The zinc complex with neutral organochalcogen ligand Mbit, [（Mbit）2Zn]（Cl O4）2（1, Mbit = 1,1＇-methylenebis（3-methyl-imidazole-2-thione））, has been synthesized and characterized. The complex has been character...The zinc complex with neutral organochalcogen ligand Mbit, [（Mbit）2Zn]（Cl O4）2（1, Mbit = 1,1＇-methylenebis（3-methyl-imidazole-2-thione））, has been synthesized and characterized. The complex has been characterized by elemental analysis, NMR and IR spectra. The molecular structure of 1 has been determined by X-ray crystallography. For the complex, C18H24Cl2N8O8S4 Zn, Mr = 744.96, triclinic, space group P1, a = 11.2923（18）, b = 11.9353（19）, c = 13.837（3） , α = 114.763（2）, β = 92.132（2）, γ = 116.039（2）°, V = 1464.6（5） 3, Z = 2, Dc = 1.689 g/cm3, λ = 1.54184 , μ = 1.363 mm-1, F（000） = 760, S = 1.098, the final R = 0.0554 and w R = 0.0.1579. Complex 1 exhibits photocatalytic activity for methyl orange（MO） degradation under UV light and shows good stability toward photocatalysis.展开更多
基金financially supported by the National Natural Science Foundation of China(21102004)National Training Programs of Innovation and Entrepreneurship for Undergraduates(201410370040)Training Programs of Innovation and Entrepreneurship of Anhui Province for Undergraduates(AH201410370040)
文摘The zinc complex with neutral organochalcogen ligand Mbit, [（Mbit）2Zn]（Cl O4）2（1, Mbit = 1,1＇-methylenebis（3-methyl-imidazole-2-thione））, has been synthesized and characterized. The complex has been characterized by elemental analysis, NMR and IR spectra. The molecular structure of 1 has been determined by X-ray crystallography. For the complex, C18H24Cl2N8O8S4 Zn, Mr = 744.96, triclinic, space group P1, a = 11.2923（18）, b = 11.9353（19）, c = 13.837（3） , α = 114.763（2）, β = 92.132（2）, γ = 116.039（2）°, V = 1464.6（5） 3, Z = 2, Dc = 1.689 g/cm3, λ = 1.54184 , μ = 1.363 mm-1, F（000） = 760, S = 1.098, the final R = 0.0554 and w R = 0.0.1579. Complex 1 exhibits photocatalytic activity for methyl orange（MO） degradation under UV light and shows good stability toward photocatalysis.
