Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis tha...Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis that this effect can be explained by ortho-para magnetic spin interactions in water molecules within the water-air interface layer. Water molecules, consisting of hydrogen and oxygen, exhibit different nuclear spin states: ortho-(triplet) and para-(singlet). The interaction of polarized light with these spin states may induce transitions between the rotational levels of ortho- and para-forms due to catalysts like triplet oxygen (O2) in its inhomogeneous magnetic field. Resonance pumping at 532 nm (~18,797 cm−1) due to the transition v1-v2-v3 ~ 0-8-2 (~18,796 cm−1) results in an increase in molecular energy sufficient to overcome intermolecular forces at the water surface, thereby causing evaporation. The proposed ortho-para conversion mechanism involves spin-orbit coupling and specific resonance conditions. This theory provides a quantum mechanical perspective on the photomolecular effect, potentially offering insights into natural processes such as cloud formation and climate modeling, as well as practical applications in solar desalination and industrial drying. Further experimental validation is required to confirm the role of spin interactions in light-induced water evaporation.展开更多
Constructional and micro-dynamic process of the water-transferring composite was analyzed. This composite can transmit water to soil with a self-adjustable speed to ensure the survival of seedlings in arid and semi-ar...Constructional and micro-dynamic process of the water-transferring composite was analyzed. This composite can transmit water to soil with a self-adjustable speed to ensure the survival of seedlings in arid and semi-arid regions when it is embedded in soil around the roots of the seedlings. It is obtained from natural plant fiber coated with a colloid made by mixing a certain proportion of polyacrylamide and montmorillonite. The rules of water being transmitted to soil by the coating under different condition were tested by M-30 quick moisture measure instrument. The process of water-desorption of the coating material was investigated by a Perkin Elmer Diamond S Ⅱ thermal multi-analyzer. Moreover, the micro-dynamic behavior was detected by a FEIQuanta 2000 environment scanning electron microscope. The results demonstrate that montmorillonite has lower water-desorption energy barrier than polyacrylamide and can lose water more easily. montmorillonite particles bridge up to be the main water-transmit material at low water potential （when the soil relatively dry or when the temperature is high）, and they break bridge at high water potential while the polyacrylamide acts as the main water-transmit material.展开更多
Aimed at the abominable influences to blind equaliza-tion algorithms caused by complex time-space variability existing in underwater acoustic channels, a new self-adjusting decision feedback equalization （DFE） algor...Aimed at the abominable influences to blind equaliza-tion algorithms caused by complex time-space variability existing in underwater acoustic channels, a new self-adjusting decision feedback equalization （DFE） algorithm adapting to different under-water acoustic channel environments is proposed by changing its central tap position. Besides, this new algorithm behaves faster convergence speed based on the analysis of equalizers’ working rules, which is more suitable to implement communications in dif-ferent unknown channels. Corresponding results and conclusions are validated by simulations and spot experiments.展开更多
文摘Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis that this effect can be explained by ortho-para magnetic spin interactions in water molecules within the water-air interface layer. Water molecules, consisting of hydrogen and oxygen, exhibit different nuclear spin states: ortho-(triplet) and para-(singlet). The interaction of polarized light with these spin states may induce transitions between the rotational levels of ortho- and para-forms due to catalysts like triplet oxygen (O2) in its inhomogeneous magnetic field. Resonance pumping at 532 nm (~18,797 cm−1) due to the transition v1-v2-v3 ~ 0-8-2 (~18,796 cm−1) results in an increase in molecular energy sufficient to overcome intermolecular forces at the water surface, thereby causing evaporation. The proposed ortho-para conversion mechanism involves spin-orbit coupling and specific resonance conditions. This theory provides a quantum mechanical perspective on the photomolecular effect, potentially offering insights into natural processes such as cloud formation and climate modeling, as well as practical applications in solar desalination and industrial drying. Further experimental validation is required to confirm the role of spin interactions in light-induced water evaporation.
基金Funded by the National Natural Science Foundation of China (50772131)the National Hi-Tech Research and Development Program of China (2001AA322100)
文摘Constructional and micro-dynamic process of the water-transferring composite was analyzed. This composite can transmit water to soil with a self-adjustable speed to ensure the survival of seedlings in arid and semi-arid regions when it is embedded in soil around the roots of the seedlings. It is obtained from natural plant fiber coated with a colloid made by mixing a certain proportion of polyacrylamide and montmorillonite. The rules of water being transmitted to soil by the coating under different condition were tested by M-30 quick moisture measure instrument. The process of water-desorption of the coating material was investigated by a Perkin Elmer Diamond S Ⅱ thermal multi-analyzer. Moreover, the micro-dynamic behavior was detected by a FEIQuanta 2000 environment scanning electron microscope. The results demonstrate that montmorillonite has lower water-desorption energy barrier than polyacrylamide and can lose water more easily. montmorillonite particles bridge up to be the main water-transmit material at low water potential （when the soil relatively dry or when the temperature is high）, and they break bridge at high water potential while the polyacrylamide acts as the main water-transmit material.
基金supported by the National Natural Science Foundation of China(61101205)the Natural Science Foundation of Hubei Province of China(2009CDB337)the Natural Science Foundation of Naval University of Engineering(HGDQNJJ13019)
文摘Aimed at the abominable influences to blind equaliza-tion algorithms caused by complex time-space variability existing in underwater acoustic channels, a new self-adjusting decision feedback equalization （DFE） algorithm adapting to different under-water acoustic channel environments is proposed by changing its central tap position. Besides, this new algorithm behaves faster convergence speed based on the analysis of equalizers’ working rules, which is more suitable to implement communications in dif-ferent unknown channels. Corresponding results and conclusions are validated by simulations and spot experiments.
