A novel equilateral triangular patch with a rectangular notch etched to one radiating edge on organic magnetic substrate is proposed for dual frequency operation. Both operations of these dual frequencies arise from t...A novel equilateral triangular patch with a rectangular notch etched to one radiating edge on organic magnetic substrate is proposed for dual frequency operation. Both operations of these dual frequencies arise from the perturbation of TM 10 and TM 11 mode by simply cutting a rectangular notch at the patch bottom. Simulations and experiments have shown the validity of this design. Using an organic magnetic material as the substrate, the antenna exhibits a broader bandwidth of 5.5% and 4.7% at dual-frequencies 1.56 GHz and 2.45 GHz, respectively, as well as a reduced size compared to the dual-frequency patch antennas on non-magnetic material.展开更多
A new azobenzene side-chain polymer (TEMPO-PAZ) containing TEMPO (4-hydroxy-2, 2, 6, 6-tetramethyl-piperidinooxy) radical end group was synthesized by free radical copolymerization. Photoinduced alignment was studied ...A new azobenzene side-chain polymer (TEMPO-PAZ) containing TEMPO (4-hydroxy-2, 2, 6, 6-tetramethyl-piperidinooxy) radical end group was synthesized by free radical copolymerization. Photoinduced alignment was studied onthe polymer films at room temperature with linearly polarized light of 514.5 nm, The experimental results showed that themagnetic response intensity of the TEMPO-PAZ could be easily controlled by choosing the appropriate polarized lightirradiating times, presumably due to the nitroxide radical in the TEMPO-PAZ molecular structure. For the polymerinvestigated here, the photoinduced alignment technique was introduced to increase the magnetic response intensity ofpolymer under irradiation, aiming originally at searching for a new photo-active organic magnetic multifunctional materials.On the other hand, experimental results also showed that the TEMPO-PAZ can be used as a material for optical image storage.展开更多
To allow anisotropies of optical properties in a magnetic field, nitroxide radical is introduced into the ortho-position of the phenylene ring in the side chain. A new azobenzene side-chain polymer (TEMPO-PAZ) contain...To allow anisotropies of optical properties in a magnetic field, nitroxide radical is introduced into the ortho-position of the phenylene ring in the side chain. A new azobenzene side-chain polymer (TEMPO-PAZ) containing TEMPO radical was synthesized. The polymer has a good solubility in organic solvents. The ESR spectrum of the polymer indicated three absorption lines characteristic of TEMPO radical. The optical phase conjugated responses (I-4) of the polymer films were investigated by degenerate four-wave mixing (DFWM). The experimental results showed that optical phase conjugated response of the TEMPO-PAZ could be easily controlled by choosing the appropriate direction of magnetic field presumably due to the nitroxide radical in the TEMPO-PAZ molecular structure. For the polymer investigated here, the nitroxide radical was introduced to increase optical phase conjugated response intensity in a magnetic field, aiming originally at searching for a new photo-active organic magnetic multifunctional materials.展开更多
文摘A novel equilateral triangular patch with a rectangular notch etched to one radiating edge on organic magnetic substrate is proposed for dual frequency operation. Both operations of these dual frequencies arise from the perturbation of TM 10 and TM 11 mode by simply cutting a rectangular notch at the patch bottom. Simulations and experiments have shown the validity of this design. Using an organic magnetic material as the substrate, the antenna exhibits a broader bandwidth of 5.5% and 4.7% at dual-frequencies 1.56 GHz and 2.45 GHz, respectively, as well as a reduced size compared to the dual-frequency patch antennas on non-magnetic material.
基金This work was supported by National Natural Science Foundation of China (No. 20134010, 20274003).
文摘A new azobenzene side-chain polymer (TEMPO-PAZ) containing TEMPO (4-hydroxy-2, 2, 6, 6-tetramethyl-piperidinooxy) radical end group was synthesized by free radical copolymerization. Photoinduced alignment was studied onthe polymer films at room temperature with linearly polarized light of 514.5 nm, The experimental results showed that themagnetic response intensity of the TEMPO-PAZ could be easily controlled by choosing the appropriate polarized lightirradiating times, presumably due to the nitroxide radical in the TEMPO-PAZ molecular structure. For the polymerinvestigated here, the photoinduced alignment technique was introduced to increase the magnetic response intensity ofpolymer under irradiation, aiming originally at searching for a new photo-active organic magnetic multifunctional materials.On the other hand, experimental results also showed that the TEMPO-PAZ can be used as a material for optical image storage.
基金This work was supported by National Natural Science Foundation of China (No. 20134010) and Scientific Foundation for Returned Overseas Chinese Scholars. Ministry of Education.
文摘To allow anisotropies of optical properties in a magnetic field, nitroxide radical is introduced into the ortho-position of the phenylene ring in the side chain. A new azobenzene side-chain polymer (TEMPO-PAZ) containing TEMPO radical was synthesized. The polymer has a good solubility in organic solvents. The ESR spectrum of the polymer indicated three absorption lines characteristic of TEMPO radical. The optical phase conjugated responses (I-4) of the polymer films were investigated by degenerate four-wave mixing (DFWM). The experimental results showed that optical phase conjugated response of the TEMPO-PAZ could be easily controlled by choosing the appropriate direction of magnetic field presumably due to the nitroxide radical in the TEMPO-PAZ molecular structure. For the polymer investigated here, the nitroxide radical was introduced to increase optical phase conjugated response intensity in a magnetic field, aiming originally at searching for a new photo-active organic magnetic multifunctional materials.
