Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechan...Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechanical systems.The multi-field coupling and free vibration of a sandwiched FGPS plate are studied,and the governing equation and natural frequency are derived with the consideration of electron movement.The material properties in the functionally-graded layers are assumed to vary smoothly,and the first-order shear deformation theory is introduced to derive the multi-field coupling in the plate.The total strain energy of the plate is obtained,and the governing equations are presented by using Hamilton’s principle.By introducing the boundary conditions,the coupling physical fields are solved.In numerical examples,the natural frequencies of sandwiched FGPS plates under different geometrical and physical parameters are discussed.It is found that the initial electron density can be used to modulate the natural frequencies and vibrational displacement of sandwiched FGPS plates in the case of nano-size.The effects of the material properties of FGPS layers on the natural frequencies are also examined in detail.展开更多
The single photon scattering properties in a pair of waveguides coupled by a whispering-gallery resonator in- teracting with a semiconductor quantum dot are investigated theoretically. The two waveguides support four ...The single photon scattering properties in a pair of waveguides coupled by a whispering-gallery resonator in- teracting with a semiconductor quantum dot are investigated theoretically. The two waveguides support four possible ports for an incident single photon. The quantum dot is considered a V-type system. The incident direction-dependent single photon scattering properties are studied and equal-output probability from the four ports for a single photon incident is discussed. The influences of backscattering between the two modes of the whispering-gallery resonator for incident direction-dependent single photon scattering properties are also pre- sented.展开更多
We utilize three parallel reservoir computers using semiconductor lasers with optical feedback and light injection to model radar probe signals with delays.Three radar probe signals are generated by driving lasers con...We utilize three parallel reservoir computers using semiconductor lasers with optical feedback and light injection to model radar probe signals with delays.Three radar probe signals are generated by driving lasers constructed by a threeelement laser array with self-feedback.The response lasers are implemented also by a three-element lase array with both delay-time feedback and optical injection,which are utilized as nonlinear nodes to realize the reservoirs.We show that each delayed radar probe signal can be predicted well and to synchronize with its corresponding trained reservoir,even when parameter mismatches exist between the response laser array and the driving laser array.Based on this,the three synchronous probe signals are utilized for ranging to three targets,respectively,using Hilbert transform.It is demonstrated that the relative errors for ranging can be very small and less than 0.6%.Our findings show that optical reservoir computing provides an effective way for applications of target ranging.展开更多
We demonstrate the curvature of coupled twin circular-side-octagon microcavity(TCOM)lasers as the degree of freedom to realize manipulation of mode quality(Q)factor and lasing characteristics.Numerical simulation resu...We demonstrate the curvature of coupled twin circular-side-octagon microcavity(TCOM)lasers as the degree of freedom to realize manipulation of mode quality(Q)factor and lasing characteristics.Numerical simulation results indicate that mode Q factors varying from 10^(4) to 10^(8),wavelength intervals of different transverse modes,and mode numbers for four-bounce modes can be manipulated for five different deformations.Global mode distributes throughout coupled microcavity with mode Q factor around the order of 10^(4) or 10^(5).Four-bounce modes lase with injection currents applied single microcavity.By pumping both microcavities simultaneously,single-mode lasing for global modes with side mode suppression ratios(SMSRs)of 30,32,32,31,and 36 dB is achieved at the deformation of 0,0.5,1,1.5,and 2 with four-bounce modes suppressed,respectively.Moreover,the linewidths less than 11 MHz for the single mode are obtained with the deformation of 2.The results show that the lasing modes can be efficiently manipulated considering variable curvature for TCOM lasers,which can promote practical applications of microcavity lasers.展开更多
This paper describes interlayer exchange coupling (IEC) phenomena in ferromagnetic multilayer structures, focusing on the unique IEC features observed in ferromagnetic semiconductor (Ga,Mn)As-based systems. The depend...This paper describes interlayer exchange coupling (IEC) phenomena in ferromagnetic multilayer structures, focusing on the unique IEC features observed in ferromagnetic semiconductor (Ga,Mn)As-based systems. The dependence of IEC on the structural parameters, such as non-magnetic spacer thickness, number of magnetic layers, and carrier density in the systems has been investigated by using magnetotransport measurements. The samples in the series show both a typical anisotropic magnetoresistance (AMR) and giant magnetoresistance (GMR)-like effects indicating realization of both ferromagnetic (FM) and antiferromagnetic (AFM) IEC in (Ga,Mn)As-based multilayer structures. The results revealed that the presence of carriers in the nonmagnetic spacer is an important factor to realize AFM IEC in this system. The studies further reveal that the IEC occurs over a much longer distance than predicted by current theories, strongly suggesting that the IEC in (Ga,Mn)As-based multilayers is a long-range interaction. Due to the long-range nature of IEC in the (Ga,Mn)As-based systems, the next nearest neighbor (NNN) IEC cannot be ignored and results in multi-step transitions during magnetization reversal that correspond to diverse spin configurations in the system. The strength of NNN IEC was experimentally determined by measuring minor loops that correspond to magnetization flips in specific (Ga,Mn)As layer in the multilayer system.展开更多
In this paper,the fabrication of 1.3μm InGaAsP/InP gain-coupled DFB lasers with lossgrating is reported for the first time.A technique of regrowth on corrugated surface usingLPE is developed.By using GaAs as the cove...In this paper,the fabrication of 1.3μm InGaAsP/InP gain-coupled DFB lasers with lossgrating is reported for the first time.A technique of regrowth on corrugated surface usingLPE is developed.By using GaAs as the cover of thermal protection and controlling theamount of the super cooling,high quality epitxial layers on corrugated surface are obtained.The oxide stripe lasers with a stripe width of 20μm are fabricated.Single-mode oscillation isachieved at 1.293μm,and a high single-mode oscillation yield is also obtained.展开更多
We have studied the characteristics of current-induced nonequilibrium spin polarization in semiconductor-nanowire/swave superconductor junctions with strong spin–orbit coupling. It was found that within some paramete...We have studied the characteristics of current-induced nonequilibrium spin polarization in semiconductor-nanowire/swave superconductor junctions with strong spin–orbit coupling. It was found that within some parameter regions the magnitude of the current-induced nonequilibrium spin polarization density in such structures will increase(or decrease) with the decrease(or increase) of the charge current density, in contrast to that found in normal spin–orbit coupled semiconductor structures. It was also found that the unusual characteristics of the current-induced nonequilibrium spin polarization in such structures can be well explained by the effect of the Andreev reflection.展开更多
Influence of spin–orbit coupling on spin-polarized electronic transport in magnetic semiconductor nanowires with nanosized sharp domain walls is investigated theoretically.It is shown that the Rashba spin–orbit coup...Influence of spin–orbit coupling on spin-polarized electronic transport in magnetic semiconductor nanowires with nanosized sharp domain walls is investigated theoretically.It is shown that the Rashba spin–orbit coupling can enhance significantly the spin-flip scattering of charge carriers from a nanosized sharp domain wall whose extension is much smaller than the carrier's Fermi wavelength.When there are more than one domain wall presented in a magnetic semiconductor nanowire,not only the spin-flip scattering of charge carriers from the domain walls but the quantum interference of charge carriers in the intermediate domain regions between neighboring domain walls may play important roles on spin-polarized electronic transport,and in such cases the influences of the Rashba spin–orbit coupling will depend sensitively both on the domain walls' width and the domain walls' separation.展开更多
This paper investigates the effect of Dresselhaus spin orbit coupling on the spin-transport properties of ferromagnet/insulator/semiconductor/insulator/ferromagnet double-barrier structures. The influence of the thick...This paper investigates the effect of Dresselhaus spin orbit coupling on the spin-transport properties of ferromagnet/insulator/semiconductor/insulator/ferromagnet double-barrier structures. The influence of the thickness of the insulator between the ferromagnet and the semiconductor on the polarization is also considered. The obtained results indicate that (i) the polarization can be enhanced by reducing the insulator layers at zero temperature, and (ii) the tunnelling magnetoresistance inversion can be illustrated by the influence of the Dresselhaus spin-orbit coupling effect in the double-barrier structure. Due to the Dresselhaus spin-orbit coupling effect, the tunnelling magnetoresistance inversion occurs when the energy of a localized state in the barrier matches the Fermi energy EF of the ferromagnetic electrodes.展开更多
In this paper,to better reveal the surface effect and the screening effect as well as the nonlinear multi-field coupling characteristic of the multifunctional piezoelectric semiconductor(PS)nanodevice,and to further i...In this paper,to better reveal the surface effect and the screening effect as well as the nonlinear multi-field coupling characteristic of the multifunctional piezoelectric semiconductor(PS)nanodevice,and to further improve its working performance,a magneto-mechanical-thermo coupling theoretical model is theoretically established for the extensional analysis of a three-layered magneto-electro-semiconductor coupling laminated nanoplate with the surface effect.Next,by using the current theoretical model,some numerical analyses and discussion about the surface effect,the corresponding critical thickness of the nanoplate,and the distributions of the physical fields(including the electron concentration perturbation,the electric potential,the electric field,the average electric displacement,the effective polarization charge density,and the total charge density)under different initial state electron concentrations,as well as their active manipulation via some external magnetic field,pre-stress,and temperature stimuli,are performed.Utilizing the nonlinear multi-field coupling effect induced by inevitable external stimuli in the device operating environment,this paper not only provides theoretical support for understanding the size-dependent tuning/controlling of carrier transport as well as its screening effect,but also assists the design of a series of multiferroic PS nanodevices.展开更多
Extending the ionic conductivity is the pre-requisite of electrolytes in fuel cell technology for high-electrochemical performance.In this regard,the introduction of semiconductor-oxide materials and the approach of h...Extending the ionic conductivity is the pre-requisite of electrolytes in fuel cell technology for high-electrochemical performance.In this regard,the introduction of semiconductor-oxide materials and the approach of heterostructure formation by modulating energy bands to enhance ionic conduction acting as an electrolyte in fuel cell-device.Semiconductor(n-type;SnO_(2))plays a key role by introducing into p-type SrFe_(0.2)Ti_(0.8)O_(3-δ)(SFT)semiconductor perovskite materials to construct p-n heterojunction for high ionic conductivity.Therefore,two different composites of SFT and SnO_(2)are constructed by gluing p-and n-type SFT-SnO_(2),where the optimal composition of SFT-SnO_(2)(6∶4)heterostructure electrolyte-based fuel cell achieved excellent ionic conductivity 0.24 S cm^(-1)with power-output of 1004 mW cm^(-2)and high OCV 1.12 V at a low operational temperature of 500℃.The high power-output and significant ionic conductivity with durable operation of 54 h are accredited to SFT-SnO_(2)heterojunction formation including interfacial conduction assisted by a built-in electric field in fuel cell device.Moreover,the fuel conversion efficiency and considerable Faradaic efficiency reveal the compatibility of SFT-SnO_(2)heterostructure electrolyte and ruled-out short-circuiting issue.Further,the first principle calculation provides sufficient information on structure optimization and energy-band structure modulation of SFT-SnO_(2).This strategy will provide new insight into semiconductor-based fuel cell technology to design novel electrolytes.展开更多
The optical absorption spectra of the covalent crystals ZnX(X=S,Se) doped with Co 2+ are studied using the double covalency factors,which considers the anisotropic distortion of e g and t 2g orbits for d el...The optical absorption spectra of the covalent crystals ZnX(X=S,Se) doped with Co 2+ are studied using the double covalency factors,which considers the anisotropic distortion of e g and t 2g orbits for d electron.When the paramagnetic g factor is calculated,the contributions of the spin orbit coupling from the ligand ions are taken into account besides that from the central ion,which is the double ξ model.The calculated results indicate that the theoretical values coincide with the experimental values very well.This suggests that the method presented in this paper could be more valid to some strongly covalent crystals.展开更多
A brief review of Huang–Rhys theory and Albrechtos theory is provided,and their connection and applications are discussed.The former is a first order perturbative theory on optical transitions intended for applicatio...A brief review of Huang–Rhys theory and Albrechtos theory is provided,and their connection and applications are discussed.The former is a first order perturbative theory on optical transitions intended for applications such as absorption and emission involving localized defect or impurity centers,emphasizing lattice relaxation or mixing of vibrational states due to electron–phonon coupling.The coupling strength is described by the Huang–Rhys factor.The latter theory is a second order perturbative theory on optical transitions intended for Raman scattering,and can in-principle include electron–phonon coupling in both electronic states and vibrational states.These two theories can potentially be connected through the common effect of lattice relaxation – non-orthonormal vibrational states associated with different electronic states.Because of this perceived connection,the latter theory is often used to explain resonant Raman scattering of LO phonons in bulk semiconductors and further used to describe the size dependence of electron–phonon coupling or Huang–Rhys factor in semiconductor nanostructures.Specifically,the A term in Albrechtos theory is often invoked to describe the multi-LO-phonon resonant Raman peaks in both bulk and nanostructured semiconductors in the literature,due to the misconception that a free-exciton could have a strong lattice relaxation.Without lattice relaxation,the A term will give rise to Rayleigh or elastic scattering.Lattice relaxation is only significant for highly localized defect or impurity states,and should be practically zero for either single particle states or free exciton states in a bulk semiconductor or for confined states in a semiconductor nanostructure that is not extremely small.展开更多
Based on the density matrix approach and iterative procedure, a detailed procedure for the calculation of the linear and nonlinear intersubband optical absorption coefficients is given in wurtzite GaN-based coupling q...Based on the density matrix approach and iterative procedure, a detailed procedure for the calculation of the linear and nonlinear intersubband optical absorption coefficients is given in wurtzite GaN-based coupling quantum wells (CQWs). The simple analytical formulas for electronic eigenstates and the linear and nonlinear optical absorption coefficients in the systems are also deduced. Numerical result on a typical A1GaN/GaN CQW shows that, the linear and nonlinear optical absorption coefficients sensitively depend on the structural parameters of the CQW system as well as the incident optics beam intensity.展开更多
基金supported by the National Natural Science Foundation of China(Nos.12172236 and 12202289)。
文摘Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechanical systems.The multi-field coupling and free vibration of a sandwiched FGPS plate are studied,and the governing equation and natural frequency are derived with the consideration of electron movement.The material properties in the functionally-graded layers are assumed to vary smoothly,and the first-order shear deformation theory is introduced to derive the multi-field coupling in the plate.The total strain energy of the plate is obtained,and the governing equations are presented by using Hamilton’s principle.By introducing the boundary conditions,the coupling physical fields are solved.In numerical examples,the natural frequencies of sandwiched FGPS plates under different geometrical and physical parameters are discussed.It is found that the initial electron density can be used to modulate the natural frequencies and vibrational displacement of sandwiched FGPS plates in the case of nano-size.The effects of the material properties of FGPS layers on the natural frequencies are also examined in detail.
基金Supported by the National Natural Science Foundation of China under Grant No 11105001the Anhui Provincial Natural Science Foundation under Grant Nos 1408085QA22 and 1608085MA09
文摘The single photon scattering properties in a pair of waveguides coupled by a whispering-gallery resonator in- teracting with a semiconductor quantum dot are investigated theoretically. The two waveguides support four possible ports for an incident single photon. The quantum dot is considered a V-type system. The incident direction-dependent single photon scattering properties are studied and equal-output probability from the four ports for a single photon incident is discussed. The influences of backscattering between the two modes of the whispering-gallery resonator for incident direction-dependent single photon scattering properties are also pre- sented.
基金the National Natural Science Foundation of China(Grant No.62075168)Guang Dong Basic and Applied Basic Research Foundation(Grant No.2020A1515011088)Special Project in Key Fields of Guangdong Provincial Department of Education of China(Grant No.2020ZDZX3052 and 2019KZDZX1025)。
文摘We utilize three parallel reservoir computers using semiconductor lasers with optical feedback and light injection to model radar probe signals with delays.Three radar probe signals are generated by driving lasers constructed by a threeelement laser array with self-feedback.The response lasers are implemented also by a three-element lase array with both delay-time feedback and optical injection,which are utilized as nonlinear nodes to realize the reservoirs.We show that each delayed radar probe signal can be predicted well and to synchronize with its corresponding trained reservoir,even when parameter mismatches exist between the response laser array and the driving laser array.Based on this,the three synchronous probe signals are utilized for ranging to three targets,respectively,using Hilbert transform.It is demonstrated that the relative errors for ranging can be very small and less than 0.6%.Our findings show that optical reservoir computing provides an effective way for applications of target ranging.
基金Project supported by the Strategic Priority Research Program,Chinese Academy of Sciences(Grant No.XDB43000000)the Key Research Program of Frontier Sciences,Chinese Academy of Sciences(Grant No.QYZDJSSW-JSC002)the National Natural Science Foundation of China(Grant Nos.61874113,61875188,and 61935018).
文摘We demonstrate the curvature of coupled twin circular-side-octagon microcavity(TCOM)lasers as the degree of freedom to realize manipulation of mode quality(Q)factor and lasing characteristics.Numerical simulation results indicate that mode Q factors varying from 10^(4) to 10^(8),wavelength intervals of different transverse modes,and mode numbers for four-bounce modes can be manipulated for five different deformations.Global mode distributes throughout coupled microcavity with mode Q factor around the order of 10^(4) or 10^(5).Four-bounce modes lase with injection currents applied single microcavity.By pumping both microcavities simultaneously,single-mode lasing for global modes with side mode suppression ratios(SMSRs)of 30,32,32,31,and 36 dB is achieved at the deformation of 0,0.5,1,1.5,and 2 with four-bounce modes suppressed,respectively.Moreover,the linewidths less than 11 MHz for the single mode are obtained with the deformation of 2.The results show that the lasing modes can be efficiently manipulated considering variable curvature for TCOM lasers,which can promote practical applications of microcavity lasers.
基金supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2018R1D1A1A 02042965)Ministry of Science ICT (2018R1A4A1024157)+1 种基金a Korea University Future Research Grantthe National Science Foundation Grant DMR 1400432
文摘This paper describes interlayer exchange coupling (IEC) phenomena in ferromagnetic multilayer structures, focusing on the unique IEC features observed in ferromagnetic semiconductor (Ga,Mn)As-based systems. The dependence of IEC on the structural parameters, such as non-magnetic spacer thickness, number of magnetic layers, and carrier density in the systems has been investigated by using magnetotransport measurements. The samples in the series show both a typical anisotropic magnetoresistance (AMR) and giant magnetoresistance (GMR)-like effects indicating realization of both ferromagnetic (FM) and antiferromagnetic (AFM) IEC in (Ga,Mn)As-based multilayer structures. The results revealed that the presence of carriers in the nonmagnetic spacer is an important factor to realize AFM IEC in this system. The studies further reveal that the IEC occurs over a much longer distance than predicted by current theories, strongly suggesting that the IEC in (Ga,Mn)As-based multilayers is a long-range interaction. Due to the long-range nature of IEC in the (Ga,Mn)As-based systems, the next nearest neighbor (NNN) IEC cannot be ignored and results in multi-step transitions during magnetization reversal that correspond to diverse spin configurations in the system. The strength of NNN IEC was experimentally determined by measuring minor loops that correspond to magnetization flips in specific (Ga,Mn)As layer in the multilayer system.
基金Supported by National Natural Science Foundation of Chinathe Trans-Century Training Porgramme Foundation for Talents of the State Education Commission.
文摘In this paper,the fabrication of 1.3μm InGaAsP/InP gain-coupled DFB lasers with lossgrating is reported for the first time.A technique of regrowth on corrugated surface usingLPE is developed.By using GaAs as the cover of thermal protection and controlling theamount of the super cooling,high quality epitxial layers on corrugated surface are obtained.The oxide stripe lasers with a stripe width of 20μm are fabricated.Single-mode oscillation isachieved at 1.293μm,and a high single-mode oscillation yield is also obtained.
基金Project supported by the National Natural Science Foundation of China(Grant No.11474106)
文摘We have studied the characteristics of current-induced nonequilibrium spin polarization in semiconductor-nanowire/swave superconductor junctions with strong spin–orbit coupling. It was found that within some parameter regions the magnitude of the current-induced nonequilibrium spin polarization density in such structures will increase(or decrease) with the decrease(or increase) of the charge current density, in contrast to that found in normal spin–orbit coupled semiconductor structures. It was also found that the unusual characteristics of the current-induced nonequilibrium spin polarization in such structures can be well explained by the effect of the Andreev reflection.
文摘Influence of spin–orbit coupling on spin-polarized electronic transport in magnetic semiconductor nanowires with nanosized sharp domain walls is investigated theoretically.It is shown that the Rashba spin–orbit coupling can enhance significantly the spin-flip scattering of charge carriers from a nanosized sharp domain wall whose extension is much smaller than the carrier's Fermi wavelength.When there are more than one domain wall presented in a magnetic semiconductor nanowire,not only the spin-flip scattering of charge carriers from the domain walls but the quantum interference of charge carriers in the intermediate domain regions between neighboring domain walls may play important roles on spin-polarized electronic transport,and in such cases the influences of the Rashba spin–orbit coupling will depend sensitively both on the domain walls' width and the domain walls' separation.
基金supported by the National Natural Science Foundation of China (Grant No 10674040)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No 20060094002)
文摘This paper investigates the effect of Dresselhaus spin orbit coupling on the spin-transport properties of ferromagnet/insulator/semiconductor/insulator/ferromagnet double-barrier structures. The influence of the thickness of the insulator between the ferromagnet and the semiconductor on the polarization is also considered. The obtained results indicate that (i) the polarization can be enhanced by reducing the insulator layers at zero temperature, and (ii) the tunnelling magnetoresistance inversion can be illustrated by the influence of the Dresselhaus spin-orbit coupling effect in the double-barrier structure. Due to the Dresselhaus spin-orbit coupling effect, the tunnelling magnetoresistance inversion occurs when the energy of a localized state in the barrier matches the Fermi energy EF of the ferromagnetic electrodes.
基金supported by the National Natural Science Foundation of China(Nos.12072253,11972176,and 12062011)the Doctoral Science Fund of Lanzhou University of Technology of China(No.062002)the Opening Project from the State Key Laboratory for Strength and Vibration of Mechanical Structures of China(No.SV2021-KF-19)。
文摘In this paper,to better reveal the surface effect and the screening effect as well as the nonlinear multi-field coupling characteristic of the multifunctional piezoelectric semiconductor(PS)nanodevice,and to further improve its working performance,a magneto-mechanical-thermo coupling theoretical model is theoretically established for the extensional analysis of a three-layered magneto-electro-semiconductor coupling laminated nanoplate with the surface effect.Next,by using the current theoretical model,some numerical analyses and discussion about the surface effect,the corresponding critical thickness of the nanoplate,and the distributions of the physical fields(including the electron concentration perturbation,the electric potential,the electric field,the average electric displacement,the effective polarization charge density,and the total charge density)under different initial state electron concentrations,as well as their active manipulation via some external magnetic field,pre-stress,and temperature stimuli,are performed.Utilizing the nonlinear multi-field coupling effect induced by inevitable external stimuli in the device operating environment,this paper not only provides theoretical support for understanding the size-dependent tuning/controlling of carrier transport as well as its screening effect,but also assists the design of a series of multiferroic PS nanodevices.
基金supported by the National Natural Science Foundation of China(Grant No.32250410309 and 52105582)Natural Science Foundation of Guangdong Province(Grant No.2022A1515010894 and 2022B0303040002)+1 种基金Fundamental Research Foundation of Shenzhen(JCYJ20210324095210030 and JCYJ20220818095810023)Shenzhen-Hong Kong-Macao S&T Program(Category C:SGDX20210823103200004)
文摘Extending the ionic conductivity is the pre-requisite of electrolytes in fuel cell technology for high-electrochemical performance.In this regard,the introduction of semiconductor-oxide materials and the approach of heterostructure formation by modulating energy bands to enhance ionic conduction acting as an electrolyte in fuel cell-device.Semiconductor(n-type;SnO_(2))plays a key role by introducing into p-type SrFe_(0.2)Ti_(0.8)O_(3-δ)(SFT)semiconductor perovskite materials to construct p-n heterojunction for high ionic conductivity.Therefore,two different composites of SFT and SnO_(2)are constructed by gluing p-and n-type SFT-SnO_(2),where the optimal composition of SFT-SnO_(2)(6∶4)heterostructure electrolyte-based fuel cell achieved excellent ionic conductivity 0.24 S cm^(-1)with power-output of 1004 mW cm^(-2)and high OCV 1.12 V at a low operational temperature of 500℃.The high power-output and significant ionic conductivity with durable operation of 54 h are accredited to SFT-SnO_(2)heterojunction formation including interfacial conduction assisted by a built-in electric field in fuel cell device.Moreover,the fuel conversion efficiency and considerable Faradaic efficiency reveal the compatibility of SFT-SnO_(2)heterostructure electrolyte and ruled-out short-circuiting issue.Further,the first principle calculation provides sufficient information on structure optimization and energy-band structure modulation of SFT-SnO_(2).This strategy will provide new insight into semiconductor-based fuel cell technology to design novel electrolytes.
文摘The optical absorption spectra of the covalent crystals ZnX(X=S,Se) doped with Co 2+ are studied using the double covalency factors,which considers the anisotropic distortion of e g and t 2g orbits for d electron.When the paramagnetic g factor is calculated,the contributions of the spin orbit coupling from the ligand ions are taken into account besides that from the central ion,which is the double ξ model.The calculated results indicate that the theoretical values coincide with the experimental values very well.This suggests that the method presented in this paper could be more valid to some strongly covalent crystals.
文摘A brief review of Huang–Rhys theory and Albrechtos theory is provided,and their connection and applications are discussed.The former is a first order perturbative theory on optical transitions intended for applications such as absorption and emission involving localized defect or impurity centers,emphasizing lattice relaxation or mixing of vibrational states due to electron–phonon coupling.The coupling strength is described by the Huang–Rhys factor.The latter theory is a second order perturbative theory on optical transitions intended for Raman scattering,and can in-principle include electron–phonon coupling in both electronic states and vibrational states.These two theories can potentially be connected through the common effect of lattice relaxation – non-orthonormal vibrational states associated with different electronic states.Because of this perceived connection,the latter theory is often used to explain resonant Raman scattering of LO phonons in bulk semiconductors and further used to describe the size dependence of electron–phonon coupling or Huang–Rhys factor in semiconductor nanostructures.Specifically,the A term in Albrechtos theory is often invoked to describe the multi-LO-phonon resonant Raman peaks in both bulk and nanostructured semiconductors in the literature,due to the misconception that a free-exciton could have a strong lattice relaxation.Without lattice relaxation,the A term will give rise to Rayleigh or elastic scattering.Lattice relaxation is only significant for highly localized defect or impurity states,and should be practically zero for either single particle states or free exciton states in a bulk semiconductor or for confined states in a semiconductor nanostructure that is not extremely small.
基金supported by State Key Basic Research Program of China under Grant No 2006CB921607the Natural Science Foundation of Guangzhou Education Bureau under Grant No.2060
文摘Based on the density matrix approach and iterative procedure, a detailed procedure for the calculation of the linear and nonlinear intersubband optical absorption coefficients is given in wurtzite GaN-based coupling quantum wells (CQWs). The simple analytical formulas for electronic eigenstates and the linear and nonlinear optical absorption coefficients in the systems are also deduced. Numerical result on a typical A1GaN/GaN CQW shows that, the linear and nonlinear optical absorption coefficients sensitively depend on the structural parameters of the CQW system as well as the incident optics beam intensity.