A new oxazole compound, 1,4 bis(naphtho[1,2 d][1,3]oxazol 2 yl)benzene(BNOB) was synthesized and incorporated into a thin plasticized polymeric membrane for sensing Amrinon. The sensor exhibits a linear response t...A new oxazole compound, 1,4 bis(naphtho[1,2 d][1,3]oxazol 2 yl)benzene(BNOB) was synthesized and incorporated into a thin plasticized polymeric membrane for sensing Amrinon. The sensor exhibits a linear response to Amrinon in the range of 7 98×10 -7 —1 52×10 -4 mol/L at pH 3 28—4 04. The response mainly originates from the Primary Inner Filter Effect, which causes a decrease in the fluorescence intensity of the sensor membrane. The distinct advantages of the proposed sensor are of full reversibility, high sensitivity and selectivity as well as short response time(<1 min), indicating that the sensor can be used to monitor Amrinon in serum samples.展开更多
Laminar optical tomography(LOT)is a mesoscopic tomographic imaging technique ranging between confocal microscopy and diffuse optical tomography(DOT).Fluorescence LOT(FLOT)provides depth-resolved molecular information ...Laminar optical tomography(LOT)is a mesoscopic tomographic imaging technique ranging between confocal microscopy and diffuse optical tomography(DOT).Fluorescence LOT(FLOT)provides depth-resolved molecular information with 100-200μm resolution over 2-3mm depth.In this study,we use Monte Carlo simulation and singular-value analysis(SVA)to optimize the source-detector configurations for potential enhancement of FLOT imaging performance.The effects of different design parameters,including source incidence and detector collection angles,detector number,and sampling density,are presented.The results indicate that angled incidence/detection configuration might improve the imaging resolution and depth sensitivity,especially for low-scattering medium.Increasing the number of detectors and the number of scanning steps will also result in enhanced imaging performance.We also demonstrate that the optimal imaging performance depends upon the background scattering coe±cient.Our result might provide an optimization strategy for FLOT or LOT experimental setup.展开更多
[Objective]Using fiber optic chemical sensor based fluorescence method to accurately determine the content of VB2tablets.[Method]VB2tablets were dissolved in aqueous solution and the detection system of fiber optic ch...[Objective]Using fiber optic chemical sensor based fluorescence method to accurately determine the content of VB2tablets.[Method]VB2tablets were dissolved in aqueous solution and the detection system of fiber optic chemical sensor based fluorescence method was used to measure the spectrum of the solution and to quantitative analyze the content of VB2.[Result]With this method the maximum emission wavelength of VB2was 533 nm.The mass concentration was3.2×10^-5-8×10^-4mg/ml,which had good linear relationship with fluorescence intensity.The detection line was 1.55×10^-8mg/ml and within-day precision was 0.19%while day to day precision was 1.2%,and the recovery was 97.9%-105.1%.[Conclusion]The degree of accuracy was high and the detection line was low when this method was used to determine the content of VB2tablets,and the results were satisfactory.展开更多
Cross-linked polystyrene with azo-crown ether functional side chain (PSt-1, 10-dicarbonyl-3,6,9-trizaoeylcode-cane) was prepared under microwave irradiation and the structure was characterized through FT-IR and elemen...Cross-linked polystyrene with azo-crown ether functional side chain (PSt-1, 10-dicarbonyl-3,6,9-trizaoeylcode-cane) was prepared under microwave irradiation and the structure was characterized through FT-IR and element analysis. The functionalized cross-linked polystyrene (cross-link degree, 3.5%) combining with immobilized catalyst system (CuBr and ethylα-bromo-isobutyrate) can catalyze atom transfer radical polymerization of Styrene. Neat polymer products can be obtained then. Complex of La and the polymer end group (EBiB) was synthesized. The third order nonlinear optical property of the polymer-La complex was investigated and the structure was also characterized by FT-IR and XPS.展开更多
A fiber optic 2-cholrophenol(2-CP) sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-...A fiber optic 2-cholrophenol(2-CP) sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris(2,2′-bipyridyl) ruthenium(II) chloride complexes(Ru(II)(byp)3Cl2) were immobilized in cellulose acetate(CA) via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L(S/N=3) and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.展开更多
WO_3 oxides with relatively high phonon energy and different concentrations were introduced into the Nd^(3+)-doped tellurite-based glasses of Te O_2-Zn O-Na_2 O to improve the 1.32 μm band fluorescence emission. The ...WO_3 oxides with relatively high phonon energy and different concentrations were introduced into the Nd^(3+)-doped tellurite-based glasses of Te O_2-Zn O-Na_2 O to improve the 1.32 μm band fluorescence emission. The absorption spectra,Raman spectra,1.32 μm band fluorescence spectra and differential scanning calorimeter(DSC) curves were measured,together with the Judd-Ofelt intensity parameters,stimulated emission and gain parameters were calculated to evaluate the effects of WO_3 amount on the glass structure and spectroscopic properties of 1.32 μm band fluorescence. It is shown that the introduction of an appropriate amount of WO_3 oxide can effectively improve the 1.32 μm band fluorescence intensity through the enhanced multi-phonon relaxation(MPR) processes between the excited levels of Nd^(3+). The results indicate that the prepared Nd^(3+)-doped tellurite glass with an appropriate amount of WO_3 oxide is a potential gain medium applied for the O-band broad and high-gain fiber amplifier.展开更多
Highly efficient nonlinear optical(NLO) materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. F...Highly efficient nonlinear optical(NLO) materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. Fluorenone analogues have been demonstrated to be promising candidates as building blocks for assembly of organic NLO materials thanks to their synergistic supramolecular interactions and brilliant optical properties. Here we have studied the polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies. These polymorphic microcrystals exhibit very distinctive NLO properties, highly related to their supramolecular and electronic structures.展开更多
文摘A new oxazole compound, 1,4 bis(naphtho[1,2 d][1,3]oxazol 2 yl)benzene(BNOB) was synthesized and incorporated into a thin plasticized polymeric membrane for sensing Amrinon. The sensor exhibits a linear response to Amrinon in the range of 7 98×10 -7 —1 52×10 -4 mol/L at pH 3 28—4 04. The response mainly originates from the Primary Inner Filter Effect, which causes a decrease in the fluorescence intensity of the sensor membrane. The distinct advantages of the proposed sensor are of full reversibility, high sensitivity and selectivity as well as short response time(<1 min), indicating that the sensor can be used to monitor Amrinon in serum samples.
文摘Laminar optical tomography(LOT)is a mesoscopic tomographic imaging technique ranging between confocal microscopy and diffuse optical tomography(DOT).Fluorescence LOT(FLOT)provides depth-resolved molecular information with 100-200μm resolution over 2-3mm depth.In this study,we use Monte Carlo simulation and singular-value analysis(SVA)to optimize the source-detector configurations for potential enhancement of FLOT imaging performance.The effects of different design parameters,including source incidence and detector collection angles,detector number,and sampling density,are presented.The results indicate that angled incidence/detection configuration might improve the imaging resolution and depth sensitivity,especially for low-scattering medium.Increasing the number of detectors and the number of scanning steps will also result in enhanced imaging performance.We also demonstrate that the optimal imaging performance depends upon the background scattering coe±cient.Our result might provide an optimization strategy for FLOT or LOT experimental setup.
基金Supported by National Natural Science Foundation of China(21162030)College Student Innovation Fund Project of Xinjiang Medical University(CX201435)
文摘[Objective]Using fiber optic chemical sensor based fluorescence method to accurately determine the content of VB2tablets.[Method]VB2tablets were dissolved in aqueous solution and the detection system of fiber optic chemical sensor based fluorescence method was used to measure the spectrum of the solution and to quantitative analyze the content of VB2.[Result]With this method the maximum emission wavelength of VB2was 533 nm.The mass concentration was3.2×10^-5-8×10^-4mg/ml,which had good linear relationship with fluorescence intensity.The detection line was 1.55×10^-8mg/ml and within-day precision was 0.19%while day to day precision was 1.2%,and the recovery was 97.9%-105.1%.[Conclusion]The degree of accuracy was high and the detection line was low when this method was used to determine the content of VB2tablets,and the results were satisfactory.
基金Project supported by Jiangsu Province Natural Science Foundation (BK 2002042)
文摘Cross-linked polystyrene with azo-crown ether functional side chain (PSt-1, 10-dicarbonyl-3,6,9-trizaoeylcode-cane) was prepared under microwave irradiation and the structure was characterized through FT-IR and element analysis. The functionalized cross-linked polystyrene (cross-link degree, 3.5%) combining with immobilized catalyst system (CuBr and ethylα-bromo-isobutyrate) can catalyze atom transfer radical polymerization of Styrene. Neat polymer products can be obtained then. Complex of La and the polymer end group (EBiB) was synthesized. The third order nonlinear optical property of the polymer-La complex was investigated and the structure was also characterized by FT-IR and XPS.
基金Funded by the National Natural Science Foundation of China(No.61377092)
文摘A fiber optic 2-cholrophenol(2-CP) sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris(2,2′-bipyridyl) ruthenium(II) chloride complexes(Ru(II)(byp)3Cl2) were immobilized in cellulose acetate(CA) via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L(S/N=3) and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.
基金supported by the National Natural Science Foundation of China(No.61178063)the Natural Science Foundation of Ningbo City(No.2016A610061)+1 种基金the K.C.Wong Magna FundHu Lan Outstanding Doctoral Fund in Ningbo University
文摘WO_3 oxides with relatively high phonon energy and different concentrations were introduced into the Nd^(3+)-doped tellurite-based glasses of Te O_2-Zn O-Na_2 O to improve the 1.32 μm band fluorescence emission. The absorption spectra,Raman spectra,1.32 μm band fluorescence spectra and differential scanning calorimeter(DSC) curves were measured,together with the Judd-Ofelt intensity parameters,stimulated emission and gain parameters were calculated to evaluate the effects of WO_3 amount on the glass structure and spectroscopic properties of 1.32 μm band fluorescence. It is shown that the introduction of an appropriate amount of WO_3 oxide can effectively improve the 1.32 μm band fluorescence intensity through the enhanced multi-phonon relaxation(MPR) processes between the excited levels of Nd^(3+). The results indicate that the prepared Nd^(3+)-doped tellurite glass with an appropriate amount of WO_3 oxide is a potential gain medium applied for the O-band broad and high-gain fiber amplifier.
基金the financial supports from the National Natural Science Foundation of China(NSFC) (Nos.21773168, 51503143 and 21761132007)the Tianjin Natural Science Foundation(No. 16JCQNJC05000)+5 种基金the Innovation Foundation of Tianjin University (No. 2016XRX-0017)the China International Science and Technology Projects(No. S2016G3413)The Netherlands Organization for Scientific Research (NWO) with the Veni Grant (No. 680-47-437)The Royal Netherlands Academy of Arts and Sciences(KNAW) with the China-Exchange Program (No. 530-4CDPO2)the Tianjin 1000 Youth Talents Planthe Chinese Scholarship Council (CSC)
文摘Highly efficient nonlinear optical(NLO) materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. Fluorenone analogues have been demonstrated to be promising candidates as building blocks for assembly of organic NLO materials thanks to their synergistic supramolecular interactions and brilliant optical properties. Here we have studied the polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies. These polymorphic microcrystals exhibit very distinctive NLO properties, highly related to their supramolecular and electronic structures.