An easy-to-make ozone generator which can be made with readily available materials is proposed. Concentration of the ozone prepared with this generator could reach that of ozone in equilibrium with oxygen. Cured with ...An easy-to-make ozone generator which can be made with readily available materials is proposed. Concentration of the ozone prepared with this generator could reach that of ozone in equilibrium with oxygen. Cured with the ozone thus prepared, GC capillary columns with immobilized SE-54 phase and excellent chromatographic performance were successfully prepared.展开更多
This paper presents experimental results concerning the effect of dielectric type on ozone concentration and the efficiency of its generation in plasma reactor with two mesh electrodes.Three types of dielectric solid ...This paper presents experimental results concerning the effect of dielectric type on ozone concentration and the efficiency of its generation in plasma reactor with two mesh electrodes.Three types of dielectric solid were used in the study; glass, micanite and Kapton insulating foil. The experiments were conducted for voltage ranges from 2.3 to 13 k V. A plasma reactor equipped with two 0.3×0.3 mm^2 mesh electrodes made of acid resistant AISI 304 mesh was used in the experiments. The influence of the dielectric type on the concentration and efficiency of ozone generation was described. The resulting maximum concentration of the ozone was about 2.70–9.30 g O3 m^-3, depending on the dielectrics used. The difference between the maximum and the minimum ozone concentration depends on the dielectric used,this accounts for 70% at the variance. The reactor capacity has also been described in the paper; total Ct and dielectric capacitance Cd depending on the dielectric used and its thickness.展开更多
A novel electrode design for the in situ generation of ozone in the reaction zone of a tubular reactor is described in this work.The ozone generator uses a porous inner electrode tube in the corona discharge assembly,...A novel electrode design for the in situ generation of ozone in the reaction zone of a tubular reactor is described in this work.The ozone generator uses a porous inner electrode tube in the corona discharge assembly,and the ozone generated around the outer periphery of the porous tube diffuses into the tubular reactor and reacts with the contaminants in the fluid that is being treated.A mathematical model that includes absorption and second order reaction in the film is developed to describe ozonation kinetics of a contaminant dye in the tubular reactor.The model describes the experimental data for dye decolorization,oxidation byproducts,dissolved ozone,and ozone gas concentrations well.Model analysis indicates that the fast dye decolorization reaction occurs partly in the liquid film and partly in the bulk fluid.The model can be used in the selection of appropriate gas-liquid contactors for efficient oxidation of contaminants in effluents.展开更多
文摘An easy-to-make ozone generator which can be made with readily available materials is proposed. Concentration of the ozone prepared with this generator could reach that of ozone in equilibrium with oxygen. Cured with the ozone thus prepared, GC capillary columns with immobilized SE-54 phase and excellent chromatographic performance were successfully prepared.
文摘This paper presents experimental results concerning the effect of dielectric type on ozone concentration and the efficiency of its generation in plasma reactor with two mesh electrodes.Three types of dielectric solid were used in the study; glass, micanite and Kapton insulating foil. The experiments were conducted for voltage ranges from 2.3 to 13 k V. A plasma reactor equipped with two 0.3×0.3 mm^2 mesh electrodes made of acid resistant AISI 304 mesh was used in the experiments. The influence of the dielectric type on the concentration and efficiency of ozone generation was described. The resulting maximum concentration of the ozone was about 2.70–9.30 g O3 m^-3, depending on the dielectrics used. The difference between the maximum and the minimum ozone concentration depends on the dielectric used,this accounts for 70% at the variance. The reactor capacity has also been described in the paper; total Ct and dielectric capacitance Cd depending on the dielectric used and its thickness.
基金Supported in part by a research grant(BES-0209343) from the U.S.National Science Foundation
文摘A novel electrode design for the in situ generation of ozone in the reaction zone of a tubular reactor is described in this work.The ozone generator uses a porous inner electrode tube in the corona discharge assembly,and the ozone generated around the outer periphery of the porous tube diffuses into the tubular reactor and reacts with the contaminants in the fluid that is being treated.A mathematical model that includes absorption and second order reaction in the film is developed to describe ozonation kinetics of a contaminant dye in the tubular reactor.The model describes the experimental data for dye decolorization,oxidation byproducts,dissolved ozone,and ozone gas concentrations well.Model analysis indicates that the fast dye decolorization reaction occurs partly in the liquid film and partly in the bulk fluid.The model can be used in the selection of appropriate gas-liquid contactors for efficient oxidation of contaminants in effluents.
