多输入多输出(Multiple-Input Multiple-Output,MIMO)雷达在阵元故障时虚拟阵列输出数据矩阵会出现大量的整行数据丢失,由于阵列接收数据矩阵的不完整而导致对波达方向(Direction of Arrival,DOA)的估计性能恶化。大多数低秩矩阵填充算...多输入多输出(Multiple-Input Multiple-Output,MIMO)雷达在阵元故障时虚拟阵列输出数据矩阵会出现大量的整行数据丢失,由于阵列接收数据矩阵的不完整而导致对波达方向(Direction of Arrival,DOA)的估计性能恶化。大多数低秩矩阵填充算法要求缺失数据随机分布于不完整的矩阵中,无法适用于整行缺失数据的恢复问题。为此,提出了一种基于低秩块Hankel矩阵正则化的阵元故障MIMO雷达DOA估计方法。首先,通过奇异值分解(Singular Value Decomposition,SVD)降低虚拟阵列输出矩阵的维度,以减少计算复杂度。然后,对降维数据矩阵建立基于块Hankel矩阵正则化的低秩矩阵填充模型,在该模型中将MIMO雷达降维数据矩阵排列成块Hankel矩阵并施加Schatten-p范数作为正则项。最后,结合交替方向乘子法(Alternate Direction Multiplier Method,ADMM)求解该模型,获得完整的MIMO雷达降维数据矩阵。仿真结果表明,所提方法能够有效恢复降维数据矩阵中的整行数据缺失,具有较高的DOA估计精度和实时性,在阵元故障率低于50.0%时DOA估计精度优于现有方法。展开更多
Metal-organic frameworks(MOFs) are a class of porous inorganic-organic hybrid materials, which are constructed from diverse inorganic building units and multi-functional organic ligands. Highly ordered pore structures...Metal-organic frameworks(MOFs) are a class of porous inorganic-organic hybrid materials, which are constructed from diverse inorganic building units and multi-functional organic ligands. Highly ordered pore structures and tailored functionalization have made MOF materials potential for applications in many fields. Among various MOF materials, 3p-block metal(Al, Ga, and In)-based MOFs exhibit higher chemical stability than divalent transition metal-based MOFs due to their higher valence. In this review, Al-MOFs and In-MOFs were mainly discussed from the perspective of categories of inorganic building blocks, coordination types, and numbers of organic ligands. This review will give intuitive guidance to the design and synthesis of novel 3p-block metal-based MOFs with potential applications.展开更多
p-block metal composite oxides Sr_(1.36)Sb_(2)O_(6) and Sr_(2)Sb_(2)O_(7) synthesized by a hydrothermal method as photocatalysts in the degradation of tetracycline hydrochloride under UV light irradiation have been ex...p-block metal composite oxides Sr_(1.36)Sb_(2)O_(6) and Sr_(2)Sb_(2)O_(7) synthesized by a hydrothermal method as photocatalysts in the degradation of tetracycline hydrochloride under UV light irradiation have been extensively studied.The effects of synthesis conditions on the photocatalytic activity were discussed.The Sr_(1.36)Sb_(2)O_(6)-100°C-24 h-5 and Sr_(2)Sb_(2)O_(7)-150℃-24 h^(-2) samples prepared under optimal conditions exhibited remarkably different photocatalytic activities.The essential factors influencing the difference of photocatalytic performance were revealed.The results showed that the different photocatalytic activities observed for Sr_(1.36)Sb_(2)O_(6)and Sr_(2)Sb_(2)O_(7) could be attributed to their different electronic and crystal structures.Our work will provide a new perspective for the screening and design of p-block metal composite oxide photocatalysts to enhance the removal of organic pollutants in the environment.展开更多
Recently, the inverse connected p-median problem on block graphs G(V,E,w) under various cost functions, say rectilinear norm, Chebyshev norm, and bottleneck Hamming distance. Their contributions include finding a nece...Recently, the inverse connected p-median problem on block graphs G(V,E,w) under various cost functions, say rectilinear norm, Chebyshev norm, and bottleneck Hamming distance. Their contributions include finding a necessary and sufficient condition for the connected p-median problem on block graphs, developing algorithms and showing that these problems can be solved in O(n log n) time, where n is the number of vertices in the underlying block graph. Using similar technique, we show that some results are incorrect by a counter-example. Then we redefine some notations, reprove Theorem 1 and redescribe Theorem 2, Theorem 3 and Theorem 4.展开更多
文摘多输入多输出(Multiple-Input Multiple-Output,MIMO)雷达在阵元故障时虚拟阵列输出数据矩阵会出现大量的整行数据丢失,由于阵列接收数据矩阵的不完整而导致对波达方向(Direction of Arrival,DOA)的估计性能恶化。大多数低秩矩阵填充算法要求缺失数据随机分布于不完整的矩阵中,无法适用于整行缺失数据的恢复问题。为此,提出了一种基于低秩块Hankel矩阵正则化的阵元故障MIMO雷达DOA估计方法。首先,通过奇异值分解(Singular Value Decomposition,SVD)降低虚拟阵列输出矩阵的维度,以减少计算复杂度。然后,对降维数据矩阵建立基于块Hankel矩阵正则化的低秩矩阵填充模型,在该模型中将MIMO雷达降维数据矩阵排列成块Hankel矩阵并施加Schatten-p范数作为正则项。最后,结合交替方向乘子法(Alternate Direction Multiplier Method,ADMM)求解该模型,获得完整的MIMO雷达降维数据矩阵。仿真结果表明,所提方法能够有效恢复降维数据矩阵中的整行数据缺失,具有较高的DOA估计精度和实时性,在阵元故障率低于50.0%时DOA估计精度优于现有方法。
基金This work was supported by the National Natural Science Foundation of China(No. 21771078).
文摘Metal-organic frameworks(MOFs) are a class of porous inorganic-organic hybrid materials, which are constructed from diverse inorganic building units and multi-functional organic ligands. Highly ordered pore structures and tailored functionalization have made MOF materials potential for applications in many fields. Among various MOF materials, 3p-block metal(Al, Ga, and In)-based MOFs exhibit higher chemical stability than divalent transition metal-based MOFs due to their higher valence. In this review, Al-MOFs and In-MOFs were mainly discussed from the perspective of categories of inorganic building blocks, coordination types, and numbers of organic ligands. This review will give intuitive guidance to the design and synthesis of novel 3p-block metal-based MOFs with potential applications.
基金financially supported by the National Natural Science Foundation of China(21875037,51502036)the National Key Research and Development Program of China(2016YFB0302303,2019YFC1908203)the Natural Science Foundation of Distinguished Young Scholars of Fujian Province(2019J06015)。
文摘p-block metal composite oxides Sr_(1.36)Sb_(2)O_(6) and Sr_(2)Sb_(2)O_(7) synthesized by a hydrothermal method as photocatalysts in the degradation of tetracycline hydrochloride under UV light irradiation have been extensively studied.The effects of synthesis conditions on the photocatalytic activity were discussed.The Sr_(1.36)Sb_(2)O_(6)-100°C-24 h-5 and Sr_(2)Sb_(2)O_(7)-150℃-24 h^(-2) samples prepared under optimal conditions exhibited remarkably different photocatalytic activities.The essential factors influencing the difference of photocatalytic performance were revealed.The results showed that the different photocatalytic activities observed for Sr_(1.36)Sb_(2)O_(6)and Sr_(2)Sb_(2)O_(7) could be attributed to their different electronic and crystal structures.Our work will provide a new perspective for the screening and design of p-block metal composite oxide photocatalysts to enhance the removal of organic pollutants in the environment.
文摘Recently, the inverse connected p-median problem on block graphs G(V,E,w) under various cost functions, say rectilinear norm, Chebyshev norm, and bottleneck Hamming distance. Their contributions include finding a necessary and sufficient condition for the connected p-median problem on block graphs, developing algorithms and showing that these problems can be solved in O(n log n) time, where n is the number of vertices in the underlying block graph. Using similar technique, we show that some results are incorrect by a counter-example. Then we redefine some notations, reprove Theorem 1 and redescribe Theorem 2, Theorem 3 and Theorem 4.
