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An Economical Method for Preparative Purification of Five Alkaloids from Coptis Chinensis Franch by High-Speed Counter-Current Chromatography Using Singled Prepared Solvent System by GC 被引量:1
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作者 Lianhong Yin Lina Xu +5 位作者 Xiaona Wang Binan Lu Yingnan Li Mingming Hu Yuetao Liu Jinyong Peng 《American Journal of Analytical Chemistry》 2011年第4期411-421,共11页
Coptis chinensis Franch, a widely used Traditional Chinese Medicine, shows various kinds of bioactivity. The major active components of the herb are considered to be alkaloids. Thus, preparative separation of these al... Coptis chinensis Franch, a widely used Traditional Chinese Medicine, shows various kinds of bioactivity. The major active components of the herb are considered to be alkaloids. Thus, preparative separation of these alkaloids is critical important for further pharmacology and mechanism studies. In the paper, five alkaloids from C. chinensis were purified by HSCCC using the solvent system composed of chloro-form-metha- nol-water (2:1:1, v/v/v) single prepared. The content of each solvent in solvent system were determined by gas chromatography (GC), then according the ratios of solvents in each phase to prepare the mobile and stationary phase respectively. And a comparative study was carried out between together preparation and single preparation of the solvent system. The purities and recoveries of all the products were over 98.5% and 92%. However, 134 mL chloroform, 336 mL methanol and 452 mL water were saved when the two phase were singled by GC. Our research showed an economical method for separating alkaloids from C. chinensis by HSCCC using the solvent system single prepared by GC. 展开更多
关键词 ALKALOID Coptis CHINENSIS Franch High Speed counter-current Chromaotgraphy Gas CHROMATOGRAPHY Solvent System
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Response characteristics of gas pressure under simultaneous static and dynamic load:Implication for coal and gas outburst mechanism 被引量:4
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作者 Longyong Shu Liang Yuan +3 位作者 Qixian Li Wentao Xue Nannan Zhu Zhengshuai Liu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第2期155-171,共17页
Coal and gas outbursts are dynamic disasters in which a large mass of gas and coal suddenly emerges in a mining space within a split second.The interaction between the gas pressure and stress environment is one of the... Coal and gas outbursts are dynamic disasters in which a large mass of gas and coal suddenly emerges in a mining space within a split second.The interaction between the gas pressure and stress environment is one of the key factors that induce coal and gas outbursts.In this study,first,the coupling relationship between the gas pressure in the coal body ahead of the working face and the dynamic load was investigated using experimental observations,numerical simulations,and mine-site investigations.It was observed that the impact rate of the dynamic load on the gas-bearing coal can significantly change the gas pressure.The faster the impact rate,the speedier the increase in gas pressure.Moreover,the gas pressure rise was faster closer to the impact interface.Subsequently,based on engineering background,we proposed three models of stress and gas pressure distribution in the coal body ahead of the working face:static load,stress disturbance,and dynamic load conditions.Finally,the gas pressure distribution and outburst mechanism were investigated.The high concentration of gas pressure appearing at the coal body ahead of the working face was caused by the dynamic load.The gas pressure first increased gradually to a peak value and then decreased with increasing distance from the working face.The increase in gas pressure plays a major role in outburst initiation by resulting in the ability to more easily reach the critical points needed for outburst initiation.Moreover,the stronger the dynamic load,the greater the outburst initiation risk.The results of this study provide practical guidance for the early warning and prevention of coal and gas outbursts. 展开更多
关键词 Coal and gas outburst Gas pressure Dynamic load outburst mechanism
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Mechanism of gas pressure action during the initial failure of coal containing gas and its application for an outburst inoculation 被引量:1
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作者 Chaojie Wang Lutan Liu +2 位作者 Xiaowei Li Changhang Xu Kai Li 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第12期1511-1525,共15页
Faced with the continuous occurrence of coal and gas outburst(hereinafter referred to as“outburst”)disasters,as a main controlling factor in the evolution process of an outburst,for gas pressure,it is still unclear ... Faced with the continuous occurrence of coal and gas outburst(hereinafter referred to as“outburst”)disasters,as a main controlling factor in the evolution process of an outburst,for gas pressure,it is still unclear about the phased characteristics of the coupling process with in situ stress,which induce coal damage and instability.Therefore,in the work based on the mining stress paths induced by typical outburst accidents,the gradual and sudden change of three-dimensional stress is taken as the background for the mechanical reconstruction of the disaster process.Then the true triaxial physical experiments are conducted on the damage and instability of coal containing gas under multiple stress paths.Finally,the response characterization between coal damage and gas pressure has been clarified,revealing the mechanism of action of gas pressure during the initial failure of coals.And the main controlling mechanism during the outburst process is elucidated in the coupling process of in situ stress with gas pressure.The results show that during the process of stress loading and unloading,the original gas pressure enters the processes of strengthening and weakening the action ability successively.And the strengthening effect continues to the period of large-scale destruction of coals.The mechanical process of gas pressure during the initial failure of coals can be divided into three stages:the enhancement of strengthening action ability,the decrease of strengthening action ability,and the weakening action ability.The entire process is implemented by changing the dominant action of in situ stress into the dominant action of gas pressure.The failure strength of coals is not only affected by its original mechanical strength,but also by the stress loading and unloading paths,showing a particularly significant effect.Three stages can be divided during outburst inoculation process.That is,firstly,the coals suffer from initial damage through the dominant action of in situ stress with synergy of gas pressure;secondly,the coals with spallation of structural division are generated through the dominant action of gas pressure with synergy of in situ stress,accompanied by further fragmentation;and finally,the fractured coals suffer from fragmentation and pulverization with the gas pressure action.Accordingly,the final broken coals are ejected out with the gas action,initiating an outburst.The research results can provide a new perspective for deepening the understanding of coal and gas outburst mechanism,laying a theoretical foundation for the innovation of outburst prevention and control technologies. 展开更多
关键词 Coal and gas outburst outburst mechanism Main controlling mechanism Coal damage Mining stress Dilatation phenomenon
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Separation and Purification of Acetophenones from Cynanchum bengei Decne Root Bark by Combination of Silica Gel and High-speed Counter-current Chromatography 被引量:1
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作者 Huaizhi LI Lingchuan XU +4 位作者 Xiao WANG Qian LIU Jia LI Peng YANG Bingtian YANG 《Medicinal Plant》 2017年第2期8-11,共4页
[Objectives] To develop a method for separation and purification of acetophenones from Cynanchum bengei Decne root bark by combination of silica gel and high-speed counter-current chromatography( HSCCC). [Methods]The ... [Objectives] To develop a method for separation and purification of acetophenones from Cynanchum bengei Decne root bark by combination of silica gel and high-speed counter-current chromatography( HSCCC). [Methods]The crude extract of Cynanchum bengei Decne root bark was separated by silica gel column chromatography,and parts A and B containing acetophenones were obtained. Then,parts A and B were separated by HSCCC with a two-phase solvent system composed of petroleum ether-ethyl acetate-methanol-water( 4∶ 6∶ 4. 5∶ 5. 5 and4∶ 6 ∶ 3 ∶ 7, V/V), respectively. [Results] From 260 mg of part A, four compounds with p-dihydroxybenzene 3. 9 mg(Ⅰ),4-hydroxyacetophenone 17. 1 mg( Ⅱ),2,5-di-hydroxyacetophenone 13. 3 mg(Ⅲ) and 2,4-dihydroxyaceto-phenone 21. 0 mg(Ⅳ) were obtained. And from 300 mg of part B,136 mg of Radix Cynanchi Bungei benzophenone(Ⅴ) was obtained. The purity of compounds determined by HPLC was 97. 0%,96. 6%,99. 2%,99. 7%,99. 5%,respectively. [Conclusions] The established method is simple and efficient. It can be used for separation of acetophenones from Cynanchum bengei Decne root bark and has better practical value,which could provide a reference basis for development and utilization of Cynanchum bengei Decne root bark. 展开更多
关键词 Silica GEL column CHROMATOGRAPHY High-speed counter-current chromatography(HSCCC) Acetophenones CYNANCHUM bengei Decne root BARK
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Elimination mechanism of coal and gas outburst based on geo‑dynamic system with stress–damage–seepage interactions 被引量:1
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作者 Lingjin Xu Chaojun Fan +4 位作者 Mingkun Luo Sheng Li Jun Han Xiang Fu Bin Xiao 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第4期47-61,共15页
Coal and gas outburst is a complex dynamic disaster during coal underground mining.Revealing the disaster mechanism is of great signifcance for accurate prediction and prevention of coal and gas outburst.The geo-dynam... Coal and gas outburst is a complex dynamic disaster during coal underground mining.Revealing the disaster mechanism is of great signifcance for accurate prediction and prevention of coal and gas outburst.The geo-dynamic system of coal and gas outburst is proposed.The framework of geo-dynamic system is composed of gassy coal mass,geological dynamic environment and mining disturbance.Equations of stress–damage–seepage interaction for gassy coal mass is constructed to resolve the outburst elimination process by gas extraction with boreholes through layer in foor roadway.The results show the occurrence of outburst is divided into the evolution process of gestation,formation,development and termination of geo-dynamic system.The scale range of outburst occurrence is determined,which provides a spatial basis for the prevention and control of outburst.The formation criterion and instability criterion of coal and gas outburst are established.The formation criterion F1 is defned as the scale of the geo-dynamic system,and the instability criterion F2 is defned as the scale of the outburst geo-body.According to the geo-dynamic system,the elimination mechanism of coal and gas outburst—‘unloading+depressurization’is established,and the gas extraction by boreholes through layer in foor roadway for outburst elimination is given.For the research case,when the gas extraction is 120 days,the gas pressure of the coal seam is reduced to below 0.4 MPa,and the outburst danger is eliminated efectively. 展开更多
关键词 Coal and gas outburst Geo-dynamic system Stress–damage–seepage coupling Elimination mechanism Instability criterion Gas extraction
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Comparison of Co-Current and Counter-Current Flow Fields on Extraction Performance in Micro-Channels
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作者 Subramaniam Pushpavanam Benny Malengier 《Advances in Chemical Engineering and Science》 2012年第2期309-320,共12页
Several applications such as liquid-liquid extraction in micro-fluidic devices are concerned with the flow of two immiscible liquid phases. The commonly observed flow regimes in these systems are slug-flow and stratif... Several applications such as liquid-liquid extraction in micro-fluidic devices are concerned with the flow of two immiscible liquid phases. The commonly observed flow regimes in these systems are slug-flow and stratified flow. The latter regime in micro-channels has the inherent advantage that separation of the two liquids at the exit is efficient. Recently extraction in a stratified counter-current flow has been studied experimentally and it has been shown to be more efficient than co-current flow. An analytical as well as a numerical method to determine the steady-state solution of the corresponding convection-diffusion equation for the two flow-fields is presented. It is shown that the counter-current process is superior to the co-current process for the same set of parameters and operating conditions. A simplified model is proposed to analyse the process when diffusion in the transverse direction is not rate limiting. Different approaches to determining mass transfer coefficient are compared. The concept of log mean temperature difference used in design of heat exchangers is extended to describe mass transfer in the system. 展开更多
关键词 PLUG Flow DIFFUSION Extraction CO-CURRENT counter-current
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Dynamic behavior of outburst two-phase flow in a coal mine T-shaped roadway:The formation of impact airflow and its disaster-causing effect
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作者 Liang Cheng Jiang Xu +4 位作者 Shoujian Peng Hailin Yang Feng Jiao Bin Zhou Fazhi Yan 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第8期1001-1017,共17页
The study of the dynamic disaster mechanism of coal and gas outburst two-phase flow is crucial for improving disaster reduction and rescue ability of coal mine outburst accidents.An outburst test in a T-shaped roadway... The study of the dynamic disaster mechanism of coal and gas outburst two-phase flow is crucial for improving disaster reduction and rescue ability of coal mine outburst accidents.An outburst test in a T-shaped roadway was conducted using a self-developed large-scale outburst dynamic disaster test system.We investigated the release characteristics of main energy sources in coal seam,and obtained the dynamic characteristics of outburst two-phase flow in a roadway.Additionally,we established a formation model for outburst impact flow and a model for its flow in a bifurcated structure.The results indicate that the outburst process exhibits pulse characteristics,and the rapid destruction process of coal seam and the blocking state of gas flow are the main causes of the pulse phenomenon.The outburst energy is released in stages,and the elastic potential energy is released in the vertical direction before the horizontal direction.In a straight roadway,the impact force oscillates along the roadway.With an increase in the solid–gas ratio,the two-phase flow impact force gradually increases,and the disaster range extends from the middle of the roadway to the coal seam.In the area near the coal seam,the disaster caused by the two-phase flow impact is characterized by intermittent recovery.In a bifurcated roadway,the effect of impact airflow on impact dynamic disaster is much higher than that of two-phase flow,and the impact force tends to weaken with increasing solid-gas ratio.The impact force is asymmetrically distributed;it is higher on the left of the bifurcated roadway.With an increase in the solid-gas ratio,the static pressure rapidly decreases,and the bifurcated structure accelerates the attenuation of static pressure.Moreover,secondary acceleration is observed when the shock wave moves along the T-shaped roadway,indicating that the bifurcated structure increases the shock wave velocity. 展开更多
关键词 Multiphase flow Coal and gas outburst Dynamic disaster Impact airflow T-shaped bifurcated roadway Coal seam
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In-situ gas contents of a multi-section coal seam in Sydney basin for coal and gas outburst management
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作者 Zhongbei Li Ting Ren +4 位作者 Dennis Black Ming Qiao Itmam Abedin Jessica Juric Mike Wang 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第4期34-46,共13页
The gas content is crucial for evaluating coal and gas outburst potential in underground coal mining. This study focuses on investigating the in-situ coal seam gas content and gas sorption capacity in a representative... The gas content is crucial for evaluating coal and gas outburst potential in underground coal mining. This study focuses on investigating the in-situ coal seam gas content and gas sorption capacity in a representative coal seam with multiple sections (A1, A2, and A3) in the Sydney basin, where the CO_(2) composition exceeds 90%. The fast direct desorption method and associated devices were described in detail and employed to measure the in-situ gas components (Q_(1), Q_(2), and Q_(3)) of the coal seam. The results show that in-situ total gas content (Q_(T)) ranges from 9.48 m^(3)/t for the A2 section to 14.80 m^(3)/t for the A3 section, surpassing the Level 2 outburst threshold limit value, thereby necessitating gas drainage measures. Among the gas components, Q_(2) demonstrates the highest contribution to Q_(T), ranging between 55% and 70%. Furthermore, high-pressure isothermal gas sorption experiments were conducted on coal samples from each seam section to explore their gas sorption capacity. The Langmuir model accurately characterizes CO_(2) sorption behavior, with ft coefcients (R^(2)) greater than 0.99. Strong positive correlations are observed between in-situ gas content and Langmuir volume, as well as between residual gas content (Q_(3)) and sorption hysteresis. Notably, the A3 seam section is proved to have a higher outburst propensity due to its higher Q_(1) and Q_(2) gas contents, lower sorption hysteresis, and reduced coal toughness f value. The insights derived from the study can contribute to the development of efective gas management strategies and enhance the safety and efciency of coal mining operations. 展开更多
关键词 In-situ coal seam gas content Direct desorption method Gas component Sorption capacity Coal and gas outburst
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基于径向基网络的堰塞体溃决峰值流量预测研究 被引量:2
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作者 王琳 张润宇 +1 位作者 苑鹏飞 王桑蓬 《水力发电学报》 CSCD 北大核心 2024年第5期68-79,共12页
堰塞体由天然滑坡堆积而成,受上游来流冲刷和渗透极易发生溃决,给下游人们生命财产造成严重威胁。快速、准确地预测溃决峰值流量是堰塞体抢险工作的重中之重。现有研究基于数据库—统计回归—溃决模型的思想,提出了一系列堰塞体溃决峰... 堰塞体由天然滑坡堆积而成,受上游来流冲刷和渗透极易发生溃决,给下游人们生命财产造成严重威胁。快速、准确地预测溃决峰值流量是堰塞体抢险工作的重中之重。现有研究基于数据库—统计回归—溃决模型的思想,提出了一系列堰塞体溃决峰值流量预测模型,但均未综合考虑堰塞体冲蚀特性和颗粒组成对溃决流量的影响,且随着数据的不断扩充,预测模型难以取得预期效果。因此,本研究基于国内外2060例堰塞体溃决信息数据库,通过考虑堰塞体几何特征、冲蚀特性和颗粒组成,提炼出堰塞体高度(H_(d))、堰塞体宽度(W_(d))、堰塞体体积(V_(d))、水库库容(V_(l))、溃口深度(H_(w))、溃口平均宽度(W_(b))、堰塞体中值粒径(d_(50))7个影响参数,并将堰塞体冲蚀程度分为5类,构建了考虑冲蚀特性的堰塞体溃决峰值流量预测模型。选取数据齐全的120座堰塞体溃决案例对模型进行验证,均方根误差(RMSE)和相关系数(R2)分别为9581 m^(3)/s与0.965,并和国内外已有典型参数模型进行比较。结果表明,考虑堰塞体冲蚀特性和d50参数的模型可以更好地预测溃决峰值流量,能够为堰塞体溃决抢险进程中的溃决洪水演进、下游受灾区域划分等工作内容提供合理参考。 展开更多
关键词 堰塞体 冲蚀特性 溃决流量 参数模型
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1950-2022年中国煤与瓦斯突出事故的时空分布规律
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作者 范超军 张鑫鹏 +3 位作者 杨雷 富向 杨振华 李胜 《辽宁工程技术大学学报(自然科学版)》 CAS 北大核心 2024年第3期279-287,共9页
为厘清煤与瓦斯突出事故的发生规律,从时间和空间2个维度,对1950-2022年中国煤与瓦斯突出事故进行统计分析并提出防突措施与建议。研究结果表明:1950-2022年中国煤与瓦斯突出事故的时间分布特征可划分为大幅上升时期(1950-1980年)、持... 为厘清煤与瓦斯突出事故的发生规律,从时间和空间2个维度,对1950-2022年中国煤与瓦斯突出事故进行统计分析并提出防突措施与建议。研究结果表明:1950-2022年中国煤与瓦斯突出事故的时间分布特征可划分为大幅上升时期(1950-1980年)、持续好转时期(1981-2000年)和稳定下降时期(2001-2022年)。空间分布特征为范围广、较集中、南多北少、南重北轻。煤与瓦斯突出事故发生次数随时间逐渐减少,死亡人数与煤矿事故总死亡人数之比随时间波动上涨。煤与瓦斯突出矿井的空间分布总体呈南多北少的特点。研究结果为中国煤与瓦斯突出事故防治提供参考。 展开更多
关键词 煤与瓦斯突出 突出矿井 突出事故 灾害防治 时空分布
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松软薄煤层条带消突下斜定向钻孔成孔护孔技术研究与应用 被引量:1
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作者 陈建忠 王建强 +3 位作者 李延辉 管强盛 张宇昊 王锋伟 《煤炭工程》 北大核心 2024年第9期98-104,共7页
针对松软薄煤层煤巷条带消突长距离下斜钻孔,存在成孔难、易钻遇煤层顶底板、积水堵塞瓦斯抽采通道的难题,提出了氮气排渣下斜定向钻进成孔与护孔技术,采用高压氮气排渣、大功率气动螺杆钻具定向、“波浪式”轨迹控制和三层管护孔排水技... 针对松软薄煤层煤巷条带消突长距离下斜钻孔,存在成孔难、易钻遇煤层顶底板、积水堵塞瓦斯抽采通道的难题,提出了氮气排渣下斜定向钻进成孔与护孔技术,采用高压氮气排渣、大功率气动螺杆钻具定向、“波浪式”轨迹控制和三层管护孔排水技术,在河南省平煤股份一矿开展现场试验,完成8个孔深超300 m下斜定向长钻孔,煤层钻遇率90%以上,全孔段下三层护排水管,平均下入深度302 m,支管平均抽采纯量1.66 m^(3)/min,平均瓦斯浓度17.5%。试验结果表明:该技术可有效解决松软薄煤层下斜钻孔长距离定向成孔、全孔段筛管护孔和排水的技术难题,提高了钻孔成孔深度和煤层钻遇率,实现了下斜孔全孔段护孔和排水,保障了瓦斯抽采效果,为松软薄煤层煤巷条带长距离消突提供技术保障,在类似地层条件具有广泛的应用推广价值。 展开更多
关键词 松软薄煤层 定向钻进 煤巷条带 下斜定向钻孔 氮气排渣 消突
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基于多区组合煤体的煤与瓦斯突出动力学机制
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作者 李峰 王琛琛 +3 位作者 王博 荆亚东 闫正旭 张民波 《煤田地质与勘探》 EI CAS CSCD 北大核心 2024年第5期12-24,共13页
煤与瓦斯突出(以下简称“突出”)严重影响煤炭安全开采,其背后涉及的众多科学问题仍未解决。为降低煤体力学性质各向异性对突出研究的困扰,构建多区组合煤体模型;基于上覆岩层应力分布特征及应力波传播机制确定“弱区”煤体位置,将研究... 煤与瓦斯突出(以下简称“突出”)严重影响煤炭安全开采,其背后涉及的众多科学问题仍未解决。为降低煤体力学性质各向异性对突出研究的困扰,构建多区组合煤体模型;基于上覆岩层应力分布特征及应力波传播机制确定“弱区”煤体位置,将研究对象由“突出中心体”具体为“弱区”。由于外部动载扰动是导致突出的激发条件,采用冲击试验研究应力波在层状组合煤岩体中的传播规律,构建组合煤岩体应力-应变本构模型。进而明确卸载波作用下,煤体轴向多层层裂是煤体质点内撞击形成加载冲击波在自由面反射形成拉应力波导致的;煤体径向平面,由于泊松效应形成卸载波追赶塑性加载波的情形,生成多个径向裂隙及环向裂隙,得到煤体层裂片厚度动态演化规律。从而明确在外部动载扰动下,煤体“弱区”最先破坏,轴向产生多层层裂、径向平面产生多个径向及环向裂隙的三维损伤路径。基于此,提出一种基于多区组合煤体的突出动力学机制,将突出划分为准备、启动、发展、终止四个阶段。突出准备阶段,煤体上覆岩层应力转移、集中,高瓦斯压力梯度形成,为后续煤体失稳破坏创造条件;突出启动阶段,煤体受外部动载扰动,轴向“弱区”煤体最先发生破坏、形成多层层裂,径向平面形成多个径向及环向裂隙;突出发展阶段,吸附态瓦斯解吸与游离态瓦斯积聚形成高压瓦斯抛出煤体,导致突出继续向深部煤体发展,形成二次损伤;突出终止阶段,积聚形成的瓦斯压力低于煤体抗拉强度,形成稳定的纺锤形突出腔体,突出终止。该机制初步解释了突出过程中“响煤炮”“口小腔大”突出孔洞等动力现象成因,为矿井防突工作提供了新思路。 展开更多
关键词 煤与瓦斯突出 多区组合煤体模型 弱区 应力波 层裂 突出动力学机制
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突出煤层分层切削钻孔瓦斯释放特征及应用研究
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作者 王永龙 赵澳琪 +5 位作者 余在江 王振锋 刘晓 麻登辉 张辉 刘春 《煤田地质与勘探》 EI CAS CSCD 北大核心 2024年第8期220-230,共11页
【目的】突出煤层钻进过程中的喷孔瓦斯超限是威胁矿井高效生产的安全隐患,分层切削钻进方法有助于在孔内削弱喷孔瓦斯压力,但分层切削形成的梯形钻孔周围瓦斯释放特征不明,限制了分层切削钻具结构设计和应用效果。【方法】以不同层间... 【目的】突出煤层钻进过程中的喷孔瓦斯超限是威胁矿井高效生产的安全隐患,分层切削钻进方法有助于在孔内削弱喷孔瓦斯压力,但分层切削形成的梯形钻孔周围瓦斯释放特征不明,限制了分层切削钻具结构设计和应用效果。【方法】以不同层间距、层厚差的分层切削钻孔为研究对象,建立数学模型分析钻孔周围瓦斯流动规律,并定量描述了分层切削钻孔瓦斯流量与层间距、层厚差之间的关系,在此基础上,通过数值模拟分析了分层切削钻具瓦斯释放调控机制,优化了分层切削钻具结构,并开展了现场钻进工业性试验。【结果和结论】结果表明:(1)多次切削成孔方式使钻孔的揭露面积逐渐增大,有效控制了瓦斯释放面积,进而调控了瓦斯释放流量,通过合理设计钻孔层厚差Hj与层间距Li,能够将瓦斯释放流量降低18.3%以上。(2)在一定层间距范围内,双层切削钻具调控效果将优于三层切削钻具,直径为63.5 mm刻槽阻尼钻杆在推力140 kN和扭矩4600 N·m作用下,最小安全系数为3.009,满足强度设计要求。(3)优选双层切削钻具,其揭露直径73 mm,终孔直径113 mm,层间距0.8 m,通过工业性试验,钻遇高压瓦斯富集区时,孔口瓦斯体积分数降低了37.7%,孔口瓦斯体积分数均未超过0.5%。表明分层切削钻具调控钻孔周围煤体瓦斯释放量、削弱瓦斯释放强度的作用显著,为预防钻孔喷孔瓦斯超限问题提供了新的解决思路。 展开更多
关键词 突出煤层 分层切削 瓦斯抽采 瓦斯超限 数值模拟
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铁路隧道煤与瓦斯突出危险性判定分析
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作者 付开隆 崔建宏 +1 位作者 陈明浩 李沧海 《高速铁路技术》 2024年第3期39-44,共6页
铁路隧道在施工开挖过程中判定具有煤与瓦斯突出危险性,会导致投资增加和工期延长等问题。本文解读了国家煤矿安监局煤安监技装〔2019〕28号文附件《防治煤与瓦斯突出细则》与TB 10120-2019《铁路瓦斯隧道技术规范》中关于煤与瓦斯突出... 铁路隧道在施工开挖过程中判定具有煤与瓦斯突出危险性,会导致投资增加和工期延长等问题。本文解读了国家煤矿安监局煤安监技装〔2019〕28号文附件《防治煤与瓦斯突出细则》与TB 10120-2019《铁路瓦斯隧道技术规范》中关于煤与瓦斯突出危险性判定的规定。通过对比不同铁路隧道煤与瓦斯突出危险性判定实例,讨论了铁路隧道各阶段煤与瓦斯突出危险性判定的原则。研究发现:勘察阶段钻孔内瓦斯测试数据欠准确的原因主要包括:(1)钻孔内测试深度与施工揭示煤层的深度不一致;(2)钻孔内煤层深度过大影响测试准确性。 展开更多
关键词 煤与瓦斯突出 突出煤层 突出危险性预测 瓦斯压力
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基于离散-连续耦合的岩溶隧道防突岩体安全厚度预测
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作者 晏启祥 刘琛尧 +3 位作者 孙润方 王绪 谢文清 陈耀 《中国铁道科学》 EI CAS CSCD 北大核心 2024年第2期90-100,共11页
为有效预防岩溶隧道施工中的突涌水灾害,首先,调研近年来国内岩溶隧道突涌水典型案例,总结隧道突涌水形成机理及其影响因素;其次,建立离散-连续耦合模型并采用多元回归理论的方法,明确防突岩体破坏的判定准则,划分岩溶隧道防突岩体破坏... 为有效预防岩溶隧道施工中的突涌水灾害,首先,调研近年来国内岩溶隧道突涌水典型案例,总结隧道突涌水形成机理及其影响因素;其次,建立离散-连续耦合模型并采用多元回归理论的方法,明确防突岩体破坏的判定准则,划分岩溶隧道防突岩体破坏模式并提出裂缝发育规律;然后,基于对防突岩体最小安全厚度造成影响的各因素,针对溶洞位于隧道上方、下方及侧方3种情况分别建立防突岩体最小安全厚度预测计算式;最后,依托德庆隧道工程进行验证。结果表明:防突岩体破坏模式主要有弯折破坏、整体剪切破坏和复合破坏3种,可基于裂隙发展速度将其破坏过程分为初始阶段、快速发育阶段、平缓发育阶段3个阶段;各因素按影响显著程度由大到小依次为溶腔内水压、围岩黏结参数、溶腔跨度、溶腔高跨比和隧道埋深;计算得到德庆隧道3处施工段的防突岩体最小安全厚度分别为2.964,5.263和0.961 m,突涌水评估结果准确。防突岩体最小安全厚度预测计算式可用于预测并评估岩溶隧道突涌水风险。 展开更多
关键词 岩溶隧道 离散-连续耦合模型 防突岩体 破坏模式 安全厚度
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隧道突出气体特征及形成机理研究
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作者 强新刚 袁东 +2 位作者 何平 岳志勤 张广泽 《高速铁路技术》 2024年第2期39-44,共6页
为研究高原隧道不明突出气体特征及形成机理,本文采用资料收集、现场调查测试与监测、室内岩石学、地球化学试验等方法与手段,研究突出气体赋存地质环境,揭示突出气体成分、演化过程及演化规律,结合区域地质条件演化过程,建立突出气体... 为研究高原隧道不明突出气体特征及形成机理,本文采用资料收集、现场调查测试与监测、室内岩石学、地球化学试验等方法与手段,研究突出气体赋存地质环境,揭示突出气体成分、演化过程及演化规律,结合区域地质条件演化过程,建立突出气体形成、演化模式。研究结果表明:(1)该横洞及周边地区不具备发育大规模油气资源的岩性条件,该突出气体应属有机成因与无机成因混合气范畴;(2)突出气体含量随时间呈逐渐减小趋势,气体储量有限,不具有易燃性,具有微~中等腐蚀性;(3)该横洞突出气体是一类成分多样、形成演化过程复杂的有机成因和无机成因混合气,其形成先后经历有机成因阶段与无机成因阶段,区域地质历史时期活跃的岩浆活动和出气孔处发育的碳酸盐岩为突出气体的无机成因提供了证据。研究成果可为类似高原隧道突出气体研究和评价提供参考。 展开更多
关键词 隧道 突出气体 气体检测 成因机制
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瓦斯气体水合固化作用影响因素分析
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作者 谢军 姜安琪 +3 位作者 付伟 赵贺春 王法铨 陈军 《煤炭工程》 北大核心 2024年第4期138-143,共6页
瓦斯与水的水合作用可以促使煤层中的瓦斯气体以水合物的形态固化于煤层之中,为研究外在条件对瓦斯水合物生成的影响,自主搭建了静态水合物合成实验装置,开展了瓦斯水合作用实验,分别考察了促进剂添加量、初始压力对瓦斯水合作用的影响... 瓦斯与水的水合作用可以促使煤层中的瓦斯气体以水合物的形态固化于煤层之中,为研究外在条件对瓦斯水合物生成的影响,自主搭建了静态水合物合成实验装置,开展了瓦斯水合作用实验,分别考察了促进剂添加量、初始压力对瓦斯水合作用的影响规律,分析了促进剂、初始压力对瓦斯水合物生成促进作用机理。结果表明:促进剂的添加有效增加了水合作用效果但却存在极限浓度,当促进剂浓度介于3 wt%-8.7 wt%时会促进水合作用的进行,浓度达到8.7 wt%时作用效果最佳,而当促进剂浓度在14.4 wt%时,则会减缓水合作用进程;初始压力与水合作用效果呈正相关关系,初始压力越高水合作用的速率越快,水合作用时间越长;通过对反应余气中甲烷组分的监测表明,促进剂和初始压力能够改变水合作用的进程,对于瓦斯水合固化效果起着决定性的作用。 展开更多
关键词 煤与瓦斯突出 瓦斯水合作用 促进剂浓度 初始压力
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炭质泥岩地层隧道瓦斯突出成因及处治措施研究
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作者 田娇 杨洪 杨智成 《公路交通技术》 2024年第4期158-165,共8页
为解决炭质泥岩地层隧道瓦斯突出问题,依托兰州至海口国家高速公路重庆至遵义段(贵州境)扩容工程桐梓隧道,通过现场调查和理论分析,总结了该隧道瓦斯突出动力现象及特点,分析了其瓦斯突出的规律以及影响因素,提出了钻孔泄压方案及处治... 为解决炭质泥岩地层隧道瓦斯突出问题,依托兰州至海口国家高速公路重庆至遵义段(贵州境)扩容工程桐梓隧道,通过现场调查和理论分析,总结了该隧道瓦斯突出动力现象及特点,分析了其瓦斯突出的规律以及影响因素,提出了钻孔泄压方案及处治措施。结果表明:经处治后,炭质泥岩施工掌子面的动力现象有了明显减少和减弱,工程施工基本不受影响,表明了该处治措施的效果较好。研究结果可供炭质泥岩地层及其他非煤系地层瓦斯隧道的设计和施工参考。 展开更多
关键词 炭质泥岩地层 公路隧道 瓦斯突出 处治措施
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煤矿冲击地压和煤与瓦斯突出事故自动发现与报警方法研究
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作者 孙继平 程继杰 《工矿自动化》 CSCD 北大核心 2024年第5期1-5,13,共6页
煤矿冲击地压和煤与瓦斯突出自动感知报警方法是及时发现事故并应急救援,减少人员伤亡,避免或减少瓦斯和煤尘爆炸等次生事故发生,遏制事故迟报、漏报和瞒报的有效措施。煤矿冲击地压事故感知难,目前还没有煤矿冲击地压事故自动发现和报... 煤矿冲击地压和煤与瓦斯突出自动感知报警方法是及时发现事故并应急救援,减少人员伤亡,避免或减少瓦斯和煤尘爆炸等次生事故发生,遏制事故迟报、漏报和瞒报的有效措施。煤矿冲击地压事故感知难,目前还没有煤矿冲击地压事故自动发现和报警方法,煤矿冲击地压事故主要靠人工发现。目前仅有基于甲烷、风速和风向传感器的煤与瓦斯突出自动报警方法,但存在响应速度慢、甲烷传感器损毁前监测不到甲烷浓度大幅升高等问题。提出了煤矿冲击地压和煤与瓦斯突出图像感知报警方法:根据煤矿冲击地压和煤与瓦斯突出温度、颜色、深度、掩埋等图像特征,识别煤矿冲击地压和煤与瓦斯突出;再根据巷道空间和采掘工作面的甲烷浓度变化,区分冲击地压和煤与瓦斯突出,如果甲烷浓度大面积迅速升高,则判定为煤与瓦斯突出,否则判定为冲击地压。该方法具有直观、响应速度快、非接触、监测范围广、简单可靠等优点,可直观地记录煤矿冲击地压和煤与瓦斯突出真实情况;当煤矿冲击地压和煤与瓦斯突出事故报警后,调度室值班人员可以通过录像,立即确认事故,及时进行应急救援。提出了减少煤矿冲击地压和煤与瓦斯突出抛出的煤岩对图像感知影响的方法:摄像机多点布置,摄像机设置在较高位置,视频数据及时传输,甲烷传感器多点布置等。 展开更多
关键词 冲击地压 煤与瓦斯突出 煤矿事故感知 灾害报警 图像识别
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基于机器学习的煤与瓦斯突出预测研究进展及展望 被引量:2
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作者 薛生 郑晓亮 +2 位作者 袁亮 来文豪 张玉婷 《煤炭学报》 EI CAS CSCD 北大核心 2024年第2期664-694,共31页
我国煤矿安全生产形势不断好转,但煤与瓦斯突出事故仍时有发生。煤与瓦斯突出预测不仅能指导防突措施科学的运用、减少防突措施工程量,在一定程度上也可以确保煤矿工人的作业安全。机器学习(Machine Learning, ML)是一门涉及概率论、统... 我国煤矿安全生产形势不断好转,但煤与瓦斯突出事故仍时有发生。煤与瓦斯突出预测不仅能指导防突措施科学的运用、减少防突措施工程量,在一定程度上也可以确保煤矿工人的作业安全。机器学习(Machine Learning, ML)是一门涉及概率论、统计学和计算机学等领域的交叉学科,可以挖掘突出事故和指标间的非线性关系。将机器学习用于煤与瓦斯突出预测,已得到相对广泛的关注,并随着人工智能和计算机技术的快速进步,其在突出预测领域将发挥更大作用。因此,对机器学习在煤与瓦斯突出预测中的研究进行了全面的综述,分析其在突出预测中面临的难点并展望其发展方向。首先,简述煤与瓦斯突出假说、发生机理与预测指标选择的研究现状;介绍机器学习在煤与瓦斯突出预测领域的主要研究进展,包括支持向量机(Support Vector Machines,SVM)、人工神经网络(Artificial Neural Network, ANN)、极限学习机(Extreme Learning Machines,ELM)和集成学习(Ensemble Learning, EL)等算法的应用,以及特征选择和缺失数据填补在数据处理等方面的创新,同时也指出了目前基于机器学习的突出预测研究面临的挑战及存在的问题,例如事故与非事故样本的不平衡、数据的指标缺失和机器学习中的小样本等;最后,展望了基于机器学习的煤与瓦斯突出预测的未来发展方向,包括改进算法性能、优化特征工程和增加样本量等。随着计算机性能的提升,有望开发出更为复杂、精准的模型,以提高对突出事故的准确预测能力。 展开更多
关键词 煤与瓦斯突出 机器学习 突出预测 特征选择
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