In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd...In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd/carbon nanosphere(CNS),obtained via immobilization of ultrafine Pd nanoparticles onto CNS,are developed and employed for both selective H_(2)generation from HCOOH dehydrogenation and O_(2)evolution from H_(2)O_(2)decomposition.In these reactions,the highest activities for Pd/CNS-800(i.e.,calcinated at 800℃)are 2478 h−1 and 993 min^(−1)for H_(2)and O_(2)evolution,respectively.The highly efficient and selective“on-off”switch for selective H_(2)generation from HCOOH is successfully realized by pH adjustment.This novel and highly efficient nanocatalyst Pd/CNS-800 not only provides new approaches for the promising application of HCOOH and H_(2)O_(2)as economic and safe H_(2)and O_(2)carriers,respectively,for fuel cells,but also promotes the development of“on-off”switch for on-demand H_(2)evolution.展开更多
针对转运系统转载物料过程中料斗衬板的磨损影响运输效率的问题,改用新型钢基陶瓷复合衬板来代替传统耐磨钢,采用离散元法(distinct element method,DEM)描述颗粒物料运动过程,通过Archard磨损模型分析预测不同工况条件下衬板磨损规律,...针对转运系统转载物料过程中料斗衬板的磨损影响运输效率的问题,改用新型钢基陶瓷复合衬板来代替传统耐磨钢,采用离散元法(distinct element method,DEM)描述颗粒物料运动过程,通过Archard磨损模型分析预测不同工况条件下衬板磨损规律,并通过磨损规律和磨损特征验证了磨损模型的合理性。基于DEM的有限元法(finite element method,FEM)耦合方法分析了衬板应力与变形特性。研究结果表明:料斗衬板的最大磨损深度随颗粒度增大而减小,随传送带带速、衬板安装高度、衬板安装倾角的增大而增大。结合实际来看,衬板在粒径25mm、带速2.8m/s、高度3000mm、角度60°的工况下磨损最小。铁矿石散料对衬板的摩擦和冲击作用造成的应力较大的位置主要集中在衬板连接的螺栓孔周围,磨损最严重的位置多为颗粒与衬板优先接触区域,因此,为了降低应力集中,应该在衬板连接处加强螺栓孔的强度并进行圆角设计。展开更多
基金National Natural Science Foundation of China,Grant/Award Number:21805166111 Project of China,Grant/Award Number:D20015+1 种基金Ministryof Education,Hubei province,China,Grant/Award Number:T2020004Foundation of Science and Technology Bureau of Yichang City,Grant/Award Number:A21‐3‐012。
文摘In spite of the numerous advances in the development of H_(2)and O_(2)evolutions upon water splitting,the separation of H_(2)from O_(2)still remains a severe challenge.Herein,the novel dual-functional nanocatalysts Pd/carbon nanosphere(CNS),obtained via immobilization of ultrafine Pd nanoparticles onto CNS,are developed and employed for both selective H_(2)generation from HCOOH dehydrogenation and O_(2)evolution from H_(2)O_(2)decomposition.In these reactions,the highest activities for Pd/CNS-800(i.e.,calcinated at 800℃)are 2478 h−1 and 993 min^(−1)for H_(2)and O_(2)evolution,respectively.The highly efficient and selective“on-off”switch for selective H_(2)generation from HCOOH is successfully realized by pH adjustment.This novel and highly efficient nanocatalyst Pd/CNS-800 not only provides new approaches for the promising application of HCOOH and H_(2)O_(2)as economic and safe H_(2)and O_(2)carriers,respectively,for fuel cells,but also promotes the development of“on-off”switch for on-demand H_(2)evolution.
文摘针对转运系统转载物料过程中料斗衬板的磨损影响运输效率的问题,改用新型钢基陶瓷复合衬板来代替传统耐磨钢,采用离散元法(distinct element method,DEM)描述颗粒物料运动过程,通过Archard磨损模型分析预测不同工况条件下衬板磨损规律,并通过磨损规律和磨损特征验证了磨损模型的合理性。基于DEM的有限元法(finite element method,FEM)耦合方法分析了衬板应力与变形特性。研究结果表明:料斗衬板的最大磨损深度随颗粒度增大而减小,随传送带带速、衬板安装高度、衬板安装倾角的增大而增大。结合实际来看,衬板在粒径25mm、带速2.8m/s、高度3000mm、角度60°的工况下磨损最小。铁矿石散料对衬板的摩擦和冲击作用造成的应力较大的位置主要集中在衬板连接的螺栓孔周围,磨损最严重的位置多为颗粒与衬板优先接触区域,因此,为了降低应力集中,应该在衬板连接处加强螺栓孔的强度并进行圆角设计。
