Photoelectrochemical NO_(3)^(-)reduction(PEC NITRR)not only provides a promising solution for promoting the global nitrogen cycle,but also converts NO_(3)^(-)to the important chemicals(NH_(3)).However,it is still a gr...Photoelectrochemical NO_(3)^(-)reduction(PEC NITRR)not only provides a promising solution for promoting the global nitrogen cycle,but also converts NO_(3)^(-)to the important chemicals(NH_(3)).However,it is still a great challenge to prepare catalysts with excellent NO_(3)^(-)adsorption/activation capacity to achieve high NITRR.Herein,we designed a novel Fe^(2+)~Cu^(2+)Fe^(3+)LDH/BiVO_(4)(FCF-LDH/BVO)catalyst with synergistic effect of chemical adsorption and physical enrichment.Fe^(2+)in FCF-LDH/BVO provides the rich Lewis acid sites for the adsorption of NO_(3)^(-),and the appropriate layer spacing of FCF-LDH further promotes the physical enrichment of NO_(3)^(-)in its interior,thus realizing the effective contact between NO_(3)^(-)and active sites(Fe^(2+)).FCF-LDH/BVO showed excellent NH_(3)production performance(FE_(NH_(3))=66.1%,r_(NH_(3))=13.8μg h^(-1)cm^(-2))and selectivity(FE_(NO_(2)^(-))=2.5%,r_(NO_(2)^(-))=4.9μg h^(-1)cm^(-2))in 0.5 mol L^(-1)Na_(2)SO_(4)electrolyte.In addition,FCF-LDH/BVO maintains the desirable PEC stability for six cycle experiments,showing great potential for practical application.The^(14)NO_(3)^(-)and^(15)NO_(3)^(-)isotope test provides strong evidence for further verification of the origin of N in the generated NH_(3).This LDH catalyst has a great potential in PEC removal of NO_(3)^(-)from groundwater.展开更多
The inspection and quarantine standard is one of important basics to executeinspection and quarantine by laws. In recent years, with the development of economy and trade inChina, standardization has played an importan...The inspection and quarantine standard is one of important basics to executeinspection and quarantine by laws. In recent years, with the development of economy and trade inChina, standardization has played an important role in inspection and quarantine. During 2002-2004,department of Standards of Inspection and Quarantine, Certification and Accreditation Administrationof China has organized the research of the standards of inspection and quarantine, and has builtstandard sub- systems of nine fields in inspection and quarantine.展开更多
In order to study vegetation evolution and environmental changes around 2.5 Ma B.P., a total of 146 pollen samples with an average time resolution of 7 000 years were analyzed in the deep-sea record at the depth of 13...In order to study vegetation evolution and environmental changes around 2.5 Ma B.P., a total of 146 pollen samples with an average time resolution of 7 000 years were analyzed in the deep-sea record at the depth of 135 - 95 m （in composition depth） from ODP Site 1143 （9° 22＇ N, 113° 17＇ E） in the southern South China Sea. The results show that the pollen influx has a distinct change. During 2.6 - 2.0 Ma B.P., the average value of pollen influx increased evidently compared with that of 3.0 - 2.6 Ma B.P. It shows that the sea level of SCS dropped dramatically around 2.6 Ma B.P., corresponding to the formation of the Northern Hemisphere ice-sheets and the enhancement of the East Asian Monsoon. The pollen influx variations reflect the glacial-interglacial cycles corresponding with the deep-sea oxygen isotope curve and indicate that the sea level of SCS rose and dropped many times after 2.6 Ma B.P. The spectrum analysis results of pollen influx show that there are cycles at 0.1Ma （eccentricity） and 46.9 ka （obliquity） during 3.0 - 2.0 Ma B.P.展开更多
Based on the samples collected from the west wall of the ABYT2004 at Yuhuicun Site in Bengbu, Anhui Province, the multi-environmental substitute indexes such as the grain-size, Rb/Sr, zircon crystal morphology and mag...Based on the samples collected from the west wall of the ABYT2004 at Yuhuicun Site in Bengbu, Anhui Province, the multi-environmental substitute indexes such as the grain-size, Rb/Sr, zircon crystal morphology and magnetic susceptibility were analyzed. The age of archaeological strata was determined by AMS^14C dating. According to the results, combined with the information of the ancient human activities and the cultural heritage data obtained from the Longshan cultural archaeological strata, it can be concluded that （1） Before 4500 aBP, the climate was humid and water level was high in the Huaihe River and its tributaries, the drainage basin and its surrounding areas were even flooded, so the site area was submerged and there were no human activities around the site. （2） About 4500 aBP, the climate began to become drier and water level of the Huaihe River and its tributaries began to decline, thus floodplain gradually appeared, Yuhuicun Site and Longshan Culture began to appear. （3） Around 4100 aBP, the climate was humid and rainfall was abundant, which resulted in frequent flood disasters in the whole Huaihe River Basin. （4） After 4100 aBP, the climate gradually transited to be cold and dry, agricultural production was constrained to reduce the food source, Yuhuicun Site was almost abandoned. （5） The environmental information in sedimentary strata and historical records based on ancient books agree with each other. In addition, Yuhuicun Site was related to Dayu Zhishui （Yu the Great in taming the floods） in ancient books.展开更多
Objective To compare the acute hemodynamic effects of five different pacing modes in patients with cardiac function NYHA class Ⅰ to Ⅱ without bundle branch block (BBB). Methods This study included 12 patients (SSS ...Objective To compare the acute hemodynamic effects of five different pacing modes in patients with cardiac function NYHA class Ⅰ to Ⅱ without bundle branch block (BBB). Methods This study included 12 patients (SSS 7, Ⅲ°AVB 5) undergoing pacemaker implantation. Right ventricular apex (RVA), right ventricular outflow tract (RVOT), right ventricular bifocal (RV-Bi), left ventricular base (LVB) and bi -ventricular (Bi-Ⅴ) pacing at 60 -80 ppm were done in VVI mode prior to implantation of DDD pacemaker. The cardiac index (CI), mean pulmonary artery pressure (mPAP) and pulmonary capillary wedge pressure (PCWP) were measured with Swan - Ganz thermodilution catheter after 5 minutes of each pacing mode. Results (1) Comparing to pacing at RVA (CI: 2. 41± 0. 38 L/min per m2, PCWP: 16. 7 ±3.3 mmHg), the CI increased and the PCWP decreased significantly in pacing at RVOT(CI: 2. 63 ± 0.46, PCWP: 13. 8±2. 3), LVB(CI: 2. 78±0.52, PCWP: 14. 4±3.1), RV-Bi(CI: 2. 83±0.57, PCWP: 12. 8± 2. 5) and Bi -Ⅴ pacing (CI: 2. 94± 0.60, PCWP: 12. 7±2. 5), P < 0. 01, respectively. (2) The CI of RV-Bi and Bi-Ⅴ pacing was higher than that of RVOT and LVB pacing, the PCWP was lower, P < 0. 05, respectively. (3) There was no significant difference between RV - Bi pacing and Bi-Ⅴ pacing in CI and PCWP. Conclusion There is no significant difference between RV - Bi pacing and Bi -V pacing in the acute hemodynamic effects; however,dual - site pacing is much better than single site pacing in that aspect for patients with cardiac function NYHA class Ⅰ to Ⅱ without BBB. Among single site pacing, the RVOT and LVB pacing is better than RVA pacing in cardiac function.展开更多
基金National Natural Science Foundation of China(22075112)Jiangsu Province and Education Ministry Co-Sponsored Synergistic Innovation Center of Modern Agricultural Equipment(XTCX2027)Jiangsu Province Innovation Support Program International Science and Technology Cooperation Project(BZ2022045)。
文摘Photoelectrochemical NO_(3)^(-)reduction(PEC NITRR)not only provides a promising solution for promoting the global nitrogen cycle,but also converts NO_(3)^(-)to the important chemicals(NH_(3)).However,it is still a great challenge to prepare catalysts with excellent NO_(3)^(-)adsorption/activation capacity to achieve high NITRR.Herein,we designed a novel Fe^(2+)~Cu^(2+)Fe^(3+)LDH/BiVO_(4)(FCF-LDH/BVO)catalyst with synergistic effect of chemical adsorption and physical enrichment.Fe^(2+)in FCF-LDH/BVO provides the rich Lewis acid sites for the adsorption of NO_(3)^(-),and the appropriate layer spacing of FCF-LDH further promotes the physical enrichment of NO_(3)^(-)in its interior,thus realizing the effective contact between NO_(3)^(-)and active sites(Fe^(2+)).FCF-LDH/BVO showed excellent NH_(3)production performance(FE_(NH_(3))=66.1%,r_(NH_(3))=13.8μg h^(-1)cm^(-2))and selectivity(FE_(NO_(2)^(-))=2.5%,r_(NO_(2)^(-))=4.9μg h^(-1)cm^(-2))in 0.5 mol L^(-1)Na_(2)SO_(4)electrolyte.In addition,FCF-LDH/BVO maintains the desirable PEC stability for six cycle experiments,showing great potential for practical application.The^(14)NO_(3)^(-)and^(15)NO_(3)^(-)isotope test provides strong evidence for further verification of the origin of N in the generated NH_(3).This LDH catalyst has a great potential in PEC removal of NO_(3)^(-)from groundwater.
文摘The inspection and quarantine standard is one of important basics to executeinspection and quarantine by laws. In recent years, with the development of economy and trade inChina, standardization has played an important role in inspection and quarantine. During 2002-2004,department of Standards of Inspection and Quarantine, Certification and Accreditation Administrationof China has organized the research of the standards of inspection and quarantine, and has builtstandard sub- systems of nine fields in inspection and quarantine.
基金the National Natural Science Foundation of China projects （40371116） the National Major Basic Research Program of China （G200078502）.
文摘In order to study vegetation evolution and environmental changes around 2.5 Ma B.P., a total of 146 pollen samples with an average time resolution of 7 000 years were analyzed in the deep-sea record at the depth of 135 - 95 m （in composition depth） from ODP Site 1143 （9° 22＇ N, 113° 17＇ E） in the southern South China Sea. The results show that the pollen influx has a distinct change. During 2.6 - 2.0 Ma B.P., the average value of pollen influx increased evidently compared with that of 3.0 - 2.6 Ma B.P. It shows that the sea level of SCS dropped dramatically around 2.6 Ma B.P., corresponding to the formation of the Northern Hemisphere ice-sheets and the enhancement of the East Asian Monsoon. The pollen influx variations reflect the glacial-interglacial cycles corresponding with the deep-sea oxygen isotope curve and indicate that the sea level of SCS rose and dropped many times after 2.6 Ma B.P. The spectrum analysis results of pollen influx show that there are cycles at 0.1Ma （eccentricity） and 46.9 ka （obliquity） during 3.0 - 2.0 Ma B.P.
基金National Natural Science Foundation of China, No.40971115 No.40701190+1 种基金 National Key Technology R＆D Program, No.2006BAK21B02 The Key Subject Foundation of Human Geography in West Anhui University The authors thank Prof. Zhou Kunshu of Institute of Geology and Geophysics, Chinese Academy of Sciences, Prof. Wang Fubao of Nanjing University, and Prof. Huang Run of West Anhui University for their constructive advices to the paper.
文摘Based on the samples collected from the west wall of the ABYT2004 at Yuhuicun Site in Bengbu, Anhui Province, the multi-environmental substitute indexes such as the grain-size, Rb/Sr, zircon crystal morphology and magnetic susceptibility were analyzed. The age of archaeological strata was determined by AMS^14C dating. According to the results, combined with the information of the ancient human activities and the cultural heritage data obtained from the Longshan cultural archaeological strata, it can be concluded that （1） Before 4500 aBP, the climate was humid and water level was high in the Huaihe River and its tributaries, the drainage basin and its surrounding areas were even flooded, so the site area was submerged and there were no human activities around the site. （2） About 4500 aBP, the climate began to become drier and water level of the Huaihe River and its tributaries began to decline, thus floodplain gradually appeared, Yuhuicun Site and Longshan Culture began to appear. （3） Around 4100 aBP, the climate was humid and rainfall was abundant, which resulted in frequent flood disasters in the whole Huaihe River Basin. （4） After 4100 aBP, the climate gradually transited to be cold and dry, agricultural production was constrained to reduce the food source, Yuhuicun Site was almost abandoned. （5） The environmental information in sedimentary strata and historical records based on ancient books agree with each other. In addition, Yuhuicun Site was related to Dayu Zhishui （Yu the Great in taming the floods） in ancient books.
文摘Objective To compare the acute hemodynamic effects of five different pacing modes in patients with cardiac function NYHA class Ⅰ to Ⅱ without bundle branch block (BBB). Methods This study included 12 patients (SSS 7, Ⅲ°AVB 5) undergoing pacemaker implantation. Right ventricular apex (RVA), right ventricular outflow tract (RVOT), right ventricular bifocal (RV-Bi), left ventricular base (LVB) and bi -ventricular (Bi-Ⅴ) pacing at 60 -80 ppm were done in VVI mode prior to implantation of DDD pacemaker. The cardiac index (CI), mean pulmonary artery pressure (mPAP) and pulmonary capillary wedge pressure (PCWP) were measured with Swan - Ganz thermodilution catheter after 5 minutes of each pacing mode. Results (1) Comparing to pacing at RVA (CI: 2. 41± 0. 38 L/min per m2, PCWP: 16. 7 ±3.3 mmHg), the CI increased and the PCWP decreased significantly in pacing at RVOT(CI: 2. 63 ± 0.46, PCWP: 13. 8±2. 3), LVB(CI: 2. 78±0.52, PCWP: 14. 4±3.1), RV-Bi(CI: 2. 83±0.57, PCWP: 12. 8± 2. 5) and Bi -Ⅴ pacing (CI: 2. 94± 0.60, PCWP: 12. 7±2. 5), P < 0. 01, respectively. (2) The CI of RV-Bi and Bi-Ⅴ pacing was higher than that of RVOT and LVB pacing, the PCWP was lower, P < 0. 05, respectively. (3) There was no significant difference between RV - Bi pacing and Bi-Ⅴ pacing in CI and PCWP. Conclusion There is no significant difference between RV - Bi pacing and Bi -V pacing in the acute hemodynamic effects; however,dual - site pacing is much better than single site pacing in that aspect for patients with cardiac function NYHA class Ⅰ to Ⅱ without BBB. Among single site pacing, the RVOT and LVB pacing is better than RVA pacing in cardiac function.
