Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported.Through two steps hyperbranched polyethylenimine(HPEI) polymers terminated with different amount ...Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported.Through two steps hyperbranched polyethylenimine(HPEI) polymers terminated with different amount of D-phenylalanine(D-Phe),L-phenylalanine(L-Phe) or DL-phenylalanine(DL-Phe) were prepared and characterized.The analyses on the solution properties by turbidimetry,dynamic light scattering,fluorescence probe and 1H-NMR demonstrated that all the polymers exhibited specific thermoresponsive behaviours in water,including:(1) In the dilute polymer concentration region,increasing the polymer concentration led to the increase of phase transition temperature;(2) The optically inactive thermoresponsive hyperbranched polymers showed a higher cloud-point temperature(Tcp) than their corresponding optically active ones in a relatively higher polymer concentration;(3) At the same polymer concentration the hydrophobic groups of the optically inactive HPEI-DL-Phe formed more perfect hydrophobic domain than those of the optically active HPEI-L-Phe and HPEI-D-Phe.展开更多
A novel scheme for all-optical inverted wavelength conversion with 40-Gb/s pseudorandom bit sequences (PRBSs) based on a modified terahertz optical asymmetric demultiplexer (TOAD) is proposed. The performance of the p...A novel scheme for all-optical inverted wavelength conversion with 40-Gb/s pseudorandom bit sequences (PRBSs) based on a modified terahertz optical asymmetric demultiplexer (TOAD) is proposed. The performance of the proposed wavelength converter is analyzed in term of extinction ratio (ER) through numerical simulations. For a typical ER of 10 dB, some key characteristic parameters of the semiconductor optical amplifier (SOA) are designed. With the properly designed parameters, a high quality eye diagram is achievable, indicating that the amplitude fluctuation of the output signal is effectively reduced.展开更多
We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be...We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be 0.0005 dB, which makes it possible for the detection of the minor reflectivity change of the film at different temperatures. The temperature sensitivity is 0.0034 d B/℃, so the resolution can achieve 0.2℃. The maximum difference of the temperature output values of the sensor at 20℃ at different points in time is 0.39℃. The low cost, ultra-small size, high stability, and good repeatability of the sensor make it a promising temperature sensing device for practical application.展开更多
To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modifie...To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modified moire fringes vary more sensitively with the actual misalignment. Hence, the alignment accuracy is significantly improved. Using the proposed method, a 20 μm thick, four-level Fresnel diffractive polyimide membrane optic with a 200 mm diameter is made, which exhibits over 62% diffraction efficiency into the +1 order, and an efficiency root mean square of 0.051.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.20804027 and 21274106)Shanghai Key Laboratory of Magnetic Resonance
文摘Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported.Through two steps hyperbranched polyethylenimine(HPEI) polymers terminated with different amount of D-phenylalanine(D-Phe),L-phenylalanine(L-Phe) or DL-phenylalanine(DL-Phe) were prepared and characterized.The analyses on the solution properties by turbidimetry,dynamic light scattering,fluorescence probe and 1H-NMR demonstrated that all the polymers exhibited specific thermoresponsive behaviours in water,including:(1) In the dilute polymer concentration region,increasing the polymer concentration led to the increase of phase transition temperature;(2) The optically inactive thermoresponsive hyperbranched polymers showed a higher cloud-point temperature(Tcp) than their corresponding optically active ones in a relatively higher polymer concentration;(3) At the same polymer concentration the hydrophobic groups of the optically inactive HPEI-DL-Phe formed more perfect hydrophobic domain than those of the optically active HPEI-L-Phe and HPEI-D-Phe.
文摘A novel scheme for all-optical inverted wavelength conversion with 40-Gb/s pseudorandom bit sequences (PRBSs) based on a modified terahertz optical asymmetric demultiplexer (TOAD) is proposed. The performance of the proposed wavelength converter is analyzed in term of extinction ratio (ER) through numerical simulations. For a typical ER of 10 dB, some key characteristic parameters of the semiconductor optical amplifier (SOA) are designed. With the properly designed parameters, a high quality eye diagram is achievable, indicating that the amplitude fluctuation of the output signal is effectively reduced.
基金supported by the National Natural Science Foundation of China(Nos.11574397,61775238,61705262,and 61705263)the Scientific Research Project of National University of Defense Technology(No.JC15-11-02)
文摘We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be 0.0005 dB, which makes it possible for the detection of the minor reflectivity change of the film at different temperatures. The temperature sensitivity is 0.0034 d B/℃, so the resolution can achieve 0.2℃. The maximum difference of the temperature output values of the sensor at 20℃ at different points in time is 0.39℃. The low cost, ultra-small size, high stability, and good repeatability of the sensor make it a promising temperature sensing device for practical application.
基金supported by the National Natural Science Foundation of China under Grant No.11375175
文摘To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modified moire fringes vary more sensitively with the actual misalignment. Hence, the alignment accuracy is significantly improved. Using the proposed method, a 20 μm thick, four-level Fresnel diffractive polyimide membrane optic with a 200 mm diameter is made, which exhibits over 62% diffraction efficiency into the +1 order, and an efficiency root mean square of 0.051.