Functional Optical Fiber Sensors Detecting Imperceptible Physical/Chemical Changes for Smart Batteries

The battery technology progress has been a contradictory process in which performance improvement and hidden risks coexist.Now the battery is still a“black box”,thus requiring a deep understanding of its internal state.The battery should“sense its internal physical/chemical conditions”,which puts strict requirements on embedded sensing parts.This paper summarizes the application of advanced optical fiber sensors in lithium-ion batteries and energy storage technologies that may be mass deployed,focuses on the insights of advanced optical fiber sensors into the processes of one-dimensional nano-micro-level battery material structural phase transition,electrolyte degradation,electrode-electrolyte interface dynamics to three-dimensional macro-safety evolution.The paper contributes to understanding how to use optical fiber sensors to achieve“real”and“embedded”monitoring.Through the inherent advantages of the advanced optical fiber sensor,it helps clarify the battery internal state and reaction mechanism,aiding in the establishment of more detailed models.These advancements can promote the development of smart batteries,with significant importance lying in essentially promoting the improvement of system consistency.Furthermore,with the help of smart batteries in the future,the importance of consistency can be weakened or even eliminated.The application of advanced optical fiber sensors helps comprehensively improve the battery quality,reliability,and life.

A Fiber Optic Sensor for the Simultaneous Measurement of Dual-parameter Based on Hydrogel-immobilized Enzyme Complex

A novel fiber optic sensor based on hydrogel-immobilized enzyme complex was developed for the simultaneous measurement of dual-parameter,the leap from a single parameter detecting fiber optic sensor to a fiber optic sensor that can continuously detect two kinds of parameters was achieved.By controlling the temperature from high to low,the function of fiber sulfide sensor and fiber DCP sensor can be realized,so as to realize the continuous detection of dual-parameter.The different variables affecting the sensor performance were evaluated and optimized.Under the optimal conditions,the response curves,linear detection ranges,detection limits and response times of the dual-parameter sensor for testing sulfide and DCP were obtained,respectively.The sensor displays high selectivity,good repeatability and stability,which have good potentials in analyzing sulfide and DCP concentration of practical water samples.

Modeling, Simulation and Experimental Studies of Refractometric Fiber Optic Sensor

Refractometric fiber optic sensors have a number of applications in industry due to advantages like remote sensing ability, compact size, easy to fit, etc. A refractometric sensor contains a pair of parallel fibers and a gap between the sensor probe and reflector, wherein the liquid whose refractive index is to be measured is filled. This paper describes the importance of mathematical modeling of this sensor. Ray tracing approach is used to model the sensor mathematically. This mathematical model is generalized for any scenario which is useful to avoid tedious trial and error techniques to design the sensor prototype. Mathematical modelling is a useful tool to optimize the gap distance for a detection of refractive index of liquid. The model is developed and analyzed rigorously considering adulteration of diesel by kerosene where refractive index varies from 1.44 to 1.46. Simulation experiments are carried out to optimize the gap distance which is found to be 6.8 mm using both models. Experiments are carried out where sensor probe is fabricated and results are analyzed. It is observed that for suggested gap distance sensor output varies almost linear over the entire range.

An Optical Fiber Sensor for Simultaneous Measurement of pO2 and pH

Whether in the monitoring of critically ill patients such as shock, respiratory failure, brain injury, or in major anesthesia surgeries, it is necessary to evaluate the patient’s pO2 and pH. An optical fiber sensor presented is capable of monitoring the presence of oxygen partial pressure (pO2) and pH in the real-time. The sensor is based on fluorescence sensing of polymer immobilized in the oxygen/pH-sensitive membranes and covalently attached to the optical fiber probe. The design of this sensor uses LED as light source, which is an excitation light source, inducing specific wavelengths of fluorescence on the oxygen/pH-sensitive membrane. The intensity and lifetime of fluorescence are related to the pO2 and pH. So the pO2 and pH can be measured by the relationship between the pO2/pH values and the intensity and lifetime of fluorescence. The signal conditioning system based on DSP and STM32 was used to store and process data, and display test values. The response of the sensor for pO2 and pH monitoring with nitrogen (N2) as a balancing gas in the laboratory was performed. Finally, the oxygen/pH sensing scheme presented in this work is intended for using in biological, medical and environmental applications.

DETERMINATION OF INTERNAL STRAIN IN 3-D BRAIDED COMPOSITES USING OPTIC FIBER STRAIN SENSORS

A reliable understanding of the properties of 3-D braided composites is of primary importance for proper utilization of these materials. A new method is introduced to study the mechanical performance of braided composite materials using embedded optic fiber sensors. Experimental research is performed to devise a method of incorporating optic fibers into a 3-D braided composite structure. The efficacy of this new testing method is evaluated on two counts. First, the optical performance of optic fibers is studied before and after incorporated into 3-D braided composites, as well as after completion of the manufacturing process for 3-D braided composites, to validate the ability of the optic fiber to survive the manufacturing process. On the other hand, the influence of incorporated optic fiber on the original braided composite is also researched by tension and compression experiments. Second, two kinds of optic fiber sensors are co-embedded into 3-D braided composites to evaluate their respective ability to measure the internal strain. Experimental results show that multiple optic fiber sensors can be co-braided into 3-D braided composites to determine their internal strain which is difficult to be fulfilled by other current existing methods.

3D printed fiber-optic nanomechanical bioprobe

Ultrasensitive nanomechanical instruments,e.g.atomic force microscopy(AFM),can be used to perform delicate biomechanical measurements and reveal the complex mechanical environment of biological processes.However,these instruments are limited because of their size and complex feedback system.In this study,we demonstrate a miniature fiber optical nanomechanical probe(FONP)that can be used to detect the mechanical properties of single cells and in vivo tissue measurements.A FONP that can operate in air and in liquids was developed by programming a microcantilever probe on the end face of a single-mode fiber using femtosecond laser two-photon polymerization nanolithography.To realize stiffness matching of the FONP and sample,a strategy of customizing the microcantilever’s spring constant according to the sample was proposed based on structure-correlated mechanics.As a proof-of concept,three FONPs with spring constants varying from 0.421 N m^(−1)to 52.6 N m^(−1)by more than two orders of magnitude were prepared.The highest microforce sensitivity was 54.5 nmμN^(−1)and the detection limit was 2.1 nN.The Young’s modulus of heterogeneous soft materials,such as polydimethylsiloxane,muscle tissue of living mice,onion cells,and MCF-7 cells,were successfully measured,which validating the broad applicability of this method.Our strategy provides a universal protocol for directly programming fiber-optic AFMs.Moreover,this method has no special requirements for the size and shape of living biological samples,which is infeasible when using commercial AFMs.FONP has made substantial progress in realizing basic biological discoveries,which may create new biomedical applications that cannot be realized by current AFMs.

Optical Fiber Grating Sensor for Force Measurement of Anchor Cable

The development of the sensor suitable for measuring large load stress to the anchor cable becomes an important task in bridge construction and maintenance. Therefore, a new type of optical fiber sensor was developed in the laboratory - optical fiber grating sensor for force measurement of anchor cable （OFBFMAC）. No similar report about this kind of sensor has been found up to now in China and other countries. This sensor is proved to be an effective way of monitoring in processes of anchor cable installation, cable cutting, cable force regulation, etc, with the accurate and repeatable measuring results. Its successful application in the tie bar cable force safety monitoring for Wuhan Qingchuan bridge is a new exploration of optical fiber grating sensing technology in bridge tie bar monitoring system.

Remote structural health monitoring with serially multiplexed fiber optic acoustic emission sensors

Development and testing of a serially multiplexed fiber optic sensor system is described.The sensor differs from conventional fiber optic acoustic systems,as it is capable of sensing AE emissions at several points along the length of a single fiber.Multiplexing provides for single channel detection of cracks and their locations in large structural systems. An algorithm was developed for signal recognition and tagging of the AE waveforms for detection of' crack locations,Labora- tory experiments on plain concrete beams and post-tensioned FRP tendons were pcrlormed to evaluate the crack detection capability of the sensor system.The acoustic emission sensor was able to detect initiation,growth and location of the cracks in concrete as well as in the FRP tendons.The AE system is potentially suitable lot applications involving health monitoring of structures following an earthquake.

A Fiber Optic Sensor for 2,4-dichlorophenol Analysis based on Optical Composite Oxygen-sensitive Film

A novel fiber optic sensor based on optical composite oxygen-sensitive film was developed for determination of 2,4-dichlorophenol(DCP).The optical composite oxygen-sensitive film consists of tris(2,2’-bipyridyl)dichloro ruthenium(II)hexahydrate(Ru(bpy)3Cl2)as the fluorescence indicator and iron(III)tetrasulfophthalocyanine(Fe(III)PcTs)as bionic enzyme.A lock-in amplifier was used for detecting the lifetime of the composite oxygen-sensitive film by measuring the phase delay of the sensor head.The different variables affecting the sensor performance were evaluated and optimized.Under the optimal conditions(i e,pH 6.0,25℃,Fe(III)PcTs concentration of 5.0×10^-5 mol/L),the linear detection range,detection limit and response time of the fiber optic sensor are 3.0×10^-7-9.0×10^-5 mol/L,4.8×10^-8 mol/L(S/N=3),and 220 s,respectively.The sensor displays high selectivity,good repeatability and stability,which have good potentials in analyzing DCP concentration in practical water samples.

NOVEL SPECTRUM ABSORPTION OPTICAL FIBER METHANE SENSOR

Based on spectrum principle and analyzing the infrared absorption spectrum ofmethane, a kind of optical fiber methane gas sensor and its system are developed. DFBLD(Distributedfeedback laser diode) in 1 300 nm waveband is used as illuminant and phase-detecting technology isused to carry out harmonic wave detecting the concentration of methane. The sensitivity can arriveat 10^(-5). Experiments results show that the performance targets of the sensor such as sensitivitycan basically satisfy the requests of methane detection.

Fiber optic strain twin-sensor-array for smart structural health monitoring

A multiplexed white light interferometric fiber optic twin-sensor-array was designed to monitor the structural health of large buildings.In this sensing system,based on a Michelson interferometer,an optical path matching technique is used to demodulate each twin-sensor.Each twin-sensor-array consists of a 2×N sensing element linked by a 3 dB coupler.When one of the twin-sensor is used to measure strain,variations caused by temperature can be compensated for by referencing the other twin-sensor.The multiplexing capacity of the sensing scheme has been analyzed and experimental results with a 2×3 twin-sensor-array are given.

DISTRIBUTED OPTICAL FIBER SENSOR FOR LONG-DISTANCE OIL PIPELINE HEALTH

A fully distributed optical fiber sensor （DOFS） for monitoring long-distance oil pipeline health is proposed based on optical time domain reflectometry （OTDR）. A smart and sensitive optical fiber cable is installed along the pipeline acting as a sensor, The experiments show that the cable swells when exposed to oil and induced additional bending losses inside the fiber, and the optical attenuation of the fiber coated by a thin skin with periodical hardness is sensitive to deformation and vibration caused by oil leakage, tampering, or mechanical impact. The region where the additional attenuation occurred is detected and located by DOFS based on OTDR, the types of pipeline accidents are identified according to the characteristics of transmitted optical power received by an optical power meter, Another prototype of DOFS based on a forward traveling frequency-modulated continuous-wave （FMCW） is also proposed to monitor pipeline. The advantages and disadvantages of DOFSs based on OTDR and FMCW are discussed. The experiments show that DOFSs are capable of detecting and locating distant oil pipeline leakages and damages in real time with an estimated precision of ten meters over tens of kilometers.

Distributed optical fiber acoustic sensor for in situ monitoring of marine natural gas hydrates production for the first time in the Shenhu Area,China

The distributed acoustic sensor(DAS)uses a single optical cable as the sensing unit,which can capture the acoustic and vibration signals along the optical cable in real-time.So it is suitable for monitoring downhole production activities in the process of oil and gas development.The authors applied the DAS system in a gas production well in the South China Sea for in situ monitoring of the whole wellbore for the first time and obtained the distributed acoustic signals along the whole wellbore.These signals can clearly distinguish the vertical section,curve section,and horizontal production section.The collected acoustic signal with the frequency of approximately 50 Hz caused by the electric submersible pump exhibit a signal-to-noise ratio higher than 27 dB.By analyzing the acoustic signals in the production section,it can be located the layers with high gas production rates.Once an accurate physical model is built in the future,the gas production profile will be obtained.In addition,the DAS system can track the trajectory of downhole tools in the wellbore to guide the operation.Through the velocity analysis of the typical signals,the type of fluids in the wellbore can be distinguished.The successful application of the system provides a promising whole wellbore acoustic monitoring tool for the production of marine gas hydrate,with a good application prospect.

Loading Localization by Small-Diameter Optical Fiber Sensors

Structural health monitoring(SHM)in service has attracted increasing attention for years.Load localization on a structure is studied hereby.Two algorithms,i.e.,support vector machine(SVM)method and back propagation neural network(BPNN)algorithm,are proposed to identify the loading positions individually.The feasibility of the suggested methods is evaluated through an experimental program on a carbon fiber reinforced plastic laminate.The experimental tests involve in application of four optical fiber-based sensors for strain measurement at discrete points.The sensors are specially designed fiber Bragg grating(FBG)in small diameter.The small-diameter FBG sensors are arrayed in 2-D on the laminate surface.The testing results indicate that the loading position could be detected by the proposed method.Using SVM method,the 2-D FBG sensors can approximate the loading location with maximum error less than 14 mm.However,the maximum localization error could be limited to about 1 mm by applying the BPNN algorithm.It is mainly because the convergence conditions(mean square error)can be set in advance,while SVM cannot.

An Optical Fiber Sensor Probe Using a PMMA/CPR Coated Bent Optical Fiber as a Transducer for Monitoring Trace Ammonia

Ammonia sensors have broad spectrum of applications for industrial process control as well as for environ-mental monitoring. An optical fiber ammonia sensor probe has been developed by using a bent optical fiber having dual poly(methyl methacrylate) (PMMA)/chlorophenol red (CPR) coatings as a transducer. This sen-sor probe was tested for monitoring trace ammonia in gas samples using air as sample matrix. The reaction of ammonia with CPR causes a color change of the reagent, which was detected by using fiber optic evanes-cent wave absorption spectrometry as a sensing signal. By adopting a dual layer coating structure, the sensor probe has faster response compared to a sensor using a broadly accepted sensing reagent-immobilized poly-mer coating structure. The sensor developed in this work is sensitive, has a detection limit of 2.7 ppb NH3 in air, which is the most sensitive among the reported optical fiber ammonia sensors to the best knowledge of the authors. The sensor is also reversible and has a response time of 25 minutes. The features of high sensi-tivity, reversibility and reasonable response time make this sensor technique very attractive for air quality monitoring.

A Fiber Optic Sensor for Determination of 2,4-dichlorophenol based on Iron(Ⅱ) Phthalocyanine Catalysis

A new fi ber optic sensor based on the oxidation of 2,4-dichlorophenol（DCP） catalyzed by iron（II） phthalocyanine（Fe（II）Pc） was developed for the determination of DCP. The optical oxygen sensing fi lm containing fl uorescence indicator Ru（bpy）3Cl2 was used to detect the consumption of oxygen in solution. Moreover, a lock-in amplifier was used to determine the lifetime of the sensor head by detecting its phase delay change. The results reveal that the sensor has a linear detection range of 1.0×10^-6- 9.0×10^-5 mol/L and a response time of 5 min. The sensor also has high selectivity, good repeatability and stability. It can be used effectively to determine DCP concentration in real samples.

Strain measurement of fiber optic sensor surface bonding on host material

Fiber optic sensor has been widely used as a structural health monitoring device by either embedding into or surface bonding onto the structures. The strain of optic fiber induced by the host material is strongly dependent on the bonding characteristics which include the protective coating, adhesive layer and the length of bonding. The strains between the fiber optics and host structure are not exact the same. The existence of the protective coating and adhesive layer would affect the strain measured by the surface bonding optic sensor. The analytical expression of the strain in the optic fiber induced by the host material was presented. The results were validated by the finite element method. The theoretical predictions reveal that the strain in the optical fiber is lower than the strain of host material. Parametric study shows that a long bonding length and high modulus of protective coating would increase the percentage of strain transferring into the optical fiber. Experiments were conducted by using Mach-Zehnder interferometer to measure the strain of the surface bonding optic fiber induced by the host structure. Good agreements were observed in comparison with the experimental results and theoretical predictions.

Stress Sensing by an Optical Fiber Sensor: Method and Process for the Characterization of the Sensor Response Depending on Several Designs

In this paper we propose an analyzing of the response of a stress optical fiber sensor of which we proposed several design. We show that an optical fiber sensor with these designs can covenanting allow the measuring the force/stress applied to a mechanical structure or which it is linked, by optimizing the uses of appropriate materials for constituting the sensor support. The experiment that we introduce to validate our approach based in principles includes design with a support bearing a multimode optical fiber organized in such a way that the transmitted light is attenuated when the fiber-bending angle coming from stitching in holes of the support is modified by the effects of the force/stress applied to the optical fiber sensor realized in this way. The tests realized concern the most relevant parameters that define the performances of the stress sensor that we propose. We present the problems that we to solved for the optimization of the sensor for selecting the more efficient material for the optical fiber sensor support related to a relevant choice of optical fibers.

Absolute Measurement Fiber-optic Sensors inLarge Structural Monitoring

The security of civil engineering is an important task due to the economic, social and environmental significance. Compared with conventional sensors, the optical fiber sensors have their unique characteristics.Being durable, stable and insensitive to external perturbations,they are particular interesting for the long-term monitoring of civil structures.Focus is on absolute measurement optical fiber sensors, which are emerging from the monitoring large structural, including SOFO system, F-P optical fiber sensors, and fiber Bragg grating sensors. The principle, characteristic and application of these three kinds of optical fiber sensors are described together with their future prospects.

Flexible Optical Waveguide Bent Loss Attenuation Effects Analysis and Modeling Application to an Intrinsic Optical Fiber Temperature Sensor

The temperature dependence of the bending loss light energy in multimode optical fibers is reported and analyzed. The work described in this paper aims to extend an initial previous analysis concerning planar optical waveguides, light energy loss, to circular optical waveguides. The paper also presents à novel intrinsic fiber optic sensing device base on this study allowing to measure temperatures parameters. The simulation results are validated theoretically in the case of silica/silicone optical fiber. A comparison is done between results obtained with an optical fiber and the results obtained from the previous curved optical planar waveguide study. It is showed that the bending losses and the temperature measurement range depend on the curvature radius of an optical fiber or waveguide and the kind of the optical waveguide on which the sensing process is implemented.