Accumulation and losses of soil organic carbon(SOC),total nitrogen(TN)and sulphur(S)influence food security and global warming.Therefore,their spatial distribution and variability at regional scale,and their relation ...Accumulation and losses of soil organic carbon(SOC),total nitrogen(TN)and sulphur(S)influence food security and global warming.Therefore,their spatial distribution and variability at regional scale,and their relation to topographical variables are of great interest.In this study,the variability of SOC,TN and S content was evaluated in apple orchard soils of Kashmir region,at three depths(D1:0-10,D2:10-20,and D3:20-30 cm)on slope gradient i.e.:flat,medium,and high.With an increase in slope,a significant decrease of SOC and TN was observed,with concentration of SOC and TN recorded highest(14.3±2.06 g kg-1&0.97±0.35 g kg-1)in flat slope orchards and lowest(9.6±2.07 g kg-1&0.84±0.41 g kg-1)in high slope orchards.On stock basis,the values recorded for flat,medium,and high slope orchards,for SOC and TN were 54.62±4.24 Mg ha-1&0.38±0.06 Mg ha-1,44.13±5.11 Mg ha-1&0.32±0.09 Mg ha-1,and 38.73±5.94 Mg ha-1&0.28±0.10,respectively.The differences for S concentration and stocks were modest,with flat(0.21±0.15 mg kg-1&0.09±0.0.003 Mg ha-1)>high(0.16±0.07 mg kg-1&0.06±0.007 Mg ha-1)>medium(0.12±0.04 mg kg-1&0.075±0.009 Mg ha-1).Across slopes,SOC,TN and S decreased with increasing soil depth,suggesting clear downward trend.Overall,SOC and TN increased with the increase of altitude,precipitation and clay content while its relationship with soil acidity and soil bulk density was negative.The findings may provide scientific basis to structure agricultural development plans or prioritize regions for soil conservation efforts.展开更多
The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized wi...The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized with the sulphur dioxide formation,and the process chemical mechanism does not depend on the quality of organic matter.The medium-metamorphized coal,capable of turning into a plastic state and cake in the range of investigated temperatures(350~450 ℃),is desulphurized with the greatest difficulty.The chemical mechanism dealing with the transformations of pyritic sulphur present in brown coal differs from similar processes taking place in black coal and anthracite,because FeS2 is converted with hydrogen sulphide formation at desulphurization.展开更多
Nanchuan lean coal in which inorganic sulphur had been removed was used to investigate the effect of electrolysis conditions on organic sulphur removal from coal The results indicated that the amount of sulfur remov...Nanchuan lean coal in which inorganic sulphur had been removed was used to investigate the effect of electrolysis conditions on organic sulphur removal from coal The results indicated that the amount of sulfur removed in creases with time, but the removal rate becomes slower When the concentration of HCl is lower than 32?M, the sulfur removal changes little; when it is 32?M~48?M, the sulfur removal is improved significantly The higher concentration of coal slurry, the lower the sulfur removal rate The desulfrization of organic sulphur is 18% for 005?g/mL coal slurry in 10?h in acidic medium Therefore, organic sulphur is more difficult to be removed than inorganic sulphur by展开更多
基金Financial assistance awarded to first author under Young Scientist Startup Grant(DST/SERB/337-2014)from Science and Engineering Research BoardDepartment of Science and TechnologyGovernment of India is highly acknowledged。
文摘Accumulation and losses of soil organic carbon(SOC),total nitrogen(TN)and sulphur(S)influence food security and global warming.Therefore,their spatial distribution and variability at regional scale,and their relation to topographical variables are of great interest.In this study,the variability of SOC,TN and S content was evaluated in apple orchard soils of Kashmir region,at three depths(D1:0-10,D2:10-20,and D3:20-30 cm)on slope gradient i.e.:flat,medium,and high.With an increase in slope,a significant decrease of SOC and TN was observed,with concentration of SOC and TN recorded highest(14.3±2.06 g kg-1&0.97±0.35 g kg-1)in flat slope orchards and lowest(9.6±2.07 g kg-1&0.84±0.41 g kg-1)in high slope orchards.On stock basis,the values recorded for flat,medium,and high slope orchards,for SOC and TN were 54.62±4.24 Mg ha-1&0.38±0.06 Mg ha-1,44.13±5.11 Mg ha-1&0.32±0.09 Mg ha-1,and 38.73±5.94 Mg ha-1&0.28±0.10,respectively.The differences for S concentration and stocks were modest,with flat(0.21±0.15 mg kg-1&0.09±0.0.003 Mg ha-1)>high(0.16±0.07 mg kg-1&0.06±0.007 Mg ha-1)>medium(0.12±0.04 mg kg-1&0.075±0.009 Mg ha-1).Across slopes,SOC,TN and S decreased with increasing soil depth,suggesting clear downward trend.Overall,SOC and TN increased with the increase of altitude,precipitation and clay content while its relationship with soil acidity and soil bulk density was negative.The findings may provide scientific basis to structure agricultural development plans or prioritize regions for soil conservation efforts.
文摘The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized with the sulphur dioxide formation,and the process chemical mechanism does not depend on the quality of organic matter.The medium-metamorphized coal,capable of turning into a plastic state and cake in the range of investigated temperatures(350~450 ℃),is desulphurized with the greatest difficulty.The chemical mechanism dealing with the transformations of pyritic sulphur present in brown coal differs from similar processes taking place in black coal and anthracite,because FeS2 is converted with hydrogen sulphide formation at desulphurization.
文摘Nanchuan lean coal in which inorganic sulphur had been removed was used to investigate the effect of electrolysis conditions on organic sulphur removal from coal The results indicated that the amount of sulfur removed in creases with time, but the removal rate becomes slower When the concentration of HCl is lower than 32?M, the sulfur removal changes little; when it is 32?M~48?M, the sulfur removal is improved significantly The higher concentration of coal slurry, the lower the sulfur removal rate The desulfrization of organic sulphur is 18% for 005?g/mL coal slurry in 10?h in acidic medium Therefore, organic sulphur is more difficult to be removed than inorganic sulphur by