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The organic geochemistry of crude oil in the Saltpond Basin(Ghana):Organic source input,depositional environment,and thermal maturity
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作者 Kojo Amoako Ningning Zhong +1 位作者 Nancy Pearl Osei-Boakye Ebenezer Apesegah 《Acta Geochimica》 EI CAS CSCD 2024年第3期424-440,共17页
The Saltpond Basin,situated within the South Atlantic margin of Ghana,is a significant area for petro-leum exploration but has received relatively limited research attention.Previous studies have examined source rock ... The Saltpond Basin,situated within the South Atlantic margin of Ghana,is a significant area for petro-leum exploration but has received relatively limited research attention.Previous studies have examined source rock com-position,but data on crude oil organic chemistry are lack-ing,hindering understanding of the basin’s petroleum system and evolution.To address this gap,we analyzed biomarkers and stable carbon-isotope ratios in Saltpond Basin crude oil using gas chromatography–mass spectrometry and gas chromatography–isotope ratio mass spectrometry to eluci-date organic matter source,depositional environment,and thermal maturity.Findings were compared with oils from the West African segment of the South Atlantic margin,namely the Tano Basin and the Niger Delta Basin,to iden-tify potential correlations and gain insights into regional variations.Molecular and isotopic results unveiled a sig-nificant prevalence of organic matter derived from lower marine organisms.Patterns of organic matter deposition and preservation in Saltpond oil samples suggested a suboxic marine transitional environment,contradicting conventional understanding of terrestrial dominance in such settings.Moreover,the potential for degradation processes to obscure differentiation between terrestrial and marine organic mat-ter origins underscores the complex nature of organic mat-ter dynamics in transitional marine environments.Analysis of molecular thermal maturity indices suggested Saltpond oils were expelled from source rocks exhibiting thermal maturity at the early maturity stage.Correlation analysis unveiled genetic disparities among crude oils sourced from the Saltpond Basin and those from the Tano and Niger Delta Basin,primarily due to variations in source input and depo-sitional environment conditions.Saltpond oil exhibits lower terrestrial organic input than Tano Basin’s crude oils,which also have less terrestrial input than Niger Delta Basin crude oils.Additionally,its paleodepositional environment nota-bly differs from oils in the Tano Basin(anoxic transitional marine-lacustrine settings)and the Niger Delta Basin(sub-oxic–oxic terrigenous deltaic or marine or lacustrine envi-ronments).Thermal maturity range of Saltpond oil is com-parable to oils in the Tano Basin but lower than oils in the Niger Delta Basin.Thesefindings provide valuable insights into petroleum generation history and unique organic geo-chemical characteristics within the Saltpond Basin,essen-tial for exploration,production,and environmental manage-ment efforts in the region.Furthermore,correlation studies provide evidence that distinct biological,geological,and paleoenvironmental conditions shaped various oil types in the West African segment of the South Atlantic margin. 展开更多
关键词 Biomarkers Carbon isotopes crude oil Saltpond Basin Ghana
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Effects of biodegradation on diamondoid distribution in crude oils from the Bongor Basin,Chad
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作者 Huanxin Song Menghan Chen +2 位作者 Lirong Dou Dingsheng Cheng Zhigang Wen 《Energy Geoscience》 EI 2024年第2期120-128,共9页
The sensitivity of biodegradation on diamondoids was investigated using a series of biodegraded oil samples from the Ronier tectonic unit of Bongor Basin,Chad.The results suggest that diamondoids,including adamantanes... The sensitivity of biodegradation on diamondoids was investigated using a series of biodegraded oil samples from the Ronier tectonic unit of Bongor Basin,Chad.The results suggest that diamondoids,including adamantanes(As)and diamantanes(Ds),are relatively resistant to biodegradation and obvious biodegradation was observed in oils with a Peters-Moldowan(PM)biodegradation rank of 6 or more.Overall,the sensibility of biodegradation on diamondoids is generally similar to hopanes and regular steranes.As biodegradation evolves,the changes in concentration and components of diamondoids show that the biodegradation process is selective and stepwise.The significant increase of MD/MA and DMD/DMA for oils with a PM ranking 6^(+) indicates that diamantanes are generally more resistant to biodegradation than adamantanes.The similar trends of DMA/MA,EA/MA,MD/D,DMD/MD and other relevant indexes,show that higher alkylation homologs are more resistant to biodegradation.The commonly used diamondoid ratios,such as MAI,EAI,MDI and DMID-1,are obviously affected by biodegradation at the stage of high-level biodegradation,which may indicate that these ratios should be used with caution in case of severely degraded oils. 展开更多
关键词 DIAMONDOIDS BIODEGRADATION Sensitivity crude oil Bongor Basin CHAD
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Data-driven Wasserstein distributionally robust chance-constrained optimization for crude oil scheduling under uncertainty
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作者 Xin Dai Liang Zhao +4 位作者 Renchu He Wenli Du Weimin Zhong Zhi Li Feng Qian 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期152-166,共15页
Crude oil scheduling optimization is an effective method to enhance the economic benefits of oil refining.But uncertainties,including uncertain demands of crude distillation units(CDUs),might make the production plans... Crude oil scheduling optimization is an effective method to enhance the economic benefits of oil refining.But uncertainties,including uncertain demands of crude distillation units(CDUs),might make the production plans made by the traditional deterministic optimization models infeasible.A data-driven Wasserstein distributionally robust chance-constrained(WDRCC)optimization approach is proposed in this paper to deal with demand uncertainty in crude oil scheduling.First,a new deterministic crude oil scheduling optimization model is developed as the basis of this approach.The Wasserstein distance is then used to build ambiguity sets from historical data to describe the possible realizations of probability distributions of uncertain demands.A cross-validation method is advanced to choose suitable radii for these ambiguity sets.The deterministic model is reformulated as a WDRCC optimization model for crude oil scheduling to guarantee the demand constraints hold with a desired high probability even in the worst situation in ambiguity sets.The proposed WDRCC model is transferred into an equivalent conditional value-at-risk representation and further derived as a mixed-integer nonlinear programming counterpart.Industrial case studies from a real-world refinery are conducted to show the effectiveness of the proposed method.Out-of-sample tests demonstrate that the solution of the WDRCC model is more robust than those of the deterministic model and the chance-constrained model. 展开更多
关键词 DISTRIBUTIONS Model OPTIMIZATION crude oil scheduling Wasserstein distance Distributionally robust chance constraints
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Performance Evaluation of the Halophilic Crude Oildegrading Bacterial Consortium XH-1 for Oilfield Wastewater Treatment
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作者 Gong Xihui Zhang Manlin +2 位作者 Wang Wenna Sun Zhichao Liu Chunshuang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第3期24-32,共9页
A total of 14 halophilic hydrocarbon-degrading strains were isolated from crude oil-contaminated sites,using petroleum as the sole carbon and energy source.Among these,four highly efficient strains were selected to cr... A total of 14 halophilic hydrocarbon-degrading strains were isolated from crude oil-contaminated sites,using petroleum as the sole carbon and energy source.Among these,four highly efficient strains were selected to create the mixed bacterial agent XH-1.These four strains were identified through 16S rRNA gene-based sequencing as belonging to Acinetobacter,Bacillus paramycoides,Rhodococcus sp.,and Enterobacter sp.,respectively.The optimal cultivation time for the mixed consortium XH-1 was found to be 48 h,and a nitrogen-phosphorus molar ratio of 10:1 was determined to be beneficial for crude oil degradation.XH-1 showed notable crude oil degradation even at a salinity of up to 30 g/L,with little inhibition observed at sulfide concentrations as high as 150 mg/L and initial oil concentrations of 500 mg/L.Gas chromatography analysis revealed that XH-1 was able to efficiently degrade C9–C29 n-alkanes.Moreover,a bio-contact oxidation reactor enhanced by XH-1 showed promising results in treating oilfield wastewater.These findings suggest that XH-1 can be applied for the treatment of oilfield wastewater. 展开更多
关键词 crude oil degradation mixed strains oilfield wastewater degradation characteristics
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Research on a TOPSIS energy efficiency evaluation system for crude oil gathering and transportation systems based on a GA-BP neural network
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作者 Xue-Qiang Zhang Qing-Lin Cheng +2 位作者 Wei Sun Yi Zhao Zhi-Min Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期621-640,共20页
As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crud... As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crude oil gathering and transportation systems and identify the energy efficiency gaps.In this paper,the energy efficiency evaluation system of the crude oil gathering and transportation system in an oilfield in western China is established.Combined with the big data analysis method,the GA-BP neural network is used to establish the energy efficiency index prediction model for crude oil gathering and transportation systems.The comprehensive energy consumption,gas consumption,power consumption,energy utilization rate,heat utilization rate,and power utilization rate of crude oil gathering and transportation systems are predicted.Considering the efficiency and unit consumption index of the crude oil gathering and transportation system,the energy efficiency evaluation system of the crude oil gathering and transportation system is established based on a game theory combined weighting method and TOPSIS evaluation method,and the subjective weight is determined by the triangular fuzzy analytic hierarchy process.The entropy weight method determines the objective weight,and the combined weight of game theory combines subjectivity with objectivity to comprehensively evaluate the comprehensive energy efficiency of crude oil gathering and transportation systems and their subsystems.Finally,the weak links in energy utilization are identified,and energy conservation and consumption reduction are improved.The above research provides technical support for the green,efficient and intelligent development of crude oil gathering and transportation systems. 展开更多
关键词 crude oil gathering and transportation system GA-BP neural network Energy efficiency evaluation TOPSIS evaluation method Energy saving and consumption reduction
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Heavy Metal Levels and Ecological Risk in Crude Oil-Contaminated Soils from Okpare-Olomu, Niger Delta, Nigeria
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作者 Adedoyin Olubunmi Bankole Akinyemi Olufemi Ogunkeyede +5 位作者 Harrison Agboro Prince Alex Ekhorutomwen Osasenaga Israel Otuomagie Khadijah Ateda Isimekhai Ekaette Akpan Fadairo Efe Jeffery Isukuru 《Journal of Environmental Protection》 2024年第4期415-438,共24页
Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the pres... Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the presence of metallic ions. The Okpare-Olomu community has borne the brunt of crude oil pollution from illicit bunkering, sabotage, and equipment malfunction. This study targets an evaluation of ecological hazards linked to heavy metals (HMs) in crude oil impacted agriculturally soils within Okpare-Olomu in Ughelli South LGA of Delta State. In this study, 24 topsoil samples were obtained from areas affected by crude oil pollution;the heavy metal content was evaluated through atomic absorption spectrometry. The concentration ranges for HMs (mg/kg) in soil were: 24.1 - 23,174 (Cu);0.54 - 37.1 (Cd);9.05 - 54 (Cr);12 - 174 (Ni);18.5 - 8611 (Pb);and 148 - 9078 (Zn) at a soil depth of 0 - 15 cm. Notably, metal concentrations were recorded to be above permissible World Health Organization limits. Predominantly, Zn and Pb recorded higher heavy metal concentration when compared to other heavy metals analysed, notably at sampling points PT7 through PT24. Zinc and Pb contamination exhibited highly significant contamination factors, and contamination severity was evidenced across all sample points, signifying a grave risk level. Pollution load indices indicated pervasive extreme pollution levels. Geoaccumulation indices signaled moderate to strong pollution, mainly by Pb and Zn. Ecological risk assessments revealed variable levels of heavy metal contamination, from low to very high, with potential ecological risk reflecting markedly elevated levels. This study underscores the imperative for soil remediation to rectify ecological imbalances in agriculturally affected soil constituents. 展开更多
关键词 Heavy Metals crude oil POLLUTION Degree of Contamination Potential Risk Index
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Prediction Model of Wax Deposition Rate in Waxy Crude Oil Pipelines by Elman Neural Network Based on Improved Reptile Search Algorithm
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作者 Zhuo Chen Ningning Wang +1 位作者 Wenbo Jin Dui Li 《Energy Engineering》 EI 2024年第4期1007-1026,共20页
A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax depositi... A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax deposition in crude oil pipelines.Aiming at the shortcomings of the ENN prediction model,which easily falls into the local minimum value and weak generalization ability in the implementation process,an optimized ENN prediction model based on the IRSA is proposed.The validity of the new model was confirmed by the accurate prediction of two sets of experimental data on wax deposition in crude oil pipelines.The two groups of crude oil wax deposition rate case prediction results showed that the average absolute percentage errors of IRSA-ENN prediction models is 0.5476% and 0.7831%,respectively.Additionally,it shows a higher prediction accuracy compared to the ENN prediction model.In fact,the new model established by using the IRSA to optimize ENN can optimize the initial weights and thresholds in the prediction process,which can overcome the shortcomings of the ENN prediction model,such as weak generalization ability and tendency to fall into the local minimum value,so that it has the advantages of strong implementation and high prediction accuracy. 展开更多
关键词 Waxy crude oil wax deposition rate chaotic map improved reptile search algorithm Elman neural network prediction accuracy
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Optimization of Diesel and Crude Oil Degradation in a Ghanaian Soil Using Organic Wastes as Amendment
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作者 Adama Sawadogo Innocent Yao Dotse Lawson +2 位作者 Hama Cissé Cheikna Zongo Aly Savadogo 《Journal of Agricultural Chemistry and Environment》 2024年第1期1-12,共12页
Soil contamination by hydrocarbons poses numerous environmental, health and agricultural problems. The degradation of these pollutants can occur naturally but very slowly. It is therefore generally necessary to stimul... Soil contamination by hydrocarbons poses numerous environmental, health and agricultural problems. The degradation of these pollutants can occur naturally but very slowly. It is therefore generally necessary to stimulate this degradation by different means. Thus, this study aimed to improve the bio-degradation of diesel and crude oil in a Ghanaian soil by biostimulation. For this, the sampled soil was characterized by standard methods and contaminated with diesel and crude oil at a proportion of 1% (w/w). Then, contaminated soil samples were supplemented with biochar-compost, poultry manure or cow dung at the proportion of 10% (w/w). Periodically, fractions of these samples were taken to evaluate the density of hydrocarbon utilizing bacteria (HUB) and the residual quantities of diesel or crude oil. The characteristics of the soil used show the need for supplementation for better degradation of hydrocarbons. The results of the study show that supplementing the soil with organic substrates increases HUB loads in soils contaminated by diesel and crude oil. They also show that the residual quantities of diesel and crude oil are generally significantly lower in supplemented soils (p = 0.048 and p < 0.0001 respectively). In addition, the study shows that degradation was generally greater in soils contaminated by diesel compared to those contaminated by crude oil, especially at the end of the study. 展开更多
关键词 BIODEGRADATION BIOSTIMULATION Soil DIESEL crude oil Organic Amendment Ghana
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Improving Supply Chain Strategies towards Mitigating the Effect of Crude Oil Theft and Pipeline Vandalism in the Nigerian Oil and Gas Industry: A Case Study of the Nigerian National Petroleum Corporation (NNPC)
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作者 Ruth Agwom Panle 《Open Journal of Yangtze Oil and Gas》 2024年第3期75-93,共19页
Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities,... Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities, planning and control of the flow of information and materials in a firm, management of relationships with other organizations and government intervention, However, crude oil theft and pipeline vandalism are established products supply chain disruptors in Nigeria which are rendering the task of running an efficient petroleum supply chain onerous. This paper aims to establish the importance of effective supply chain strategies for companies in the oil and gas industry with special focus on the Nigerian oil and gas sector and the strategies by which the state oil and gas corporation in this sector may mitigate disruptions to its supply chain. This study investigates the enhancement of supply chain strategies towards meeting the challenge of crude oil theft and pipeline vandalism, using the Nigerian National Corporation (NNPC) as a case study. Based on this study, data were collected from two sources: A summary of incident reports obtained from NNPC and an interview with personnel in the PPMC Department. Incident report refers to a report produced when accidents such as equipment failure, injury, loss of life, or fire occur at the work site. Content analysis is utilized to evaluate data obtained from interview responses, CBN financial stability reports, NDIC annual reports, circulars, banking supervision reports and implementation guidelines. The study found out that NNPC should endeavor to sustain its value chain and ward of pipeline vandals and crude oil thieves by engaging in community partnership, detailing security outfits to ensure its pipelines’ right of way and bridging. Concluded that the oil supply chain of the Nigerian National Petroleum Corporation has been plagued by disruptions in the form of crude oil theft and pipeline vandalism which has had debilitating effects on its value. 展开更多
关键词 Supply Chain Strategies Management Production crude oil THEFT Pipeline Vandalism Information Technology Operations
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Components of Paraffin-Base and Naphthenic-Base Crude Oil and Their Effects on Interfacial Performance
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作者 Zhu Yin Pingnan Yuan +2 位作者 Xiang Lian Yancheng Zheng Heng Zheng 《Open Journal of Yangtze Oil and Gas》 2019年第4期270-284,共15页
The saturate,aromatics,resin and asphaltene components of paraffin-base(PB)and naphthenic-base(HB)crude oil are separated by chromatographic column.The acidic components of crude oil are extracted by compounded polar ... The saturate,aromatics,resin and asphaltene components of paraffin-base(PB)and naphthenic-base(HB)crude oil are separated by chromatographic column.The acidic components of crude oil are extracted by compounded polar solvents and identified by methyl esterification of diazomethane.The acidic components before and after asphaltene removal are investigated by gas chromatography-mass spectrometer.The effect of four fractions in simulated oil on interfacial activity is discussed.The results show PB is rich in naphthalene series and tri-aromatic steroids,and HB has a high content of phenanthrene series,chrysene series and methylpyrene,besides higher content of naphthalene series.The long carbon chain acids in HB oil decrease significantly by asphaltenes removal,confirming the presence of heavy oil acids in asphaltene.A little amount of saturates and aromatics in simulated oil can reduce the interfacial tension(IFT).When the content of asphaltenes of simulated oil is increased,IFT is initially decreased and finally increased because of stability of asphaltenes.When resin is increased,IFT is initially increased and then decreased.Simulated oil containing the resin from naphthenic-base oil is more sensitive to alkali than that of paraffin-base resin,which can reduce the IFT between oil and water at a larger range. 展开更多
关键词 Component Separation Carboxylic Acids Group Composition paraffin-base oil Naphthenic-Base oil INTERFACIAL Activity
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Pre-heating temperature induced flowability and wax deposition characteristics of crude oil adding wax inhibitors 被引量:1
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作者 Bo Yao Hao-Ran Zhu +4 位作者 Bao-Dong Yan Chuan-Xian Li Fei Yang Guang-Yu Sun Hong-Bo Zeng 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2468-2478,共11页
This paper investigated the effects of pre-heating treatment temperatures(T_(pre))on the flowability and wax deposition characteristics of a typical waxy crude oil after adding wax inhibitors.It is found that there is... This paper investigated the effects of pre-heating treatment temperatures(T_(pre))on the flowability and wax deposition characteristics of a typical waxy crude oil after adding wax inhibitors.It is found that there is little difference in wax precipitation exothermic characteristics of crude oils at different T_(pre),as well as the wax crystal solubility coefficient in the temperature range of 25-30℃.For the undoped crude oil,the flowability after wax precipitation gets much improved and the wax deposition is alleviated as T_(pre)increasing.At T_(pre)=50℃,the viscosity and wax deposition rate of crude oil adding wax inhibitors are higher than those of the undoped crude oil.When the T_(pre)increases to 60,70,and 80℃,the flowability of the doped crude oil are largely improved and the wax deposition is suppressed with the T_(pre)increase,but the wax content of wax deposit increases gradually.It is speculated that,on the one hand,the T_(pre)increase helps the dispersion of asphaltenes into smaller sizes,which facilitates the co-crystallization with paraffin waxes and generates more aggregated wax crystal flocs.This weakens the low-temperature gel structure and increases the solid concentration required for the crosslink to form the wax deposit.On the other hand,the decrease in viscosity increases the diffusion rate of wax molecules and accelerates the aging of wax deposits.The experimental results have important guiding significance for the pipeline transportation of doped crude oils. 展开更多
关键词 Pre-heating treatment Wax inhibitor FLOWABILITY Wax deposition Waxy crude oil
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Molecular composition of naphthenic acids in a Chinese heavy crude oil and their impacts on oil viscosity 被引量:1
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作者 Qian-Hui Zhao Shuai M +7 位作者 Jian-Xun Wu Wei-Feng Chang Sheng-Fei Zhang Xin-Ge Sun Bing Zhou Zeng-Min Lun Keng H.Chung Quan Shi 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1225-1230,共6页
Most heavy crude oils underwent biodegradation and generated a significant amount of naphthenic acids. Naphthenic acids are polar compounds with the carboxylic group and are considered as a major factor affecting the ... Most heavy crude oils underwent biodegradation and generated a significant amount of naphthenic acids. Naphthenic acids are polar compounds with the carboxylic group and are considered as a major factor affecting the oil viscosity. However, the relationship between the molecular composition of naphthenic acids and oil viscosity is not well understood. This study examined a “clean” heavy oil with low contents of heteroatoms but had a high content of naphthenic acids. Naphthenic acids were fractionated by distillation and caustic extraction. The molecular composition was characterized by high-resolution Orbitrap mass spectrometry. It was found that the 2- and 3-ring naphthenic monoacids with 15–35 carbon atoms are dominant components of the acid fractions;the caustic extraction is capable of isolating naphthenic acids with less than 35 carbons, which is equivalent to the upper limit of the distillable components, but not those in the residue fraction;the total acid number of the heavy distillates is higher than that of the residue fraction;the viscosity of the distillation fraction increases exponentially with an increased boiling point of the distillates. Blending experiments indicates that there is a strong correlation between the oil viscosity and acids content, although the acid content is only a few percent of the total oil. 展开更多
关键词 Heavy crude oil VISCOSITY High-resolution mass spectrometer Naphthenic acid
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Rheo-optic in situ synchronous study on the gelation behaviour and mechanism of waxy crude oil emulsions 被引量:1
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作者 Jian Zhao Xiao-Feng Li +1 位作者 Hang Dong Zhi-Hua Wang 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1266-1288,共23页
An improved rheo-optic in situ synchronous measurement system was employed to investigate the gelation behaviour and mechanism of waxy crude oil emulsions. By combining transmitted natural light and reflected polarize... An improved rheo-optic in situ synchronous measurement system was employed to investigate the gelation behaviour and mechanism of waxy crude oil emulsions. By combining transmitted natural light and reflected polarized light microscopy, a multiangle composite light source was built to achieve the simultaneous observation of wax crystals and emulsified water droplets, as well as their dynamic aggregation process. Main outcomes on the microscopic mechanism were obtained by developed microscopic image processing method. It was found that the microstructure of W/O waxy crude oil emulsion has the evolution of “individual structure--homogeneous aggregate structure--heterogeneous coaggregate structure--floc structure” during the static cooling, which results in the four stages during gelation process. Different from previous studies, the aggregation of emulsified water droplets was found to be more significant and contributes to the formation and development of the wax crystals-emulsified water droplets coaggregate, which plays a decisive role in the further evolution of the gelled microstructure. Time series microscopic images show the dynamic aggregation of emulsified water droplets and wax crystals. Two different aggregation behaviours between wax crystals and water droplets were observed. That wax crystals can not only embed in gaps between adjacent water droplets and enhance the structure, but also surround the outside of the water droplets and continue to grow resulting in the interconnection of different coaggregates to form a larger floc structure. In addition, correlation between viscoelasticity and microstructure evolution of waxy crude oil emulsions of different water contents was discussed. With increasing water contents, the microstructure is changed from wax crystal flocculation structure as the main skeleton and the emulsified water droplets embedded in it, into the aggregation of emulsified water droplets occupying the main position. When the number of wax crystals and water droplets reaches a certain ratio, did wax crystals form coaggregates with emulsified water droplets, and the remaining wax crystals formed an overall flocculation structure, the viscoelasticity of the waxy crude oil emulsion is the highest. 展开更多
关键词 Waxy crude oil emulsion Rheo-optic in situ synchronous measurement GELATION Microscopic mechanism Structural behaviour
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Effect of nanocomposite pour point depressant EVAL/CNT on flow properties of waxy crude oil
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作者 Yang Liu Zheng-Nan Sun +3 位作者 Sheng-Zhu Ji Yi-Hai Yang Jian-Qi Xu Guo-Lin Jing 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3807-3818,共12页
The nanocomposite EVAL-CNT was produced by chemical grafting in the solution system through the esterification of ethylene-vinyl alcohol copolymer (EVAL) and carboxylated multi-walled carbon nanotubes (O-MWCNT), and i... The nanocomposite EVAL-CNT was produced by chemical grafting in the solution system through the esterification of ethylene-vinyl alcohol copolymer (EVAL) and carboxylated multi-walled carbon nanotubes (O-MWCNT), and its structural properties were characterized. The improvement of the rheological properties of the waxy oil system by the novel pour point depressant was investigated using macroscopic rheological measurements and microscopic observations. The results showed that EVAL-CNT nanocomposite pour point depressant (PPD) could significantly reduce the pour point and improve the low temperature fluidity of crude oil and had better performance than EVAL-GO at the same addition level. The best effect was achieved at the dosing concentration of 400 ppm, which reduced the pour point by 13 ℃ and the low-temperature viscosity by 85.4%. The nanocomposites dispersed in the oil phase influenced the precipitation and crystallization of wax molecules through heterogeneous crystallization templates, which led to the increase of wax crystal size and compact structure and changed the wax crystal morphology, which had a better effect on the rheological properties of waxy oil. 展开更多
关键词 Pour point depressant Carbon nanotubes NANOCOMPOSITES Waxy crude oil Rheological behavior
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New Method for the Deep Dehydration and Desalination of Crude Oil
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作者 Lu Yuejia Jiang Peng +1 位作者 Song Yueqin Zhou Xiaolong 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2023年第4期74-85,共12页
The present work focused on the environmentally friendly deep desalination of crude oil using ethylene glycol as the extraction solvent and quartz sand as the demulsifier.The effect of droplet size distribution in the... The present work focused on the environmentally friendly deep desalination of crude oil using ethylene glycol as the extraction solvent and quartz sand as the demulsifier.The effect of droplet size distribution in the emulsion on the dehydration results and desalination efficiency was investigated.Experimental results showed that the desalination efficiencies of Sarir and Basra crude oils were 93.3%and 90.0%,respectively.Furthermore,the desalination efficiency of Basra crude oil using ethylene glycol could be enhanced up to 96.7%by adding 30 g/L quartz sand with a particle size of 15μm.Finally,94%of the ethylene glycol and 86%of the quartz sand could be recovered from the emulsion.This process offers an alternative method to the deep desalination of crude oil. 展开更多
关键词 crude oil deep desalination DEMULSIFICATION quartz sand
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Improving Crude Oil Flow Using Graphene Flakes under an Applied Electric Field
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作者 Thaer Al-Jadir Laith S.Sabri +2 位作者 Wafaa A.Kadhim Saja Mohsen Alardhi Raheek I.Ibrahim 《Fluid Dynamics & Materials Processing》 EI 2023年第8期2067-2081,共15页
Graphene flakes(GF)have been prepared and assessed as a material for improving flow in oil pipelines under the effect of an electric field.In particular,different amounts of GFs have been considered in order to determ... Graphene flakes(GF)have been prepared and assessed as a material for improving flow in oil pipelines under the effect of an electric field.In particular,different amounts of GFs have been considered in order to determine the optimal flow conditions.The GFs were prepared from graphite foam,derived from the dehydration of sugar with a particle size of 500-600μm,which was dispersed in ethanol and exfoliated in a ball mill under a shear force.After 15 h of exfoliation,sonication,and subsequent high-speed centrifugation at 3000 rpm,irregular-shaped GFs of 50-140 nm were produced and characterized using scanning electron microscopy,X-ray diffractometry,atomic force microscopy,and Raman spectroscopy.The prepared graphene sheets have been found to display excellent morphology and good graphitic structure.Experiments on flow improvement were conducted using the central composite rotatable design method for three parameters:stimulation time(15,30,45,and 60 s),applied voltage(150,170,200,and 220 V),and concentration of the GFs(0,100,200,and 400 mg/L).The optimal conditions for improved crude oil flow were then determined using the STATISTICA and WinQSB software packages.The results have confirmed the effectiveness of the use of the prepared GFs as a flow improver for crude oil,where the flow improvement is essentially a result of a reduction in viscosity and suppression of friction in the crude oil system. 展开更多
关键词 Graphene flakes flow improvement crude oil pipelines electrical field optimization
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Enhancing Heavy Crude Oil Flow in Pipelines through Heating-Induced Viscosity Reduction in the Petroleum Industry
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作者 Ramzy S.Hamied Anwar N.Mohammed Ali Khalid A.Sukkar 《Fluid Dynamics & Materials Processing》 EI 2023年第8期2027-2039,共13页
The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter... The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter on the flow rate of heavy crude oil have been assessed.Moreover,the total discharge and energy losses have been evaluated in order to demonstrate the improvements potentially achievable by using solar heating method replacing pipe,and adjusting the value of the initial pressure difference.Crude oil of API=20 has been used for the experiments,with the studied pipelines sections connecting the separator unit to the storage tank operating at a temperature of 25℃-100℃,pressure drop of 3,4,5,and 6 kg/cm^(2),and with pipe diameter of 4,6,and 8 in.The results show that on increasing the temperature and/or the pressure drop,the flow rate through the pipeline becomes higher,thus raising the total pumping energy(as the pipe diameter increase),while energy losses increase from the last separator to the storage tank in the field.A pipe diameter increase can also produce a growth of the total pumping energy(i.e.,energy losses increase).The results of the present analysis suggest that employing an optimal temperature(50℃)is needed to ensure good performance. 展开更多
关键词 Petroleum industry heavy crude oil horizontal flow viscosity reduction
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A Deep Learning Ensemble Method for Forecasting Daily Crude Oil Price Based on Snapshot Ensemble of Transformer Model
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作者 Ahmed Fathalla Zakaria Alameer +1 位作者 Mohamed Abbas Ahmed Ali 《Computer Systems Science & Engineering》 SCIE EI 2023年第7期929-950,共22页
The oil industries are an important part of a country’s economy.The crude oil’s price is influenced by a wide range of variables.Therefore,how accurately can countries predict its behavior and what predictors to emp... The oil industries are an important part of a country’s economy.The crude oil’s price is influenced by a wide range of variables.Therefore,how accurately can countries predict its behavior and what predictors to employ are two main questions.In this view,we propose utilizing deep learning and ensemble learning techniques to boost crude oil’s price forecasting performance.The suggested method is based on a deep learning snapshot ensemble method of the Transformer model.To examine the superiority of the proposed model,this paper compares the proposed deep learning ensemble model against different machine learning and statistical models for daily Organization of the Petroleum Exporting Countries(OPEC)oil price forecasting.Experimental results demonstrated the outperformance of the proposed method over statistical and machine learning methods.More precisely,the proposed snapshot ensemble of Transformer method achieved relative improvement in the forecasting performance compared to autoregressive integrated moving average ARIMA(1,1,1),ARIMA(0,1,1),autoregressive moving average(ARMA)(0,1),vector autoregression(VAR),random walk(RW),support vector machine(SVM),and random forests(RF)models by 99.94%,99.62%,99.87%,99.65%,7.55%,98.38%,and 99.35%,respectively,according to mean square error metric. 展开更多
关键词 Deep learning ensemble learning transformer model crude oil price
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Modeling and Study Influence of the Temperature Parameter on Corrosion Factors in the Atmospheric Distillation Column of Crude Oil
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作者 Ndiassé Fall Dialo Diop +4 位作者 Sossé Ndiaye Kharouna Talla Haroun Ali Adannou Astou Sarr Aboubaker Chèdikh Beye 《Open Journal of Yangtze Oil and Gas》 CAS 2023年第1期1-10,共10页
Atmospheric distillation is the first step in separating crude oil into by-products. It uses the different boiling temperatures of the components of crude oil to separate them. But crude oil contains a large quantity ... Atmospheric distillation is the first step in separating crude oil into by-products. It uses the different boiling temperatures of the components of crude oil to separate them. But crude oil contains a large quantity of acids and corrosive gases, including sulfur compounds, naphthenic acids, carbon dioxide, oxygen, etc. However, the temperature has an important influence on the aggressiveness of the corrosion factors in the atmospheric distillation column. This paper aims to investigate the role of temperature on corrosive products in the atmospheric distillation column. The results of the developed model show that the temperature increases the corrosion rate in the atmospheric distillation column but above a certain temperature value (about 600 K), it decreases. This illustrates the dual role played by temperature in the study of corrosion within the atmospheric distillation column. 展开更多
关键词 Atmospheric Distillation CORROSION crude oil Materials TEMPERATURE
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Laboratory Design Criteria for Monitoring Biostimulated Bioremediation of a Crude Oil Contaminated Soil in Niger Delta Using Total Petroleum Hydrocarbon
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作者 Justin Nnaemeka Okorondu 《Journal of Geoscience and Environment Protection》 2023年第1期139-149,共11页
The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/... The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/sediment in muddy, dry soil and wetlands. Though, there have been varied environmental conditions that have hampered the success of the bioremediation process. This study has evaluated the effectiveness of a biostimulated bioremediation of crude oil-impacted soil using some design criteria—nutrient amendment (NPK fertilizer) and moisture content. Soil sample sets—A, B, C, D, E, F, and G were impacted with crude oil at a ratio of 10 g/kg and amended with varying amounts of nutrient 30, 60, and 80 g of N.P.K fertilizer. The medium for the inoculation of the nutrient was water and the volume of water applied varied from 30% to 80% saturation. The soil sample sets were harvested at an interval of 3 months for 180 days to determine the concentration of total petroleum hydrocarbon left in the soil. The analysis of the total petroleum hydrocarbon was achieved using a GC-FID with a capillary column and autosampler. Soil samples were extracted with mixed solvent dichloromethane and acetone at a 1:1 ratio. The total petroleum hydrocarbon results show that biostimulated bioremediation achieved better results in soil sample sets with low moisture content (30% water saturation) and moderate nutrient amendment. The biodegradation of the sample sets with high water saturation and a high nutrient amendment was slow with a higher amount of total hydrocarbon content at the end of the 180 days. The variability in the hydrocarbon degradation pattern of contaminated soil shows that biostimulated bioremediation achieved better results in soils with low moisture content than in soil environments with high water content (saturation). More so, nutrient overdosing of the substrate hampered the effectiveness of the remediation process. 展开更多
关键词 BIOREMEDIATION Soil NUTRIENT Moisture Content Total Petroleum Hydrocarbon crude oil
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