spe...This article deals with the biochemical characteristics of varieties of Saint Mary’s Thistle such as Panacea, Debut and Samaryanka. Based on the studies, it was found that the highest oil content was found in the species Debut (26%). <span style="font-family:Verdana;">The lowest oil content was observed in the variety </span><span style="font-family:Verdana;">Samaryanka</span><span style="font-family:Verdana;"> (19%). The highest protein content and the sum of total amino acids in the seeds of St. Mary’s Thistle varieties were found in the variety Debut (131.1), and the lowest indication was observed in the species Samaryanka (79.2). By the number of replaceable amino acids existing in the seeds of the species of St. Mary’s Thistle, it was found in the Varieties Debut (126.3), and the lowest indication was observed in the variety Samaryanka (112). Based on the results of studies and the noted biochemical characteristics and varietal differences of the St. Mary’s Thistle, the possibility and expediency of expanding the crops of this species in the soil and climatic conditions of the Khorezm region are suggested. The research was conducted 2017-2019 y.</span>展开更多
Because the U.S.is a major player in the international oil market,it is interesting to study whether aggregate and state-level economic conditions can predict the subse-quent realized volatility of oil price returns.T...Because the U.S.is a major player in the international oil market,it is interesting to study whether aggregate and state-level economic conditions can predict the subse-quent realized volatility of oil price returns.To address this research question,we frame our analysis in terms of variants of the popular heterogeneous autoregressive realized volatility(HAR-RV)model.To estimate the models,we use quantile-regression and quantile machine learning(Lasso)estimators.Our estimation results highlights the dif-ferential effects of economic conditions on the quantiles of the conditional distribution of realized volatility.Using weekly data for the period April 1987 to December 2021,we document evidence of predictability at a biweekly and monthly horizon.展开更多
The effect of packaging materials and lighting conditions on quality of extra virgin olive oil (EVOO) was investigated during six months. The results highlighted an influence of light and type of packaging material ...The effect of packaging materials and lighting conditions on quality of extra virgin olive oil (EVOO) was investigated during six months. The results highlighted an influence of light and type of packaging material on EVOO-quality with storage time. At shelf, all packages maintained EVOO at the end of storage in terms of acidity, peroxide value, K232, while K270 exceeded limit of EVOO in glass and PET-stored oil. Loss of phenols was the highest in glass-stored oil and the lowest in high-density polyethylene (HDPE)-stored oil. In terms of sensory evaluation, glass-stored oil lost EVOO grade after three months and its edible compliance after six months, while HDPE-stored oil maintained EVOO grade 90 days and was virgin after six months. In extended lighting, acidity, peroxide value and K232 did not exceed EVOO grade, while K270 exceeded EVOO grade after 30 days in glass and polyethylene terephthalate (PET)-stored oil and after 90 days in HDPE. The loss of phenols was the largest in glass and smallest in HDPE-stored oil. Glass stored-oil lost organoleptic edible compliance before 90 days, while that in PET was virgin at 90 days and that in HDPE maintained EVOO quality 90 days. At the end of experiment, oils in all packages were not edible. In dark, all packages maintained oil in EVOO quality in terms of all indices. The loss of phenols was marginal but was the least in glass and the highest in HDPE. It was concluded that HDPE bottles conserve stored olive oil at shelf or illumination better than PET or glass, while in dark, glass was superior over plastic.展开更多
[Objectives]To explore the extraction conditions of essential oil from eucalyptus leaves.[Methods]The essential oil of eucalyptus leaves was extracted by steam distillation,and the yields of essential oil from eucalyp...[Objectives]To explore the extraction conditions of essential oil from eucalyptus leaves.[Methods]The essential oil of eucalyptus leaves was extracted by steam distillation,and the yields of essential oil from eucalyptus leaves under different extraction times,soaking times and different solid-liquid ratios were analyzed through orthogonal test with three factors and three variables.[Results]The effects of various factors on extraction results were:distillation time>solid-liquid ratio>soaking time.When the extraction time and soaking time were 1.5 and 2 h,and the solid-liquid ratio of eucalyptus leaves to distilled water was 1:10,the yield of essential oil was the highest(0.8%).The yield of essential oil increased with the increase of extraction and soaking time,but when reaching the optimal value,the yield decreased with the extension of time.Increasing the solid-liquid ratio can improve the yield of essential oil,but beyond a certain value the yield increased gradually while the cost performance decreased.[Conclusions]The results will provide some reference for the recovery and utilization of eucalyptus leaves.展开更多
Medicinal plants provide an important source of cure since ancient time. Poor soil resources, scarce and saline water and the harsh environment limited the production of plants in the Arabian Gulf countries. This stud...Medicinal plants provide an important source of cure since ancient time. Poor soil resources, scarce and saline water and the harsh environment limited the production of plants in the Arabian Gulf countries. This study aimed to investigate the production potential of rosemary (Rosmarinus officinalis L.) grown on different growth media under greenhouse conditions. Three growth media agricultural soil, compost and hydroponic system were used, whereas tuff (inert volcanic material) was used as substrate. The result indicated that the high salinity of the agricultural soil limited growth and oil yield in rosemary. Shoot height increased in 11 weeks, by 62%, 65% and 114% in plants grown in agricultural soil, hydroponic system and compost, respectively. Na content in plants grown in agricultural soil was significantly higher than in plants grown in the other treatment. Essential oil yield in plants grown in compost exceeded those in agricultural soil by 114%. Essential oil content (0.66%-1.5% w/w) and chemical constituents concentrations did not change significantly with growth media. The main constituents, more or less, are comparable to essential oils constituents reported from other countries. In comparison, better yields are obtained for individual components of the oils of plants grown under our green house conditions. This study demonstrated the great potential of commercial production of rosemary in the greenhouse without compromising the oil quality and oil yield.展开更多
Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging inform...Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.展开更多
Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs, two kinds of natural ga...Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs, two kinds of natural gases with different relationships between C2/C3 and C1/C2, C2/C3 and C1/C3, C2/C3 and 100×C1/(C1-C5) were identified in the Tarim Basin, and proposed further by the authors. The relationship charts of C2/C3 and C1/C2, C2/C3 and C1/C3, C2/C3 and 100×C1/(C1-C5) can be used to effectively distinguish oil-cracking gas from kerogen-cracking gas. Petro-leum geological analysis of the oil-cracking gas reservoirs showed that the distribution of oil-cracking gas is mostly related with deep-seated faults or faults with a large fault throw, and the burial depth of paleo-oil reservoir is rela-tively high; crude oil-cracking gas resources have been evaluated by using both forward and inversion methods. The plots of C2/C3 vs. C1/C2, C2/C3 vs. C1/C3, and C2/C3 vs. 100×C1/(C1-C5) were used to distinguish between oil-crack-ing gas and kerogen-cracking gas, and estimate the mixed ratios of the two kinds of natural gases in the main gas reservoirs of the platform area.展开更多
This study dealt with the rhythmic Qian 3410 of the intersalt shale series in the Qianjiang Depression,in which the geological condition for oil accumulation in the rhythmic shale was investigated by using the basic d...This study dealt with the rhythmic Qian 3410 of the intersalt shale series in the Qianjiang Depression,in which the geological condition for oil accumulation in the rhythmic shale was investigated by using the basic drilling,core and well logging data,as well as data obtained from the thin section identification,SEM,mercury injection,X-ray diffraction and rock freezing heat analyses.The study result indicated that:1)the intersalt shale series are characterized by TOC in a range of 0.35%-6.38%(averaging 3.19%),Types I and II1 organic matter,and from immature to mature oil,indicative of a potential for generating a great volume of immature oil;2)in the target layer,mineral compositions are complicated,which can divide into argillaceous dolomite facies,argillaceous limestone facies,dolomitic mudstone facies,and calcium-mirabilite-filling dolomitic mudstone facies;and 3)of them,the argillaceous dolomite facies is the most contributory,with reservoir spaces consisting of intergranular pores as dominant,as well as rare dissolution pores and seams.It is characterized by high organic abundance(4.23%-6.38%),high content of brittle mineral(50%-71%),low content of clay mineral(18%-33%),high porosity(10.8%-26.3%)and good oil-bearing properties(S1 distributed in 3.48-5.64 mg/g,and S1/TOC value in a range of 348-564 oil mg/g).Therefore,the argillaceous dolomite facies was considered the key target series to be explored for the intersalt shale oil in the study area in the coming days.展开更多
Oil, protein and starch are key chemical components of maize kernels. A population of 245 recombinant inbred lines(RILs) derived from a cross between a high-oil inbred line, By804, and a regular inbred line, B73, was ...Oil, protein and starch are key chemical components of maize kernels. A population of 245 recombinant inbred lines(RILs) derived from a cross between a high-oil inbred line, By804, and a regular inbred line, B73, was used to dissect the genetic interrelationships among oil, starch and protein content at the individual QTL level by unconditional and conditional QTL mapping. Combined phenotypic data over two years with a genetic linkage map constructed using 236 markers, nine, five and eight unconditional QTL were detected for oil, protein and starch content, respectively. Some QTL for oil, protein and starch content were clustered in the same genomic regions and the direction of their effects was consistent with the sign of their correlation. In conditional QTL mapping, 37(29/8) unconditional QTL were not detected or showed reduced effects, four QTL demonstrated similar effects under unconditional and conditional QTL mapping, and 17 additional QTL were identified by conditional QTL mapping. These results imply that there is a strong genetic relationship among oil, protein and starch content in maize kernels. The information generated in the present investigation could be helpful in marker-assisted breeding for maize varieties with desirable kernel quality traits.展开更多
Electromotor on oil platform often has mechanical failures.In order to achieve monitoring and diagnosis of the electromotor,common diagnostic methods of electromotor are summarized first,and then vibration monitoring ...Electromotor on oil platform often has mechanical failures.In order to achieve monitoring and diagnosis of the electromotor,common diagnostic methods of electromotor are summarized first,and then vibration monitoring is regarded as a suitable method for monitoring and diagnosing of mechanical failures by comparing the advantages and disadvantages of each method and characteristics of mechanical faults.At last,the fault frequencies and arrangements of vibration measuring points are analyzed.By using vibration monitoring method,the diagnosis of bearing faults of electromotor is carried out.The results show that the analysis of condition monitoring methods for electromotor is meanning for machine maintenance and repair,and it lays foundation for computerized repair system and resource management system.展开更多
Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, f...Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, for the first time. The obtained characterization results of the prepared materials reveal that in-situ addition of Ti into AlSi shows ordered mesoporous structure along with uniformly dispersed Ti species in +4 and +3 oxidation states suitable for selective oxidation of allylic C—H bond. The prepared mesoporouse Ti-AlSi(n) samples exhibited excellent activity in the oxidation of cyclohexene with 100%conversion and 100% selectivity to ketone-alcohol(KA) oil(cyclohex-2-en-1-ol and 2-cyclohexen-1-one) at low temperature and reaction time(35℃ and 30 min reaction time). This study suggests that AlSi-Ti(0.05) material can be a promising catalyst for the selective oxidation of cyclohexene under mild reaction conditions.展开更多
Increase in requirement of hydrosulphuric water for improvement of the population set the task of identification of places of their possible congestion for hydrogeological service. Earlier detection of such congestion...Increase in requirement of hydrosulphuric water for improvement of the population set the task of identification of places of their possible congestion for hydrogeological service. Earlier detection of such congestions was accidental at well-drilling of different function. Therefore, development of new methodical approaches of search and allocation of perspective zones of their formation was required. It was for this purpose necessary to study in what conditions and what factors have an impact on formation of underground hydrosulphuric water. So far, definition of communication attempts only with separate geochemical signs was known. Results of studying of influence on formations of hydrosulphuric water of such factors as lithologic and facial in combination with oil-and-gas content, the geological and structural and hydrodynamic mode are given in this work. It is established that the main sign for formation of hydrosulphuric water is existence of evaporite thickness and hydrocarbon congestions. Besides, it is shown that small depth (up to 2 km) of their bedding has to be an indispensable condition and existence of explosive violation on which there has to be a water infiltration (a geological and structural factor). In the Surkhandarya region, the hydrodynamic mode caused by inclined bedding of aquifers was also one of essential factors. Active water is an exchange process with washing away (oxidation) sulfate of the containing thicknesses and subsequently, its restoration in interaction with hydrocarbons with formation of hydrosulphuric water is described. The technique is developed and the expected card of perspective zones of formation of hydrosulphuric water is constructed.展开更多
To improve the start-up speed and efficiency of bioreactors, biofilm technology is sometimes used. This technology uses various types of materials to facilitate the adhesion of microorganisms. In this study, the surfa...To improve the start-up speed and efficiency of bioreactors, biofilm technology is sometimes used. This technology uses various types of materials to facilitate the adhesion of microorganisms. In this study, the surface characteris<span style="font-family:Verdana;">tics of inert substrates and substrates after olive oil-mill wastewater (OMWW)</span><span style="font-family:Verdana;"> conditioning film were evaluated to understand the impact of OMWW on adhesion as well as the most suitable material to optimize bacterial adhesion. Three common substrates made of different polymers were tested for bacterial adhesion before and after treatment with OMWW: PP (polypropylene), PET (Polyethylene terephthalate), and PVC (polyvinyl chloride). The </span><span style="font-family:Verdana;">surfaces’ physicochemical characteristics were studied by measuring the contact angle for the studied bacteria strain and the supports, before and after treatment with OMWW. Results of initial adhesion tests for untreated and treated supports showed differences in how bacterial cells adhered to substrates. Before treatment with OMWW, PVC and then PP showed a significant adhesion capacity, double that of PET [PVC: 1.58</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">, PP: 1.48</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> and PET: 0.72</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">]. After treatment with OMWW, initial bacterial adhesion increased by 10</span><sup><span style="font-family:Verdana;">6</span></sup><span style="font-family:Verdana;"> (from 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> for untreated supports to 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> for treated supports), and PET followed by PP demonstrated the highest adhesion capacity, 2 and 1.7 times more than PVC, respectively [PET: 1.39</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">, PP: 1.15</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> and PVC: 0.67</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">].</span><a name="_Hlk36219009"></a><span style="font-family:Verdana;"> OMWW conditioning film affects the physicochemical characteristics of plastic supports, especially the donor electron character, and improves the initial adhesion of bacteria to substrates (10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> to 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">). Therefore, surfaces’ physicochemical characteristics were important in the initial adhesion of the bacteria onto the support before and after treatment.</span></span>展开更多
The bearings in the trunnion of convertor are characterized by low-speed, heavy-load and huge-dimension. In case they experience failure in operation, the output of the convertor and even that of the whole product lin...The bearings in the trunnion of convertor are characterized by low-speed, heavy-load and huge-dimension. In case they experience failure in operation, the output of the convertor and even that of the whole product line would be affected and the huge loss would be resulted in. Thus it is very important to master the working conditions of the bearings. Vibration and oil analysis are two main techniques to monitor the conditions of the rotary machine at present. But normal vibration analysis cannot be used here because of the limitation of their sensors in signal collecting for the rotary frequencies of the bearings are too low. In this paper, the wear condition of the bearing on the driving side of the No.5 convertor during/after the run-in period was monitored through oil analysis including atomic emissive spectrum and ferrography. It has been observed that its run-in period was as long as 19 months. This is mainly attributed to the relative short accumulated working time of the bearing.展开更多
Xin’anbian Oilfield of the Ordos Basin is the large tight oilfield to be first exploration discovery in china.The production of tight oil increased significantly in recent years.It shows great exploration potential o...Xin’anbian Oilfield of the Ordos Basin is the large tight oilfield to be first exploration discovery in china.The production of tight oil increased significantly in recent years.It shows great exploration potential of Chang 7 tight oil.But the physical property and hydrocarbon enrichment characteristics of Chang 7 tight oil reservoirs were rarely studied,The forming conditions of tight oil reservoirs are systematically summarized and analyzed through the study of hydrocarbon generation,sedimentary reservoirs and hydrocarbon migration and accumulation based on production and core experimental data.The result shows that,The porosity of the Chang 7_(2)reservoir mainly distributed in 5.0-11.0%,average at 7.9%,The permeability mainly distributed in 0.04-0.18×10^(-3)μm^(2),average at 0.12×10^(-3)μm^(2),The pore diameters of the tight oil reservoir distributed in 2-8μm.The high-quality Chang 7_(3)source rocks and the micropsammite of Chang 7_(2)subaqueous distributary channel were widely distributed in the study area.The lenticular or banded sand bodies are distributed among mudstone or hydrocarbon source rocks and have the advantage of migration distance for hydrocarbon accumulation.The reservoir space is composed of micro-nanometer pores and throat,that is formed in the process of increasing pressure during hydrocarbon generation and hydrocarbon accumulation.The Chang 7 tight oil was generated in the early Cretaceous and injected into the sand of the subaqueous distributary channel driven by continuous hydrocarbon generation supercharging.The formation and accumulation of tight oil reservoirs are mainly controlled by source rocks,sedimentary microfacies and reservoirs of good quality.展开更多
It is a challenge to conserve energy for the large-scale petrochemical enterprises due to complex production process and energy diversification. As critical energy consumption equipment of atmospheric distillation oil...It is a challenge to conserve energy for the large-scale petrochemical enterprises due to complex production process and energy diversification. As critical energy consumption equipment of atmospheric distillation oil refining process, the atmospheric distillation column is paid more attention to save energy. In this paper, the optimal problem of energy utilization efficiency of the atmospheric distillation column is solved by defining a new energy efficiency indicator - the distillation yield rate of unit energy consumption from the perspective of material flow and energy flow, and a soft-sensing model for this new energy efficiency indicator with respect to the multiple working conditions and intelligent optimizing control strategy are suggested for both increasing distillation yield and decreasing energy consumption in oil refining process. It is found that the energy utilization efficiency level of the atmospheric distillation column depends closely on the typical working conditions of the oil refining process, which result by changing the outlet temperature, the overhead temperature, and the bottom liquid level of the atmospheric pressure tower. The fuzzy C-means algorithm is used to classify the typical operation conditions of atmospheric distillation in oil refining process. Furthermore, the LSSVM method optimized with the improved particle swarm optimization is used to model the distillation rate of unit energy consumption. Then online optimization of oil refining process is realized by optimizing the outlet temperature, the overhead temperature with IPSO again. Simulation comparative analyses are made by empirical data to verify the effectiveness of the proposed solution.展开更多
The major enrichment type of shale oil in the Chang 7_(3) shale of Upper Triassic Yanchang Formation in the Ordos Basin is unknown.This paper analyzes the organic matter transformation ratio,hydrocarbon expulsion effi...The major enrichment type of shale oil in the Chang 7_(3) shale of Upper Triassic Yanchang Formation in the Ordos Basin is unknown.This paper analyzes the organic matter transformation ratio,hydrocarbon expulsion efficiency and roof/floor sealing conditions of the Chang 7_(3) shale,and evaluates the major enrichment type of shale oil in this interval.The average organic matter transformation ratio of the Chang 7_(3) shale is about 45%;in other words,more than 50%of the organic matters have not transformed to hydrocarbons,and the lower the maturity,the greater the proportion of untransformed organic matters.The cumulative hydrocarbon expulsion efficiency of the transformed hydrocarbon is 27.5% on average,and the total proportion of untransformed organic matters plus retained hydrocarbons is greater than 70%.The relative hydrocarbon expulsion efficiency of the Chang 7_(3) shale is 60%on average,that is,about 40% of hydrocarbons retain in the shale.The Chang 7_(3) shale corresponds to Chang 7_(1+2) and Chang 8 sandstones as the roof and floor,respectively,and is further overlaid by Chang 6 shale,where extensive low porosity and low permeability–tight oil reservoirs have formed in the parts with relatively good porosity and permeability.Moreover,the Chang 7_(3) shale is tested to be in a negative pressure system(the pressure coefficient of 0.80–0.85).Therefore,the roof/floor sealing conditions of the Chang 7_(3) shale are poor.The retained hydrocarbons appear mostly in absorbed status,with low mobility.It is concluded that the medium–high mature shale oil is not the major enrichment type of shale oil in the Chang 7_(3) shale,but there may be enrichment opportunity for shale oil with good mobility in the areas where the sealing conditions are good without faults and fractures and oil reservoirs are formed off Chang 7_(1+2),Chang 6 and Chang 8.Furthermore,low–medium mature shale oil is believed to have great potential and is the major enrichment type of shale oil in the Chang 7_(3) shale.It is recommended to prepare relevant in-situ conversion technologies by pilot test and figure out the resource availability and distribution.展开更多
基金This work was supported by PetroChina Innovation Foundation(No.2020D-5007-0202)Opening Foundation of State Key Laboratory of Continental Dynamics,Northwest University(No.20LCD09).
文摘Tight sandstone reservoirs are widely developed in the Mesozoic Yanchang Formation of the Ordos Basin,China.There is a lack of understanding on the sedimentary setting,source-reservoir relationship and oil accumulation conditions in this area.In this study,through the comprehensive analysis of the distri-bution of tight oil,we evaluated the properties and petrological features of reservoir,geochemical characteristics of source rocks,the source-reservoir relationship,as well as the trapping,preservation and accumulation conditions of tight oil in the Chang 7 Member,and predicted the sweet spots of tight oil in the study area.The results show that the Chang 7 Member is a typical low-porosity and ultra-low permeability reservoir with great tightness,small pore throat and high capillary pressure,and must have been of near-source accumulation.The source rocks are mainly developed in the Chang 7_(3) submember,and the reservoirs mainly occur in the Chang 7_(1) and Chang 7_(2) submembers,forming a combination mode of“lower source rock and upper reservoir”.Sandbodies with good connectivity and fractures being well developed in local areas are the main hydrocarbon transport systems.The abnormal high pressure caused by hydrocarbon generation and pressurization is the main driving force of tight oil accumulation.The mode of hydrocarbon transportation is dominated by the vertical or lateral migration from under-lying source rocks or adjacent source rocks to reservoirs within a short distance.Following the integrated evaluation of lithology,physical properties and oil saturation of reservoirs and geochemical character-istics of source rocks,we grouped the sweet spots of Chang 7 Member into three types:Type I,Type II and Type III.Among others,the Type I sweet spots are the best in terms of porosity,permeability and source rock thickness and hydrocarbon enrichment which should be the focus of oilfield development.This study lays an important foundation for the economic and efficient development of tight oil in the Chang 7 Member of Heshui area,and has important implications on tight sandstone reservoirs in other regions of Ordos Basin in China.
基金Major Project of National Natural Science Foundation of China(42090020,42090025)Major Project of CNPC(2019E-2601)。
文摘Successful breakthroughs have been made in shale oil exploration in several lacustrine basins in China,indicating a promising future for shale oil exploration and production.Current exploration results have revealed the following major conditions of lacustrine shale oil accumulation:(1)stable and widely distributed shale with a high organic abundance and appropriate thermal maturity acts as a fundamental basis for shale oil retention.This shale exhibits several critical parameters,such as total organic carbon content greater than 2%,with optimal values ranging from 3% to 4%,kerogen Ⅰ and Ⅱ_(1) as the dominant organic matter types,and vitrinite reflectance(R_(o))values greater than 0.9%(0.8% for brackish water environments).(2)Various types of reservoirs exhibiting brittleness and a certain volume of micro-nanoscale pores are critical conditions for shale oil accumulation,and these reservoirs have porosities greater than 3% to 6%.Moreover,when diagenesis is incipient,pure shales are not favorable for medium-to-high maturity shale oil enrichment,whereas tight sandstone and hybrid rocks with clay content less than 20% are favorable;however,for medium-to-late-stage diagenesis,pure shales with a clay content of 40% are favorable.(3)The retention of a large amount of high-quality hydrocarbons is the factor that best guarantees shale oil accumulation with good mobility.Free hydrocarbon content exceeding a threshold value of 2 mg/g is generally required,and the optimum value is 4 mg/g to 6 mg/g.Moreover,a gas-oil ratio exceeding a threshold value of 80 m^(3)/m^(3) is required,with the optimal value ranging from 150 m^(3)/m^(3) to 300 m^(3)/m^(3).(4)High-quality roof and floor sealing conditions are essential for the shale oil enrichment interval to maintain the overpressure and retain a sufficient amount of hydrocarbons with good quality.Lacustrine shale oil distributions exhibit the following characteristics:(1)major enrichment areas of shale oil are located in semi-deep to deep lacustrine depositional areas with external materials,such as volcanic ash fallout,hydrothermal solutions,and radioactive substances with catalytic action,as inputs;(2)intervals with“four high values and one preservation condition”govern the distribution of shale oil enrichment intervals;and(3)favorable assemblages of lithofacies/lithologies determine the distribution of enrichment area.According to preliminary estimates,China has 131×10^(8) to 163×10^(8) t of total shale oil resources with medium-to-high thermal maturity,among which 67×10^(8) to 84×10^(8) t is commercial.These resources are primarily located in the Chang 7^(1+2) interval in the Ordos Basin,Qing 1+2 members in Gulong sag in the Songliao Basin,Kongdian and Shahejie formations of Cangdong sag,Qikou sag and the Jiyang depression in the Bohai Bay Basin,and Lucaogou Formation in the Junggar Basin.
文摘This article deals with the biochemical characteristics of varieties of Saint Mary’s Thistle such as Panacea, Debut and Samaryanka. Based on the studies, it was found that the highest oil content was found in the species Debut (26%). <span style="font-family:Verdana;">The lowest oil content was observed in the variety </span><span style="font-family:Verdana;">Samaryanka</span><span style="font-family:Verdana;"> (19%). The highest protein content and the sum of total amino acids in the seeds of St. Mary’s Thistle varieties were found in the variety Debut (131.1), and the lowest indication was observed in the species Samaryanka (79.2). By the number of replaceable amino acids existing in the seeds of the species of St. Mary’s Thistle, it was found in the Varieties Debut (126.3), and the lowest indication was observed in the variety Samaryanka (112). Based on the results of studies and the noted biochemical characteristics and varietal differences of the St. Mary’s Thistle, the possibility and expediency of expanding the crops of this species in the soil and climatic conditions of the Khorezm region are suggested. The research was conducted 2017-2019 y.</span>
文摘Because the U.S.is a major player in the international oil market,it is interesting to study whether aggregate and state-level economic conditions can predict the subse-quent realized volatility of oil price returns.To address this research question,we frame our analysis in terms of variants of the popular heterogeneous autoregressive realized volatility(HAR-RV)model.To estimate the models,we use quantile-regression and quantile machine learning(Lasso)estimators.Our estimation results highlights the dif-ferential effects of economic conditions on the quantiles of the conditional distribution of realized volatility.Using weekly data for the period April 1987 to December 2021,we document evidence of predictability at a biweekly and monthly horizon.
文摘The effect of packaging materials and lighting conditions on quality of extra virgin olive oil (EVOO) was investigated during six months. The results highlighted an influence of light and type of packaging material on EVOO-quality with storage time. At shelf, all packages maintained EVOO at the end of storage in terms of acidity, peroxide value, K232, while K270 exceeded limit of EVOO in glass and PET-stored oil. Loss of phenols was the highest in glass-stored oil and the lowest in high-density polyethylene (HDPE)-stored oil. In terms of sensory evaluation, glass-stored oil lost EVOO grade after three months and its edible compliance after six months, while HDPE-stored oil maintained EVOO grade 90 days and was virgin after six months. In extended lighting, acidity, peroxide value and K232 did not exceed EVOO grade, while K270 exceeded EVOO grade after 30 days in glass and polyethylene terephthalate (PET)-stored oil and after 90 days in HDPE. The loss of phenols was the largest in glass and smallest in HDPE-stored oil. Glass stored-oil lost organoleptic edible compliance before 90 days, while that in PET was virgin at 90 days and that in HDPE maintained EVOO quality 90 days. At the end of experiment, oils in all packages were not edible. In dark, all packages maintained oil in EVOO quality in terms of all indices. The loss of phenols was marginal but was the least in glass and the highest in HDPE. It was concluded that HDPE bottles conserve stored olive oil at shelf or illumination better than PET or glass, while in dark, glass was superior over plastic.
基金Supported by Doctoral Start-up Fund of Guangxi Minzu Normal University(2021 BS003).
文摘[Objectives]To explore the extraction conditions of essential oil from eucalyptus leaves.[Methods]The essential oil of eucalyptus leaves was extracted by steam distillation,and the yields of essential oil from eucalyptus leaves under different extraction times,soaking times and different solid-liquid ratios were analyzed through orthogonal test with three factors and three variables.[Results]The effects of various factors on extraction results were:distillation time>solid-liquid ratio>soaking time.When the extraction time and soaking time were 1.5 and 2 h,and the solid-liquid ratio of eucalyptus leaves to distilled water was 1:10,the yield of essential oil was the highest(0.8%).The yield of essential oil increased with the increase of extraction and soaking time,but when reaching the optimal value,the yield decreased with the extension of time.Increasing the solid-liquid ratio can improve the yield of essential oil,but beyond a certain value the yield increased gradually while the cost performance decreased.[Conclusions]The results will provide some reference for the recovery and utilization of eucalyptus leaves.
文摘Medicinal plants provide an important source of cure since ancient time. Poor soil resources, scarce and saline water and the harsh environment limited the production of plants in the Arabian Gulf countries. This study aimed to investigate the production potential of rosemary (Rosmarinus officinalis L.) grown on different growth media under greenhouse conditions. Three growth media agricultural soil, compost and hydroponic system were used, whereas tuff (inert volcanic material) was used as substrate. The result indicated that the high salinity of the agricultural soil limited growth and oil yield in rosemary. Shoot height increased in 11 weeks, by 62%, 65% and 114% in plants grown in agricultural soil, hydroponic system and compost, respectively. Na content in plants grown in agricultural soil was significantly higher than in plants grown in the other treatment. Essential oil yield in plants grown in compost exceeded those in agricultural soil by 114%. Essential oil content (0.66%-1.5% w/w) and chemical constituents concentrations did not change significantly with growth media. The main constituents, more or less, are comparable to essential oils constituents reported from other countries. In comparison, better yields are obtained for individual components of the oils of plants grown under our green house conditions. This study demonstrated the great potential of commercial production of rosemary in the greenhouse without compromising the oil quality and oil yield.
文摘Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.
基金the National Natural Science Foundation of China (Grant No. 40973041)
文摘Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs, two kinds of natural gases with different relationships between C2/C3 and C1/C2, C2/C3 and C1/C3, C2/C3 and 100×C1/(C1-C5) were identified in the Tarim Basin, and proposed further by the authors. The relationship charts of C2/C3 and C1/C2, C2/C3 and C1/C3, C2/C3 and 100×C1/(C1-C5) can be used to effectively distinguish oil-cracking gas from kerogen-cracking gas. Petro-leum geological analysis of the oil-cracking gas reservoirs showed that the distribution of oil-cracking gas is mostly related with deep-seated faults or faults with a large fault throw, and the burial depth of paleo-oil reservoir is rela-tively high; crude oil-cracking gas resources have been evaluated by using both forward and inversion methods. The plots of C2/C3 vs. C1/C2, C2/C3 vs. C1/C3, and C2/C3 vs. 100×C1/(C1-C5) were used to distinguish between oil-crack-ing gas and kerogen-cracking gas, and estimate the mixed ratios of the two kinds of natural gases in the main gas reservoirs of the platform area.
基金funded by the 2018 Undergraduate Training Program for Innovation and Entrepreneurship of Yangtze University,the project number is 2018267.
文摘This study dealt with the rhythmic Qian 3410 of the intersalt shale series in the Qianjiang Depression,in which the geological condition for oil accumulation in the rhythmic shale was investigated by using the basic drilling,core and well logging data,as well as data obtained from the thin section identification,SEM,mercury injection,X-ray diffraction and rock freezing heat analyses.The study result indicated that:1)the intersalt shale series are characterized by TOC in a range of 0.35%-6.38%(averaging 3.19%),Types I and II1 organic matter,and from immature to mature oil,indicative of a potential for generating a great volume of immature oil;2)in the target layer,mineral compositions are complicated,which can divide into argillaceous dolomite facies,argillaceous limestone facies,dolomitic mudstone facies,and calcium-mirabilite-filling dolomitic mudstone facies;and 3)of them,the argillaceous dolomite facies is the most contributory,with reservoir spaces consisting of intergranular pores as dominant,as well as rare dissolution pores and seams.It is characterized by high organic abundance(4.23%-6.38%),high content of brittle mineral(50%-71%),low content of clay mineral(18%-33%),high porosity(10.8%-26.3%)and good oil-bearing properties(S1 distributed in 3.48-5.64 mg/g,and S1/TOC value in a range of 348-564 oil mg/g).Therefore,the argillaceous dolomite facies was considered the key target series to be explored for the intersalt shale oil in the study area in the coming days.
基金supported by the National High Technology Research Program of China (No. 2012AA101104)
文摘Oil, protein and starch are key chemical components of maize kernels. A population of 245 recombinant inbred lines(RILs) derived from a cross between a high-oil inbred line, By804, and a regular inbred line, B73, was used to dissect the genetic interrelationships among oil, starch and protein content at the individual QTL level by unconditional and conditional QTL mapping. Combined phenotypic data over two years with a genetic linkage map constructed using 236 markers, nine, five and eight unconditional QTL were detected for oil, protein and starch content, respectively. Some QTL for oil, protein and starch content were clustered in the same genomic regions and the direction of their effects was consistent with the sign of their correlation. In conditional QTL mapping, 37(29/8) unconditional QTL were not detected or showed reduced effects, four QTL demonstrated similar effects under unconditional and conditional QTL mapping, and 17 additional QTL were identified by conditional QTL mapping. These results imply that there is a strong genetic relationship among oil, protein and starch content in maize kernels. The information generated in the present investigation could be helpful in marker-assisted breeding for maize varieties with desirable kernel quality traits.
文摘Electromotor on oil platform often has mechanical failures.In order to achieve monitoring and diagnosis of the electromotor,common diagnostic methods of electromotor are summarized first,and then vibration monitoring is regarded as a suitable method for monitoring and diagnosing of mechanical failures by comparing the advantages and disadvantages of each method and characteristics of mechanical faults.At last,the fault frequencies and arrangements of vibration measuring points are analyzed.By using vibration monitoring method,the diagnosis of bearing faults of electromotor is carried out.The results show that the analysis of condition monitoring methods for electromotor is meanning for machine maintenance and repair,and it lays foundation for computerized repair system and resource management system.
文摘Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, for the first time. The obtained characterization results of the prepared materials reveal that in-situ addition of Ti into AlSi shows ordered mesoporous structure along with uniformly dispersed Ti species in +4 and +3 oxidation states suitable for selective oxidation of allylic C—H bond. The prepared mesoporouse Ti-AlSi(n) samples exhibited excellent activity in the oxidation of cyclohexene with 100%conversion and 100% selectivity to ketone-alcohol(KA) oil(cyclohex-2-en-1-ol and 2-cyclohexen-1-one) at low temperature and reaction time(35℃ and 30 min reaction time). This study suggests that AlSi-Ti(0.05) material can be a promising catalyst for the selective oxidation of cyclohexene under mild reaction conditions.
文摘Increase in requirement of hydrosulphuric water for improvement of the population set the task of identification of places of their possible congestion for hydrogeological service. Earlier detection of such congestions was accidental at well-drilling of different function. Therefore, development of new methodical approaches of search and allocation of perspective zones of their formation was required. It was for this purpose necessary to study in what conditions and what factors have an impact on formation of underground hydrosulphuric water. So far, definition of communication attempts only with separate geochemical signs was known. Results of studying of influence on formations of hydrosulphuric water of such factors as lithologic and facial in combination with oil-and-gas content, the geological and structural and hydrodynamic mode are given in this work. It is established that the main sign for formation of hydrosulphuric water is existence of evaporite thickness and hydrocarbon congestions. Besides, it is shown that small depth (up to 2 km) of their bedding has to be an indispensable condition and existence of explosive violation on which there has to be a water infiltration (a geological and structural factor). In the Surkhandarya region, the hydrodynamic mode caused by inclined bedding of aquifers was also one of essential factors. Active water is an exchange process with washing away (oxidation) sulfate of the containing thicknesses and subsequently, its restoration in interaction with hydrocarbons with formation of hydrosulphuric water is described. The technique is developed and the expected card of perspective zones of formation of hydrosulphuric water is constructed.
文摘To improve the start-up speed and efficiency of bioreactors, biofilm technology is sometimes used. This technology uses various types of materials to facilitate the adhesion of microorganisms. In this study, the surface characteris<span style="font-family:Verdana;">tics of inert substrates and substrates after olive oil-mill wastewater (OMWW)</span><span style="font-family:Verdana;"> conditioning film were evaluated to understand the impact of OMWW on adhesion as well as the most suitable material to optimize bacterial adhesion. Three common substrates made of different polymers were tested for bacterial adhesion before and after treatment with OMWW: PP (polypropylene), PET (Polyethylene terephthalate), and PVC (polyvinyl chloride). The </span><span style="font-family:Verdana;">surfaces’ physicochemical characteristics were studied by measuring the contact angle for the studied bacteria strain and the supports, before and after treatment with OMWW. Results of initial adhesion tests for untreated and treated supports showed differences in how bacterial cells adhered to substrates. Before treatment with OMWW, PVC and then PP showed a significant adhesion capacity, double that of PET [PVC: 1.58</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">, PP: 1.48</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> and PET: 0.72</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">]. After treatment with OMWW, initial bacterial adhesion increased by 10</span><sup><span style="font-family:Verdana;">6</span></sup><span style="font-family:Verdana;"> (from 10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> for untreated supports to 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> for treated supports), and PET followed by PP demonstrated the highest adhesion capacity, 2 and 1.7 times more than PVC, respectively [PET: 1.39</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">, PP: 1.15</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> and PVC: 0.67</span></span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">× 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">].</span><a name="_Hlk36219009"></a><span style="font-family:Verdana;"> OMWW conditioning film affects the physicochemical characteristics of plastic supports, especially the donor electron character, and improves the initial adhesion of bacteria to substrates (10</span><sup><span style="font-family:Verdana;">5</span></sup><span style="font-family:Verdana;"> to 10</span><sup><span style="font-family:Verdana;">11</span></sup><span style="font-family:Verdana;"> CFU/cm</span><sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;">). Therefore, surfaces’ physicochemical characteristics were important in the initial adhesion of the bacteria onto the support before and after treatment.</span></span>
文摘The bearings in the trunnion of convertor are characterized by low-speed, heavy-load and huge-dimension. In case they experience failure in operation, the output of the convertor and even that of the whole product line would be affected and the huge loss would be resulted in. Thus it is very important to master the working conditions of the bearings. Vibration and oil analysis are two main techniques to monitor the conditions of the rotary machine at present. But normal vibration analysis cannot be used here because of the limitation of their sensors in signal collecting for the rotary frequencies of the bearings are too low. In this paper, the wear condition of the bearing on the driving side of the No.5 convertor during/after the run-in period was monitored through oil analysis including atomic emissive spectrum and ferrography. It has been observed that its run-in period was as long as 19 months. This is mainly attributed to the relative short accumulated working time of the bearing.
基金financially supported by the Chinese National Special Plan Project"Formation conditions,enrichment regularity and resource potential of tight oil”(No.2016ZX05046-001)。
文摘Xin’anbian Oilfield of the Ordos Basin is the large tight oilfield to be first exploration discovery in china.The production of tight oil increased significantly in recent years.It shows great exploration potential of Chang 7 tight oil.But the physical property and hydrocarbon enrichment characteristics of Chang 7 tight oil reservoirs were rarely studied,The forming conditions of tight oil reservoirs are systematically summarized and analyzed through the study of hydrocarbon generation,sedimentary reservoirs and hydrocarbon migration and accumulation based on production and core experimental data.The result shows that,The porosity of the Chang 7_(2)reservoir mainly distributed in 5.0-11.0%,average at 7.9%,The permeability mainly distributed in 0.04-0.18×10^(-3)μm^(2),average at 0.12×10^(-3)μm^(2),The pore diameters of the tight oil reservoir distributed in 2-8μm.The high-quality Chang 7_(3)source rocks and the micropsammite of Chang 7_(2)subaqueous distributary channel were widely distributed in the study area.The lenticular or banded sand bodies are distributed among mudstone or hydrocarbon source rocks and have the advantage of migration distance for hydrocarbon accumulation.The reservoir space is composed of micro-nanometer pores and throat,that is formed in the process of increasing pressure during hydrocarbon generation and hydrocarbon accumulation.The Chang 7 tight oil was generated in the early Cretaceous and injected into the sand of the subaqueous distributary channel driven by continuous hydrocarbon generation supercharging.The formation and accumulation of tight oil reservoirs are mainly controlled by source rocks,sedimentary microfacies and reservoirs of good quality.
基金Supported by the High-tech Research and Development Program of China(2014AA041802)
文摘It is a challenge to conserve energy for the large-scale petrochemical enterprises due to complex production process and energy diversification. As critical energy consumption equipment of atmospheric distillation oil refining process, the atmospheric distillation column is paid more attention to save energy. In this paper, the optimal problem of energy utilization efficiency of the atmospheric distillation column is solved by defining a new energy efficiency indicator - the distillation yield rate of unit energy consumption from the perspective of material flow and energy flow, and a soft-sensing model for this new energy efficiency indicator with respect to the multiple working conditions and intelligent optimizing control strategy are suggested for both increasing distillation yield and decreasing energy consumption in oil refining process. It is found that the energy utilization efficiency level of the atmospheric distillation column depends closely on the typical working conditions of the oil refining process, which result by changing the outlet temperature, the overhead temperature, and the bottom liquid level of the atmospheric pressure tower. The fuzzy C-means algorithm is used to classify the typical operation conditions of atmospheric distillation in oil refining process. Furthermore, the LSSVM method optimized with the improved particle swarm optimization is used to model the distillation rate of unit energy consumption. Then online optimization of oil refining process is realized by optimizing the outlet temperature, the overhead temperature with IPSO again. Simulation comparative analyses are made by empirical data to verify the effectiveness of the proposed solution.
基金Supported by the National Natural Science Foundation of China(U22B6004).
文摘The major enrichment type of shale oil in the Chang 7_(3) shale of Upper Triassic Yanchang Formation in the Ordos Basin is unknown.This paper analyzes the organic matter transformation ratio,hydrocarbon expulsion efficiency and roof/floor sealing conditions of the Chang 7_(3) shale,and evaluates the major enrichment type of shale oil in this interval.The average organic matter transformation ratio of the Chang 7_(3) shale is about 45%;in other words,more than 50%of the organic matters have not transformed to hydrocarbons,and the lower the maturity,the greater the proportion of untransformed organic matters.The cumulative hydrocarbon expulsion efficiency of the transformed hydrocarbon is 27.5% on average,and the total proportion of untransformed organic matters plus retained hydrocarbons is greater than 70%.The relative hydrocarbon expulsion efficiency of the Chang 7_(3) shale is 60%on average,that is,about 40% of hydrocarbons retain in the shale.The Chang 7_(3) shale corresponds to Chang 7_(1+2) and Chang 8 sandstones as the roof and floor,respectively,and is further overlaid by Chang 6 shale,where extensive low porosity and low permeability–tight oil reservoirs have formed in the parts with relatively good porosity and permeability.Moreover,the Chang 7_(3) shale is tested to be in a negative pressure system(the pressure coefficient of 0.80–0.85).Therefore,the roof/floor sealing conditions of the Chang 7_(3) shale are poor.The retained hydrocarbons appear mostly in absorbed status,with low mobility.It is concluded that the medium–high mature shale oil is not the major enrichment type of shale oil in the Chang 7_(3) shale,but there may be enrichment opportunity for shale oil with good mobility in the areas where the sealing conditions are good without faults and fractures and oil reservoirs are formed off Chang 7_(1+2),Chang 6 and Chang 8.Furthermore,low–medium mature shale oil is believed to have great potential and is the major enrichment type of shale oil in the Chang 7_(3) shale.It is recommended to prepare relevant in-situ conversion technologies by pilot test and figure out the resource availability and distribution.