The influence of mixed rubber processing technology on Mooney viscosity and burning time was studied.The results showed that the Mooney viscosity of mixed rubber increased with the extension of the parking time,and th...The influence of mixed rubber processing technology on Mooney viscosity and burning time was studied.The results showed that the Mooney viscosity of mixed rubber increased with the extension of the parking time,and the burning time did not change significantly.With the increase of the number of thin pass,the Mooney viscosity of mixed rubber decreases continuously,and the burning time varies with different thin pass temperature.展开更多
Based on the theory of forest burning link, the combustibility of the 6-year-old Chinese fir (Cunninghamia lanceolata) and macclure michelia (Michelia macclurei) mixed forest was determined in Youxi County, Fujian Pro...Based on the theory of forest burning link, the combustibility of the 6-year-old Chinese fir (Cunninghamia lanceolata) and macclure michelia (Michelia macclurei) mixed forest was determined in Youxi County, Fujian Province from 1988 to 1989. The results show that the daily mean moisture in the forest, moisture content of litter and the water reserves of the stand in mixed forest are 3%, 7.6% and 46.8% higher than that in pure stand respectively, the inflammables quantity and energy ratios of the stand biomass and total potential energy in mixed stand are 8.5% and 3.69% lower than that in pure stand respectively. Mixed forest can decrease the combustibility of stand.展开更多
Palladium catalysts are supported on TiO2, ZrO2, A12O3, Zro.sAlo.501.75 and TiO2-Zro.sAlo.501.75 prepared by co-precipitation method, re- spectively. Catalytic activities for methane and CO oxidation are evaluated in ...Palladium catalysts are supported on TiO2, ZrO2, A12O3, Zro.sAlo.501.75 and TiO2-Zro.sAlo.501.75 prepared by co-precipitation method, re- spectively. Catalytic activities for methane and CO oxidation are evaluated in a gas mixture that simulated the exhaust from lean-burn natural gas vehicles （NGVs）. Pd/TiO2-Zro.sAlo.501.75 performs the best catalytic activity among the tested five catalysts. For CH4, the light-off temperature （Tso） is 254 ℃, and the complete conversion temperature （Tgo） is 280 ℃; for CO, Tso is 84 ℃, and Tgo was 96 ℃. Various techniques, including N2 adsorption-desorption, X-ray diffraction （XRD）, H2-temperature-programmed reduction （H2-TPR）, X-ray photoelec- tron spectroscopy （XPS）, and scanning electron microscopy （SEM） are employed to characterize the effect of supports on the physicochemical properties of prepared catalysts. N2 adsorption-desorption and SEM show that TiO2-Zro.5Al0.501.75 expresses uniform nano-particles and large meso-pore diameters of 26 nm. H2-TPR and XRD indicate that PdO is well dispersed on the supports and strongly interacted with each other. The results of XPS show that the electron density around PdO and the proportion of active oxygen on TiO2-Zro.sAl0.501.75 are maxima among the five supports.展开更多
Fresh straw burning （SB） particles were generated in the laboratory by the combustion of rice straw and corn straw. The chemical composition and mixing state of the fresh SB particles were investigated by an Aerosol...Fresh straw burning （SB） particles were generated in the laboratory by the combustion of rice straw and corn straw. The chemical composition and mixing state of the fresh SB particles were investigated by an Aerosol Time-of-Flight Mass Spectrometer （ATOFMS）. Based on the mass spectral patterns, the SB particles were clustered into four major types： Salt, Organic Carbon （OC）, Elemental Carbon （EC）, and internally mixed particles of EC and OC （EC-OC）. In addition, particles containing ash, polycyclic aromatic hydrocarbons, heavy metals or nicotine were also observed. Physical and chemical changes of the SB particles immediately after the emission were analyzed with highly time-resolved data. During the aging processes, the average particle size increased steadily. Freshly emitted organic compounds were gradu- ally oxidized to more oxygenated compounds in the OC- containing particles. Meanwhile, an important displace- ment reaction （2KCI＋ SO24- KzSO4 ＋ 2C1-） was observed. The marker ions for SB particles were optimized and applied to identify the SB particles in the ambient atmosphere. The fluctuation of the number fraction of ambient SB particles sorted by ATOFMS agrees well with that of water soluble K＋ measured by an online ion chromatography, demonstrating that the optimized marker ions could be good tracers for SB particles in field measurements.展开更多
文摘The influence of mixed rubber processing technology on Mooney viscosity and burning time was studied.The results showed that the Mooney viscosity of mixed rubber increased with the extension of the parking time,and the burning time did not change significantly.With the increase of the number of thin pass,the Mooney viscosity of mixed rubber decreases continuously,and the burning time varies with different thin pass temperature.
文摘Based on the theory of forest burning link, the combustibility of the 6-year-old Chinese fir (Cunninghamia lanceolata) and macclure michelia (Michelia macclurei) mixed forest was determined in Youxi County, Fujian Province from 1988 to 1989. The results show that the daily mean moisture in the forest, moisture content of litter and the water reserves of the stand in mixed forest are 3%, 7.6% and 46.8% higher than that in pure stand respectively, the inflammables quantity and energy ratios of the stand biomass and total potential energy in mixed stand are 8.5% and 3.69% lower than that in pure stand respectively. Mixed forest can decrease the combustibility of stand.
基金supported by the National Natural Science Foundation of China(21173153)
文摘Palladium catalysts are supported on TiO2, ZrO2, A12O3, Zro.sAlo.501.75 and TiO2-Zro.sAlo.501.75 prepared by co-precipitation method, re- spectively. Catalytic activities for methane and CO oxidation are evaluated in a gas mixture that simulated the exhaust from lean-burn natural gas vehicles （NGVs）. Pd/TiO2-Zro.sAlo.501.75 performs the best catalytic activity among the tested five catalysts. For CH4, the light-off temperature （Tso） is 254 ℃, and the complete conversion temperature （Tgo） is 280 ℃; for CO, Tso is 84 ℃, and Tgo was 96 ℃. Various techniques, including N2 adsorption-desorption, X-ray diffraction （XRD）, H2-temperature-programmed reduction （H2-TPR）, X-ray photoelec- tron spectroscopy （XPS）, and scanning electron microscopy （SEM） are employed to characterize the effect of supports on the physicochemical properties of prepared catalysts. N2 adsorption-desorption and SEM show that TiO2-Zro.5Al0.501.75 expresses uniform nano-particles and large meso-pore diameters of 26 nm. H2-TPR and XRD indicate that PdO is well dispersed on the supports and strongly interacted with each other. The results of XPS show that the electron density around PdO and the proportion of active oxygen on TiO2-Zro.sAl0.501.75 are maxima among the five supports.
基金This work was supported by The National Natural Science Foundation of China （Grant Nos. 21177027 and 41275126）, Ministry of Science and Technology of China （2012YQ220113-4）, the Science ＆ Technology Commission of Shanghai Municipality （12DJ1400100, 14XD 1400600）, and the Jiangsu Provincial Collaborative Innovation Center of Climate Change.
文摘Fresh straw burning （SB） particles were generated in the laboratory by the combustion of rice straw and corn straw. The chemical composition and mixing state of the fresh SB particles were investigated by an Aerosol Time-of-Flight Mass Spectrometer （ATOFMS）. Based on the mass spectral patterns, the SB particles were clustered into four major types： Salt, Organic Carbon （OC）, Elemental Carbon （EC）, and internally mixed particles of EC and OC （EC-OC）. In addition, particles containing ash, polycyclic aromatic hydrocarbons, heavy metals or nicotine were also observed. Physical and chemical changes of the SB particles immediately after the emission were analyzed with highly time-resolved data. During the aging processes, the average particle size increased steadily. Freshly emitted organic compounds were gradu- ally oxidized to more oxygenated compounds in the OC- containing particles. Meanwhile, an important displace- ment reaction （2KCI＋ SO24- KzSO4 ＋ 2C1-） was observed. The marker ions for SB particles were optimized and applied to identify the SB particles in the ambient atmosphere. The fluctuation of the number fraction of ambient SB particles sorted by ATOFMS agrees well with that of water soluble K＋ measured by an online ion chromatography, demonstrating that the optimized marker ions could be good tracers for SB particles in field measurements.
