Comparative investigation of coal-and oil-fired boilers based on emission factors,ozone and secondary organic aerosol formation potentials of VOCs

Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate system.In this study,VOC emission factors,O3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3)and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired boilers.Emission factors ofΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg)than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired boilers.Benzene,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired boilers.Total OFP ranged from 3.99 to 11.39 mg-O3/kg for coal-fired boilers.For oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O3/kg.Moreover,total secondary organic aerosol potential(SOAP)ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively.

Environmental performance assessments of different methods of coal preparation for use in small-capacity boilers: experiment and theory

The purpose of this article is to receive environmental assessments of combustion of different types of coal fuel depending on the preparation(unscreened,size-graded,briquetted and heat-treated)in automated boilers and boilers with manual load-ing.The assessments were made on the basis of data obtained from experimental methods of coal preparation and calculated methods of determining the amount of pollutant and greenhouse gas emissions,as well as the mass of ash and slag waste.The main pollutants from coal combustion are calculated:particulate matter,benz(a)pyrene,nitrogen oxides,sulfur dioxide,carbon monoxide.Of the greenhouse gases carbon dioxide is calculated.As a result of conducted research it is shown that the simplest preliminary preparation(size-graded)of coal significantly improves combustion efficiency and environmental performance:emissions are reduced by 13%for hard coal and up to 20%for brown coal.The introduction of automated boil-ers with heat-treated coal in small boiler facilities allows to reduce emissions and ash and slag waste by 2-3 times.The best environmental indicators correspond to heat-treated lignite,which is characterized by the absence of sulfur dioxide emissions.

Analysis of Prese nt Operating Situati on of Large Size Coal-F ired Utility Boilers

Large size utility boilers develop rapidly in China, both their reliability and economics have reached better level. The operating situations of various existing boilers on the basis of different coals are analyzed, it is held that, the notable energy imbalance of furnace exit, ever existing in the tangential firing boilers has been solved, with comparatively lower NOX emission concentration of gained. The higher NOX emission concentration and furnace slagging etc. problems existing in wall firing boilers are notable. The comprehensive analysis shows that, it is appropriate to choose lower furnace volume heat release rate and higher flame height in the type selection design of boilers, and sufficient margin should be kept in the selection of coal pulverizing mills.

INTRODUCTION TO INCONEL ALLOY 740: AN ALLOY DESIGNED FOR SUPERHEATER TUBING IN COAL-FIRED ULTRA SUPERCRITICAL BOILERS

Chinese utilities as well as those worldwide are facing increased demand for additional electricity, reduced plant emissions and greater efficiency. To meet this challenge will require increasing boiler temperature, pressure and coal ash corrosion resistance of the materials of boiler construction of future coal-fired boilers. A new nickel-based tube alloy, INCONEL^R alloy 740, is described aiming at meeting this challenge. Emphasis will be on describing the alloy＇ s mechanical properties, coal-ash and steam corrosion resistance. Microstructural stability as a function of temperature and time is addressed as well as some of the early methodology em- ployed to arrive at the current chemical composition.

Optimal dynamic dispatch of surplus gas among buffer boilers in steel plant

As valuable energy in iron-and steel-making process,by-product gas is widely used in heating and technical processes in steel plant.After being used according to the technical requirements,the surplus by-product gas is usually used for buffer boilers to produce steam.With the rapid development of energy conservation technology and energy consumption level,surplus gas in steel plant continues to get larger.Therefore,it is significant to organize surplus gas among buffer boilers.A dynamic programming model of that issue was established in this work,considering the ramp rate constraint of boilers and the influences of setting gasholders.Then a case study was done.It is shown that dynamic programming dispatch gets more steam generation and less specific gas consumption compared with current proportionate dispatch depending on nominal capacities of boilers.The ignored boiler ramp rate constraint was considered and its contribution to the result validity was pointed out.Finally,the significance of setting gasholders was studied.

NO_x emission model for coal-fired boilers using partial least squares and extreme learning machine

To implement a real-time reduction in NOx,a rapid and accurate model is required.A PLS-ELM model based on the combination of partial least squares(PLS)and the extreme learning machine(ELM)for the establishment of the NOx emission model of utility boilers is proposed.First,the initial input variables of the NOx emission model are determined according to the mechanism analysis.Then,the initial input data is extracted by PLS.Finally,the extracted information is used as the input of the ELM model.A large amount of real data was obtained from the distributed control system(DCS)historical database of a 1 000 MW power plant boiler to train and validate the PLS-ELM model.The modeling performance of the PLS-ELM was compared with that of the back propagation(BP)neural network,support vector machine(SVM)and ELM models.The mean relative errors(MRE)of the PLS-ELM model were 1.58%for the training dataset and 1.69%for the testing dataset.The prediction precision of the PLS-ELM model is higher than those of the BP,SVM and ELM models.The consumption time of the PLS-ELM model is also shorter than that of the BP,SVM and ELM models.

Optimization of Load Assignment to Boilers in Industrial Boiler Plants

Along with the increasing importance of sustainable energy, the optimization of load assignment to boilers in an industrial boiler plant becomes one of the major projects for the optimal operation of boiler plants. Optimal load assignment for power systems has been a long-lasting subject, while it is quite new for industrial boiler plants. The existing methods of optimal load assignment for boiler plants are explained and analyzed briefly in the paper. They all need the fuel cost curves of boilers. Thanks to some special features of the curves for industrial boilers, a new model referred to as minimized departure model (MDM) of optimization of load assignment for boiler plants is developed and proposed in the paper. It merely relies upon the accessible data of two typical working conditions to build the model, viz. the working conditions with the highest efficiency of a boiler and with no-load. Explanation of the algorithm of computer program is given, and effort is made so as to determine in advance how many and which boilers are going to work. Comparison between the results using MDM and the results reported in references is carried out, which proves that MDM is preferable and practicable.

Shock resistance of supercharged boilers through integration with ship structure

The non-linear finite element software ABAQUS was used to simulate the dynamic response of a marine supercharged boiler when subjected to impact loading. Shock resistance was analyzed by the time-domain simulation method. After exhaustive simulations,the effect of air pressure induced by different working conditions on the shock response of a supercharged boiler was reviewed,leading to conclusions about the variability of structural response with different loading parameters. In order to simulate the real impulsive environments of supercharged boilers,the integration of equipment and ship structure was then primarily used to analyze shock response. These distinctly different equipment shock test methods,run under equivalent work conditions,were compared and the causes of discrepancy were analyzed. The main purpose of this paper is to present references for the anti-shock design of marine supercharged boilers.

Fault Diagnostics on Steam Boilers and Forecasting System Based on Hybrid Fuzzy Clustering and Artificial Neural Networks in Early Detection of Chamber Slagging/Fouling

The slagging/fouling due to the accession of fireside deposits on the steam boilers decreases boiler efficiency and availability which leads to unexpected shut-downs. Since it is inevitably associated with the three major factors namely the fuel characteristics, boiler operating conditions and ash behavior, this serious slagging/fouling may be reduced by varying the above three factors. The research develops a generic slagging/fouling prediction tool based on hybrid fuzzy clustering and Artificial Neural Networks (FCANN). The FCANN model presents a good accuracy of 99.85% which makes this model fast in response and easy to be updated with lesser time when compared to single ANN. The comparison between predictions and observations is found to be satisfactory with less input parameters. This should be capable of giving relatively quick responses while being easily implemented for various furnace types.

R&D and Demonstration of Large Domestic CFB Boilers

In order to develop large CFB boilers with independent intellectual property, Xi'an Thermal Power Research Institute (TPRI) established a laboratory with complete functions for the technical development of CFB boilers. This laboratory consists of a 1-MW and a 4-MW CFB combustion test facilities and a laboratory for limestone desulphurization performance evaluation. It carried out tests on CFB combustion and desulphurization for Chinese typical coals and limestone and research on heat-transfer characteristics and key parts, and developed the first home-made 100-MW CFB boiler. Based on the experience of R&D, the laboratory further researched key techniques for enlarging capacity systematically, and cooperating with Harbin Boiler Co. (HBC), developed the first domestic 210-MW CFB boiler with independent intellectual property and put it into engineering demonstration, laying a solid foundation for the development of CFB boilers of even larger capacity.

Development of 600 MW Class Coal Fired Boilers in China

This article introduces the present status anddevelopment of 600 MW class boilers in China. The statisticaldata indicate that most 600 MW generating units experiencedrelatively length" growing up" period. In this period, unitscould not operate stably , their unplanned outage times weremany and durations long, and availabilities low. On the basis oftesting and research and the summing-up of practice, it wasindicated slagging in the furnace, deviation of tine gas energy atthe exit of furnace, and overheating bursting of superheater andreheater etc, endangering the safety and economics ofoperation,main problems could be completely alleviated oravoided through design and type selection of boiler furnace andburners, coal characteristics and coal handling management,and optimization management of operation conditions etc.

Atmospheric Dry Deposition in the Proximity of Oil-Fired Power Plants at Mexican Pacific Coast

Dry deposition samples were collected in a weekly basis during 2010 in a site located at the Mexican Pacific Coast: Manzanillo, Colima. Samples were collected with an automatic wet/dry deposition sampler using nylon filters as surrogate surfaces. Samples were extracted with deionized water and analyzed for pH, conductivity, Na+, K+, Ca2+, Mg2+, NH4-, NO3-, SO42- and Cl-. Nitrate and sulfate were the most abundant ions, contributing with 53% to the total ionic mass;and their levels exceeded the hemispheric background concentrations proposed for marine remote sites. The influence of the power plants burning combustoleo located upwind the sampling site was completely evident. From meteorological analysis, it could be observed that the sampling site was all time under the influence of power plants as a result of the effect of breezes. However, in spite of the high levels of NO3- and SO42- found in the samples collected, pH value average was almost neutral, with 28% of samples slightly acid. Potassium was the most abundant cation and from the quantification of the neutralization effect of the main alkaline components, the prevalence role of K+ was completely evident, suggesting the influence of the mining complex Pe?a Colorada located upwind the sampling site, where amyl xanthate potassium is used as collector in tailing dams. Dry deposition fluxes were estimated for all ions measured. Nitrogen dry deposition at Manzanillo is already in the upper extreme of the threshold value reported for sensible ecosystems. On the other hand, sulfur deposition exceeded slightly the critical load value reported for some ecosystems in Europe. Even at this moment, nitrogen and sulfur deposition is not a problem, it is necessary to take steps to avoid that total deposition of these elements exceeds critical loads, considering that results reported in this study not include the wet deposition fluxes.

Development and Installation of High Pressure Boilers for Co-Generation Plant in Sugar Industries

The sugar cane containing minimum 30% fiber was referred as bagasse and used the generation of power required for the operation of sugar mill. The bagasse is fired in the boiler for producing steam at high pressure, which is extracted through various single high capacity turbines and used in the process. The installation of high pressure boilers and high pressure turbo-generators has provision for the operation of co-generation plant during the off-season also that enhances the power generation from 9MW to 23MW. The annual monetary benefits achieved are Rs. 204.13 million and this was based on cost of power sold to the grid @ Rs 2.548 per unit, sugar season of 219 days and off season of 52 days. This required an investment of Rs 820.6 million. The investment had an attractive simple payback period of 48 months.

Smart Boilers: Grid Support Services from Non-Critical Loads

The aim of this paper is to present the concept of a simple and cheap upgrade for electric water boilers, allowing them to provide power quality services to the distribution grid. The upgrade requires only minimum additional hardware and it is easily installable. “Smart Boilers”, as the upgraded boilers are named, perform precise active and reactive power control, but most significantly mitigate line current harmonics. Αctive and reactive power control is implemented by appropriate regulation of the modulation sinewave amplitude and phase, respectively. This type of control is easily customizable in order to accommodate a variety of power quality targets, depending on the required level of services and available grid monitoring equipment. The method used for line current harmonic compensation is based on the injection of mirror harmonics created at the modulation stage of the converter. It is indifferent of harmonic source: it is equally successful at mitigating harmonics caused by the power electronic converter of the Smart Boiler, other sources of current harmonics or loads. The achieved grid services are clearly beyond the “on/off” operation of electric boilers, currently implemented by Demand Side Management (DSM) in order to shift load away from peak hours. It has been demonstrated through simulations, that Smart Boilers can assist voltage regulation at terminal buses, compensate reactive power and suppress harmonic currents at lines.

800-MW Supercritical Coal-Fired Boilers in Suizhong Power Plant

This article reviews the problems of Russia-made 800-MW coal-fired supercritical boilers in Suizhong Power Plant, such as burner bumout, water-wall leakage, slag screenⅠexplosion, crack happened on the desuperheater outlet of reheater and welding defect of economizer; tells the process of renovating these units by modifying the original design and adjusting the operation parameters. After several years' effort, all the problems have been well solved. The experience may be useful for other imported units in China.

Work Boilers in the Real Heat Loads

Analysis was performed on the boiler for solid fuels in a corresponding real-thermal load. The tests were conducted with the use of a low-temperature top-loading KWSM water boiler. For control of the burning process, three control algorithms were used as implemented in microprocessor temperature controls. The analysis aimed at determination of influence of the control algorithm upon quality of the buming process in conditions of actual demand for thermal energy. The detailed analysis of operating parameters in relation to the variable thermal load of the boiler provided necessary information and made it possible to state that control algorithms do influence quality of the controlled process. Particular attention was paid to a situation, in which demand for thermal energy is decreased.

Correlating furnace characteristics of utility boilers with coal characteristics

1.IntroductionCoal is listed in China’s energy policy as the predominant fuelto be used for thermal power generation.It includes nearly the wholespectrum of coals that China has,ranging from anthracite to browncoal.This poses a situation to China’s utility boiler manufacturers thattheir products have to cope with all kinds of coal available.China is now producing a full range of utility boilers with ca-pacities from 35 t/h through 2000 t/h.They have successfully burnedanthracities with volatile matter greater than 7% and low grade coalswith high moisture and high ash contents.They burn bituminouscoals and lignites with satisfactory efficacy.

Power Generation Systems Using Continuous Blowdown Waste Heat from Drum Boilers Driving an Organic Rankine Cycle

提出了一种利用汽包锅炉排污系统余热的有机朗肯循环发电系统,有机工质回收扩容器疏水的热量,并通过气轮机发电。建立了系统的热力性能分析模型,并对R227ea、RC318、R236ea、R245fa、R245ca、R123和R113等7种工质的热力性能进行了优化。结果表明,临界温度高的工质,其o2循环的最佳主气温度（蒸发温度）反而低；亚临界循环采用干流体时,过热不利于余热的利用；超临界循环可以改善热源与工质间的温度匹配,有利于增大系统输出功,但是其运行压力高、大比热区的传热恶化等问题是实际运行和设计需要考虑的因素；R236ea的热力性能优于其余6种工质。

Discussion on Selection of Pulverizer and Moisture of Pulverized Coal for Lignite Boilers

In China,the abrasion index and the free moisture are regarded as the criteria for determining whether the medium-speed pulverizer or the fan pulverizer could be selected.Based on comprehensive studies on foreign methods for choosing the pulverizing system for lignite boilers,it is suggested that the particle size of coal,the drying time,the drying temperature and the humidity should be taken into account when measuring the free moisture of lignite,and the total moisture could also be the principle for type selection of pulverizer for lignite boilers.Furthermore,the determination of pulverized-coal moisture has great influence on the running of pulverizing systems.The actual moisture of certain pulverized coals is compared with that calculated with different methods and a feasible method for determining the moisture of the pulverized coal is suggested.

Effects of particle type on the particle fluidization and distribution in a liquid–solid circulating fluidized bed boiler

A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.