Ten nitrated polycyclic aromatic hydrocarbons(nPAHs)and 4 oxygenated polycyclic aromatic hydrocarbons(oPAHs)in fine particulate matter(PM2.5)samples from Mount Tai were analyzed during summer(June to August),2015.Duri...Ten nitrated polycyclic aromatic hydrocarbons(nPAHs)and 4 oxygenated polycyclic aromatic hydrocarbons(oPAHs)in fine particulate matter(PM2.5)samples from Mount Tai were analyzed during summer(June to August),2015.During the observation campaign,themean concentration of total nPAHs and oPAHs was 31.62 pg/m^(3)and 0.15 ng/m^(3),respectively.Two of the monitored compounds,namely 9-nitro-anthracene(9N-ANT)(6.86 pg/m^(3))and 9-fluorenone(9FO)(0.05 ng/m^(3))were the predominant compounds of nPAHs and oPAHs,respectively.The potential source and long-range transportation of nPAHs and oPAHs were investigated by the positive matrix factorization(PMF)method and the potential source contribution function(PSCF)methods.The results revealed that biomass/coal burning,gasoline vehicle emission,diesel vehicle emission and secondary formation were the dominant sources of nPAHs and oPAHs,which were mainly from Henan province and Beijing-Tianjin-Hebei region and Bohai sea.The incremental life cancer risk(ILCR)values were calculated to evaluate the exposure risk of nPAHs and oPAHs for three group people(infant,children and adult),and the values of ILCR were 7.02×10^(−10),3.49×10^(−9)and 1.41×10^(−8)for infant,children and adults,respectively.All these values were lower than the standard of EPA(Environmental Protection Agency)(<10−6),indicating acceptable health risk of nPAHs and oPAHs.展开更多
基金supported by the China Postdoctoral Science Foundation(No.2020M670667)the Tianjin Municipal Education Commission Research Project(No.2017KJ244)+1 种基金the Key Research and Development Plan of Tianjin(No.18YFZCSF01400)the National Natural Science Foundation of China(Nos.41701579,21806158).
文摘Ten nitrated polycyclic aromatic hydrocarbons(nPAHs)and 4 oxygenated polycyclic aromatic hydrocarbons(oPAHs)in fine particulate matter(PM2.5)samples from Mount Tai were analyzed during summer(June to August),2015.During the observation campaign,themean concentration of total nPAHs and oPAHs was 31.62 pg/m^(3)and 0.15 ng/m^(3),respectively.Two of the monitored compounds,namely 9-nitro-anthracene(9N-ANT)(6.86 pg/m^(3))and 9-fluorenone(9FO)(0.05 ng/m^(3))were the predominant compounds of nPAHs and oPAHs,respectively.The potential source and long-range transportation of nPAHs and oPAHs were investigated by the positive matrix factorization(PMF)method and the potential source contribution function(PSCF)methods.The results revealed that biomass/coal burning,gasoline vehicle emission,diesel vehicle emission and secondary formation were the dominant sources of nPAHs and oPAHs,which were mainly from Henan province and Beijing-Tianjin-Hebei region and Bohai sea.The incremental life cancer risk(ILCR)values were calculated to evaluate the exposure risk of nPAHs and oPAHs for three group people(infant,children and adult),and the values of ILCR were 7.02×10^(−10),3.49×10^(−9)and 1.41×10^(−8)for infant,children and adults,respectively.All these values were lower than the standard of EPA(Environmental Protection Agency)(<10−6),indicating acceptable health risk of nPAHs and oPAHs.
