The Raman and infrared spectra, resistivity as well as thermoelectric power of Y 1- x Nd x Sr 2Cu 2.7 Mo 0.3 O 7- δ ( x =0, 0.1, 0.2, 0.5, 0.8 and 1.0) are studied carefully. It was found that the structure character...The Raman and infrared spectra, resistivity as well as thermoelectric power of Y 1- x Nd x Sr 2Cu 2.7 Mo 0.3 O 7- δ ( x =0, 0.1, 0.2, 0.5, 0.8 and 1.0) are studied carefully. It was found that the structure characteristics of RSr 2Cu 2.7 Mo 0.3 O 7- δ cuprates are different from those of RBa 2Cu 3O 7- δ . The variations of the microstructure in Y 1- x Nd x Sr 2Cu 2.7 Mo 0.3 O 7- δ with Nd doping affect the carrier distribution, so as a result the superconductivity changes. Furthermore, it is pointed out that the microstructure variations with the large rare earth ionic substitution cause the widely existing rare earth ionic size effect in HTSC.展开更多
文摘The Raman and infrared spectra, resistivity as well as thermoelectric power of Y 1- x Nd x Sr 2Cu 2.7 Mo 0.3 O 7- δ ( x =0, 0.1, 0.2, 0.5, 0.8 and 1.0) are studied carefully. It was found that the structure characteristics of RSr 2Cu 2.7 Mo 0.3 O 7- δ cuprates are different from those of RBa 2Cu 3O 7- δ . The variations of the microstructure in Y 1- x Nd x Sr 2Cu 2.7 Mo 0.3 O 7- δ with Nd doping affect the carrier distribution, so as a result the superconductivity changes. Furthermore, it is pointed out that the microstructure variations with the large rare earth ionic substitution cause the widely existing rare earth ionic size effect in HTSC.