Analysis of atmospheric boundary ozone profiles in winter in hinterland of Taklimakan Desert

In order to reveal the variation characteristics of ozone （03） concentration in the atmosphere boundary layer over a desert in winter, an observation experiment was carried out in the Tazhong area by means of a tethered balloon during January 18-25, 2008. The vertical distribution of O3 concentration and its correlation with temperature and humidity were analyzed based on experimental observation data and related data. Results show that： （1） The concentration of O3 mainly ranges from 10 to 50 μg/L, with a maximum of 56.1 μg/L, minimum of 2.6 μg/L, and a daily average concentration of 34.4 μg/L. （2） O3 profiles can be divided into three types： peak, uniform, and growth, where uniform accounts for the majority. （3） Temperature and moisture are influential on O3 concentrations in atmospheric boundary layer. Temperature inversion and water vapor increase in an atmospheric boundary layer leads to a decrease of O3. （4） O3 concentration has an obvious daily change in Tazhong. It is lower at night, begins to increase after sunrise, and reaches a maximum at noon. The maximum appears at 17：00 BJT （Beijing Time）, and the minimum appears at 08：00 BJT.

A Method for Retrieving Vertical Ozone Profiles from Limb Scattered Measurements

A two-step method is employed in this study to retrieve vertical ozone profiles using scattered measure- ments from the limb of the atmosphere. The combination of the Differential Optical Absorption Spectroscopy （DOAS） and the Multiplicative Algebraic Reconstruction Technique （MART） is proposed. First, the limb radiance, measured over a range of tangent heights, is processed using the DOAS technique to recover the effective column densities of atmospheric ozone. Second, these effective column densities along the lines of sight （LOSs） are inverted using the MART coupled with a forward model SCIATRAN （radiative transfer model for SCIAMACHY） to derive the ozone profiles. This method is applied to Optical Spectrograph and Infra Red Imager System （OSIRIS） radiance, using the wavelength windows 571–617 nm. Vertical ozone profiles between 10 and 48 km are derived with a vertical resolution of 1 km. The results illustrate a good agreement with the cloud-free coincident SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY （SCIAMACHY） ozone measurements, with deviations less than ± 10% （ ± 5% for altitudes from 17 to 47 km）. Furthermore, sensitivities of retrieved ozone to aerosol, cloud parameters and NO 2 concentration are also investigated.

从中国首台紫外-可见光高光谱卫星仪器反演得到的高空间分辨率臭氧廓线

Understanding the vertical distribution of ozone is crucial when assessing both its horizontal and vertical transport,as well as when analyzing the physical and chemical properties of the atmosphere.One of the most effective ways to obtain high spatial resolution ozone profiles is through satellite observations.The Environmental Trace Gases Monitoring Instrument(EMI)deployed on the Gaofen-5 satellite is the first Chinese ultraviolet-visible hyperspectral spectrometer.However,retrieving ozone profiles using backscattered radiance values measured by the EMI is challenging due to unavailable measurement errors and a low signal-to-noise ratio.The algorithm developed for the Tropospheric Monitoring Instrument did not allow us to retrieve 87%of the EMI pixels.Therefore,we developed an algorithm specific to the characteristics of the EMI.The fitting residuals are smaller than 0.3%in most regions.The retrieved ozone profiles were in good agreement with ozonesonde data,with maximum mean biases of 20%at five latitude bands.By applying EMI averaging kernels to the ozonesonde profiles,the integrated stratospheric column ozone and tropospheric column ozone also showed excellent agreement with ozonesonde data,The lower layers(0-7.5 km)of the EMI ozone profiles reflected the seasonal variation in surface ozone derived from the China National Environmental Monitoring Center(CNEMC).However,the upper layers(9.7-16.7 km)of the ozone profiles show different trends,with the ozone peak occurring at an altitude of 9.7-16.7 km in March,2019.A stratospheric intrusion event in central China from August 11 to 15,2019,is captured using the EMI ozone profiles,potential vorticity data,and relative humidity data.The increase in the CNEMC ozone co ncentration showed that downward transport enhanced surface ozone pollution.

Ozone Vertical Profile Characteristics over Qinghai Plateau Measured by Electrochemical Concentration Cell Ozonesondes

An analysis of 50 ozonesondings in Xining (36.43 o N, 101.45 o E , 2296 m, ASL), between April 1995 and August 1996 is presented. General vertical distribution characteristics and seasonal changing of ozone profile are reported. The analysis indicates that the stratospheric ozone concentrations of Autumn and Summer are lower than those of Spring and Winter; and the highest value of the tropospheric ozone concentrations is found in Summer; ozone concentration changing is bigger from the troposphere to the lower stratosphere altitude region, while it is stable in the middle and upper stratosphere region; there is a lower ozone concentration region in 10 -1 5 km altitude; the result why higher ozone concentration of the troposphere occurs in Summer is the ozone injecting from the middle and upper stratosphere.

Vertical Distribution of Stratospheric Ozone over China

Based on the Stratospheric Aerosol and Gas Experiment (SAGE) II and the Halogen Occultation Ex-periment (HALOE) ozone profiles and the Total Ozone Mapping Spectrometer (TOMS) total ozone data sets,the characteristics and variations of the vertical distribution of stratospheric ozone covering the latitude bands of 50oN±5oN,40oN±5oN,30oN±5oN,and 20oN±5oN and the longitude range of 75-135oE are investigated.The results indicate that the ozone distribution pattern over China not only has general behaviors,but also has particular char-acteristics.In view of the situation that ozone distribu-tions have substantial deviation from zonal symmetry in northern China,the differences of the vertical ozone dis-tribution between the east and the west part of northern China are studied.The results indicate that during winter,spring,and autumn,in the latitude bands of 50oN±5oN,40oN±5oN,ozone concentrations in the eastern part (105 -135oE) are obviously higher than those of the west (75-105oE) at the altitudes of ozone density maximum and below;during summer,in the latitude band of 50oN±5oN,the east-west ozone profile difference is small,but in the latitude band of 40oN±5oN,the east-west total ozone difference becomes as large as 14.0 DU,and the east-west ozone profile difference mainly exists in the lowermost stratosphere and troposphere.

Numerical Experiment of Combined Infrared and Ultraviolet Radiation Remote Sensing to Determine the Profile and Total Content of Atmospheric Ozone

A new remote sensing method is described to determine the vertical distribution and total content of atmospheric ozone. The method combines surface infrared, satellite infrared and ultraviolet channels. The width of the infrared channels is 0.01 cm-1, less than Lorentz half-width at the earth's surface, rather than the present width, because these channels can obtain information about variations in the ozone profile below the profile main-peak. The numerical experiments show that the method has a satisfactory precision in determining total ozone content, just about I percent error, and vertical distribution from the earth to 65 km space. In addition, some semi-analysis functions lor calculating backscattered ultraviolet and a relaxation equation are described in this paper.

Comparison of Suomi-NPP OMPS total column ozone with Brewer and Dobson spectrophotometers measurements

The objective of this study is to evaluate the accuracy of the daily nadir total column ozone products derived from the nadir mapper instrument on the Ozone Mapping and Profiler Suite （OMPS） flying onboard the Suomi National Polar-orbiting Partnership satellite （S- NPP） launched as a part of the Joint Polar Satellite System （JPSS） program between NOAA and NASA. Since NOAA is already operationally processing OMPS nadir total ozone products, evaluations were made in this study on the total column ozone research products generated by NASA＇s science team, utilizing the latest version of their Backscatter Ultraviolet （BUV） retrieval algorithms, to provide insight into the performance of the operation system. Comparisons were made with globally distributed ground-based Brewer and Dobson spectrophotometer total column ozone measurements. Linear regressions show fair agreement between OMPS and ground-based total column ozone measurements with a root-mean-square error （RMSE） of approximately 3% （10 DU）. The comparison results indicate that the OMPS total column ozone data are 0.59% higher than the Brewer measurements with a standard deviation of 2.82% while 1.09% higher than the Dobson measurements with a standard deviation of 3.27%. Additionally, the variability of relative differences between OMPS and ground total column ozone were analyzed as a function of latitude, time, viewing geometry, and total column ozone value. Results show a 2% bias over most latitudes and viewing conditions when total column ozone value varies between 220 DU and 450 DU.

Measurement and Analyses of Atmospheric Ozone Profile in Qinghai Plateau

The ozone profiles from August 1991 to December 1993 in Qinghai Gonghe Station (the altitude:3000 m,latitude: 36°16.45’N, longitude: 100°37.11’E) have been got through the measurement with a Brewer Ozone spectrophotometer and Umkehr retrieval program of AES. The method we used is the short Umkehr method