A new anodic material of ternary Pb-0.8%Ag-(0-5.0%)Bi alloy for zinc electrowinning was obtained by doping Bi.The anodic oxygen evolution potential,corrosion rate,surface products after polarization,and microstructure...A new anodic material of ternary Pb-0.8%Ag-(0-5.0%)Bi alloy for zinc electrowinning was obtained by doping Bi.The anodic oxygen evolution potential,corrosion rate,surface products after polarization,and microstructures before and after polarization were studied and compared with those of Pb-0.8%Ag anode used in industry.The results show the anodic overpotential decreases with the increase of Bi content in the alloys.When the content of Bi is 1.0%(mass fraction),the anodic overpotential is 40-50 mV lower than that of Pb-0.8%Ag anode.While the corrosion rate decreases and then increases with the increase of Bi content.The Pb-0.8%Ag-0.1%Bi anode has the lowest corrosion rate(0.090 6 mg/(h·cm2).Doping Bi influences the structure of the anodic layer,but does not change the phase.The Pb-0.8%Ag-1.0%Bi anode layer is of a more fine-grained structure compared with Pb-0.8%Ag anode.展开更多
SnO2intermediate layers were coated on the titanium(Ti)substrate by thermal decomposition.Scanning electronmicroscope(SEM)and X-ray diffraction(XRD)results show that uniform SnO2intermediate layers with rutile crystal...SnO2intermediate layers were coated on the titanium(Ti)substrate by thermal decomposition.Scanning electronmicroscope(SEM)and X-ray diffraction(XRD)results show that uniform SnO2intermediate layers with rutile crystal structure weresuccessfully achieved.According to the results of linear sweep voltammetry(LSV),oxygen evolution potential(OEP)of theTi/SnO2/MnO2electrodes decreases with increasing SnO2content,indicating that the electro-catalytic oxidation activity of theelectrode increases.Accelerated service life tests results demonstrate that SnO2intermediate layer can improve the service life of theTi/SnO2/MnO2electrode.As the content of SnO2intermediate layer increases,the cell voltage and the energy consumption decreaseapparently.展开更多
基金Project(2007SK2009)supported by the Science and Technology Research Project of Hunan Province,China
文摘A new anodic material of ternary Pb-0.8%Ag-(0-5.0%)Bi alloy for zinc electrowinning was obtained by doping Bi.The anodic oxygen evolution potential,corrosion rate,surface products after polarization,and microstructures before and after polarization were studied and compared with those of Pb-0.8%Ag anode used in industry.The results show the anodic overpotential decreases with the increase of Bi content in the alloys.When the content of Bi is 1.0%(mass fraction),the anodic overpotential is 40-50 mV lower than that of Pb-0.8%Ag anode.While the corrosion rate decreases and then increases with the increase of Bi content.The Pb-0.8%Ag-0.1%Bi anode has the lowest corrosion rate(0.090 6 mg/(h·cm2).Doping Bi influences the structure of the anodic layer,but does not change the phase.The Pb-0.8%Ag-1.0%Bi anode layer is of a more fine-grained structure compared with Pb-0.8%Ag anode.
基金Project(51574287) supported by the National Natural Science Foundation of ChinaProject supported by the Collaborative Innovation Center of Manganese-Zinc-Vanadium Industrial Technology
文摘SnO2intermediate layers were coated on the titanium(Ti)substrate by thermal decomposition.Scanning electronmicroscope(SEM)and X-ray diffraction(XRD)results show that uniform SnO2intermediate layers with rutile crystal structure weresuccessfully achieved.According to the results of linear sweep voltammetry(LSV),oxygen evolution potential(OEP)of theTi/SnO2/MnO2electrodes decreases with increasing SnO2content,indicating that the electro-catalytic oxidation activity of theelectrode increases.Accelerated service life tests results demonstrate that SnO2intermediate layer can improve the service life of theTi/SnO2/MnO2electrode.As the content of SnO2intermediate layer increases,the cell voltage and the energy consumption decreaseapparently.
