Element geochemical characteristics of a soil profile developed on dolostone in central Guizhou, southern China: implications for parent materials

This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of Si O_2, Al_2O_3 and Fe_2O_3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment(L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment(L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al_2O_3 versus Fe_2O_3and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versusGd_N/Yb_Nand ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.

Weathering and soils formation on different parent materials in Golestan Province,Northern Iran

Geochemical, mineralogical, and micromorphologieal characteristics of soils and their relevant parent rocks including loess, ignimbrite, sandstone and limestone were investigated to identify the soil-parent material uniformity and the weathering degree of soils in Golestan Province, northern Iran. Highly developed Caleixerolls and moderately developed Haploxerepts were formed on loess and limestone, respectively. In contrast, the soils formed on ignimbrite and sandstone were non- developed Entisols. Illite was the dominant clay mineral found in ignimbrite and sandstone in both the A horizon and parent material. In loess derived soils however, smectite was dominant especially in the Bt horizon compared to its parent material indicating partly to its pedogenic formation. In limestone, illite and vermiculite were dominant both in the A and C horizons. Ti/Zr ratio proved that the studied soils were closely related to their underlying parent materials geochemically. Chemical index of alteration （CIA）, micromorphological index of soil development （MISECA）, smectite/illite＋chlorite ratio and magnetic susceptibility were applied to investigate the degree of soil development. Results showed that the most and the least developed soils were those formed on loess deposits and limestone,respectively. Application of the different geochemical and pedogenetic approaches was proved to be useful in identifying the relevance of soils to their underlying parent materials and also their degree of development.

Preliminary Study on Relationship Between Soil Parent Materials and Tea Quality

Six tea plantations with different soil-forming parent materials, the same tea variety and tea age and similar landforms and management were selected to conduct a systematic study on the relationship between soil properties and tea quality. The results showed that the quality of tea grown on the soils derived from granites, arenaceous shales, argillaceous sandstones, was superior; those on the soils derived from limestones,dolomites, Quaternary red clays, were inferior. Further study showed that sandy soils were beneficial to improving amino acid content of tea, and clayey soils made it decrease; high content of bases might decrease the contents of tea polypenols, caffeine, water extracts, but promote the content of amino acids; available phosphorous was significantly positively correlated with water extracts, but significantly negatively correlated with carbine; slowly available potassium was positively correlated with amino acid content. Soil parent materials should be regarded as an important factor in evaluating the adaptability of tea to soils.

Oil Palm Soil Variability in West Malaysia as Affected by Its Parent Materials

The research aimed to analyze soil variability induced by parent materials for oil palm in West Malaysia. The research results can provide basic information on potential reserves of nutrients to improve soil productivity for oil palm. Soil samples were collected from two locations （granite soils and basalt soils）. The collected soil samples were completely analyzed in laboratory. The research results showed that based on mineral resistance to weathering （sand and silt mineral sizes）, mineral weathering of granite and basalt is divided into three categories, i.e., very slow weathered mineral （quartz and muscovite）, slowly weathered mineral （K-feldspar, Na and Ca-feldspar and biotite）, and easily weathered mineral （hornblende, augit, olivine, dolomite, calcite and gypsum） Losing mineral during weathering process from granite to clay is determined by containing mineral in rocks. Such minerals （CaO, Na：O, KzO, MgO and SiO2） loosed 100%, 95.0%, 83.5%, 74.7% and 52.5%, respectively, but Fe203 is disappeared only 14.4%. Soil properties characters of granite soil is more acid, has very low to low chemical soil fertility and is dominated by sand fraction, furthermore basalt soil is acid, has low to moderate chemical soil fertility and is dominated by clay fraction. Granite and basalt soils are able to produce FFB of oil palm （Fresh Fruit Bunches） 13-18 ton/ha in a year and 19-24 ton/ha in a year, respectively. The production difference of both soils is around 6.0 ton/ha in a year.

Soil Carbon Sequestrations in Forest Soils in Relation to Parent Material and Soil Depth in South-Eastern Nigeria

There has been increased interest in soil organic carbon in recent times because of its role in carbon sequestration. Different parent materials affect soil properties and hence will influence how much carbon is sequestered by soil. The study was conducted in June 2019 to investigate soil carbon stock in forest soils with respect to their parent materials in three States in South-eastern Nigeria. Sampling was aided by the location map of the area and free soil survey method was used to locate sampling points. 0ne profile was dug in each location and described using the Food and Agricultural Organization guideline. A total of twelve soil samples were collected and analyzed for selected properties. Results showed that sand content was significantly higher in soils under coastal plain sands (851.96 g·kg−1) and was lowest in soils of Imo clay shale (605.60 g·kg−1). Clay content was higher in soils of Imo clay shale (277.34 g·kg−1) and was lowest in coastal plain sand (118.80 g·kg−1). Silt and clay had moderate variation in coastal plain sand (>15 ≤ 35%) and high variations in Asu River and Imo clay shale (CV > 35%). The soils studied were generally acidic with values ranging (3.52) in soils formed from coastal plain sand, followed by forest soils of Imo clay shale (3.64) and Asu river group (3.85). Soil organic carbon decreased with increase in soil depth in all soil parent materials studied. Mean values ranged from 6.14 g·kg−1 in soil underlain by coastal plain sand to 10.62 g·kg−1) in soils of Imo clay shale. Soil carbon sequestered under the three different parent materials ranged from 1575 - 4676.41 (g·cm−2). Also, soil depth had a notable impact on carbon sequestration with values ranging from 1529.42 - 4374.0541 (g·cm−2) and the thicker the horizon, the more carbon sequestered. Hence, the study concluded that more carbon is sequestered in the subsurface horizons of the soil pedons than in the epipedons.

Changes in Soil pH and Exchangeable Acidity of Selected Parent Materials as Influenced by Amendments in South East of Nigeria

Soil chemical degradation caused by acidity is a serious constraint to food production in most parts of the Tropics. It was in the bid to proffer solution to this that the present study was conceived. Anincubation study was conducted at the laboratory of Soil Science and Meteorology Department of Michael Okpara University of Agriculture Umudike. The aim was to ascertain the effect of amendments namely: Control (no amendment), Biochar, Ash, Lime, Biochar + Poultry Manure, Ash + Poultry Manure and Lime + Poultry Manure, on soil pH and exchangeable acidity of Sandstone, Shale and Alluvium. The rate of application was 1.43 g for the sole amendments and 0.72 g each for the combined amendments to give an equivalent of 2 t/ha. They were applied to 100 g of the soil and replicated three times in a Completely Randomized Design. The incubation study lasted for eighty-four days, the pH and exchangeable acidity were determined at fourteen days intervals. The result obtained revealed that all the treatments increased the soil pH and decreased the exchangeable acidity over the control. In all parent materials, applied Lime and Lime + Pm significantly (p < 0.05) gave the highest pH of 6.6, 6.9 and 7.2 for Shale, Sandstone and Alluvium respectively on the 28th day of incubation which, was the time, the maximum pH value was attained. Biochar and Biochar + Pm were considered the appropriate amendments because the pH values they gave were towards neutral, unlike that of Lime and Lime + Pm that were towards alkaline. It is recommended that field trial of this work is conducted.

Using GIS Spatial Distribution to Predict Soil Organic Carbon in Subtropical China

Spatial distribution of organic carbon in soils is difficult to estimatebecause of inherent spatial variability and insufficient data. A soil-landscape model for a region,based on 151 samples for parent material and topographic factors, was established using a GISspatial analysis technique and a digital elevation model (DEM) to reveal spatial distributioncharacteristics of soil organic carbon (SOC). Correlations between organic carbon and topographicfactors were analyzed and a regression model was established to predict SOC content. Results forsurface soils (0-20 cm) showed that the average SOC content was 12.8 g kg^(-1), with the SOC contentbetween 6 and 12 g kg^(-1) occupying the largest area and SOC over 24 g kg^(-1) the smallest. Also,soils derived from phyllite were the highest in the SOC content and area, while soils developed onpurple shale the lowest. Although parent material, elevation, and slope exposure were allsignificant topographic variables (P < 0.01), slope exposure had the highest correlation to SOCcontent (r = 0.66). Using a multiple regression model (R^2 = 0.611) and DEM (with a 30 m X 30 mgrid), spatial distribution of SOC could be forecasted.

Site quality evaluation of loblolly pine on the South Carolina Lower Coastal Plain,USA

Eleven soil types, which can be identified and delineated using conventional soil survey procedures, were characterized for loblolly pine （Pinus taeda L.） productivity. Four 4-hectare study sites, each containing four measurement plots, were established for every soil type studied. In a stepwise multiple regression, both soil parent material （i.e. a combination of subsoil texture and geology） （p〈0.001）, and drainage class （p=0.006） were significant predictors of site index （tree age 25）, and the overall linear regression model had an R2 value of 0.55. The extremes of soil parent material differed by 3.9 m site index （loamy subsoil on the Wicomico-Penholoway surfaces versus clayey subsoil on the Pamlico-Princess Anne surfaces）. Each increment of drainage class differed by 0.7 m site index. For example, a poorly drained soil had 0.7 m lower site index than a somewhat poorly drained soil. For seven of the eleven soil types studied, there is greater than 80% probability that estimated mean site index is within ±0.8 m of the actual soil type mean site index. The other four soil types （labeled G, I, C and K） need to be either redefined or sampled more intensively. Two of these need to be subdivided in order to adequately characterize site quality, one based on geology （Soil type G） and one based on soil drainage class （Soil type I）. Variation in soil drainage class and varying amounts of topsoil displaced into windrows were both factors influencing site quality variation of a third soil type （Soil type C）. The wide variation in site index data for a fourth soil type （Soil type K） appeared to be due, in part, to sampling study locations and individual measurement plots with less than optimum bedding and/or artificial drainage. Soil parent material （subsoil texture and geology） along with drainage class were found to be important factors influencing site quality on the South Carolina Lower Coastal Plain.

Silicate Adsorption in Paddy Soils of Guangdong Province, China

Silicate adsorption in eight paddy soils developed from four different parent materials in Guangdong Province, China was examined to obtain fundamental knowledge of silicate adsorption to improve the efficacy of silicate fertilizer use in these areas. A correlation analysis showed that silicate adsorption did not obey the Langmuir equation (r = -0.664-0.301) but did obey the Freundlich and Temkin equations (P < 0.01, r = 0.885-0.990). When the equilibrium silicate concentration (Ci) was less than 45 mg SiO2 kg-1, the adsorption capacity was in the following decreasing order of paddy soils: basalt-derived > Pearl River Delta sediment-derived > granite-derived > sand-shale-derived. Stepwise regression and path analysis showed that for the investigated paddy soils amorphous MnO and Al2O3 were the two most important materials that affected silicate adsorption. Moreover, as Ci increased, amorphous Al2O3 tended to play a more important role in silicate adsorption, while the effects of amorphous MnO on silicate adsorption tended to decrease.

Influence of Particle Size on Magnetic Properties of Soils in Zhejiang Province, China

The relationship between magnetic properties and particle size of soils derived from metamorphic rock, basalt, granite, Quaternary red clay, limestone and mudstone from Zhejiang Province, East China was studied. Based on the variations of the mass magnetic susceptibility (X), anhysteretic remanent magnetization (ARM), and saturation isothermal remanent magnetization (SIRM) with soil particle size, the relationship could be classified into three groups. For the soils derived from metamorphic rock and basalt, magnetic values were the highest in the gravel and coarse sand fractions and decreased with decreasing soil particle size. The soils derived from sedimentary rock had a bimodal distribution of magnetic values, with peaks in 1-0.5 and 0.005-0.000 5 mm fractions. The soil developed on granite was characterized by a peak of magnetic value in 0.001-0.000 5 mm fractions. Frequency-dependent susceptibility (Xfd ) and ratics of magnetic parameters (ARM/X, SIRM/X and SIRM/ARM) of soil particle fractions showed that variations in ferrimagnetic grain size paralleled those in particle size. Xfd peaked in clay fraction and decreased with increasing particle size, irrespective of soil parent materials. The acquisition curves of IRM and demagnetization parameter of different soil particles indicated that there were different magnetic minerals assemblages in different particle fractions.

Impacts of soil properties on phosphorus adsorption and fractions in purple soils

Information on phosphorus(P) adsorption and its impacts on the redistribution of the P fraction in soil profiles are important for environmental management under intensive agricultural practices.To clarify the dominant factors influencing soil phosphorus adsorption in an Entisol(locally known as purple soil), P adsorption experiments were conducted in Sichuan Basin of southwestern China for cropland and woodland soils with acidic, neutral and calcareous origins throughout their profile. After various doses of P were added during incubation experiments, soil P fractions were also analyzed. The results showed that there were no significant differences in Fe-oxides and P adsorption along the vertical gradients. Agricultural practices and lower p H conditions reduced the P adsorption capacity of purple soils throughout the soil profiles. For acidic and neutral purple soil profiles, the P adsorption capability was mainly influenced by Fe-oxides and soil texture. Ca-bound P and Fe-Al-bound P represented the majority of the total inorganic P of calcareous soils.There was a saturation of adsorption capacity by sesquioxide and a high risk of dissoluble reactive P(NH_4 Cl-P) being released out of the soil profile in acidic and neutral purple soils after the greatest P addition, indicated by the higher proportions of NH_4 Cl-P(over 40%) and decreasing Fe-Al-P fraction.P fractions migrated with greater difficulty in calcareous purple soil profiles as Ca-P fraction peaked over 65% when adding a P dose at or greater than 80 g P kg^(-1), indicating the high potential of P adsorption.The X-Ray Diffraction analysis also verified the formation of brushite. Adaptive management practices should be designed to alleviate P losses for acidic and neutral purple soils.

Implications of Non-Carbonate Dolomite Minerals in the Formation of Red Soils in a Paleokarstic Context in the Taoudeni Basin in Burkina Faso

Uncertainties remain as to the ability of certain carbonate rocks to form the red soils covering them. These doubts, which have been the subject of debate for several decades, become real when carbonate rocks are pure and low in insoluble residues. In the carbonate rocks of the Taoudeni basin in Burkina Faso, brown-red to red soils develop, at the top of hillsides and in karstic cavities. No study in the region has yet shown the existence in these carbonate rocks of sufficient insolubles to form soils after decalcification. The objective of this study was therefore to identify and quantify the minerals of carbonate rocks in order to identify the origin of red soils. Petrographic, chemical (XRF) and mineralogical (XRD) investigations on dominant carbonate rocks features in the study area show that the rocks studied are mainly magnesian dolomites (Dolomite > 50% of carbonate minerals and Ca/Mg ratio < 1.5). Non-carbonate residues from detrital and hydrothermal origin, negligible in certain pure dolomites (<2%), are on the other hand significant (>12%) in other dolomitic features. These insoluble silicates formed of quartz, potassium feldspar (orthoclase), clays (talc, phlogopite and kaolinite) and iron oxides constitute the main original material of reddened soils in karstic cavities.

Land Suitability Evaluation for Oil Palm (<i>Elaeis guineensis</i>Jacq.) in Coastal Plains of Southwest Cameroon

Declining yields in oil palm fresh fruit bunch (FFB) have been recorded over the past years in the coastal lowlands of southwest Cameroon and current actual yields are very low (<12 t FFB ha−1•yr−1) compared to the potential yields (25 t FFB ha−1•yr−1). One of the problems limiting optimum oil palm production is lack of detailed pedological information to guide plantation establishment and management. A land suitability evaluation was carried out for some major oil palm producing areas of southwest Cameroon to identify land qualities limiting optimal production. Thirteen sites (9 with sedimentary parent materials and 4 with volcanic parent material) were evaluated using a parametric method. Results indicate that climate was not a major limiting factor for oil palm production in coastal plains of southwest Cameroon. However, soil physical characteristics (mainly clayey texture and poor drainage) and soil fertility constitute limitations to oil palm production. Specifically, limitations in cation exchange capacity (CEC), base saturation (BS), organic carbon (OC) and pH were slight to moderate while K mole fraction was the most severe and the most limiting in all the sites. The fertility limitations were more pronounced in soils derived from sedimentary parent materials where 33% had limitations caused by soil pH and OC compared to none for volcanic soils. In addition, 77.8% of sedimentary soils had limitations caused by CEC compared to 25% for volcanic soils. Considering the overall suitability, soils derived from volcanic parent materials were potentially more suitable for oil palm cultivation ((S3)—50%, (S2)—50%) compared to sedimentary soils ((N)—11%, (S3)—78% and (S2)—11%). Based on the suitability classes of the different soils derived from dissimilar parent materials, appropriate site-specific soil management is needed to improve oil palm yields, especially with emphasis on K fertilization and improved soil water management. Plantation management in coastal plains of South West Cameroon therefore should factor in differences in soil parent material.

Rice planting acceleration of the activation and loss of soil iron in the red soil region of southern China

Rice planting decreased total iron but increased active iron.Iron activation varied greatly among different paddy soils but not in woodland soils.Paddy soil iron was mainly affected by pH,SOC and particle composition.The decrease of soil Fe was mainly in the form of Fec and was closely related to SOC.

Heavy Metal Contamination of Agricultural Soils in Taiyuan, China

To evaluate the current state of the environmental quality of agricultural soils in Taiyuan City, a hotspot for China's industrial development, the concentrations of 8 heavy metals in soils were investigated by means of extensive sampling in farmlands, forestlands,and grasslands in the city. Statistical analyses and spatial distribution maps were used to identify the most significant heavy metal pollutants. The mean concentrations of As, Cd, Cu, Hg, Pb, Zn, Ni, and Cr were slightly higher than their background values in Taiyuan's topsoil, but were lower than the maximum permissible concentrations in the Chinese Environmental Quality Standard for agricultural soils. Farmland soils in Taiyuan had the highest average Cd, Cu, Hg, Pb, Zn, and Cr concentrations, but the As and Ni concentrations did not differ significantly among the farmland, forestland, and grasslands. Soil contamination by Cd, Cu, Hg, Pb,Zn, and Cr was mainly derived from farming practices, especially the use of sewage water for irrigation. In contrast, As and Ni might derive mainly from the soil parent material. The identification of heavy metal sources in agricultural soils may provide a basis for taking appropriate action to protect soil quality.

Major Elements in Soils Along a 2.8-km Altitudinal Gradient on the Tibetan Plateau,China

There are a series of special mountain soils on the Tibetan Plateau of China in an alpine environment for the high altitude. However, very few studies have focused on major soil elements in relation to soil formation in this area. Aluminum （Al）, iron （Fe）, calcium （Ca）, sodium （Na）, potassium （K） and magnesium （Mg） contents of 237 topsoil samples covering a 2.8-km altitudinal gradient in uncultivated areas along the Qinghai-Tibet Railway of China were measured using inductively coupled plasma atomic emission spectroscopy. The spatial distribution of the elements and its relationship to the parent rocks and climatic parameters were analyzed. Soils along the gradient are derived from a range of parent materials, but most are less than 30 cm deep with little development （Cambisols）. Soil Al, Fe and Mg contents showed a decreasing trend from the start station （Xining Station） to end station （Lhasa Station） of the Qinghai-Tibet Railway, whereas soil K and Na contents were relative stable from Xining Station to the Kunlun Mountains and then increased gradually. Soil Ca content was lower in the southern part of the Tanggula Mountains. The major soil element contents clearly reflected the parent rock and climatic influences. Soils with higher Ca content appeared in areas with Ca-Mg carbonate rocks, soils with higher Al were found in areas with silicate-rich and high-Al silicate clastic rocks and silicate-rich aluminosilicate loose sediments. Soils with higher K and Na contents appeared in areas with high-K, high-Na and silicate-rich aluminosilicate rocks. Soil Na and K contents were affected by temperature, whereas the contents of Mg, Fe, Ca and Al were more affected by precipitation. Soil Na and K contents increased with increasing temperatures, whereas the contents of Mg, Fe, Ca and Al decreased with increasing precipitation. This analysis provides a relationship between soil properties and rapidly changing environmental conditions. The data can be used to investigate the effect of the climate or land use change on soil properties.

Factors Affecting the Occurrence of Palygorskite in Central Iranian Soils Developed on Tertiary Sediments

Limited information is available on the distribution and origin of palygorkite in soils developed on Tertiary sediments as the major soil parent materials in central Iran and other Middle Eastern countries. The objectives of this study were to determine the distribution and origin of palygorskite in soils developed on Tertiary sediments, and to identify the major soil properties that influence palygorskite distribution in the soils studied. Sixteen soil profiles developed on Paleocene, Eocene, Oligocene, Oligocene-Miocene, Miocene and Pliocene sediments were studied by X-ray diffraction analysis, transmission electron microscope, and scanning electron microscopy. Physicochemical characteristics of the soils and sediments including particle size distribution, pH, electrical conductivity, organic carbon, gypsum, carbonates, and soluble Si, Ca and Mg were determined. The principal component analysis was used to establish the relationships between palygorskite and the physicochemical characteristics of the soils studied. Results showed that clay fraction of all the soils in the study area was dominated by palygorskite. The highest amount of palygorskite was found in horizons where simultaneous accumulation of both carbonates and gypsum occurred. Limited amount of palygorskite was found in salic and calcic horizons. Palygorskite seemed to be of eolian origin in the surface horizon of all the soils. Using principal component analysis, the soluble Mg/Ca ratio, pH, soluble Si and gypsum contents were identified as the most important factors affecting the distribution and genesis of palygorskite in the soils studied. Results might suggest the neoformation of palygorskite by precipitation from solutions in which evaporation fluxes were very high. However, palygorskite in soils developed on Tertiary sediments in central Iran seems to be of both inherited and pedogenic origins.