Three methods for studying wave groups and their main parameters for describing wave groupiness are reviewed in this paper. Then they are analyzed and compared combined with field data from both aspects of group heigh...Three methods for studying wave groups and their main parameters for describing wave groupiness are reviewed in this paper. Then they are analyzed and compared combined with field data from both aspects of group height and group length. A method and two parameters that can describe wave groupiness are suggested. The groupiness parameters of sea waves at three field stations are given. The effects of groupiness on both distributions of the wave height and the phase of component waves are investigated. The effects of datum length on the calculated value of grouping parameters are also discussed.展开更多
Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modifi...Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modified UNIFAC model for the improvement of predicting vapor-liquid equilibria. The predictions of vapor-liquid equilibria for 62 systems including alcohol- alkane, alcohol-benzene, and amine-water systems demonstrate that the revised parameters remarkably improve the prediction accuracy for many systems. Especially for amine-water system, the mean deviation of components decreases from 0.094 to 0.021, and the mean deviation of pressure from 22.45% to 4.41%.展开更多
The group solubility parameter （GSP） model was used to analyze the liquid-liquid equilibrium （LLE） of ternary and quaternary systems. The GSP parameters are divided into four dimensions representing the four major...The group solubility parameter （GSP） model was used to analyze the liquid-liquid equilibrium （LLE） of ternary and quaternary systems. The GSP parameters are divided into four dimensions representing the four major intermolecular forces. The values of the parameters were determined by regression using the nonlinear SIMPLEX optimization method to fit the LLE data of 548 ternary and 26 quaternary systems selected from the literature. LLE predictions of 8 ternary systems were then made using the fit parameters. Comparison of the results with predictions using the modified UNIFAC model shows that the GSP model has less adjustable parameters to achieve a similar accuracy and that the parameter values are easily acquired by analysis of available data.展开更多
文摘Three methods for studying wave groups and their main parameters for describing wave groupiness are reviewed in this paper. Then they are analyzed and compared combined with field data from both aspects of group height and group length. A method and two parameters that can describe wave groupiness are suggested. The groupiness parameters of sea waves at three field stations are given. The effects of groupiness on both distributions of the wave height and the phase of component waves are investigated. The effects of datum length on the calculated value of grouping parameters are also discussed.
文摘Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modified UNIFAC model for the improvement of predicting vapor-liquid equilibria. The predictions of vapor-liquid equilibria for 62 systems including alcohol- alkane, alcohol-benzene, and amine-water systems demonstrate that the revised parameters remarkably improve the prediction accuracy for many systems. Especially for amine-water system, the mean deviation of components decreases from 0.094 to 0.021, and the mean deviation of pressure from 22.45% to 4.41%.
文摘The group solubility parameter （GSP） model was used to analyze the liquid-liquid equilibrium （LLE） of ternary and quaternary systems. The GSP parameters are divided into four dimensions representing the four major intermolecular forces. The values of the parameters were determined by regression using the nonlinear SIMPLEX optimization method to fit the LLE data of 548 ternary and 26 quaternary systems selected from the literature. LLE predictions of 8 ternary systems were then made using the fit parameters. Comparison of the results with predictions using the modified UNIFAC model shows that the GSP model has less adjustable parameters to achieve a similar accuracy and that the parameter values are easily acquired by analysis of available data.
