分别用聚合物辅助沉积法和金属有机物分解法制备了WO_3和BiVO_4半导体薄膜电极。利用固体紫外-可见漫反射光谱、电化学阻抗和线性扫描伏安法,对WO_3和BiVO_4半导体薄膜电极的能带结构进行了表征。制备了WO_3/BiVO_4异质结复合光电极,并...分别用聚合物辅助沉积法和金属有机物分解法制备了WO_3和BiVO_4半导体薄膜电极。利用固体紫外-可见漫反射光谱、电化学阻抗和线性扫描伏安法,对WO_3和BiVO_4半导体薄膜电极的能带结构进行了表征。制备了WO_3/BiVO_4异质结复合光电极,并通过扫描电子显微镜、X射线衍射和X射线光电子能谱,对该复合光电极的断面形貌、晶型结构和物质组成进行了分析。最后,对WO_3/BiVO_4复合光电极的光电转化性能进行了研究。研究结果表明:均为单斜晶型的WO_3和BiVO_4之间形成了膜厚约为450 nm的II型异质结;在施加相对于可逆氢电极1.23 V的电势时,WO_3/BiVO_4光电极的光电流密度可以达到1.926 m A/cm^2,表现出了良好的光电转化性能。展开更多
Nano-TiO2 thin films are deposited by radio frequency （RF） magnetron sputtering using TiO2 ceramic target and characterized by X-ray diffractometer, atomic force microscope, and ultraviolet-visible spectrophotometer...Nano-TiO2 thin films are deposited by radio frequency （RF） magnetron sputtering using TiO2 ceramic target and characterized by X-ray diffractometer, atomic force microscope, and ultraviolet-visible spectrophotometer. The photocatalytic activity is evaluated by light-induced degradation of methyl orange solutions （5, 10, and 20 ppm） using a high pressure mercury lamp as the light source. The film is amorphous, and its energy gap is 3.02 eV. The photocatalytic degradation of methyl orange solution is the first-order reaction and the apparent reaction rate constants are 0.00369, 0.0024, and 0.00151 for the methyl orange solution concentrations of 5, 10, and 20 ppm, respectively.展开更多
文摘分别用聚合物辅助沉积法和金属有机物分解法制备了WO_3和BiVO_4半导体薄膜电极。利用固体紫外-可见漫反射光谱、电化学阻抗和线性扫描伏安法,对WO_3和BiVO_4半导体薄膜电极的能带结构进行了表征。制备了WO_3/BiVO_4异质结复合光电极,并通过扫描电子显微镜、X射线衍射和X射线光电子能谱,对该复合光电极的断面形貌、晶型结构和物质组成进行了分析。最后,对WO_3/BiVO_4复合光电极的光电转化性能进行了研究。研究结果表明:均为单斜晶型的WO_3和BiVO_4之间形成了膜厚约为450 nm的II型异质结;在施加相对于可逆氢电极1.23 V的电势时,WO_3/BiVO_4光电极的光电流密度可以达到1.926 m A/cm^2,表现出了良好的光电转化性能。
基金supported by the National Natural Science Foundation of China (Nos.50872001 and 50642038)the Scientific Research Foundation of Education Ministry of Anhui Province of China (Nos.KJ2009A006Z,KJ2007B132,and 2005KJ224)+2 种基金the Foundation of Construction of Quality Project of Anhui University of China (No.XJ200907)the Research Foundation for the Doctoral Program of Higher Education of China (No.20060357003)the Graduate Student Innovation Programs of Anhui University of China (No.20072006)
文摘Nano-TiO2 thin films are deposited by radio frequency （RF） magnetron sputtering using TiO2 ceramic target and characterized by X-ray diffractometer, atomic force microscope, and ultraviolet-visible spectrophotometer. The photocatalytic activity is evaluated by light-induced degradation of methyl orange solutions （5, 10, and 20 ppm） using a high pressure mercury lamp as the light source. The film is amorphous, and its energy gap is 3.02 eV. The photocatalytic degradation of methyl orange solution is the first-order reaction and the apparent reaction rate constants are 0.00369, 0.0024, and 0.00151 for the methyl orange solution concentrations of 5, 10, and 20 ppm, respectively.
