Recent advances in one-dimensional nanostructures for energy electrocatalysis

Catalysts play decisive roles in determining the energy conversion efficiencies of energy devices.Up to now,various types of nanostructured materials have been studied as advanced electrocatalysts.This review highlights the application of one‐dimensional(1D)metal electrocatalysts in energy conversion,focusing on two important reaction systems-direct methanol fuel cells and water splitting.In this review,we first give a broad introduction of electrochemical energy conversion.In the second section,we summarize the recent significant advances in the area of 1D metal nanostructured electrocatalysts for the electrochemical reactions involved in fuel cells and water splitting systems,including the oxygen reduction reaction,methanol oxidation reaction,hydrogen evolution reaction,and oxygen evolution reaction.Finally,based on the current studies on 1D nanostructures for energy electrocatalysis,we present a brief outlook on the research trend in 1D nanoelectrocatalysts for the two clean electrochemical energy conversion systems mentioned above.

One-Dimensional (1D) ZnS Nanomaterials and Nanostructures

One-dimensional （1D） nanomaterials and nanostructures have received much attention due to their potential interest for understanding fundamental physical concepts and for applications in constructing nanoscale electric and optoelectronic devices. Zinc sulfide （ZnS） is an important semiconductor compound of Ⅱ-Ⅵ group, and the synthesis of 1D ZnS nanomaterials and nanostructures has been of growing interest owing to their promising application in nanoscale optoelectronic devices. This paper reviews the recent progress on 1D ZnS nanomaterials and nanostructures, including nanowires, nanowire arrays, nanorods, nanobelts or nanoribbons, nanocables, and hierarchical nanostructures etc. This article begins with a survey of various methods that have been developed for generating 1D nanomaterials and nanostructures, and then mainly focuses on structures, synthesis, characterization, formation mechanisms and optical property tuning, and luminescence mechanisms of 1D ZnS nanomaterials and nanostructures. Finally, this review concludes with personal views towards future research on 1D ZnS nanomaterials and nanostructures.

Solution-phase Synthesis of One-dimensional Semiconductor Nanostructures

The synthesis of one-dimensional （1D） semiconductor nanostructures has been studied intensively for a wide range of materials due to their unique structural and physical properties and promising potential for future technological applications. Among various strategies for synthesizing 1D semiconductor nanostructures, solution-phase synthetic routes are advantageous in terms of cost, throughput, modulation of composition, and the potential for large-scale and environmentally benign production. This article gives a concise review on the recent developments in the solution-phase synthesis of ID semiconductor nanostructures of different compositions, sizes, shapes, and architectures. We first introduce several typical solution-phase synthetic routes based on controlled precipitation from homogeneous solutions, including hydrothermal/solvothermal process, solution-liquid-solid （SLS） process, high-temperature organic-solution process, and low-temperature aqueous-solution process. Subsequently, we discuss two solution-phase synthetic strategies involving solid tem- plates or substrates, such as the chemical transformation of 1D sacrificial templates and the oriented growth of 1D nanostructure arrays on solid substrates. Finally, prospects of the solution-phase approaches to 1D semiconductor nanostructures will be briefly discussed.

Morphology-Controlled Growth of A1N One-Dimensional Nanostructures

Aluminum nitride （AIN） nanowires, serrated nanoribbons, and nanoribbons were selectively obtained through a simple chloride assisted chemical vapor deposition process. The morphologies of the products could be controlled by adjusting the deposition position and the flux of the reactant gas. The morphologies and structures of the AIN products were investigated in detail. The formation mechanism of the as-prepared different morphologies of AIN one-dimensional （ID） nanostructures was discussed on the basis of the experimental results.

An easy way to controllably synthesize one-dimensional Sm B_6 topological insulator nanostructures and exploration of their field emission applications

A convenient fabrication technique for samarium hexaboride（SmB6） nanostructures（nanowires and nanopencils） is developed, combining magnetron-sputtering and chemical vapor deposition. Both nanostructures are proven to be single crystals with cubic structure, and they both grow along the [001] direction. Formation of both nanostructures is attributed to the vapor-liquid-solid（VLS） mechanism, and the content of boron vapor is proposed to be the reason for their different morphologies at various evaporation distances. Field emission（FE） measurements show that the maximum current density of both the as-grown nanowires and nanopencils can be several hundred μA/cm^2, and their FN plots deviate only slightly from a straight line. Moreover, we prefer the generalized Schottky-Nordheim（SN） model to comprehend the difference in FE properties between the nanowires and nanopencils. The results reveal that the nonlinearity of FN plots is attributable to the effect of image potential on the FE process, which is almost independent of the morphology of the nanostructures.All the research results suggest that the SmB6 nanostructures would have a more promising future in the FE area if their surface oxide layer was eliminated in advance.

Low-dimensional structures formed by irradiation of laser

Some kinds of low-dimensional nanostructures can be formed by irradiation of laser on the pure silicon sample and the SiGe alloy sample. This paper has studied the photoluminescence （PL） of the hole-net structure of silicon and the porous structure of SiGe where the PL intensity at 706nm and 725nm wavelength increases obviously. The effect of intensity-enhancing in the PL peaks cannot be explained within the quantum confinement alone. A mechanism for increasing PL emission in the above structures is proposed, in which the trap states of the interface between SiO2 and nanocrystal play an important role.

Numerical study on three-dimensional flow field of continuously rotating detonation in a toroidal chamber

Gaseous detonation propagating in a toroidal chamber was numerically studied for hydrogen/oxygen/nitrogen mixtures. The numerical method used is based on the three-dimensional Euler equations with detailed finiterate chemistry. The results show that the calculated streak picture is in qualitative agreement with the picture recorded by a high speed streak camera from published literature. The three-dimensional flow field induced by a continuously rotating detonation was visualized and distinctive features of the rotating detonations were clearly depicted. Owing to the unconfined character of detonation wavelet, a deficit of detonation parameters was observed. Due to the effects of wall geometries, the strength of the outside detonation front is stronger than that of the inside portion. The detonation thus propagates with a constant circular velocity. Numerical simulation also shows three-dimensional rotating detonation structures, which display specific feature of the detonation- shock combined wave. Discrete burning gas pockets are formed due to instability of the discontinuity. It is believed that the present study could give an insight into the interest- ing properties of the continuously rotating detonation, and is thus beneficial to the design of continuous detonation propulsion systems.

One-dimensional Ga N nanomaterials transformed from one-dimensional Ga_2O_3 and Ga nanomaterials

One-dimensional(1D) GaN nanomaterials exhibiting various morphologies and atomic structures were prepared via ammoniation of either Ga_2O_3 nanoribbons, Ga_2O_3 nanorods or Ga nanowires filled into carbon nanotubes(CNTs). The 1D GaN nanomaterials transformed from Ga_2O_3 nanoribbons consisted of numerous GaN nanoplatelets having the close-packed plane, i.e.(0002)2H or(111)3C parallel to the axes of starting nanoribbons. The 1D GaN nanomaterials converted from Ga_2O_3 nanorods were polycrystalline rods covered with GaN nanoparticles along the axes. The 1D GaN nanomaterials prepared from Ga nanowires filled into CNTs displayed two dominant morphologies:(i) single crystalline Ga N nanocolumns coated by CNTs, and(ii) pure single crystalline Ga N nanowires. The cross-sectional shape of Ga N nanowires were analyzed through the transmission electron microscopy(TEM) images. Formation mechanism of all-mentioned 1D GaN nanomaterials is then thoroughly discussed.

Infinite Three-Dimensional Coordination Polymers: Synthesis and Structures of [Cd (4,4'-bpy)_2 (H_2O)_2]_n (pic)_(2n),[Zn (4,4'-bpy)_2 (H_2O)_2]_n(pic)_(2n) (H_2O)_(2n), and [Zn (4,4'-bpy)_2 (H_2O)_2]_n (4,4'-bpy)_n(H_2O)_n (pic)_(2n)

Three Complexes of the formula [Cd (4,4'-bpy)_2 (H_2O)_2]_n. (pic)_(2n) (1) [Zn (4,4'-bpy)_2 (H_2O)]_n (4,4'-bpy)_n(H_2O)_n (pic)-(2n) (2) and [Zn (4,4'-bpy)_2 (H_2O)]_n (4,4'-bpy)_n (pic)-(2n)(H_2O)_n (3) (4.4'-bpy = 4.4'-bipyridine. pic = picric anion ) have been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. They all have infinite three-dimensional network structure. crystallizing in the monoclinic space group C2/c (1) and Cc (2.3).

3-Dimensional Body Measurement Technology

3 - dimensional body measurement technology, the basis of developing high technology in industry, accelerates digital development of aplparel industry. This paper briefly introduces the history of 3 - dimensional body measurement technology, and recounts the principle and primary structure of some types of 3 - dimensional automatic body measurement system. With this understanding, it discusses prospect of 3- dimensional CAD and virtual technology used in apparel industry.

First-principles investigation of chemical modification on two-dimensional iron-phthalocyanine sheet

Successful synthesis of single iron-phthalocyanie （FePc） framework layer on substrate and its transferrable properties open the door for decorating the separately distributed transition metals for exploring the diverse properties. We have studied the effects of chemical modification on two-dimensional FePc organometallic framework with density functional theory. For simplicity, the non-metal atoms with variant valence electrons are used as prototypes to estimate the effects ＆ore chemical modifications with different functional groups. The thermo-stabilities of the non-metal atom decorated complex sheet materials have been estimated by the first-principles constant energy molecular dynamic simulations. Upon the non- metal atom adsorption, the magnetic moment could be changed from 2 ~tB to 0, 1, 2, and 3 ~tB per unit cell for the case of tetra-, penta-, hexa-, and hepta-valent non-metal modifications, respectively, showing interesting promise to tailor its magnetic properties for potential applications.

Preparation,Properties,and Applications of Low-Dimensional Molecular Organic Nanomaterials

In recent years, great progress has been made in research and development of small-molecule organic materials with various low-dimensional nanostructures. This paper presents a comprehensive review of recent research progress in this field, including preparation, electronic and optoelectronic properties and applications. First, an introduction gives to the reprecipitation, soft templates methods, and progress in synthesis and morphological control of low-dimensional small-molecule organic nanomaterials. Their unique optical and electronic properties and research progress in these aspects are reviewed and discussed in detail. Applications based on low-dimensional small-molecule organic nanomaterials are briefly described. Finally, some perspectives to the future development of this field are addressed.

Parametric study on single shot peening by dimensional analysis method incorporated with finite element method

Shot peening is a widely used surface treatment method by generating compressive residual stress near the surface of metallic materials to increase fatigue life and re- sistance to corrosion fatigue, cracking, etc. Compressive re- sidual stress and dent profile are important factors to eval- uate the effectiveness of shot peening process. In this pa- per, the influence of dimensionless parameters on maximum compressive residual stress and maximum depth of the dent were investigated. Firstly, dimensionless relations of pro- cessing parameters that affect the maximum compressive residual stress and the maximum depth of the dent were de- duced by dimensional analysis method. Secondly, the in- fluence of each dimensionless parameter on dimensionless variables was investigated by the finite element method. Fur- thermore, related empirical formulas were given for each di- mensionless parameter based on the simulation results. Fi- nally, comparison was made and good agreement was found between the simulation results and the empirical formula, which shows that a useful approach is provided in this pa- per for analyzing the influence of each individual parameter.

One-Dimensional ZnO Nanostructures： Solution Growth and Functional Properties

One-dimensional （1D） ZnO nanostructures have been studied intensively and extensively over the last decade not only for their remarkable chemical and physical properties, but also for their diverse current and future technological applications. This article gives a comprehensive overview of the progress that has been made within the context of 1D ZnO nanostructures synthesized via wet chemical methods. We will cover the synthetic methodologies and the corresponding growth mechanisms, various nanostructures grown, their doping and alloying, and position-controlled growth on substrates. Finally, we will review their functional properties in catalysis, hydrophobic surface modification, sensing, and electronic, optical, optoelectronic, and energy harvesting devices.

Recent progress in molten salt synthesis of low-dimensional perovskite oxide nanostructures, structural characterization,properties, and functional applications: A review

Molten salt synthesis （MSS） method has advantages of the simplicity in the process equipment, versatile and large-scale synthesis, and friendly environment, which provides an excellent approach to synthesize high pure oxide powders with controllable compositions and morphologies. Among these oxides, perovskite oxides with a composition of ABO3 exhibit a broad spectrum of physical properties and functions （e.g. ferroelectric, piezoelectric, magnetic, photovoltaic and photocatalytic properties）. The downscaling of the spatial geometry of perovskite oxides into nanometers result in novel properties that are different from the bulk and film counterparts. Recent interest in nanoscience and nanotechnology has led to great efforts focusing on the synthesis of low-dimensional perovskite oxide nanostructures （PONs） to better understand their novel physical properties at nanoscale. Therefore, the low-dimensional PONs such as perovskite nanoparticles, nanowires, nanorods, nanotubes, nanofibers, nanobelts, and two dimensional oxide nanostructures, play an important role in developing the next generation of oxide electronics. In the past few years, much effort has been made on the synthesis of PONs by MSS method and their structural characterizations. The functional applications of PONs are also explored in the fields of storage memory, energy harvesting, and solar energy conversion. This review summarizes the recent progress in the synthesis of low-dimensional PONs by MSS method and its modified ways. Their structural char- acterization and physical properties are also scrutinized. The potential applications of low-dimensional PONs in different fields such as data memory and storage, energy harvesting, solar energy conversion, are highlighted. Perspectives concerning the future research trends and challenges of low-dimensional PONs are also outlined. ~ 2017 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science ＆ Technology.

CONTROLLED FABRICATION OF ONE-DIMENSIONAL POLYMER NANOSTRUCTURES via METALLOGEL TEMPLATE POLYMERIZATION

A facile method is reported to controllably fabricate one dimensional （1D） polymer nan,astructures via metallogel template polymerization. The metallogel was prepared through coordination interactions between silver ions and a ligand （L） bearing three pyridyl groups in tetrahydrofuran （THF）. The diameters of the metallogel nanofibers could be tuned by the gel concentration （GC）. Due to its high thermal stability and facility of removal, the metallogel was used as the template for radical polymerization of diacryolyl-2,6-diaminopyridine （DADAP） to form poly-diacryolyl-2,6-diaminopyridine （PDADAP） nanostructures. The gradually eroding of the templates by PDADAP provided us an effective way to fabricate various nanostructures of the polymer. We have demonstrated that different 1D nanostructures, including n^noribbons, nanotubes and nanowires, could be selectively fabricated by adjusting polymerization time, monomer concentration and GC. The rheological properties of the gel samples were tested by a rheometer. As prolonging the reaction time, more and more polymers were formed and the strength of the resulting polymer gels became higher and higher. The simple preparation process, easy controlled microstructures and adequate gel strength would make it a facile synthetic method for different 1D polymer nanosturctures.

Flexible One-Dimensional Nanostructures:A Review

This review discusses the recent reports on one-dimensional(1D) nanostructures with unusual flexibility.We discuss the importance that flexibility could have in future applications of nanowires and other nanostructures,and detail the two main approaches that have been followed to this day to synthesize highly flexible 1D nanostructures.One approach is based on making crystals in which one or two dimensions of the structure are comparable in size with the unit cell.Such thinness has been shown to provide unusual flexibility.The other approach conjoins hard nanostructures with flexible joints.

Effects of indium doping concentration on the morphology and electrical properties of one-dimensional SnO_2 nanostructures prepared by a molten salt method

In this paper,indium doped SnO2 nanorods and nanowires have been prepared by the molten salt method,and the effects of indium doping concentration on the morphology and electrical properties of one-dimensional(1D) SnO2 nanostructures have been studied.It is found that indium doping concentration can affect the epitaxial growth,morphology and the electrical conductance of 1D SnO2 nanostructures.It is also found that the element made by using 6 mol% indium doped SnO2 nanorods responds to nitrogen gas.

溶胶-凝胶法制备新型蓄能复合材料

用溶胶 凝胶法制备C17H3 5COOH SiO2 复合材料 ,并用透射电镜、扫描电镜、差示扫描量热分析等测试手段研究其结构与性能。结果表明 ,该复合材料是三维网络状纳米复合材料 ,而且具有良好的蓄热能力 。

二维纳米结构--氧化铋纳米片的制备与表征

利用物理气相沉积法，在氲气和氧气保护下将氧化铋粉末在水平管式炉中常压加热至1050℃，然后降温沉积，在硅衬底上得到了大量具有规则矩形外形的二维纳米结构——片状氧化铋．纳米片的长约1200mm，宽约300nm，厚约10～15nm．采用扫描电镜（SEM），X-ray能谱仪（EDS）、高分辨透射电镜（HRTEM）等测试手段分析了样品的形貌、成分及微结构．研究分析了衬底放置方式对产物沉积量的影响．