To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled tur...To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled turbocharging system was carried out.In this study,a one-dimensional numerical model of the EGR,Miller cycle,and adjustable two-stage turbocharged engine based on WeiChai 6170 marine diesel engine was established.The particle swarm optimization algorithm was used to achieve multi-input and multi-objective comprehensive optimization,and the effects of EGR-coupled Miller regulation and high-pressure turbine bypass regulation on NO_(x)and BSFC were investigated.The results showed that a medium EGR rate-coupled medium Miller degree was better for the comprehensive optimization of NO_(x)and BSFC.At medium EGR rate and low turbine bypass rates,NO_(x)and BSFC were relatively balanced and acceptable.Finally,an optimal steady-state control strategy under full loads was proposed.With an increase in loads,the optimized turbine bypass rate and Miller degree gradually increased.Compared with the EGRonly system,the optimal system of EGR and Miller cycle coupled turbine bypass reduced NO_(x)by 0.87 g/(kW·h)and BSFC by 17.19 g/(kW·h)at 100%load.Therefore,the EGR and Miller cycle coupled adjustable two-stage turbocharging achieves NO_(x)and BSFC optimization under full loads.展开更多
Mineral dissemination and pore space distribution in ore particles are important features that influence heap leaching performance. To quantify the mineral dissemination and pore space distribution of an ore particle,...Mineral dissemination and pore space distribution in ore particles are important features that influence heap leaching performance. To quantify the mineral dissemination and pore space distribution of an ore particle, a cylindrical copper oxide ore sample (I center dot 4.6 mm x 5.6 mm) was scanned using high-resolution X-ray computed tomography (HRXCT), a nondestructive imaging technology, at a spatial resolution of 4.85 mu m. Combined with three-dimensional (3D) image analysis techniques, the main mineral phases and pore space were segmented and the volume fraction of each phase was calculated. In addition, the mass fraction of each mineral phase was estimated and the result was validated with that obtained using traditional techniques. Furthermore, the pore phase features, including the pore size distribution, pore surface area, pore fractal dimension, pore centerline, and the pore connectivity, were investigated quantitatively. The pore space analysis results indicate that the pore size distribution closely fits a log-normal distribution and that the pore space morphology is complicated, with a large surface area and low connectivity. This study demonstrates that the combination of HRXCT and 3D image analysis is an effective tool for acquiring 3D mineralogical and pore structural data.展开更多
The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stabili...The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stability of the solution obtained from DDF method has been investigated through optimizing the coefficient matrix, introducing a damping factor and a least square treatment. All calculations were accomplished with a microcomputer. It was shown that the average deviations of the size distribution obtained are not larger than the assigned random errors to the scattering intensities as long as the corresponding requirements are satisfied.展开更多
As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile an...As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.展开更多
In this paper, a simple and facile surfactant assisted combustion synthesis is reported for the ZnO nanoparticles. The synthesis of ZnO-NPs has been done with the assistance of non-ionic surfactant TWEEN 80. The effec...In this paper, a simple and facile surfactant assisted combustion synthesis is reported for the ZnO nanoparticles. The synthesis of ZnO-NPs has been done with the assistance of non-ionic surfactant TWEEN 80. The effect of fuel variations and comparative study of fuel urea and glycine have been studied by using characterization techniques like X-ray diffraction (XRD), transmission electron microscope (TEM) and particle size analyzer. From XRD, it indicates the presence of hexagonal wurtzite structure for ZnO-NPs. Using X-ray broadening, crystallite sizes and lattice strain on the peak broadening of ZnO-NPs were studied by using Williamson-Hall (W-H) analysis and size-strain plot. Strain, stress and energy density parameters were calculated for the XRD peaks of all the samples using (UDM), uniform stress deformation model (USDM), uniform deformation energy density model (UDEDM) and by the size-strain plot method (SSP). The results of mean particle size showed an inter correlation with W-H analysis, SSP, particle analyzer and TEM results.展开更多
The study examined the contamination levels of the soil and plantain leaves in three communities in Atakunmosa west local government area of Osun State in southwest Nigeria, where gold mining activities have recently ...The study examined the contamination levels of the soil and plantain leaves in three communities in Atakunmosa west local government area of Osun State in southwest Nigeria, where gold mining activities have recently become intensive. Plantain is a major food crop, whose leaves are used to wrap food items for household consumption. The objectives were to examine the heavy metal concentrations in the soil and plantain leaves around the gold mine site and compare them with standard recommended safe limits for the environment. Soil and plantain leaves were sampled at different locations around the sites and at a control site from a neighboring local government area with no history of gold mining activities between March 2015 and February 2016. Both soil and leave samples were processed and analyzed for selected heavy metals (Cd, As, Cu, Zn, Cr, Mn and Fe) using the Particle Induced X-ray Emission (PIXE) in the laboratory. The study showed higher concentrations than the World Health Organization’s recommended safe limits of the heavy metals in the soils and plantain leaves. Dry season concentrations of the variables were also higher than the wet season and the heavy metal concentrations at the control station were significantly (p < 0.05) lower than those of the mining environment. The study concluded that the ecosystems in the artisanal gold mining region are vulnerable to bioaccumulation of heavy metals and the leaves from the sites are sources of heavy metal contamination if consumed or used to wrap food items.展开更多
Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles inBeijing in order to examine their features and sources. Atmospheric aerosol particles were collected on el...Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles inBeijing in order to examine their features and sources. Atmospheric aerosol particles were collected on electron microscope meshes according to two size ranges: coarse particles (r>0.5μm) and fine particles (0.5μm>r>0. 1μm) by using a two-stage impactor. It was found that more than seventy percent of the fine particles and about twenty percentof the coarse particles were sulfate-containing particles. These particles were formed mainly through heterogeneousnucleation. The element composition analyses revealed that the atmospheric aerosol particles in Beijing were domi-nated by crustal particles and construction dust.展开更多
We justify and extend the standard model of elementary particle physics by generalizing the theory of relativity and quantum mechanics. The usual assumption that space and time are continuous implies, indeed, that it ...We justify and extend the standard model of elementary particle physics by generalizing the theory of relativity and quantum mechanics. The usual assumption that space and time are continuous implies, indeed, that it should be possible to measure arbitrarily small intervals of space and time, but we ignore if that is true or not. It is thus more realistic to consider an extremely small “quantum of length” of yet unknown value <em>a</em>. It is only required to be a universal constant for all inertial frames, like<em> c</em> and <em>h</em>. This yields a logically consistent theory and accounts for elementary particles by means of four new quantum numbers. They define “particle states” in terms of modulations of wave functions at the smallest possible scale in space-time. The resulting classification of elementary particles accounts also for dark matter. Antiparticles are redefined, without needing negative energy states and recently observed “anomalies” can be explained.展开更多
Zinc substituted cobalt ferrite nanoparticles (CoxZn1-xFe2O4, with x = 0.0, 0.2, 0.4, 0.8 and 1.0) were prepared via sol-gel route and the effect of zinc concentration on saturation magnetization and lattice parameter...Zinc substituted cobalt ferrite nanoparticles (CoxZn1-xFe2O4, with x = 0.0, 0.2, 0.4, 0.8 and 1.0) were prepared via sol-gel route and the effect of zinc concentration on saturation magnetization and lattice parameter were investigated. The particle sizes of the as obtained samples were found to be ~10 nm which increases upto ~92 nm on annealing at 1000oC. The frequency bands near 564-588 cm-1 and 425-442 cm-1 are assigned to the tetrahedral and octahedral clusters which confirm the presence of M-O stretching band in ferrites. The unit cell parameter ‘a’ increases linearly with increasing concentration of zinc due to larger ionic radii of Zn2+ ion . It was found that this substitution allows tunable changes in the magnetic properties of cobalt ferrite. Interestingly, saturation magnetization first increases upto x = 0.4 and then decreases for higher Zn substitution, thus tunable changes in magnetic properties of cobalt ferrite are possible. Source of such behaviour could be the variation of exchange interaction between the tetrahedral and the octahedral sites.展开更多
SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 pow...SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 powders on several occasions as well. Comparison and evaluation of various particle-sizing techniques have been made.展开更多
This study reports the development and performance of a pilot-scale barrel atmospheric plasma reactor for the atmospheric plasma activation treatment of polymer particles. The polymer particles treated included acrylo...This study reports the development and performance of a pilot-scale barrel atmospheric plasma reactor for the atmospheric plasma activation treatment of polymer particles. The polymer particles treated included acrylonitrile butadiene styrene(ABS) and polypropylene(PP). These particles had diameters in the range of 3–5 mm. The initial studies were carried out using a laboratory-scale barrel reactor designed to treat polymer particle batch sizes of 20 g. A pilot-scale reactor that could treat 500 g particle batch sizes was then developed to facilitate pre-industrial-scale treatments. The effect of operating pulse density modulation(PDM) in the range 10%–100% and plasma treatment time on the level of activation of the treated polymers were then investigated. ABS revealed a larger decrease in water contact angle compared with PP after plasma treatment under the same conditions. The optimal treatment time of ABS(400 g of polymer particles) in the pilot-scale reactor was 15 min. The plasma-activated polymer particles were used to fabricate dog-bone polymer parts through injection molding.Mechanical testing of the resulting dog-bone polymer parts revealed a 10.5% increase in tensile strength compared with those fabricated using non-activated polymer particles.展开更多
The presumed hairs of Holy Maria-Magdalena are studied here for mineral particles found on their surfaces, by the techniques of scanning electron microscopy coupled with energy dispersive X-ray. Exploration by these t...The presumed hairs of Holy Maria-Magdalena are studied here for mineral particles found on their surfaces, by the techniques of scanning electron microscopy coupled with energy dispersive X-ray. Exploration by these techniques of the hair surfaces allows us to observe and study some marble fragments that can originate from the walls of the sarcophagus in which Maria-Magdalena’s remains were kept. These new findings support the authenticity of the hair as traditionally reported in the French “tradition des Saints de Provence”.展开更多
基金Project(K16011)supported by the Marine Low-speed Engine Project-Phase I,China。
文摘To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled turbocharging system was carried out.In this study,a one-dimensional numerical model of the EGR,Miller cycle,and adjustable two-stage turbocharged engine based on WeiChai 6170 marine diesel engine was established.The particle swarm optimization algorithm was used to achieve multi-input and multi-objective comprehensive optimization,and the effects of EGR-coupled Miller regulation and high-pressure turbine bypass regulation on NO_(x)and BSFC were investigated.The results showed that a medium EGR rate-coupled medium Miller degree was better for the comprehensive optimization of NO_(x)and BSFC.At medium EGR rate and low turbine bypass rates,NO_(x)and BSFC were relatively balanced and acceptable.Finally,an optimal steady-state control strategy under full loads was proposed.With an increase in loads,the optimized turbine bypass rate and Miller degree gradually increased.Compared with the EGRonly system,the optimal system of EGR and Miller cycle coupled turbine bypass reduced NO_(x)by 0.87 g/(kW·h)and BSFC by 17.19 g/(kW·h)at 100%load.Therefore,the EGR and Miller cycle coupled adjustable two-stage turbocharging achieves NO_(x)and BSFC optimization under full loads.
基金financially supported by the National Natural Science Foundation of China(No.51304076)the Natural Science Foundation of Hunan Province,China(No.14JJ4064)
文摘Mineral dissemination and pore space distribution in ore particles are important features that influence heap leaching performance. To quantify the mineral dissemination and pore space distribution of an ore particle, a cylindrical copper oxide ore sample (I center dot 4.6 mm x 5.6 mm) was scanned using high-resolution X-ray computed tomography (HRXCT), a nondestructive imaging technology, at a spatial resolution of 4.85 mu m. Combined with three-dimensional (3D) image analysis techniques, the main mineral phases and pore space were segmented and the volume fraction of each phase was calculated. In addition, the mass fraction of each mineral phase was estimated and the result was validated with that obtained using traditional techniques. Furthermore, the pore phase features, including the pore size distribution, pore surface area, pore fractal dimension, pore centerline, and the pore connectivity, were investigated quantitatively. The pore space analysis results indicate that the pore size distribution closely fits a log-normal distribution and that the pore space morphology is complicated, with a large surface area and low connectivity. This study demonstrates that the combination of HRXCT and 3D image analysis is an effective tool for acquiring 3D mineralogical and pore structural data.
文摘The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stability of the solution obtained from DDF method has been investigated through optimizing the coefficient matrix, introducing a damping factor and a least square treatment. All calculations were accomplished with a microcomputer. It was shown that the average deviations of the size distribution obtained are not larger than the assigned random errors to the scattering intensities as long as the corresponding requirements are satisfied.
基金One of us (Z.Y. Wu) was supported by 100-Talent Research Program of The Chinese Academy of Sciences. One of the authors (K. Ibrahim) is grateful to the National Natural Science Foundation of China (NSFC) for financial support (Grant No. 10074063) The
文摘As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.
文摘In this paper, a simple and facile surfactant assisted combustion synthesis is reported for the ZnO nanoparticles. The synthesis of ZnO-NPs has been done with the assistance of non-ionic surfactant TWEEN 80. The effect of fuel variations and comparative study of fuel urea and glycine have been studied by using characterization techniques like X-ray diffraction (XRD), transmission electron microscope (TEM) and particle size analyzer. From XRD, it indicates the presence of hexagonal wurtzite structure for ZnO-NPs. Using X-ray broadening, crystallite sizes and lattice strain on the peak broadening of ZnO-NPs were studied by using Williamson-Hall (W-H) analysis and size-strain plot. Strain, stress and energy density parameters were calculated for the XRD peaks of all the samples using (UDM), uniform stress deformation model (USDM), uniform deformation energy density model (UDEDM) and by the size-strain plot method (SSP). The results of mean particle size showed an inter correlation with W-H analysis, SSP, particle analyzer and TEM results.
文摘The study examined the contamination levels of the soil and plantain leaves in three communities in Atakunmosa west local government area of Osun State in southwest Nigeria, where gold mining activities have recently become intensive. Plantain is a major food crop, whose leaves are used to wrap food items for household consumption. The objectives were to examine the heavy metal concentrations in the soil and plantain leaves around the gold mine site and compare them with standard recommended safe limits for the environment. Soil and plantain leaves were sampled at different locations around the sites and at a control site from a neighboring local government area with no history of gold mining activities between March 2015 and February 2016. Both soil and leave samples were processed and analyzed for selected heavy metals (Cd, As, Cu, Zn, Cr, Mn and Fe) using the Particle Induced X-ray Emission (PIXE) in the laboratory. The study showed higher concentrations than the World Health Organization’s recommended safe limits of the heavy metals in the soils and plantain leaves. Dry season concentrations of the variables were also higher than the wet season and the heavy metal concentrations at the control station were significantly (p < 0.05) lower than those of the mining environment. The study concluded that the ecosystems in the artisanal gold mining region are vulnerable to bioaccumulation of heavy metals and the leaves from the sites are sources of heavy metal contamination if consumed or used to wrap food items.
文摘Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles inBeijing in order to examine their features and sources. Atmospheric aerosol particles were collected on electron microscope meshes according to two size ranges: coarse particles (r>0.5μm) and fine particles (0.5μm>r>0. 1μm) by using a two-stage impactor. It was found that more than seventy percent of the fine particles and about twenty percentof the coarse particles were sulfate-containing particles. These particles were formed mainly through heterogeneousnucleation. The element composition analyses revealed that the atmospheric aerosol particles in Beijing were domi-nated by crustal particles and construction dust.
文摘We justify and extend the standard model of elementary particle physics by generalizing the theory of relativity and quantum mechanics. The usual assumption that space and time are continuous implies, indeed, that it should be possible to measure arbitrarily small intervals of space and time, but we ignore if that is true or not. It is thus more realistic to consider an extremely small “quantum of length” of yet unknown value <em>a</em>. It is only required to be a universal constant for all inertial frames, like<em> c</em> and <em>h</em>. This yields a logically consistent theory and accounts for elementary particles by means of four new quantum numbers. They define “particle states” in terms of modulations of wave functions at the smallest possible scale in space-time. The resulting classification of elementary particles accounts also for dark matter. Antiparticles are redefined, without needing negative energy states and recently observed “anomalies” can be explained.
文摘Zinc substituted cobalt ferrite nanoparticles (CoxZn1-xFe2O4, with x = 0.0, 0.2, 0.4, 0.8 and 1.0) were prepared via sol-gel route and the effect of zinc concentration on saturation magnetization and lattice parameter were investigated. The particle sizes of the as obtained samples were found to be ~10 nm which increases upto ~92 nm on annealing at 1000oC. The frequency bands near 564-588 cm-1 and 425-442 cm-1 are assigned to the tetrahedral and octahedral clusters which confirm the presence of M-O stretching band in ferrites. The unit cell parameter ‘a’ increases linearly with increasing concentration of zinc due to larger ionic radii of Zn2+ ion . It was found that this substitution allows tunable changes in the magnetic properties of cobalt ferrite. Interestingly, saturation magnetization first increases upto x = 0.4 and then decreases for higher Zn substitution, thus tunable changes in magnetic properties of cobalt ferrite are possible. Source of such behaviour could be the variation of exchange interaction between the tetrahedral and the octahedral sites.
基金This Subject was Partly Supported by the Scientific Reasearch Foundation for Returned Overseas Scholars from the State Education Department of China for RJZ(1997-436)
文摘SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 powders on several occasions as well. Comparison and evaluation of various particle-sizing techniques have been made.
基金support of the Enterprise Ireland Innovation Partnership programthe SFI funded Ⅰ-Form Advanced Manufacturing Research Centre 16/RC/3872
文摘This study reports the development and performance of a pilot-scale barrel atmospheric plasma reactor for the atmospheric plasma activation treatment of polymer particles. The polymer particles treated included acrylonitrile butadiene styrene(ABS) and polypropylene(PP). These particles had diameters in the range of 3–5 mm. The initial studies were carried out using a laboratory-scale barrel reactor designed to treat polymer particle batch sizes of 20 g. A pilot-scale reactor that could treat 500 g particle batch sizes was then developed to facilitate pre-industrial-scale treatments. The effect of operating pulse density modulation(PDM) in the range 10%–100% and plasma treatment time on the level of activation of the treated polymers were then investigated. ABS revealed a larger decrease in water contact angle compared with PP after plasma treatment under the same conditions. The optimal treatment time of ABS(400 g of polymer particles) in the pilot-scale reactor was 15 min. The plasma-activated polymer particles were used to fabricate dog-bone polymer parts through injection molding.Mechanical testing of the resulting dog-bone polymer parts revealed a 10.5% increase in tensile strength compared with those fabricated using non-activated polymer particles.
文摘The presumed hairs of Holy Maria-Magdalena are studied here for mineral particles found on their surfaces, by the techniques of scanning electron microscopy coupled with energy dispersive X-ray. Exploration by these techniques of the hair surfaces allows us to observe and study some marble fragments that can originate from the walls of the sarcophagus in which Maria-Magdalena’s remains were kept. These new findings support the authenticity of the hair as traditionally reported in the French “tradition des Saints de Provence”.