The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell paramete...The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell parameters: a=15.5314(2), b=8.0247(8), c=15.3701(2)?.β=118.832(2)°, V=1678.2(3)?3, Z=4, Mr=462.46, Dc=1.830Mg/m3, F(000)=912, μ(MoKα) = 1.694cm-1. The final R and wR are 0.0472 and 0.1272 for 1484 observed reflections with I≥3σ(I). The Ag atom is coordinated by two nitrogen atoms of 4-chloromethyl-pyridine in a linear coordination geometry. Each molecule is further linked by the weak interaction between the Cl and Ag atoms to form a one-dimensional chain structure with Ag－Cl distance of 3.240?.展开更多
Compared with traditional real aperture microwave radiometers,one-dimensional synthetic aperture microwave radiometers have higher spatial resolution.In this paper,we proposed to retrieve sea surface temperature using...Compared with traditional real aperture microwave radiometers,one-dimensional synthetic aperture microwave radiometers have higher spatial resolution.In this paper,we proposed to retrieve sea surface temperature using a one-dimensional synthetic aperture microwave radiometer that operates at frequencies of 6.9 GHz,10.65 GHz,18.7 GHz and 23.8 GHz at multiple incidence angles.We used the ERA5 reanalysis data provided by the European Centre for Medium-Range Weather Forecasts and a radiation transmission forward model to calculate the model brightness temperature.The brightness temperature measured by the spaceborne one-dimensional synthetic aperture microwave radiometer was simulated by adding Gaussian noise to the model brightness temperature.Then,a backpropagation(BP)neural network algorithm,a random forest(RF)algorithm and two multiple linear regression algorithms(RE1 and RE2)were developed to retrieve sea surface temperature from the measured brightness temperature within the incidence angle range of 0°-65°.The results show that the retrieval errors of the four algorithms increase with the increasing Gaussian noise.The BP achieves the lowest retrieval errors at all incidence angles.The retrieval error of the RE1 and RE2 decrease first and then increase with the incidence angle and the retrieval error of the RF is contrary to that of RE1 and RE2.展开更多
Background: Novel models for the assessment of non-linear data are being developed for the benefit of making better predictions from the data. Objective: To review traditional and modern models. Results, and Conclusio...Background: Novel models for the assessment of non-linear data are being developed for the benefit of making better predictions from the data. Objective: To review traditional and modern models. Results, and Conclusions: 1) Logit and probit transformations are often successfully used to mimic a linear model. Logistic regression, Cox regression, Poisson regression, and Markow modeling are examples of logit transformation;2) Either the x- or y-axis or both of them can be logarithmically transformed. Also Box Cox transformation equations and ACE (alternating conditional expectations) or AVAS (additive and variance stabilization for regression) packages are simple empirical methods often successful for linearly remodeling of non-linear data;3) Data that are sinusoidal, can, generally, be successfully modeled using polynomial regression or Fourier analysis;4) For exponential patterns like plasma concentration time relationships exponential modeling with or without Laplace transformations is a possibility. Spline and Loess are computationally intensive modern methods, suitable for smoothing data patterns, if the data plot leaves you with no idea of the relationship between the y- and x-values. There are no statistical tests to assess the goodness of fit of these methods, but it is always better than that of traditional models.展开更多
Two intense quasi-linear mesoscale convective systems（QLMCSs） in northern China were simulated using the WRF（Weather Research and Forecasting） model and the 3D-Var（three-dimensional variational） analysis system ...Two intense quasi-linear mesoscale convective systems（QLMCSs） in northern China were simulated using the WRF（Weather Research and Forecasting） model and the 3D-Var（three-dimensional variational） analysis system of the ARPS（Advanced Regional Prediction System） model.A new method in which the lightning density is calculated using both the precipitation and non-precipitation ice mass was developed to reveal the relationship between the lightning activities and QLMCS structures.Results indicate that,compared with calculating the results using two previous methods,the lightning density calculated using the new method presented in this study is in better accordance with observations.Based on the calculated lightning densities using the new method,it was found that most lightning activity was initiated on the right side and at the front of the QLMCSs,where the surface wind field converged intensely.The CAPE was much stronger ahead of the southeastward progressing QLMCS than to the back it,and their lightning events mainly occurred in regions with a large gradient of CAPE.Comparisons between lightning and non-lightning regions indicated that lightning regions featured more intense ascending motion than non-lightning regions;the vertical ranges of maximum reflectivity between lightning and non-lightning regions were very different;and the ice mixing ratio featured no significant differences between the lightning and non-lightning regions.展开更多
Rail systems are gradually becoming the most desirable form of transit infrastructure around the world, partly because they are becoming more environmentally friendly compared with airplanes and automobiles. This pape...Rail systems are gradually becoming the most desirable form of transit infrastructure around the world, partly because they are becoming more environmentally friendly compared with airplanes and automobiles. This paper examines the place of emerging countries in this move of implementing modern rail system that will eventually enhance the realization of a low-carbon society. Network model, transportation model and linear programming algorithms are used to model the present urban rail transport system in Nigeria, as an emerging country, in order to optimize it. Operational research methods, including simplex method and MODI, with the aids of computer software (excel solver and LIP solver) were adopted to solve the resulting models. The results showed that optimization of rail transport system will not only reduce carbon emission but also bring about economic development which is required for the eradication of prevalent poverty in these emerging countries.展开更多
文摘The mononuclear complex [Ag(C6H6NCl)2](ClO() has been prepared and structurally analyzed by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group C2/c with unit cell parameters: a=15.5314(2), b=8.0247(8), c=15.3701(2)?.β=118.832(2)°, V=1678.2(3)?3, Z=4, Mr=462.46, Dc=1.830Mg/m3, F(000)=912, μ(MoKα) = 1.694cm-1. The final R and wR are 0.0472 and 0.1272 for 1484 observed reflections with I≥3σ(I). The Ag atom is coordinated by two nitrogen atoms of 4-chloromethyl-pyridine in a linear coordination geometry. Each molecule is further linked by the weak interaction between the Cl and Ag atoms to form a one-dimensional chain structure with Ag－Cl distance of 3.240?.
基金The National Natural Science Foundation of China under contract Nos 41475019 and 41705007.
文摘Compared with traditional real aperture microwave radiometers,one-dimensional synthetic aperture microwave radiometers have higher spatial resolution.In this paper,we proposed to retrieve sea surface temperature using a one-dimensional synthetic aperture microwave radiometer that operates at frequencies of 6.9 GHz,10.65 GHz,18.7 GHz and 23.8 GHz at multiple incidence angles.We used the ERA5 reanalysis data provided by the European Centre for Medium-Range Weather Forecasts and a radiation transmission forward model to calculate the model brightness temperature.The brightness temperature measured by the spaceborne one-dimensional synthetic aperture microwave radiometer was simulated by adding Gaussian noise to the model brightness temperature.Then,a backpropagation(BP)neural network algorithm,a random forest(RF)algorithm and two multiple linear regression algorithms(RE1 and RE2)were developed to retrieve sea surface temperature from the measured brightness temperature within the incidence angle range of 0°-65°.The results show that the retrieval errors of the four algorithms increase with the increasing Gaussian noise.The BP achieves the lowest retrieval errors at all incidence angles.The retrieval error of the RE1 and RE2 decrease first and then increase with the incidence angle and the retrieval error of the RF is contrary to that of RE1 and RE2.
文摘Background: Novel models for the assessment of non-linear data are being developed for the benefit of making better predictions from the data. Objective: To review traditional and modern models. Results, and Conclusions: 1) Logit and probit transformations are often successfully used to mimic a linear model. Logistic regression, Cox regression, Poisson regression, and Markow modeling are examples of logit transformation;2) Either the x- or y-axis or both of them can be logarithmically transformed. Also Box Cox transformation equations and ACE (alternating conditional expectations) or AVAS (additive and variance stabilization for regression) packages are simple empirical methods often successful for linearly remodeling of non-linear data;3) Data that are sinusoidal, can, generally, be successfully modeled using polynomial regression or Fourier analysis;4) For exponential patterns like plasma concentration time relationships exponential modeling with or without Laplace transformations is a possibility. Spline and Loess are computationally intensive modern methods, suitable for smoothing data patterns, if the data plot leaves you with no idea of the relationship between the y- and x-values. There are no statistical tests to assess the goodness of fit of these methods, but it is always better than that of traditional models.
基金supported jointly by the National Key Basic Research and Development (973) Program of China (Grant No. 2014CB441401)the National Natural Science Foundation of China (Grant Nos. 41405007, 41175043, 41475002, and 41205027)
文摘Two intense quasi-linear mesoscale convective systems（QLMCSs） in northern China were simulated using the WRF（Weather Research and Forecasting） model and the 3D-Var（three-dimensional variational） analysis system of the ARPS（Advanced Regional Prediction System） model.A new method in which the lightning density is calculated using both the precipitation and non-precipitation ice mass was developed to reveal the relationship between the lightning activities and QLMCS structures.Results indicate that,compared with calculating the results using two previous methods,the lightning density calculated using the new method presented in this study is in better accordance with observations.Based on the calculated lightning densities using the new method,it was found that most lightning activity was initiated on the right side and at the front of the QLMCSs,where the surface wind field converged intensely.The CAPE was much stronger ahead of the southeastward progressing QLMCS than to the back it,and their lightning events mainly occurred in regions with a large gradient of CAPE.Comparisons between lightning and non-lightning regions indicated that lightning regions featured more intense ascending motion than non-lightning regions;the vertical ranges of maximum reflectivity between lightning and non-lightning regions were very different;and the ice mixing ratio featured no significant differences between the lightning and non-lightning regions.
文摘Rail systems are gradually becoming the most desirable form of transit infrastructure around the world, partly because they are becoming more environmentally friendly compared with airplanes and automobiles. This paper examines the place of emerging countries in this move of implementing modern rail system that will eventually enhance the realization of a low-carbon society. Network model, transportation model and linear programming algorithms are used to model the present urban rail transport system in Nigeria, as an emerging country, in order to optimize it. Operational research methods, including simplex method and MODI, with the aids of computer software (excel solver and LIP solver) were adopted to solve the resulting models. The results showed that optimization of rail transport system will not only reduce carbon emission but also bring about economic development which is required for the eradication of prevalent poverty in these emerging countries.
