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Calculation and prediction of divertor detachment via impurity seeding by using one-dimensional model
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作者 周文杰 刘晓菊 +5 位作者 邬潇河 李邦 石奇奇 樊皓尘 杨艳杰 李国强 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期370-379,共10页
Achieving the detachment of divertor can help to alleviate excessive heat load and sputtering problems on the target plates,thereby extending the lifetime of divertor components for fusion devices.In order to provide ... Achieving the detachment of divertor can help to alleviate excessive heat load and sputtering problems on the target plates,thereby extending the lifetime of divertor components for fusion devices.In order to provide a fast but relatively reliable prediction of plasma parameters along the flux tube for future device design,a one-dimensional(1D)modeling code for the operating point of impurity seeded detached divertor is developed based on Python language,which is a fluid model based on previous work(Plasma Phys.Control.Fusion 58045013(2016)).The experimental observation of the onset of divertor detachment by neon(Ne)and argon(Ar)seeding in EAST is well reproduced by using the 1D modeling code.The comparison between the 1D modeling and two-dimensional(2D)simulation by the SOLPS-ITER code for CFETR detachment operation with Ne and Ar seeding also shows that they are in good agreement.We also predict the radiative power loss and corresponding impurity concentration requirement for achieving divertor detachment via different impurity seeding under high heating power conditions in EAST and CFETR phase II by using the 1D model.Based on the predictions,the optimized parameter space for divertor detachment operation on EAST and CFETR is also determined.Such a simple but reliable 1D model can provide a reasonable parameter input for a detailed and accurate analysis by 2D or three-dimensional(3D)modeling tools through rapid parameter scanning. 展开更多
关键词 divertor detachment impurity seeding one-dimensional modeling
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Numerical Investigations on the Resonance Errors of Multiscale Discontinuous Galerkin Methods for One-Dimensional Stationary Schrödinger Equation
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作者 Bo Dong Wei Wang 《Communications on Applied Mathematics and Computation》 EI 2024年第1期311-324,共14页
In this paper,numerical experiments are carried out to investigate the impact of penalty parameters in the numerical traces on the resonance errors of high-order multiscale discontinuous Galerkin(DG)methods(Dong et al... In this paper,numerical experiments are carried out to investigate the impact of penalty parameters in the numerical traces on the resonance errors of high-order multiscale discontinuous Galerkin(DG)methods(Dong et al.in J Sci Comput 66:321–345,2016;Dong and Wang in J Comput Appl Math 380:1–11,2020)for a one-dimensional stationary Schrödinger equation.Previous work showed that penalty parameters were required to be positive in error analysis,but the methods with zero penalty parameters worked fine in numerical simulations on coarse meshes.In this work,by performing extensive numerical experiments,we discover that zero penalty parameters lead to resonance errors in the multiscale DG methods,and taking positive penalty parameters can effectively reduce resonance errors and make the matrix in the global linear system have better condition numbers. 展开更多
关键词 Discontinuous Galerkin(DG)method Multiscale method Resonance errors one-dimensional Schrödinger equation
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Laplace NMR谱图重建——从经典正则化到深度学习
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作者 杨钰 陈博 +3 位作者 吴柳滨 林恩平 黄玉清 陈忠 《波谱学杂志》 CAS 2024年第2期191-208,共18页
拉普拉斯核磁共振(Laplace NMR)可以提供待测样品的扩散系数或弛豫时间等物理参数信息,是用于研究分子化学结构、动力学和相互作用的强大工具.Laplace NMR的适用性很大程度上取决于拉普拉斯逆变换相关的信号处理算法的性能.在本文中,我... 拉普拉斯核磁共振(Laplace NMR)可以提供待测样品的扩散系数或弛豫时间等物理参数信息,是用于研究分子化学结构、动力学和相互作用的强大工具.Laplace NMR的适用性很大程度上取决于拉普拉斯逆变换相关的信号处理算法的性能.在本文中,我们首先讨论了Laplace NMR谱图重建问题的不适定性,接着回顾了经典的基于正则化约束的重建算法,并介绍了目前前沿的深度学习算法在处理Laplace反演问题方面的应用,最后总结了这些算法的优缺点,并对Laplace NMR信号处理方法未来改进方向进行了展望. 展开更多
关键词 拉普拉斯核磁共振 扩散核磁共振 扩散排序谱 拉普拉斯反演变换 深度学习
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应用于太赫兹波驱动的DNP-NMR传输线
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作者 王维 张澳歌 +4 位作者 宋韬 姚纳 焦蛟 张开春 刘頔威 《真空电子技术》 2024年第3期5-9,共5页
太赫兹波驱动的动态核极化增强核磁共振波谱系统可大幅提高信号灵敏度和缩短检测时间。该系统需采用传输线在驱动源回旋管与谱仪之间进行太赫兹波传输。本文针对400 MHz增强核磁共振系统设计了由准光模式变换器和波纹波导组成的太赫兹... 太赫兹波驱动的动态核极化增强核磁共振波谱系统可大幅提高信号灵敏度和缩短检测时间。该系统需采用传输线在驱动源回旋管与谱仪之间进行太赫兹波传输。本文针对400 MHz增强核磁共振系统设计了由准光模式变换器和波纹波导组成的太赫兹传输线,并进行了相关实验测试,测试结果表明准光模式变换器可将263 GHz回旋管TE 03模式转换成准高斯波束,其高斯成份为97%,整个传输线最终输出波束的高斯成份为96.3%。 展开更多
关键词 太赫兹 增强核磁共振 回旋管 传输线 准光模式变换
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烟草果胶和纤维素含量^(13)C MultiCP/MAS NMR同时测量
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作者 王鹏 唐杰 +5 位作者 杨明宇 朱立军 汪长国 陈昆燕 王鹏 杨俊 《安徽农业大学学报》 CAS CSCD 2024年第3期516-522,共7页
果胶和纤维素是烟草细胞壁的重要组成成分,其含量对烟草品质与安全性产生重要影响。传统分析方法难以实现果胶和纤维素的同时定量。本文在优化核磁共振波谱序列条件的基础上,采用固体^(13)C多重交叉极化/魔角旋转核磁共振波谱分析技术(^... 果胶和纤维素是烟草细胞壁的重要组成成分,其含量对烟草品质与安全性产生重要影响。传统分析方法难以实现果胶和纤维素的同时定量。本文在优化核磁共振波谱序列条件的基础上,采用固体^(13)C多重交叉极化/魔角旋转核磁共振波谱分析技术(^(13)C MultiCP/MAS NMR)建立了烟草果胶和纤维素含量的同时测量新方法。方法以聚半乳糖醛酸和微晶纤维素为标准物质,以3-(三甲基甲硅烷基)丙酸-d4钠盐(TMSP)做为内标物质,分别建立内标法标准曲线,相关系数R2为0.999 0和0.998 2。果胶测量的检出限和定量限分别为0.38和1.28 mg·g^(–1),精密度(RSD,n=5)小于3.05%。纤维素测量的检出限和定量限为1.01和3.32 mg·g^(–1),精密度(RSD,n=5)小于2.74%。应用本方法测量烟梗、烟草薄片和烟叶等不同类型样品中的果胶和纤维素含量,并对比烟草行业标准方法的测量结果,果胶含量的相对误差在-0.95%至4.51%之间,纤维素含量的相对误差在0.77%至2.46%之间。表明^(13)C MultiCP/MAS NMR方法快速,准确,适合批量样品的分析测量,为果胶和纤维素等细胞壁类大分子的同时定量分析提供重要技术支持。 展开更多
关键词 果胶 纤维素 ^(13)C MultiCP/MAS nmr 烟草
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Prediction of one-dimensional CrN nanostructure as a promising ferromagnetic half-metal
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作者 相文雨 王亚萍 +3 位作者 纪维霄 侯文杰 李胜世 王培吉 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第3期429-435,共7页
Searching for one-dimensional(1D)nanostructure with ferromagnetic(FM)half-metallicity is of significance for the development of miniature spintronic devices.Here,based on the first-principles calculations,we propose t... Searching for one-dimensional(1D)nanostructure with ferromagnetic(FM)half-metallicity is of significance for the development of miniature spintronic devices.Here,based on the first-principles calculations,we propose that the 1D CrN nanostructure is a FM half-metal,which can generate the fully spin-polarized current.The ab initio molecular dynamic simulation and the phonon spectrum calculation demonstrate that the 1D CrN nanostructure is thermodynamically stable.The partially occupied Cr-d orbitals endow the nanostructure with FM half-metallicity,in which the half-metallic gap(?s)reaches up to 1.58 eV.The ferromagnetism in the nanostructure is attributed to the superexchange interaction between the magnetic Cr atoms,and a sizable magnetocrystalline anisotropy energy(MAE)is obtained.Moreover,the transverse stretching of nanostructure can effectively modulate?s and MAE,accompanied by the preservation of half-metallicity.A nanocable is designed by encapsulating the CrN nanostructure with a BN nanotube,and the intriguing magnetic and electronic properties of the nanostructure are retained.These novel characteristics render the 1D CrN nanostructure as a compelling candidate for exploiting high-performance spintronic devices. 展开更多
关键词 HALF-METAL FERROMAGNETISM one-dimensional nanostructure first-principles calculations
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Size effect on light propagation modulation near band edges in one-dimensional periodic structures
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作者 唐洋 王佳俊 +2 位作者 赵星棋 李同宇 石磊 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第5期421-424,共4页
Periodic photonic structures can provide rich modulation in propagation of light due to well-defined band structures.Especially near band edges,light localization and the effect of near-zero refractive index have attr... Periodic photonic structures can provide rich modulation in propagation of light due to well-defined band structures.Especially near band edges,light localization and the effect of near-zero refractive index have attracted wide attention.However,the practically fabricated structures can only have finite size,i.e.,limited numbers of periods,leading to changes of the light propagation modulation compared with infinite structures.Here,we study the size effect on light localization and near-zero refractive-index propagation near band edges in one-dimensional periodic structures.Near edges of the band gap,as the structure's size shrinks,the broadening of the band gap and the weakening of the light localization are discovered.When the size is small,an added layer on the surface will perform large modulation in the group velocity.Near the degenerate point with Dirac-like dispersion,the zero-refractive-index effects like the zero-phase difference and near-unity transmittance retain as the size changes,while absolute group velocity fluctuates when the size shrinks. 展开更多
关键词 one-dimensional(1D)photonic crystal finite-size effect band gap light localization zerorefractive-index effect
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NMR、GPC和MALDI-TOF应用于聚乙二醇单甲醚的教学实验
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作者 史声宇 刘智勇 +4 位作者 张宗瑞 相益信 沈显荣 宋庆平 高建纲 《广州化工》 CAS 2024年第10期129-131,共3页
将核磁共振(NMR)、凝胶渗透色谱(GPC)和基质辅助激光解吸/电离飞行时间质谱(MALDI-TOF)三种高级分析技术整合到本科《高分子材料研究方法》课程的实验教学中。通过分析聚乙二醇单甲醚样品,学生深入学习了高分子结构和分子量的表征方法,... 将核磁共振(NMR)、凝胶渗透色谱(GPC)和基质辅助激光解吸/电离飞行时间质谱(MALDI-TOF)三种高级分析技术整合到本科《高分子材料研究方法》课程的实验教学中。通过分析聚乙二醇单甲醚样品,学生深入学习了高分子结构和分子量的表征方法,熟悉了这三种仪器的操作和原理。本实验显著提升了课程内容的深度和广度,激发了学生的学习兴趣,并且增强了学生的实践操作能力和创新思维。综合应用这些分析技术,使学生在高分子材料的研究中获得了更全面的理解和技能的提升。 展开更多
关键词 高分子 核磁共振 凝胶渗透色谱 大分子质谱
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基于^(13)C-NMR偶极去相技术的有机肥料中有机组分特征研究
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作者 王林洋 张育维 +3 位作者 李亚丽 唐杉 谢丽华 汪洪 《植物营养与肥料学报》 CAS CSCD 北大核心 2024年第8期1630-1638,共9页
【目的】在固体13C-NMR的交叉极化魔角旋转全边带抑制(cross polarization/magic angle spinning/total suppression of sidebands,CP/MAS/TOSS)技术得到的谱图中,质子碳与非质子碳的信号重叠。偶极去相(dipolar dephasing,DD)技术利用1... 【目的】在固体13C-NMR的交叉极化魔角旋转全边带抑制(cross polarization/magic angle spinning/total suppression of sidebands,CP/MAS/TOSS)技术得到的谱图中,质子碳与非质子碳的信号重叠。偶极去相(dipolar dephasing,DD)技术利用13C-1H异核耦合作用大小的差异,区分与不同质子结合的13C核基团。本研究基于DD技术探讨有机肥料中碳结构特征。【方法】供试有机肥料样品包括3种秸秆(小麦秸秆、玉米秸秆、水稻秸秆)、3种粪肥(鸡粪、牛粪、猪粪)和3种腐植酸肥(腐植酸铵、腐植酸钠、腐植酸钾)样品,利用13C-NMR谱的CP/MAS/TOSS结合DD技术,测定了不同来源的有机肥料样品图谱,比较其碳分布比例。【结果】秸秆和粪肥样品中烷氧碳组分较多,占鉴定出所有碳组分的比例分别为55%和31%~37%,非质子化的烷氧碳占比不到3%;秸秆、猪粪样品中非质子芳香碳占3%~4%,鸡粪和牛粪样品中非质子芳香碳分别占15%和11%,较秸秆和猪粪样品含有更多的非质子化芳香族化合物。粪肥和秸秆样品中甲氧基碳占比低于烷基氮。腐植酸样品以芳香碳、羧基碳和酰胺基碳为主,羧基碳和酰胺基碳占到12%~16%,总芳香族碳占48%~72%,非质子芳香碳占25%~37%,表明腐植酸芳香骨架上可能存在较多取代。【结论】基于CP/TOSS结合DD技术(偶极相移延时时间设置为40μs)分析结果发现,鸡粪和牛粪中非质子芳香碳占比高于猪粪和秸秆;腐植酸肥芳香族碳比例高于粪肥和秸秆,尤其是非质子芳香碳占比较高,表明腐植酸肥芳香化程度高于粪肥和秸秆。 展开更多
关键词 有机肥料 ^(13)C-核磁共振 交叉极化 偶极去相
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A Dugdale-Barenblatt model for elliptical orifice problem with asymmetric cracks in one-dimensional orthorhombic quasicrystals
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作者 Jing ZHANG Guanting LIU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第9期1533-1546,共14页
By means of Muskhelishvili’s method and the technique of generalized conformal mapping,the physical plane problems are transformed into regular mathematical problems in quasicrystals(QCs).The analytical solution to a... By means of Muskhelishvili’s method and the technique of generalized conformal mapping,the physical plane problems are transformed into regular mathematical problems in quasicrystals(QCs).The analytical solution to an elliptical orifice problem with asymmetric cracks in one-dimensional(1D)orthorhombic QCs is obtained.By using the Dugdale-Barenblatt model,the plastic simulation at the crack tip of the elliptical orifice with asymmetric cracks in 1D orthorhombic QCs is performed.Finally,the size of the atomic cohesive force zone is determined precisely,and the size of the atomic cohesive force zone around the crack tip of an elliptical orifice with a single crack or two symmetric cracks is obtained. 展开更多
关键词 one-dimensional(1D)orthorhombic quasicrystal(QC) Dugdale-Barenblatt model atomic cohesive force zone crack
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Robust Damage Detection and Localization Under Complex Environmental Conditions Using Singular Value Decomposition-based Feature Extraction and One-dimensional Convolutional Neural Network
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作者 Shengkang Zong Sheng Wang +3 位作者 Zhitao Luo Xinkai Wu Hui Zhang Zhonghua Ni 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第3期252-261,共10页
Ultrasonic guided wave is an attractive monitoring technique for large-scale structures but is vulnerable to changes in environmental and operational conditions(EOC),which are inevitable in the normal inspection of ci... Ultrasonic guided wave is an attractive monitoring technique for large-scale structures but is vulnerable to changes in environmental and operational conditions(EOC),which are inevitable in the normal inspection of civil and mechanical structures.This paper thus presents a robust guided wave-based method for damage detection and localization under complex environmental conditions by singular value decomposition-based feature extraction and one-dimensional convolutional neural network(1D-CNN).After singular value decomposition-based feature extraction processing,a temporal robust damage index(TRDI)is extracted,and the effect of EOCs is well removed.Hence,even for the signals with a very large temperature-varying range and low signal-to-noise ratios(SNRs),the final damage detection and localization accuracy retain perfect 100%.Verifications are conducted on two different experimental datasets.The first dataset consists of guided wave signals collected from a thin aluminum plate with artificial noises,and the second is a publicly available experimental dataset of guided wave signals acquired on a composite plate with a temperature ranging from 20℃to 60℃.It is demonstrated that the proposed method can detect and localize the damage accurately and rapidly,showing great potential for application in complex and unknown EOC. 展开更多
关键词 Ultrasonic guided waves Singular value decomposition Damage detection and localization Environmental and operational conditions one-dimensional convolutional neural network
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Analysis of Dynamical Behavior of One-Dimensional Real Maps: An Executable Dynamical Programming Software Approach
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作者 Mohammad Sharif Ullah Masuda Akter K. M. Ariful Kabir 《Applied Mathematics》 2023年第9期652-672,共21页
The dynamical behavior of real-world phenomena is implausible graphically due to the complexity of mathematical coding. The present article has mainly focused on some one-dimensional real maps’ dynamical behavior irr... The dynamical behavior of real-world phenomena is implausible graphically due to the complexity of mathematical coding. The present article has mainly focused on some one-dimensional real maps’ dynamical behavior irrespective of using coding. In continuation, linear, quadratic, cubic, higher-order, exponential, logarithmic, and absolute value maps have been used to scrutinize their dynamical behavior, including the characteristics of the orbit of points. Dynamical programming software (DPS.exe) will be proposed as a new technique to ascertain the dynamical behavior of said maps. Thus, a mathematician can automatically determine one-dimensional real maps’ dynamical behavior apart from complicated programming code and analytical solutions. 展开更多
关键词 one-dimensional Map Cobweb Orbit Diagram Fixed Point the Fate of the Orbit
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基于小型化原子磁力计的零场NMR波谱仪搭建与测试
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作者 付方跃 郭清乾 +5 位作者 冯晓宇 徐佳玉 姚泽坤 胡涛 杨晓冬 常严 《波谱学杂志》 CAS 2024年第1期87-98,共12页
常规高场NMR波谱仪依托超导技术,其体积大、维护成本高,且存在样本磁化率不均匀导致的谱线展宽现象,零场或近零场NMR技术则可实现有效互补.本文自主搭建了一套基于小型原子磁力计的可移动零场NMR波谱仪,采用以多功能采集卡(National Ins... 常规高场NMR波谱仪依托超导技术,其体积大、维护成本高,且存在样本磁化率不均匀导致的谱线展宽现象,零场或近零场NMR技术则可实现有效互补.本文自主搭建了一套基于小型原子磁力计的可移动零场NMR波谱仪,采用以多功能采集卡(National Instruments PCIe-6353)为核心的集成控制系统,仪器主磁场强度小于1nT,可实现高分辨率的J-耦合谱采集.为实现对自旋体系的有效操控,利用样品绝热初态的单脉冲激发实现对三轴脉冲线圈的精确标定.在此基础上,使用改进的组合脉冲序列实现了在^(13)C-^(1)H异核体系下的单自旋选择性操控,验证了零场NMR波谱仪的有效性. 展开更多
关键词 零场核磁共振 J-耦合谱 原子磁力计 单自旋操控
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Thermal-induced interfacial behavior of a thin one-dimensional hexagonal quasicrystal film
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作者 Huayang DANG Dongpei QI +2 位作者 Minghao ZHAO Cuiying FAN C.S.LU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第5期841-856,共16页
In this paper,we investigate the interfacial behavior of a thin one-dimensional(1D)hexagonal quasicrystal(QC)film bonded on an elastic substrate subjected to a mismatch strain due to thermal variation.The contact inte... In this paper,we investigate the interfacial behavior of a thin one-dimensional(1D)hexagonal quasicrystal(QC)film bonded on an elastic substrate subjected to a mismatch strain due to thermal variation.The contact interface is assumed to be nonslipping,with both perfectly bonded and debonded boundary conditions.The Fourier transform technique is adopted to establish the integral equations in terms of interfacial shear stress,which are solved as a linear algebraic system by approximating the unknown phonon interfacial shear stress via the series expansion of the Chebyshev polynomials.The expressions are explicitly obtained for the phonon interfacial shear stress,internal normal stress,and stress intensity factors(SIFs).Finally,based on numerical calculations,we briefly discuss the effects of the material mismatch,the geometry of the QC film,and the debonded length and location on stresses and SIFs. 展开更多
关键词 one-dimensional(1D)hexagonal quasicrystal(QC)film stress intensity factor(SIF) thermal variation Chebyshev polynomial interfacial behavior
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舒肝宁注射液的^(1)H-NMR指纹图谱分析
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作者 何峰 朱彤彤 +4 位作者 韩春月 张昀 杨翠萍 韩立峰 付志飞 《中南药学》 CAS 2024年第3期753-759,共7页
目的对舒肝宁注射液的^(1)H-NMR指纹图谱进行分析,为其质量控制标准技术升级提供参考依据。方法使用Noesygppr1d脉冲序列[recycle delay(RD)-90°-t 1-90°-t_(m)-90°-ACQ]采集1H-NMR谱图,质子共振频率为600.13 MHz,实验... 目的对舒肝宁注射液的^(1)H-NMR指纹图谱进行分析,为其质量控制标准技术升级提供参考依据。方法使用Noesygppr1d脉冲序列[recycle delay(RD)-90°-t 1-90°-t_(m)-90°-ACQ]采集1H-NMR谱图,质子共振频率为600.13 MHz,实验温度为298 K,通过方法学考察验证分析方法可靠性,采用相关系数法和夹角余弦法评价不同批次舒肝宁注射液样品的相似度。结果对舒肝宁注射液的^(1)H-NMR指纹图谱进行分析,共鉴定出88种化学成分,且不同批次的舒肝宁注射液具有较高的相似度。结论建立了一种基于^(1)H-NMR的舒肝宁注射液质量控制方法,可为舒肝宁注射液技术升级提供参考依据。 展开更多
关键词 舒肝宁注射液 1H-nmr 指纹图谱 相似度
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基于LF-NMR研究双孢菇远红外辅助热泵干燥过程中水分迁移规律及品质变化
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作者 高晓倩 刘瑞玲 +4 位作者 吴来春 孟祥红 吴伟杰 陈杭君 郜海燕 《中国食品学报》 EI CAS CSCD 北大核心 2024年第8期403-413,共11页
为研究双孢菇远红外辅助热泵干燥过程中水分分布规律及品质变化,采用低场核磁共振及成像技术分别对干燥过程的双孢菇进行弛豫特性及质子密度成像分析,并研究干燥前、后双孢菇微观结构和品质的变化。结果表明:在热泵温度分别为45,55,65℃... 为研究双孢菇远红外辅助热泵干燥过程中水分分布规律及品质变化,采用低场核磁共振及成像技术分别对干燥过程的双孢菇进行弛豫特性及质子密度成像分析,并研究干燥前、后双孢菇微观结构和品质的变化。结果表明:在热泵温度分别为45,55,65℃时,双孢菇到达干燥终点的时间分别为510,420,390 min。双孢菇的T2反演谱有3个不同的弛豫峰:T21(3~23 ms)、T22(25~155 ms)和T23(155~1084 ms),分别代表双孢菇中的结合水、不易流动水和自由水。干燥初期,T23左迁幅度很大,干燥后期,左迁幅度变小,随着干燥时间的延长,自由水的流动性降低。干燥结束时,T23对应的弛豫峰下降约99.8%,只剩下部分T21和T22对应的峰,说明自由水几乎被完全去除,双孢菇内仅剩结合水和少量不易流动水。低场核磁共振图像显示,65℃条件下,干燥360 min,水分基本被脱除,而55℃和45℃处理组分别在干燥390 min和450 min才基本脱除。双孢菇外侧的水分先被脱除,内部的水分向外迁移,并且温度越高,内部水分迁移速率越快。另外,65℃条件下的双孢菇的BI值分别比45℃和55℃条件下的BI低30.55%和22.69%,说明65℃更能维持双孢菇原有的色泽。65℃条件下干燥的双孢菇的抗坏血酸、总酚、总黄酮含量分别比干燥前下降84.62%,55.80%和36.78%,与45℃和55℃相比,65℃下双孢菇营养成分的损失最小。本研究表明低场核磁共振及成像技术为双孢菇干燥过程中水分的变化提供了直观的参考依据,也可为双孢菇的远红外辅助热泵干燥工艺优化干燥参数、提高产品质量提供理论参考。 展开更多
关键词 双孢菇 远红外辅助热泵干燥 低场核磁共振 水分分布 品质
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Postmortem ^(7)Li NMR analysis for assessing the reversibility of lithium metal electrodes in lithium metal batteries
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作者 Jaewon Baek Sunha Kim +1 位作者 Hee-Tak Kim Oc Hee Han 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期430-440,共11页
Despite the proficiency of lithium(Li)-7 NMR spectroscopy in delineating the physical and chemical states of Li metal electrodes,challenges in specimen preparation and interpretation impede its progress.In this study,... Despite the proficiency of lithium(Li)-7 NMR spectroscopy in delineating the physical and chemical states of Li metal electrodes,challenges in specimen preparation and interpretation impede its progress.In this study,we conducted a comprehensive postmortem analysis utilizing ^(7)Li NMR,employing a stan-dard magic angle spinning probe to examine protective-layer coated Li metal electrodes and LiAg alloy electrodes against bare Li metal electrodes within Li metal batteries(LMBs).Our investigation explores the effects of sample burrs,alignment with the magnetic field,the existence of liquid electrolytes,and precycling on the ^(7)Li NMR signals.Through contrasting NMR spectra before and after cycling,we identi-fied alterations in Li^(0) and Li^(+) signals attributable to the degradation of the Li metal electrode.Our NMR analyses decisively demonstrate the efficacy of the protective layer in mitigating dendrite and solid elec-trolyte interphase formation.Moreover,we noted that Li*ions near the Li metal surface exhibit magnetic susceptibility anisotropy,revealing a novel approach to studying diamagnetic species on Li metal elec-trodes in LMBs.This study provides valuable insights and practical guidelines for characterizing distinct lithium states within LMBs. 展开更多
关键词 nmr spectroscopy Lithium-7 Lithium metal battery Electrolyte Electrode-protective layer Solid electrolyte interface Magnetic susceptibility anisotropy Lithium-metal nmr signal Diamagnetic^(7)Li nmr signal
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Operando NMR methods for studying electrocatalysis
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作者 Zhiyu Zhu Ruipeng Luo Evan Wenbo Zhao 《Magnetic Resonance Letters》 2024年第2期54-64,共11页
The combination of electrochemical measurements with spectroscopic characterizations provides valuable insights into reaction mechanisms.Nuclear magnetic resonance(NMR)spectroscopy,as a powerful technique due to its a... The combination of electrochemical measurements with spectroscopic characterizations provides valuable insights into reaction mechanisms.Nuclear magnetic resonance(NMR)spectroscopy,as a powerful technique due to its atomic specificity and versatility in studying gas,liquid,and solid,allows the study of electrolyte solution,catalyst and catalyst-adsorbate interfaces.When applied in operando,NMR can offer molecular-level insights into various electrochemical processes.Operando NMR has been applied extensively in battery research,but relatively underexplored for electrocatalysis in the past two decades.In this mini review,we first introduce the operando electrochemical NMR setups,categorized by different probe designs.Then we review the applications of operando NMR for monitoring the electrolyte solution and the catalyst-adsorbate interface.Considering the high environmental impact of electrochemical conversion of CO_(2)into value-added products,we zoom in to the use of operando NMR in studying electrochemical CO_(2)reduction.Finally,we provide our perspective on further developing and applying operando NMR methods for understanding the complex reaction network of Cu-catalyzed electrochemical CO_(2)reduction. 展开更多
关键词 Operando nmr In situ nmr EC-nmr ELECTROCATALYSIS Electrochemical CO_(2)reduction
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Structural analysis of silk using solid-state NMR
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作者 Tetsuo Asakura 《Magnetic Resonance Letters》 2024年第3期19-34,共16页
Silkworms and spiders are capable of generating fibers that are both highly durable and elastic in a short span of time,using a silk solution stored within their bodies at room temperature and normal atmospheric press... Silkworms and spiders are capable of generating fibers that are both highly durable and elastic in a short span of time,using a silk solution stored within their bodies at room temperature and normal atmospheric pressure.The dragline silk fiber,which is essentially a spider's lifeline,surpasses the strength of a steel wire of equivalent thickness.Regrettably,humans have yet to replicate this process to produce fibers with similar high strength and elasticity in an eco-friendly manner.Therefore,it is of utmost importance to thoroughly comprehend the extraordinary structure and fibrillation mechanism of silk,and leverage this understanding in the manufacturing of high-strength,high-elasticity fibers.This review will delve into the recent progress in comprehending the structure of silks derived from silkworms and spiders,emphasizing the distinctive attributes of solidstate NMR. 展开更多
关键词 SILK Bombyx mori SPIDER Solid-state nmr STRUCTURE
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Structure and ion transport properties of organic ionic compounds revealed by NMR
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作者 Haijin Zhu 《Magnetic Resonance Letters》 2024年第2期2-12,共11页
Organic ionic plastic crystals(OIPCs)are emerging as an important material family for solid-state electrolytes and many other applications.They have significant advantages over conventional electrolyte materials,such ... Organic ionic plastic crystals(OIPCs)are emerging as an important material family for solid-state electrolytes and many other applications.They have significant advantages over conventional electrolyte materials,such as high ionic conductivity,non-flammability,and plasticity.Various nuclear magnetic resonance(NMR)spectroscopy techniques including solid-state NMR,pulsed-field gradient(PFG)NMR,and magnetic resonance imaging(MRI)etc.,provide us a versatile toolkit to understand the fundamental level structures,molecular dynamics,and ionic interactions in these materials.This article reviews the commonly used NMR methods including solid-and solution-state NMR,PFG-NMR,dynamic nuclear polarization(DNP)and the application of these methods in revealing the microscopic level structures and ion-transport mechanisms in OIPC materials. 展开更多
关键词 nmr ELECTROLYTE Organic ionic plastic crystals DEFECTS Diffusion Microstructure
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