Impact of Initial Soil Conditions on Soil Hydrothermal and Surface Energy Fluxes in the Permafrost Region of the Tibetan Plateau

Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)and soil moisture(SM)conditions on a land surface energy and water simulation in the permafrost region in the Tibetan Plateau(TP)using the Community Land Model version 5.0(CLM5.0).The results indicate that the default initial schemes for ST and SM in CLM5.0 were simplistic,and inaccurately represented the soil characteristics of permafrost in the TP which led to underestimating ST during the freezing period while overestimating ST and underestimating SLW during the thawing period at the XDT site.Applying the long-term spin-up method to obtain initial soil conditions has only led to limited improvement in simulating soil hydrothermal and surface energy fluxes.The modified initial soil schemes proposed in this study comprehensively incorporate the characteristics of permafrost,which coexists with soil liquid water(SLW),and soil ice(SI)when the ST is below freezing temperature,effectively enhancing the accuracy of the simulated soil hydrothermal and surface energy fluxes.Consequently,the modified initial soil schemes greatly improved upon the results achieved through the long-term spin-up method.Three modified initial soil schemes experiments resulted in a 64%,88%,and 77%reduction in the average mean bias error(MBE)of ST,and a 13%,21%,and 19%reduction in the average root-mean-square error(RMSE)of SLW compared to the default simulation results.Also,the average MBE of net radiation was reduced by 7%,22%,and 21%.

Straw mulching alters the composition and loss of dissolved organic matter in farmland surface runoff by inhibiting the fragmentation of soil small macroaggregates

Straw mulching is a widespread practice for reducing the soil carbon loss caused by erosion.However,the effects of straw mulching on dissolved organic matter(DOM)runoff loss from black soil are not well studied.How straw mulching affects the composition and loss of runoff DOM by changing soil aggregates remains largely unclear.Here,a straw mulching treatment was compared to a no mulching treatment(as a control)on sloping farmland with black soil erosion in Northeast China.We divided the soil into large macroaggregates(>2 mm),small macroaggregates(0.25-2 mm),and microaggregates(<0.25 mm).After five rain events,the effects of straw mulching on the concentration(characterized by dissolved organic carbon(DoC)and composition(analyzed by fluorescence spectroscopy)of runoff and soil aggregate DOM were studied.The results showed that straw mulching reduced the runoff amount by 54.7%.Therefore,although straw mulching increased the average DOc concentration in runoff,it reduced the total runoff DOM loss by 48.3%.The composition of runoff DOM is similar to that of soil,as both contain humic-like acid and protein-like components.With straw mulching treatment,the protein-like components in small macroaggregates accumulated and the protein-like components in runoff declined with rain events.Fluorescence spectroscopy technology may help in understanding the hydrological paths of rain events by capturing the dynamic changes of runoff and soil DOM characteristics.A variation partitioning analysis(VPA)indicated that the DOM concentration and composition of microaggregates explained 68.2%of the change in runoff DOM from no mulching plots,while the change in runoff DOM from straw mulching plots was dominated by small macroaggregates at a rate of 55.1%.Taken together,our results demonstrated that straw mulching reduces the fragmentation of small macroaggregates and the loss of microaggregates,thus effecting DOM compositions in soil and reducing the DOM loss in runoff.These results provide a theoretical basis for reducing carbon loss in sloping farmland.

Relationship between spatio-temporal evolution of soil pH and geological environment/surface cover in the eastern Nenjiang River Basin of Northeast China during the past 30 years

To illuminate the spatio-temporal variation characteristics and geochemical driving mechanism of soil pH in the Nenjiang River Basin,the National Multi-objective Regional Geochemical Survey data of topsoil,the Second National Soil Survey data and Normalized Difference Vegetation Index(NDVI)were analyzed.The areas of neutral and alkaline soil decreased by 21100 km^(2)and 30500 km^(2),respectively,while that of strongly alkaline,extremely alkaline,and strongly acidic soil increased by 19600 km^(2),18200 km^(2),and 15500 km^(2),respectively,during the past 30 years.NDVI decreased with the increase of soil pH when soil pH>8.0,and it was reversed when soil pH<5.0.There were significant differences in soil pH with various surface cover types,which showed an ascending order:Arbor<reed<maize<rice<high and medium-covered meadow<low-covered meadow<Puccinellia.The weathering products of minerals rich in K_(2)O,Na_(2)O,CaO,and MgO entered into the low plain and were enriched in different parts by water transportation and lake deposition,while Fe and Al remained in the low hilly areas,which was the geochemical driving mechanism.The results of this study will provide scientific basis for making scientific and rational decisions on soil acidification and salinization.

Influence of Vegetation Coverage on Surface Runoff and Soil Moisture in Rainy Season in Dry-hot Valley

[Objective]The research aimed to study the effects of vegetation coverage on the changes of soil moisture in rainy season in dry-hot valley.[Method]The surface runoff and soil moisture of slope with vegetation coverage and bare land in rainy reason in Jinsha River at Yuanmou County of Yunnan Province were observed continuously.Moreover,the statistical analysis was made based on the observation data.[Result]The vegetation coverage could decrease surface runoff and the surface runoff on bare land（CK） was 22 times as the plot with vegetation coverage.The soil water content in 0-180 cm layer with vegetation coverage increased by 37.8% than bare land.The stability of soil moisture content in deep layer was enhanced and the physical properties stability of soil was maintained.The soil moisture content in different depth of soil had significant difference and the changes of soil moisture content were obviously different.[Conclusion]The vegetation coverage of slope could change the soil hydrology obviously and keep soil moisture at the higher level,especially at soil layer below 20 cm.

Effects of Straw Covering and Different Types of Potassium Fertilizer on Salinity Accumulation in Surface Layer of Tobacco-planted Paddy Soil

[Objective] This study aimed to investigation the effects of straw covering and different types of potassium fertilizer on salinity accumulation in surface layer of tobacco-planted paddy soil in southern China. [Method] Tobacco variety ‘Yunyan87’ was used as the experimental material to investigate the effects of salinity accumulation in surface layer of tobacco-planted paddy soil on the growth and development of flue-cured tobacco using different types of potassium fertilizer and mulching cultivation methods. [Result] The results showed that K＋ , Ca2＋ , SO42and NO3-were the major salt ions in topsoil at different growth stages of flue-cured tobacco, Na ＋ and Mg2＋ contents were also relatively high at vigorous growth stage, indicating that these salt ions were easily accumulated in surface layer of soil; to be specific, the absolute increase of salt ion concentration showed a decreasing order of K＋ SO42- NO3-Ca2＋ Mg2＋ Na＋ Cl-, while the relative increase of salt ion concentration showed a decreasing order of Ca2＋ K＋ Na＋ NO3-SO42-Mg2＋ Cl-. At 60 d posttransplanting, total salt content in topsoil reached the minimum of 359.1 mg/kg in Treatment 2, total salt content in topsoil reached the maximum of 536.1 mg/kg in Treatment 5 （CK）, which was significantly higher than that in other treatments. At 90 d post-transplanting, no significant difference was observed in total salt content among various treatments. At harvesting period, total salt content in topsoil reached the maximum of 3 278.4 mg/kg in Treatment 1, which was significantly higher than that in other treatments. Topsoil pH showed no significant differences among various treatments at three different periods, ranging from 5.39 to 5.59. Straw covering could effectively reduce salt content in topsoil, accelerate vigorous growth of tobacco, shorten vigorous growth period and increase plant height, leaf number and lead area; at vigorous growth stage, root vitality and root volume of tobacco were improved, but the yield and output value were relatively low. Major agronomic traits and yield of tobacco showed no significant difference among various treatments. Output value of tobacco reached the maximum of 24 196.8 yuan/hm2 in Treatment 3, which was significantly higher than that in other treatments. [Conclusion] Appropriate types and proportions of potassium fertilizer and straw covering can effectively reduce the total salt content in tobacco-planted paddy soil and increase the effective supply amount of K＋ , Ca2＋ , SO42-and NO3-, thereby promoting and improving the root vitality of tobacco, which is conducive to the growth and development of tobacco and will eventually enhance the yield, quality and economic benefits of flue-cured tobacco.

Variability of Soil Moisture and Its Relationship with Surface Albedo and Soil Thermal Parameters over the Loess Plateau

Data from July 2006 to June 2008 observed at SACOL （Semi-Arid Climate and Environment Observatory of Lanzhou University, 35.946°N, 104.137°E, elev. 1961 m）, a semi-arid site in Northwest China, are used to study seasonal variability of soil moisture, along with surface albedo and other soil thermal parameters, such as heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture content. The results indicate that surface albedo decreases with increases in soil moisture content, showing a typical exponential relation between the surface albedo and the soil moisture. The heat capacity, the soil thermal diffusivity, and soil thermal conductivity show large variations between Julian day 90-212 and 450-578. The soil thermal conductivity is found to increase as a power function of soil moisture. Soil heat capacity and soil thermal diffusivity increase with increases in soil moisture. The SACOL observed soil moisture are also used to validate the AMSR-E/AQUA retrieved soil moisture and there is good agreement between them. The analysis of the relationship between satellite retrieved soil moisture and precipitation suggests that the variability of soil moisture depends on the variation of precipitation over the Loess Plateau.

Relationships Between Surface Albedo,Soil Thermal Parameters and Soil Moisture in the Semi-arid Area of Tongyu,Northeastern China

Continuous observation data collected over the whole year of 2004 on a cropland surtace m Tongyu, a senti-arid area of northeastern China （44°25＇N, 122°52＇E）, have been used to investigate the variations of surface albedo and soil thermal parameters, including heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture. The diurnal variation of surface albedo appears as a U shape curve on sunny days. Surface albedo decreases with the increase of solar elevation angle, and it tends to be a constant when solar elevation angle is larger than 40°. So the daily average surface albedo was computed using the data when solar elevation angle is larger than 40° Mean daily surface albedo is found to decrease with the increase of soil moisture, showing an exponential dependence on soil moisture. The variations of soil heat capacity are small during Julian days 90 300. Compared with the heat capacity, soil thermal conductivity has very gentle variations during this period, but the soil thermal diffusivity has wide variations during the same period. The soil thermal conductivity is found to increase as a power function of soil moisture. The soil thermal diffusivity increases firstly and then decreases with the increase of soil moisture.

Soil surface roughness change and its effect on runoff and erosion on the Loess Plateau of China

As an important parameter in the soil erosion model, soil surface roughness（SSR） is used to quantitatively describe the micro-relief on agricultural land. SSR has been extensively studied both experimentally and theoretically; however, no studies have focused on understanding SSR on the Loess Plateau of China. This study investigated changes in SSR for three different tillage practices on the Loess Plateau of China and the effects of SSR on runoff and erosion yield during simulated rainfall. The tillage practices used were zero tillage（ZT）, shallow hoeing（SH） and contour ploughing（CP）. Two rainfall intensities were applied, and three stages of water erosion processes（splash erosion（I）, sheet erosion（II） and rill erosion（III）） were analyzed for each rainfall intensity. The chain method was used to measure changes in SSR both initially and after each stage of rainfall. A splash board was used to measure the splash erosion at stage I. Runoff and sediment data were collected continuously at 2-min intervals during rainfall erosion stages II and III. We found that SSR of the tilled surfaces ranged from 1.0% to 21.9% under the three tillage practices, and the order of the initial SSR for the three treatments was ZT〈SH〈CP. For the ZT treatment, SSR increased slightly from stage I to III, whereas for the SH and CP treatments, SSR decreased by 44.5% and 61.5% after the three water erosion stages, respectively, and the greatest reduction in SSR occurred in stage I. Regression analysis showed that the changes in SSR with increasing cumulative rainfall could be described by a power function（R2〉0.49） for the ZT, SH and CP treatments. The runoff initiation time was longer in the SH and CP treatments than in the ZT treatment. There were no significant differences in the total runoff yields among the ZT, SH and CP treatments. Sediment loss was significantly smaller（P〈0.05） in the SH and CP treatments than in the ZT treatment.

Speciation and fractionation of heavy metals in soil experimentally contaminated with Pb, Cd, Cu and Zn together and effects on soil negative surface charge

Speciation and fractionation of heavy metals in soil subsamples experimentally loaded with Pb, Cd, Cu and Zn in orthogonal design was investigated by sequential extraction, and operationally defined as water soluble and exchangeable(SE), weakly specific adsorbed(WSA), Fe and Mn oxides bound(OX) and organic bound(ORG). The results showed that fractions of heavy metals in the soil subsamples depended on their speciation. About 90% of Cd and 75% of Zn existed in soil subsamples in the SE fraction. Lead and Cu existed in soil subsamples as SE, WSA and OX fractions simultaneously, although SE was still the major fraction. Organic bound heavy metals were not clearly apparent in all the soil subsamples. The concentration of some heavy metal fractions in soil subsamples showed the good correlation with ionic impulsion of soil, especially for the SE fraction. Continuous saturation of soil subsamples with 0.20 mol/L NH 4Cl, which is the first step for determination of the negative surface charge of soil by the ion retention method, resulted in desorption of certain heavy metals from the soil. It was found that the percentage desorption of heavy metals from soil subsamples depended greatly on pH, the composition and original heavy metal content of the soil subsamples. However, most of the heavy metals in the soil subsamples were still be retained after multiple saturation. Compared with the parent soil, the negative surface charge of soil subsamples loaded with heavy metals did not show difference significantly from that of the parent one by statistical analysis. Heavy metals existed in the soil subsamples mainly as exchangeable and precipitated simultaneously.

Dynamic shear modulus of undisturbed soil under different consolidation ratios and its effects on surface ground motion

The dynamic shear modulus for three types of undisturbed soil under different consolidation ratios is presented by using the resonant column test method. Its effects on surface ground motion is illustrated by calculation. The test results indicate that the power function is a suitable form for describing the relationship between the ratio of the maximum dynamic shear modulus due to anisotropic and isotropic consolidations and the increment of the consolidation ratio. When compared to sand, the increment of the maximum dynamic shear modulus for undisturbed soil due to anisotropic consolidation is much larger. Using a one-dimensional equivalent linearization method, the earthquake influence factor and the characteristic period of the surface acceleration are calculated for two soil layers subjected to several typical earthquake waves. The calculated results show that the difference in nonlinear properties due to different consolidation ratios is generally not very notable, but the degree of its influence on the surface acceleration spectrum is remarkable for the occurrence of strong earthquakes. When compared to isotropic consolidation, the consideration of actual anisotropic consolidation causes the characteristic period to decrease and the earthquake influence factor to increase.

Using multi-satellite microwave remote sensing observations for retrieval of daily surface soil moisture across China

The objective of this study was to retrieve daily composite soil moisture by jointly using brightness temperature observations from multiple operating satellites for near real-time application with better coverage and higher accuracy.Our approach was to first apply the single-channel brightness radiometric algorithm to estimate soil moisture from the respective brightness temperature observations of the SMAP,SMOS,AMSR2,FY3B,and FY3C satellites on the same day and then produce a daily composite dataset by averaging the individual satellite-retrieved soil moisture.We further evaluated our product,the official soil moisture products of the five satellites,and the ensemble mean (i.e.,arithmetic mean) of the five official satellite soil moisture products against ground observations from two networks in Central Tibet and Anhui Province,China.The results show that our product outperforms the individual released products of the five satellites and their ensemble means in the two validation areas.The root mean square error (RMSE ) values of our product were 0.06 and 0.09 m3/m3 in Central Tibet and Anhui Province,respectively.Relative to the ensemble mean of the five satellite products,our product improves the accuracy by 9.1% and 57.7% in Central Tibet and Anhui Province,respectively.This demonstrates that jointly using brightness temperature observations from multiple satellites to retrieve soil moisture not only improves the spatial coverage of daily observations but also produces better daily composite products.

Selection of Judging Indicators for Surface Morphology of Soil Crack under Different Development Degrees in Yuanmou Arid-Hot Valley Region

Quantification of complicated surface morphology of soil crack is a prerequisite and key to soil crack study. This paper takes soil crack quads in Yuanmou arid-hot valley region as examples, selecting several morphological indicators, and analyzes the soil crack＇s morphological features under various development degrees. By statistic analysis, three quantitative indicators for surface morphology are selected, namely soil crack area density, area weighted mean fractal dimension and connectivity index R, which can not only express the development intensity of soil cracks, but also effectively describe its morphological complexity and connectivity. The research results set a good base for the establishment of soil crack assessment system in Yuanmou arid-hot valley region.

Sorption of a triazol derivative by soils: importance of surface acidity

The sorption of a triazol derivative, 1-(4-chlorophenyl)- 4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)penten-3-ol with a common name of S3307D, on fifteen soils and three H_2O_2-treated soils was investigated. The sorption isotherm for each untreated and treated soil was non-linear, and was best fitted to Freundlich sorption equation. Soils containing high amount of clay content or organic matter or both sorbed much higher amounts of the chemical than soils that had low contents of these soil constituents. H_2O_2-treated soils showed considerable sorptive affinity for S3307D. It was concluded that both organic matter and mineral fraction in natural soils contributed to the sorption of the basic compound. Sorption by the H_2O_2 treated soils increased as suspension pH decreased, but all suspension pHs exceeded the pKa of the compound by more than two units. This implies that organic base protonation can occur on surfaces of soil components, and surface acidity (exchangeable acidity ) is important in sorption process of the organic base rather than suspension pH.

7~Be: A Geochemical Tracer for Seasonal Erosion of Surface Soil in Watershed of Lake Hongfeng, Guizhou, China

e penetrative depth in undisturbed surface soil is within 4 mm.7￣Be activity shows exponential decrease with soil depth, which is expressed as a diffusion process.7￣Be penetrative depth in undisturbed surface soil is apparently deeper in the fall (0.22-0.37 g cm￣(-2) than in the spring (0.11-0.28 g cm￣(-2) at the same site; Whereas, ￣7Be apparent activity at the top of surface soil is higher in the spring (0.3-2.2 Bq g￣(-1_) than in the fall (0.2-0.5 Bq g￣(-1) at the same site. The ￣7Be inventory (189-544 Bq m￣(-2) changes with both locations and seasons. Although the ￣7Be flux to the earth's surface increases with amount of precipitation, its maximum inventory in the soil profiles decreases to 30%-40% after the rainy period. Calculated by the diffusion equation, the erosion and accumulation rates of soil particles are agreeable with the observation in situ., which shows that the rates in fall are 1.5 times those in spring. The eroded soil particles almost all have been removed on the tablelands rather than transported into the drainage system. This indicstes that the soil erosion process in the karst region is only partial transportation within a short distance.

Case Analyses and Numerical Simulation of Soil ThermalImpacts on Land Surface Energy Budget Based on anOff-Line Land Surface Model

The statistical relationship between soil thermal anomaly and short-term climate change is presented based on a typical case study. Furthermore, possible physical mechanisms behind the relationship are re-vealed through using an off-line land surface model with a reasonable soil thermal forcing at the bottom of the soil layer. In the first experiment, the given heat flux is 5 W m2 at the bottom of the soil layer (in depth of 6.3 m) for 3 months, while only a positive ground temperature anomaly of 0.06°C can be found compared to the control run. The anomaly, however, could reach 0.65°C if the soil thermal conductivity was one order of magnitude larger. It could be even as large as 0.81°C assuming the heat flux at bottom is 10 W m-2. Mean-while, an increase of about 10 W m−2 was detected both for heat flux in soil and sensible heat on land sur-face, which is not neglectable to the short-term climate change. The results show that considerable response in land surface energy budget could be expected when the soil thermal forcing reaches a certain spatial-tem-poral scale. Therefore, land surface models should not ignore the upward heat flux from the bottom of the soil layer. Moreover, integration for a longer period of time and coupled land-atmosphere model are also necessary for the better understanding of this issue.

The Sensitivity of Ground Surface Temperature Prediction to Soil Thermal Properties Using the Simple Biosphere Model(SiB2)

Using the Simple Biosphere Model （SiB2）, soil thermal properties （STP） were examined in a Tibetan prairie during the monsoon period to investigate ground surface temperature prediction. We improved the SiB2 model by incorporating a revised force-restore method （FRM） to take the vertical heterogeneity of soil thermal diffusivity （k） into account. The results indicate that （1） the revised FRM alleviates daytime overestimation and nighttime underestimation in modeled ground surface temperature （Tg）, and （2） its role in little rainfall events is significant because the vertical gradient of k increases with increasing surface evaporation. Since the original formula of thermal conductivity （A） in the SiB2 greatly underestimates soil thermal conductivity, we compared five Mgorithms of A involving soil moisture to investigate the cause of overestimation during the day and underestimation at night on the basis of the revised FRM. The results show that （1） the five algorithms significantly improve Tg prediction, especially in daytime, and （2） taking one of these five algorithms as an example, the simulated Tg values in the daytime are closer to the field measurements than those in the nighttime. The differences between modeled Tg and field measurements are mostly within the margin of error of -4-2 K during 3 August to 4 September 1998.

Vertical distribution of soil moisture and surface sandy soil wind erosion for different types of sand dune on the southeastern margin of the Mu Us Sandy Land,China

Soil moisture is a critical state affecting a variety of land surface and subsurface processes. We report investigation results of the factors controlling vertical variation of soil moisture and sand transport rate of three types of dunes on the south- eastern margin of the Mu Us Sandy Land. Samples were taken from holes drilled to a depth of 4 m at different topographic sites on the dunes, and were analyzed for soil moisture, grain-size distribution and surface sediment discharge. The results show that： （1） The average soil moisture varies in different types of dunes, with the following sequences ordered from highest to lowest： in the shrubs-covered dunes and the trees-covered dunes the sequence is from inter-dunes lowland to windward slope to leeward slope. The average moisture in the bare-migratory sand dunes is sequenced from inter-dunes lowland to leeward slope to windward slope. （2） Vegetation form and surface coverage affect the range of soil moisture of different types of dunes in the same topographic position. The coefficient of variation of soil moisture for shrubs-covered dunes is higher than that of other types of dune. （3） The effect of shrubs on dune soil moisture is explained in terms of the greater ability of shrubs to trap fine-grained atmospheric dust and hold moisture. （4） The estimated sand transport rates over sand dunes with sparse shrubs are less than those over bare-migratory dunes or sand dunes with sparse trees, indicating that shrubs are more effective in inhibiting wind erosion in the sandy land area.

Soil Organic Carbon and Its Fractions Across Vegetation Types:Effects of Soil Mineral Surface Area and Microaggregates

Soil organic carbon(SOC)can act as a sink or source of atmospheric carbon dioxide;therefore,it is important to understand the amount and composition of SOC in terrestrial ecosystems,the spatial variation in SOC,and the underlying mechanisms that stabilize SOC.In this study,density fractionation and acid hydrolysis were used to assess the spatial variation in SOC,the heavy fraction of organic carbon(HFOC),and the resistant organic carbon(ROC)in soils of the southern Hulun Buir region,northeastern China,and to identify the major factors that contribute to this variation.The results showed that as the contents of clay and silt particles(0–50μm)increased,both methylene blue(MB)adsorption by soil minerals and microaggregate contents increased in the 0–20 and 20–40 cm soil layers(P<0.05).Although varying with vegetation types,SOC,HFOC,and ROC contents increased significantly with the content of clay and silt particles, MB adsorption by soil minerals,and microaggregate content(P<0.05),suggesting that soil texture,the MB adsorption by soil minerals,and microaggregate abundance might be important factors influencing the spatial heterogeneity of carbon contents in soils of the southern Hulun Buir region.

Relationship between soil surface roughness and hydraulic roughness coefficient on sloping farmland

The soil surface roughness and hydraulic roughness coefficient are important hydraulic resistance characteristic parameters. Precisely estimating the hydraulic roughness coefficient is important to understanding mechanisms of overland flow. Four tillage practices, including cropland raking, artificial hoeing, artificial digging, and straight slopes, were considered based on the local agricultural conditions to simulate different values of soil surface roughness in the Loess Plateau. The objective of this study was to investigate the relationship between the soil surface roughness and hydraulic roughness coefficient on sloping farmland using artificial rainfall simulation. On a slope with a gradient of 10°, a significant logarithmic function was developed between the soil surface roughness and Manning＇s roughness coefficient, and an exponential function was derived to describe the relationship between the soil surface roughness and Reynolds number. On the slope with a gradient of 15°, a significant power function was developed to reflect the relationship between the soil surface roughness and Manning＇s roughness coefficient, and a linear function was derived to relate the soil surface roughness to the Reynolds number. These findings can provide alternative ways to estimate the hydraulic roughness coefficient for different types of soil surface roughness.