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Combination Method of Principal Component Analysis and Support Vector Machine for On-line Process Monitoring and Fault Diagnosis 被引量:2
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作者 赵旭 文香军 邵惠鹤 《Journal of Donghua University(English Edition)》 EI CAS 2006年第1期53-58,共6页
On-line monitoring and fault diagnosis of chemical process is extremely important for operation safety and product quality. Principal component analysis (PCA) has been widely used in multivariate statistical process m... On-line monitoring and fault diagnosis of chemical process is extremely important for operation safety and product quality. Principal component analysis (PCA) has been widely used in multivariate statistical process monitoring for its ability to reduce processes dimensions. PCA and other statistical techniques, however, have difficulties in differentiating faults correctly in complex chemical process. Support vector machine (SVM) is a novel approach based on statistical learning theory, which has emerged for feature identification and classification. In this paper, an integrated method is applied for process monitoring and fault diagnosis, which combines PCA for fault feature extraction and multiple SVMs for identification of different fault sources. This approach is verified and illustrated on the Tennessee Eastman benchmark process as a case study. Results show that the proposed PCA-SVMs method has good diagnosis capability and overall diagnosis correctness rate. 展开更多
关键词 principal component analysis multiple support vector machine process monitoring fault detection fault diagnosis.
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STRONGLY CONVERGENT INERTIAL FORWARD-BACKWARD-FORWARD ALGORITHM WITHOUT ON-LINE RULE FOR VARIATIONAL INEQUALITIES
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作者 姚永红 Abubakar ADAMU Yekini SHEHU 《Acta Mathematica Scientia》 SCIE CSCD 2024年第2期551-566,共16页
This paper studies a strongly convergent inertial forward-backward-forward algorithm for the variational inequality problem in Hilbert spaces.In our convergence analysis,we do not assume the on-line rule of the inerti... This paper studies a strongly convergent inertial forward-backward-forward algorithm for the variational inequality problem in Hilbert spaces.In our convergence analysis,we do not assume the on-line rule of the inertial parameters and the iterates,which have been assumed by several authors whenever a strongly convergent algorithm with an inertial extrapolation step is proposed for a variational inequality problem.Consequently,our proof arguments are different from what is obtainable in the relevant literature.Finally,we give numerical tests to confirm the theoretical analysis and show that our proposed algorithm is superior to related ones in the literature. 展开更多
关键词 forward-backward-forward algorithm inertial extrapolation variational inequality on-line rule
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Design of ANN Based Non-Linear Network Using Interconnection of Parallel Processor
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作者 Anjani Kumar Singha Swaleha Zubair +3 位作者 Areej Malibari Nitish Pathak Shabana Urooj Neelam Sharma 《Computer Systems Science & Engineering》 SCIE EI 2023年第9期3491-3508,共18页
Suspicious mass traffic constantly evolves,making network behaviour tracing and structure more complex.Neural networks yield promising results by considering a sufficient number of processing elements with strong inte... Suspicious mass traffic constantly evolves,making network behaviour tracing and structure more complex.Neural networks yield promising results by considering a sufficient number of processing elements with strong interconnections between them.They offer efficient computational Hopfield neural networks models and optimization constraints used by undergoing a good amount of parallelism to yield optimal results.Artificial neural network(ANN)offers optimal solutions in classifying and clustering the various reels of data,and the results obtained purely depend on identifying a problem.In this research work,the design of optimized applications is presented in an organized manner.In addition,this research work examines theoretical approaches to achieving optimized results using ANN.It mainly focuses on designing rules.The optimizing design approach of neural networks analyzes the internal process of the neural networks.Practices in developing the network are based on the interconnections among the hidden nodes and their learning parameters.The methodology is proven best for nonlinear resource allocation problems with a suitable design and complex issues.The ANN proposed here considers more or less 46k nodes hidden inside 49 million connections employed on full-fledged parallel processors.The proposed ANN offered optimal results in real-world application problems,and the results were obtained using MATLAB. 展开更多
关键词 Artificial neural network(ANN) MULTIprocessOR hidden node nonlinear optimization parallel processing
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On-line Batch Process Monitoring and Diagnosing Based on Fisher Discriminant Analysis
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作者 赵旭 邵惠鹤 《Journal of Shanghai Jiaotong university(Science)》 EI 2006年第3期307-312,316,共7页
A new on-line batch process monitoring and diagnosing approach based on Fisher discriminant analysis (FDA) was proposed. This method does not need to predict the future observations of variables, so it is more sensi... A new on-line batch process monitoring and diagnosing approach based on Fisher discriminant analysis (FDA) was proposed. This method does not need to predict the future observations of variables, so it is more sensitive to fault detection and stronger implement for monitoring. In order to improve the monitoring performance, the variables trajectories of batch process are separated into several blocks. The key to the proposed approach for on-line monitoring is to calculate the distance of block data that project to low-dimension Fisher space between new batch and reference batch. Comparing the distance with the predefine threshold, it can be considered whether the batch process is normal or abnormal. Fault diagnosis is performed based on the weights in fault direction calculated by FDA. The proposed method was applied to the simulation model of fed-batch penicillin fermentation and the resuits were compared with those obtained using MPCA. The simulation results clearly show that the on-line monitoring method based on FDA is more efficient than the MPCA. 展开更多
关键词 batch process on-line process monitoring fault diagnosis Fisher discriminant analysis (FDA) multiway principal component analysis (MPCA)
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基于Arduino与Processing的心率检测计设计研究 被引量:1
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作者 臧红波 华拓 管志岳 《家电维修》 2024年第3期74-76,共3页
随着社会经济的高速发展,人们的物质生活也有了极大的提高,但同时也伴随着各种疾病的到来,身体健康已经成为人们普遍关注的焦点,因此,心率检测仪、血压计、血糖仪等各种家用医疗监测仪器已经逐渐融入日常生活。心脏病是人们难以预防的... 随着社会经济的高速发展,人们的物质生活也有了极大的提高,但同时也伴随着各种疾病的到来,身体健康已经成为人们普遍关注的焦点,因此,心率检测仪、血压计、血糖仪等各种家用医疗监测仪器已经逐渐融入日常生活。心脏病是人们难以预防的突发致命疾病之一,本文介绍的是一款基于Arduino【是基于易用硬件和软件的原型开源平台,包由可编程的电路板(简称微控制器),以及集成开发环境(称为Arduino IDE)的现成软件组成】Processing(开源编程语言,包括编辑器、编译器、展示器)的简易心率检测计系统,其功能实用、操作简单,可以测量心率,当超出正常心率范围时及时预警,是一款便携的实时心率测试仪。 展开更多
关键词 Arduino processing 心率检测计 设计研究
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On-line Estimation of Biomass in Fermentation Process Using Support Vector Machine 被引量:15
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作者 王建林 于涛 金翠云 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第3期383-388,共6页
Biomass is a key factor in fermentation process, directly influencing the performance of the fermentation system as well as the quality and yield of the targeted product. Therefore, the on-line estimation of biomass i... Biomass is a key factor in fermentation process, directly influencing the performance of the fermentation system as well as the quality and yield of the targeted product. Therefore, the on-line estimation of biomass is indispensable. The soft-sensor based on support vector machine (SVM) for an on-line biomass estimation was analyzed in detail, and the improved SVM called the weighted least squares support vector machine was presented to follow the dynamic feature of fermentation process. The model based on the modified SVM was developed and demonstrated using simulation experiments. 展开更多
关键词 BIOMASS on-line estimation support vector machine FERMENTATION
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ON-LINE PROBLEMS OF MINIMIZING MAKESPAN ON A SINGLE BATCH PROCESSING MACHINE WITH NONIDENTICAL JOB SIZES 被引量:1
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作者 Shi Yongqiang Yao Enyu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2005年第3期297-304,共8页
The on-line problem of scheduling on a batch processing machine with nonidentical job sizes to minimize makespan is considered. The batch processing machine can process a number of jobs simultaneously as long as the t... The on-line problem of scheduling on a batch processing machine with nonidentical job sizes to minimize makespan is considered. The batch processing machine can process a number of jobs simultaneously as long as the total size of these jobs being processed does not exceed the machine capacity. The processing time of a batch is given by the longest processing time of any job in the batch. Each job becomes available at its arrival time, which is unknown in advance, and its processing time becomes known upon its arrival. The paper deals with two variants: the case only with two distinct arrival times and the general case. For the first case, an on-line algorithm with competitive ratio 119/44 is given. For the latter one, a simple algorithm with competitive ratio 3 is given. For both variants the better ratios can be obtained if the problem satisfies proportional assumption. 展开更多
关键词 batch processing on-line competitive ratio.
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On-line Estimation in Fed-batch Fermentation Process Using State Space Model and Unscented Kalman Filter 被引量:13
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作者 王建林 赵利强 于涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第2期258-264,共7页
On-line estimation of unmeasurable biological variables is important in fermentation processes,directly influencing the optimal control performance of the fermentation system as well as the quality and yield of the ta... On-line estimation of unmeasurable biological variables is important in fermentation processes,directly influencing the optimal control performance of the fermentation system as well as the quality and yield of the targeted product.In this study,a novel strategy for state estimation of fed-batch fermentation process is proposed.By combining a simple and reliable mechanistic dynamic model with the sample-based regressive measurement model,a state space model is developed.An improved algorithm,swarm energy conservation particle swarm optimization(SECPSO) ,is presented for the parameter identification in the mechanistic model,and the support vector machines(SVM) method is adopted to establish the nonlinear measurement model.The unscented Kalman filter(UKF) is designed for the state space model to reduce the disturbances of the noises in the fermentation process.The proposed on-line estimation method is demonstrated by the simulation experiments of a penicillin fed-batch fermentation process. 展开更多
关键词 on-line estimation simplified mechanistic model support vector machine particle swarm optimization unscented Kalman filter
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Modeling of Microstructure Evolution and Mechanical Properties of Steel Plates Produced by Thermo-Mechanical Control Process and Its On-line Application 被引量:1
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作者 Yunbo XU, Yongmei YU, Xianghua LIU and Guodong WANGState Key Laboratory of Rolling Technology and Automation, Northeastern University, P.O. Box 105, Shenyang 110004, ChinaPh.D., 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2005年第1期13-16,共4页
An integrated metallurgical model was developed to predict microstructure evolution and mechanical properties of low-carbon steel plates produced by TMCP. The metallurgical phenomena occurring during TMCP and mechanic... An integrated metallurgical model was developed to predict microstructure evolution and mechanical properties of low-carbon steel plates produced by TMCP. The metallurgical phenomena occurring during TMCP and mechanical properties were predicted for different process parameters. In the later passes full recrystallization becomes difficult to occur and higher residual strain remains in austenite after rolling. For the reasonable temperature and cooling schedule, yield strength of 30 mm plain carbon steel plate can reach 310 MPa. The first on-line application of prediction and control of microstructure and properties (PCMP) in the medium plate production was achieved. The predictions of the system are in good agreement with measurements. 展开更多
关键词 Thermo-mechanical control process Metallurgical model Low-carbon steel Prediction and control of microstructure and properties on-line application
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On-line Monitoring for Phosphorus Removal Process and Bacterial Community in Sequencing Batch Reactor 被引量:4
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作者 崔有为 王淑莹 李晶 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第3期484-492,共9页
For efficient energy consumption and control of effluent quality, the cycle duration for a sequencing batch reactor (SBR) needs to be adjusted by real-time control according to the characteristics and loading of waste... For efficient energy consumption and control of effluent quality, the cycle duration for a sequencing batch reactor (SBR) needs to be adjusted by real-time control according to the characteristics and loading of waste-water. In this study, an on-line information system for phosphorus removal processes was established. Based on the analysis for four systems with different ecological community structures and two operation modes, anaerobic-aerobic process and anaerobic-anaerobic process, the characteristic patterns of oxidation-reduction potential (ORP) and pH were related to phosphorous dynamics in the anaerobic, anoxic and aerobic phases, for determination of the end of phosphorous removal. In the operation mode of anaerobic-aerobic process, the pH profile in the anaerobic phase was used to estimate the relative amount of phosphorous accumulating organisms (PAOs) and glycogen accumulat-ing organisms (GAOs), which is beneficial to early detection of ecology community shifts. The on-line sensor val-ues of pH and ORP may be used as the parameters to adjust the duration for phosphorous removal and community shifts to cope with influent variations and maintain appropriate operation conditions. 展开更多
关键词 on-line monitoring phosphorus removal sequencing batch reactor PH oxidation-reduction potential
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On-Line Batch Process Monitoring Using Multiway Kernel Partial Least Squares 被引量:4
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作者 胡益 马贺贺 侍洪波 《Journal of Donghua University(English Edition)》 EI CAS 2011年第6期585-590,共6页
An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partia... An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partial least squares(MPLS),are not suitable due to their intrinsic linearity when the variations are nonlinear.To address this issue,kernel partial least squares(KPLS) was used to capture the nonlinear relationship between the latent structures and predictive variables.In addition,KPLS requires only linear algebra and does not involve any nonlinear optimization.In this paper,the application of KPLS was extended to on-line monitoring of batch processes.The proposed batch monitoring method was applied to a simulation benchmark of fed-batch penicillin fermentation process.And the results demonstrate the superior monitoring performance of MKPLS in comparison to MPLS monitoring. 展开更多
关键词 process monitoring fault detection kernel partial least squares(KPLS) nonlinear process multiway kernel partial least squares(MKPLS)
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One-step Eco-friendly Fabrication of Antibacterial Polyester Via On-line Amination Reaction by Melt Coextrusion
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作者 ZHANG Huan ZHAO Qinghua +4 位作者 ZHONG Yaping CAI Ruiyan LIU Ke WANG Dong LU Zhentan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期1205-1212,共8页
The work is dedicated to develop a one-step eco-friendly method to prepare antibacterial polyethylene terephthalate(PET).We report a one-step eco-friendly method to manufacture antibacterial PET via on-line amination ... The work is dedicated to develop a one-step eco-friendly method to prepare antibacterial polyethylene terephthalate(PET).We report a one-step eco-friendly method to manufacture antibacterial PET via on-line amination reaction by melt coextrusion.Beside evenly mixing of poly(hexamethylene guanidine)(PHMG)and PET in the melt coextrusion procedure,the amination reaction also occurred between PHMG and PET under high temperature(230-270℃).The antibacterial ability of composite PET showed obvious PHMG concentration dependence,and antibacterial activity reached more than 99%when PHMG content was 2.5 wt%.Moreover,LIVE/DEAD fluorescence test further confirmed that the composite PET could kill bacteria quickly and efiectively(within 30 min);while negligible cytotoxicity was observed to HSF and HUVEC cells.Onestep eco-friendly fabrication of composite antibacterial PET was accomplished by on-line melt coextrusion.The composite antibacterial PET has potential use in multiple fields to combat with pathogenic including textiles,packaging materials,decoration materials and biomedical devices,etc. 展开更多
关键词 antibacterial polyester one-step eco-friendly method on-line amination reaction melt coextrusion cytocompatibility
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Constraints on Characteristics and Distribution of Gas Hydrate and Free Gas Using Broad-Band Processing of Three-Dimensional Seismic Data 被引量:2
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作者 WANG Xiujuan ZHOU Jilin +7 位作者 LI Sanzhong LI Lixia LI Jie LI Yuanping WANG Linfei SU Pibo JIN Jiapeng GONG Zhi 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第5期1233-1247,共15页
Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have ... Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have been confirmed by logging,coring,and production tests in the foraminifera-rich silty sediments with complex bottom-simulating reflectors(BSRs).The broad-band processing is conducted on conventional three-dimensional(3D)seismic data to improve the image and detection accuracy of gas hydratebearing layers and delineate the saturation and thickness of gas hydrate-and free gas-bearing sediments.Several geophysical attributes extracted along the base of the gas hydrate stability zone are used to demonstrate the variable distribution and the controlling factors for the differential enrichment of gas hydrate.The inverted gas hydrate saturation at the production zone is over 40% with a thickness of 90 m,showing the interbedded distribution with different boundaries between gas hydrate-and free gas-bearing layers.However,the gas hydrate saturation value at the adjacent canyon is 70%,with 30-m-thick patches and linear features.The lithological and fault controls on gas hydrate and free gas distributions are demonstrated by tracing each gas hydrate-bearing layer.Moreover,the BSR depths based on broad-band reprocessed 3D seismic data not only exhibit variations due to small-scale topographic changes caused by seafloor sedimentation and erosion but also show the upward shift of BSR and the blocky distribution of the coexistence of gas hydrate and free gas in the Pearl River Mouth Basin. 展开更多
关键词 gas hydrate free gas shift of BSR broad-band processing
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Design and optimization of a greener sinomenine hydrochloride preparation process considering variations among different batches of the medicinal herb 被引量:1
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作者 Dandan Ren Jiale Xie +2 位作者 Tianle Chen Haibin Qu Xingchu Gong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第7期77-90,共14页
The current methods used to industrially produce sinomenine hydrochloride involve several issues,including high solvent toxicity,long process flow,and low atomic utilization efficiency,and the greenness scores of the ... The current methods used to industrially produce sinomenine hydrochloride involve several issues,including high solvent toxicity,long process flow,and low atomic utilization efficiency,and the greenness scores of the processes are below 65 points.To solve these problems,a new process using anisole as the extractant was proposed.Anisole exhibits high selectivity for sinomenine and can be connected to the subsequent water-washing steps.After alkalization of the medicinal material,heating extraction,water washing,and acidification crystallization were carried out.The process was modeled and optimized.The design space was constructed.The recommended operating ranges for the critical process parameters were 3.0–4.0 h for alkalization time,60.0–80.0℃ for extraction temperature,2.0–3.0(volume ratio)for washing solution amount,and 2.0–2.4 mol·L^(-1) for hydrochloric acid concentration.The new process shows good robustness because different batches of medicinal materials did not greatly impact crystal purity or sinomenine transfer rate.The sinomenine transfer rate was about 20%higher than that of industrial processes.The greenness score increased to 90 points since the novel process proposed in this research solves the problems of long process flow,high solvent toxicity,and poor atomic economy,better aligning with the concept of green chemistry. 展开更多
关键词 Sinomenine hydrochloride process optimization ANISOLE
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On-line Estimation of Biomass in Fermentation Process Using Support Vector Machine 被引量:1
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作者 王建林 于涛 金翠云 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第3X期383-388,共6页
Biomass is a key factor in fermentation process, directly influencing the performance of the fermenta- tion system as well as the quality and yield of the targeted product. Therefore, the on-line estimation of biomass... Biomass is a key factor in fermentation process, directly influencing the performance of the fermenta- tion system as well as the quality and yield of the targeted product. Therefore, the on-line estimation of biomass is indispensable. The soft-sensor based on support vector machine (SVM) for an on-line biomass estimation was ana- lyzed in detail, and the improved SVM called the weighted least squares support vector machine was presented to follow the dynamic feature of fermentation process. The model based on the modified SVM was developed and demonstrated using simulation experiments. 展开更多
关键词 BIOMASS on-line estimation support VECTOR MACHINE FERMENTATION
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On-line Batch Process Monitoring with Improved Multi-way Independent Component Analysis 被引量:14
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作者 郭辉 李宏光 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第3期263-270,共8页
In the past decades, on-line monitoring of batch processes using multi-way independent component analysis (MICA) has received considerable attention in both academia and industry. This paper focuses on two troubleso... In the past decades, on-line monitoring of batch processes using multi-way independent component analysis (MICA) has received considerable attention in both academia and industry. This paper focuses on two troublesome issues concerning selecting dominant independent components without a standard criterion and deter- mining the control limits of monitoring statistics in the presence of non-Gaussian distribution. To optimize the number of key independent components~ we introctuce-anoveiconcept of-system-cleviation, which is ab^e'io'evalu[ ate the reconstructed observations with different independent components. The monitored statistics arc transformed to Gaussian distribution data by means of Box-Cox transformation, which helps readily determine the control limits. The proposed method is applied to on-line monitoring of a fed-hatch penicillin fermentation simulator, and the ex- _perimental results indicate the advantages of the improved MICA monitoring compared to the conventional methods. 展开更多
关键词 batch process monitoring multi-way independent componerxt analysis system deviation Box-Coxtransformation
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Investigation on taste characteristics and sensory perception of soft-boiled chicken during oral processing based on electronic tongue and electronic nose 被引量:1
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作者 Na Xu Xianming Zeng +3 位作者 Peng Wang Xing Chen Xinglian Xu Minyi Han 《Food Science and Human Wellness》 SCIE CSCD 2024年第1期313-326,共14页
The sensory perception of food is a dynamic process,which is closely related to the release of flavor substances during oral processing.It’s not only affected by the food material,but also subjected to the individual... The sensory perception of food is a dynamic process,which is closely related to the release of flavor substances during oral processing.It’s not only affected by the food material,but also subjected to the individual oral environment.To explore the oral processing characteristics of soft-boiled chicken,the sensory properties,texture,particle size,viscosity,characteristic values of electronic nose and tongue of different chicken samples were investigated.The correlation analysis showed that the physical characteristics especially the cohesiveness,springiness,resilience of the sample determined oral processing behavior.The addition of chicken skin played a role in lubrication during oral processing.The particle size of the bolus was heightened at the early stage,and the fluidity was enhanced in the end,which reduced the chewing time to the swallowing point and raised the aromatic compounds signal of electronic nose.But the effect of chicken skin on chicken thigh with relatively high fat content,was opposite in electronic nose,which had a certain masking effect on the perception of umami and sweet taste.In conclusion,fat played a critical role in chicken oral processing and chicken thigh had obvious advantages in comprehensive evaluation of soft-boiled chicken,which was more popular among people. 展开更多
关键词 Oral processing CHICKEN Electronic tongue Electronic nose
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On-line detection system of weld-based rapid prototyping process based on structured light 被引量:2
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作者 李永哲 张广军 +1 位作者 熊俊 吴林 《China Welding》 EI CAS 2013年第1期1-5,共5页
In order to realize the closed-loop control for rapid prototyping process based on gas metal arc welding, the geometric parameters of weld beads should be detected. In this study, a vision sensor system consisting of ... In order to realize the closed-loop control for rapid prototyping process based on gas metal arc welding, the geometric parameters of weld beads should be detected. In this study, a vision sensor system consisting of a linear laser projector and a CCD camera was designed to collect images of weld beads. Then, an image processing approach which combines with a Gaassian filter and an improved gravity method was used to extract the centerline of a light stripe based on VC ++. Feature points of the centerline were identical directly by means of an image fusion algorithm. Experimental results show that image fusion is an effective approach to measure the width and height of the weld bead with high accuracy. This method can identify beads effectively in multi-pass welding and avoid designing different modes to suit all kinds of shapes. 展开更多
关键词 weld-based rapid prototyping linear structured light image processing image fusion
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Toluene Processed All-Polymer Solar Cells with 18%Efficiency and Enhanced Stability Enabled by Solid Additive:Comparison Between Sequential-Processing and Blend-Casting 被引量:1
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作者 Guoping Zhang Chaoyue Zhao +13 位作者 Liangxiang Zhu Lihong Wang Wenzhao Xiong Huawei Hu Qing Bai Yaping Wang Chen Xie Peng You He Yan Dan Wu Tao Yang Mingxia Qiu Shunpu Li Guangye Zhang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第4期247-254,共8页
The emergence of polymerized small molecule acceptors(PSMAs)has significantly improved the performance of all-polymer solar cells(all-PSCs).However,the pace of device engineering lacks behind that of materials develop... The emergence of polymerized small molecule acceptors(PSMAs)has significantly improved the performance of all-polymer solar cells(all-PSCs).However,the pace of device engineering lacks behind that of materials development,so that a majority of the PSMAs have not fulfilled their potentials.Furthermore,most high-performance all-PSCs rely on the use of chloroform as the processing solvent.For instance,the recent highperformance PSMA,named PJ1-γ,with high LUMO,and HOMO levels,could only achieve a PCE of 16.1%with a high-energy-level donor(JD40)using chloroform.Herein,we present a methodology combining sequential processing(SqP)with the addition of 0.5%wt PC_(71)BM as a solid additive(SA)to achieve an impressive efficiency of 18.0%for all-PSCs processed from toluene,an aromatic hydrocarbon solvent.Compared to the conventional blend-casting(BC)method whose best efficiency(16.7%)could only be achieved using chloroform,the SqP method significantly boosted the device efficiency using toluene as the processing solvent.In addition,the donor we employ is the classic PM6 that has deeper energy levels than JD40,which provides low energy loss for the device.We compare the results with another PSMA(PYF-T-o)with the same method.Finally,an improved photostability of the SqP devices with the incorporation of SA is demonstrated. 展开更多
关键词 all-polymers solar cells sequential processing solid additive
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A New Strategy of Integrated Control and On-line Optimization on High-purity Distillation Process 被引量:10
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作者 吕文祥 朱鹰 +2 位作者 黄德先 江永亨 金以慧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第1期66-79,共14页
For high-purity distillation processes,it is difficult to achieve a good direct product quality control using traditional proportional-integral-differential(PID)control or multivariable predictive control technique du... For high-purity distillation processes,it is difficult to achieve a good direct product quality control using traditional proportional-integral-differential(PID)control or multivariable predictive control technique due to some difficulties,such as long response time,many un-measurable disturbances,and the reliability and precision issues of product quality soft-sensors.In this paper,based on the first principle analysis and dynamic simulation of a distillation process,a new predictive control scheme is proposed by using the split ratio of distillate flow rate to that of bottoms as an essential controlled variable.Correspondingly,a new strategy with integrated control and on-line optimization is developed,which consists of model predictive control of the split ratio,surrogate model based on radial basis function neural network for optimization,and modified differential evolution optimization algorithm. With the strategy,the process achieves its steady state quickly,so more profit can be obtained.The proposed strategy has been successfully applied to a gas separation plant for more than three years,which shows that the strategy is feasible and effective. 展开更多
关键词 distillation process control split ratio surrogate model optimization modified differential evolution
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