Influence of air masses on particle number concentration and size distribution at Mt. Waliguan, Qinghai Province, China

Particle size distribution of 12-500 nm was measured at Mt. Waliguan, China Global Atmosphere Watch Baseline Observatory, from Aug. in 2005 to May in 2007.72-hr back-trajectories at 100-m arrival height above ground level for the same period were calculated at 6：00, 12：00, and 21：00 （Beijing Time） for each day using the Hybrid Single-Particle Lagrangian Integrated Trajectory （HYSPLIT-4） model developed by NOAA/ARL. It was found that air mass sources significantly impact particle number concentration and size distribution at Mt. Waliguan. Cluster analysis of back-trajectories show that higher Aitken mode particle number concentration was observed when air masses came from or passed by the northeastern section of Mt. Waliguan, with short trajectory length. High number concentration of nucleation mode was associated with air masses from clean regions, with long trajectory length.

Effect of Particle Number Density on Wave Dispersion in a Two-Dimensional Yukawa System

Effect of the particle number density on the dispersion properties of longitudinal and transverse lattice waves in a two-dimensional Yukawa charged-dust system is investigated using molecular dynamics simulation. The dispersion relations for the waves are obtained. It is found that the frequencies of both the longitudinal and transverse dust waves increase with the density and when the density is sufficiently high a cutoff region appears at the short wavelength. With the increase of the particle number density, the common frequency tends to increase, and the sound speed of the longitudinal wave also increases, but that of the transverse wave remains low.

Particle number size distribution and new particle formation:New characteristics during the special pollution control period in Beijing

New particle formation is a key process in shaping the size distribution of aerosols in the atmosphere.We present here the measurement results of number and size distribution of aerosol particles （10–10000 nm in diameter） obtained in the summer of 2008,at a suburban site in Beijing,China.We firstly reported the pollution level,particle number size distribution,diurnal variation of the particle number size distribution and then introduced the characteristics of the particle formation processes.The results showed that the number concentration of ultrafine particles was much lower than the values measured in other urban or suburban areas in previous studies.Sharp increases of ultrafine particle count were frequently observed at noon.An examination of the diurnal pattern suggested that the burst of ultrafine particles was mainly due to new particle formation promoted by photochemical processes.In addition,high relative humidity was a key factor driving the growth of the particles in the afternoon.During the 2-month observations,new particle formation from homogeneous nucleation was observed for 42.7% of the study period.The average growth rate of newly formed particles was 3.2 nm/hr,and varied from 1.2 to 8.0 nm/hr.The required concentration of condensable vapor was 4.4×10 7 cm-3,and its source rate was 1.2×10 6 cm-3 sec-1.Further calculation on the source rate of sulphuric acid vapor indicated that the average participation of sulphuric acid to particle growth rates was 28.7%.

Seasonal Variations of Number Size Distributions and Mass Concentrations of Atmospheric Particles in Beijing

Particle number and mass concentrations were measured in Beijing during the winter and summer periods in 2003, together with some other parameters including black carbon (BC) and meteorological conditions. Particle mass concentrations exhibited low seasonality, and the ratio of PM2.5/PM10 in winter was higher than that in summer. Particle number size distribution (PSD) was characterized by four modes and exhibited low seasonality. BC was well correlated with the number and mass concentrations of accumulation and coarse particles, indicating these size particles are related to anthropogenic activities. Particle mass and number concentrations (except ultra-fine and nucleation particles) followed well the trends of BC concentration for the majority of the day, indicating that most particles were associated with primary emissions. The diurnal number distributions of accumulation and coarse mode particles were characterized by two peaks.

RELATIVE LEVELS OF INDOOR AND OUTDOOR PARTICLE NUMBER CONCENTRATIONS IN A RESIDENTIAL BUILDING IN XI'AN

The time series of indoor and outdoor particle number concentrations in a naturally ventilated residential building in Xi＇an were tested simultaneously for 7 days in summer. The relationships between indoor and outdoor concentrations were examined and discussed, and linear regression analysis was employed to correlate the indoor and outdoor concentrations. The diurnal cycles of indoor and outdoor particle concentrations of different particle size ranges all showed positive correlations between indoor and outdoor number concentrations, The I/O ratios of number concentrations varied with the increase of particle size in the range of 0.89 （±0.19） to 0.99 （±0.15）.

On-board measurement of particle numbers and their size distribution from a light-duty diesel vehicle:Influences of VSP and altitude

In this study,the particle size-resolved distribution from a China-3 certificated light-duty diesel vehicle was measured by using a portable emission measurement system（PEMS）.In order to examine the influences of vehicle specific power（VSP） and high-altitude operation,measurements were conducted at 8 constant speeds,which ranged from 10 to 80 km/hr at10 km/hr intervals,and two different high altitudes,namely 2200 and 3200 m.The results demonstrated that the numbers of particles in all size ranges decreased significantly as VSP increased when the test vehicle was running at lower speeds（〈 20 km/hr）,while at a moderate speed（between 30 and 60 km/hr）,the particle number was statistically insensitive to increase VSP.Under high-speed cruising conditions,the numbers of ultrafine particles and PM2.5were insensitive to changes in VSP,but the numbers of nanoparticles and PM10 surged considerably.An increase in the operational altitude of the test vehicle resulted in increased particle number emissions at low and high driving speeds;however,particle numbers obtained at moderate speeds decreased as altitude rose.When the test vehicle was running at moderate speeds,particle numbers measured at the two altitudes were very close,except for comparatively higher number concentrations of nanoparticles measured at 2200 m.

Characterization of particle number size distribution and new particle formation in Southern China

Knowledge of particle number size distribution（PND） and new particle formation（NPF）events in Southern China is essential for mitigation strategies related to submicron particles and their effects on regional air quality,haze,and human health.In this study,seven field measurement campaigns were conducted from December 2013 to May 2015 using a scanning mobility particle sizer（SMPS） at four sites in Southern China,including three urban sites and one background site.Particles were measured in the size range of15-515 nm,and the median particle number concentrations（PNCs） were found to vary in the range of 0.3× 10~4-2.2 × 10~4 cn^（-3） at the urban sites and were approximately 0.2 × 10~4 cm^（-3） at the background site.The peak diameters at the different sites varied largely from 22 to 102 nm.The PNCs in the Aitken mode（25-100 nm） at the urban sites were up to 10 times higher than they were at the background site,indicating large primary emissions from traffic at the urban sites.The diurnal variations of PNCs were significantly influenced by both rush hour traffic at the urban sites and NPF events.The frequencies of NPF events at the different sites were0%-30%,with the highest frequency occurring at an urban site during autumn.With higher SO_2 concentrations and higher ambient temperatures being necessary,NPF at the urban site was found to be more influenced by atmospheric oxidizing capability,while NPF at the background site was limited by the condensation sink.This study provides a unique dataset of particle number and size information in various environments in Southern China,which can help understand the sources,formation,and the climate forcing of aerosols in this quickly developing region,as well as help constrain and validate NPF modeling.

Identifying Supercooled Liquid Water in Cloud Based on Airborne Observations: Correlation of Cloud Particle Number Concentration with Icing Probability and Proportion of Spherical Particles

Identifying supercooled liquid water(SLW)in clouds is critical for weather modification,aviation safety,and atmospheric radiation calculations.Currently,aircraft identification in the SLW area mostly depends on emprical estimation of cloud particle number concentration(N_(c))in China,and scientific verification and quantitative identification criteria are urgently needed.In this study,the observations are from the Fast Cloud Droplets Probe,Rosemount ice detector(RICE),and Cloud Particle Imager(CP_(i))onboard a King Air aircraft during seven flights in 2018 and 2019 over central and eastern China.Based on this,the correlation among N_(c),the proportion of spherical particles(P_(s)),and the probability of icing(P_(i))in supercooled stratiform and cumulus-stratus clouds is statistically analyzed.Subsequently,this study proposes a method to identify SLW areas using N_(c) in combination with ambient temperature.The reliability of this method is evaluated through the true skill statistics(TSS)and threat score(TS)methods.Numerous airborne observations during the seven flights reveal a strong correlation among Nc,P_(s),and P_(i)at the temperature from 0 to−18°C.When Nc is greater than a certain threshold of 5 cm^(−3),there is always the SLW,i.e.,P_(i)and P_(s)are high.Evaluation results demonstrate that the TSS and TS values for Nc=5 cm^(−3)are higher than those for Nc<5 cm^(−3),and a larger Nc threshold(>5 cm^(−3))corresponds to a higher SLW identification hit rate and a higher SLW content.Therefore,Nc=5 cm^(−3)can be used as the minimum criterion for identifying the SLW in clouds at temperature lower than 0°C.The SLW identification method proposed in this study is especially helpful in common situations where aircraft are equipped with only Nc probes and without the CP_(i)and RICE.

Origin of high particle number concentrations reaching the St. Louis, Midwest Supersite

Ultrafine particles are associated with adverse health effects. Total Particle Number Concentration（TNC） of fine particles were measured during 2002 at the St. Louis — Midwest supersite. The time series showed overall low level with frequent large peaks. The time series was analyzed alongside criteria pollutant measurements and meteorological observations. Multiple regression analysis was used to identify further contributing factors and to determine the association of different pollutants with TNC levels. This showed the strong contribution of sulfur dioxide（SO2） and nitrogen oxides（NO x） to high TNC levels. The analysis also suggested that increased dispersion resulting from faster winds and higher mixing heights led to higher TNC levels. Overall, the results show that there were intense particle nucleation events in a SO2 rich plume reaching the site which contributed around 29% of TNC. A further 40% was associated with primary emissions from mobile sources. By separating the remaining TNC by time of day and clear sky conditions,we suggest that most likely 8% of TNC are due to regional nucleation events and 23% are associated with the general urban background.

Particle number conserving BCS approach in the relativistic mean field model and its application to ^32-74Ca

A fixed particle number BCS （FBCS） approach is formulated in the relativistic mean field （RMF） model. It is shown that the RMF＋FBCS model obtained can describe the weak pairing limit. We calculate the ground-state properties of the calcium isotopes ＆32-74Ca and compare the results with those obtained from the usual RMF＋BCS model. Although the results are quite similar to each other, we observe the interesting phenomenon that for ^54Ca, the FBCS approach can enhance the occupation probability of the 2p1/2 single particle level and slightly increases its radius, compared with the RMF＋BCS model. This leads to the unusual scenario that although ^54Ca is more bound with a spherical configuration, the corresponding size is not the most compact. We anticipate that such a phenomenon might happen for other neutron-rich nuclei and should be checked by further more systematic studies.

MONTE CARLO PARTICLE NUMBERING SCHEME

Revised September 2013 by J.-F. Arguin LBNL）, L. Garren （Fermilab）, F. Krauss （Durham U.）, C.-J. Lin （LBNL）, S. Navas （U. Granada）, P. Richardson （Durham U.）, and T. Sjostrand （Lund U.）.

Particle number size distribution and new particle formation (NPF) in Lanzhou,Western China

Particle number size distribution from 10 to 10,000 nm was measured by a wide-range particle spectrometer （WPS-1000XP） at a downwind site north of downtown Lanzhou, western China, from 25 june to 19 July 2006. We first report the pollution level, diurnal variation of particle concentration in different size ranges and then introduce the characteristics of the particle formation processes, to show that the number concentration of ultrafine particles was lower than the values measured in other urban or suburban areas in previous studies, However, the fraction of ultrafine particles in total aerosol number concentration was found to be much higher. Furthermore, sharp increase of ultrafine particle concentration was frequently observed at noon. An examination of the diurnal pattern suggests that the burst of the ultrafine particles was mainly due to nucleation process. During the 25-day observation, new particle formation （NPF） from homogeneous nucleation was observed during 33% of the study period. The average growth rate of the newly formed particles was 4.4 nm/h, varying from 1.3 to 16,9 nm/h. The needed concentration of condensable vapor was 6.1 × 10^7 cm-3, and its source rate was 1.1× 10^6 cm-3 s 1. Further calculation on the source rate of sulphuric acid vapor indicated that the average participation of sulphuric acid to particle growth rate was 68.3%.

Behaviors of thermalization for the Fermi–Pasta–Ulam–Tsingou system with small number of particles

We study the behaviors of thermalization in Fermi–Pasta–Ulam–Tsingou(FPUT) system with small number of particles using periodic boundary conditions. The total energy has initially equidistributed among some of the lowest frequency modes. The thermalization time t_(eq) depending on system's energy density ε scales as t_(eq) ∝ε^(-4) only within a certain range of nonlinearity. In this range of nonlinearity, energies can interchange between the initial excited modes and other modes continuously with time until reaching the thermalized state. With a further decreasing nonlinearity, a steeper growth than ε^(-4) will appear. In the very weakly nonlinear regime, energies on low frequency modes are found to be frozen on large time scales. Redistribution of mode energies happens through the resonances of high frequency modes.

Analysis of choked two-phase flows of gas and particle in a C-D nozzle

Particle-gas two-phase flows show significantly different behaviors compared to single gas flow through a convergent-divergent nozzle. Non-equilibrium effects, thermal and velocity lag results to the inefficiency of nozzle performance. In the present studies, theoretical analysis and numerical simulations were carried out to investigate particle-gas flows in a C-D nozzle. Homogeneous equilibrium model that no lag in velocity and temperature occurs between particles and gas phase was used to derive mass flow rate and sound speed of multiphase flows. Two-phase flows are regarded as isentropic flows that isentropic relations can be used for homogeneous equilibrium model. Discrete phase model （DPM） where interaction with continuous phase and discrete random walk model were considered was used to calculate particle- gas flows. Particle mass loadings were varied to investigate their effects on choking phenomena of particle-gas flows. Mass flow rate and sound speed of mixture flows were theoretically calculated by homogeneous equilibrium model and compared with numerical results. Shock wave structure and particle number density were also obtained to be different at different particle mass loading and operating pressure conditions.

Two-phase micro-and macro-time scales in particle-laden turbulent channel flows

The micro- and macro-time scales in two-phase turbulent channel flows are investigated using the direct nu- merical simulation and the Lagrangian particle trajectory methods for the fluid- and the particle-phases, respectively. Lagrangian and Eulerian time scales of both phases are cal- culated using velocity correlation functions. Due to flow anisotropy, micro-time scales are not the same with the theo- retical estimations in large Reynolds number （isotropic） tur- bulence. Lagrangian macro-time scales of particle-phase and of fluid-phase seen by particles are both dependent on particle Stokes number. The fluid-phase Lagrangian inte- gral time scales increase with distance from the wall, longer than those time scales seen by particles. The Eulerian inte- gral macro-time scales increase in near-wall regions but de- crease in out-layer regions. The moving Eulerian time scales are also investigated and compared with Lagrangian integral time scales, and in good agreement with previous measure- ments and numerical predictions. For the fluid particles the micro Eulerian time scales are longer than the Lagrangian ones in the near wall regions, while away from the walls the micro Lagrangian time scales are longer. The Lagrangian integral time scales are longer than the Eulerian ones. The results are useful for further understanding two-phase flow physics and especially for constructing accurate prediction models of inertial particle dispersion.

Turbulent Modulation in Particulate Flow: A Review of Critical Variables

A review of the main mechanisms influencing turbulent modulation in the presence of spherical and non-spherical particles is presented. The review demonstrates the need for more numerical and experimental work with higher accuracy than obtained so far and the need to resolve the flow near the surface of particles with the aim to re-evaluate the quantitative effect of different parameters on turbulent modulation. The review reveals that non-spherical particles have more adverse effect on turbulence as compared to spherical ones, for the same ambient conditions.

Characteristics of settling of dilute suspension of particles with different density at high Reynolds numbers

Dilute suspension of particles with same density and size develops clusters when settle at high Reynolds number(≥250).It is due to particles entrapment in the wakes produced by upstream particles.In this work,this phenomenon is studied for suspension having particles with different densities by numerical simulations.The particle-fluid interactions are modelled using immersed boundary method and inter-particle collisions are modelled using discrete element method.In simulations,settling Reynolds number is always kept above 250 and the suspension solid volume fraction is nearly 0.1 percent.Two particle density ratios(i.e.density of heavy particles to lighter particles)equal to 4:1 and 2:1 and particles with same density are studied.For each density ratio,the percentage volume fraction of each particle density is nearly varied from 0.8 to 0.2.Settling characteristics such as microstructures of settling particle,average settling velocity and velocity fluctuations of settling particles are studied.Simulations show that for different density particles settling characteristics of suspension is largely dominated by heavy particles.At the end of paper,the underlying physics is explained for the anomalies observed in simulation.

Impacts of continuously regenerating trap and particle oxidation catalyst on the NO_2 and particulate matter emissions emitted from diesel engine

Two continuously regenerating diesel particulate filter （CRDPF） with different configurations and one particles oxidation catalyst （POC） were employed to perform experiments in a controlled laboratory setting to evaluate their effects on NO2, smoke and particle number emissions. The results showed that the application of the after-treatments increased the emission ratios of NO2/NOx significantly. The results of smoke emissions and particle number （PN） emissions indicated that both CRDPFs had sufficient capacity to remove more than 90% of total particulate matter （PM） and more than 97% of solid particles. However, the POC was able to remove the organic components of total PM, and only partially to remove the carbonaceous particles with size less than 30 nm. The negligible effects of POC on larger particles were observed due to its honeycomb structure leads to an inadequate residence time to oxidize the solid particles or trap them. The particles removal efficiencies of CRDPFs had high degree of correlations with the emission ratio of NO2/NOx. The PN emission results from two CRDPFs indicated that more NO2 generating in diesel oxidation catalyst section could obtain the higher removal efficiency of solid particles. However this also increased the risk of NO2 exposure in atmosphere.

Application of nanoparticle tracking analysis for characterising the fate of engineered nanoparticles in sediment-water systems

Novel applications of nanotechnology may lead to the release of engineered nanoparticles（ENPs）, which result in concerns over their potential environmental hazardous impact. It is essential for the research workers to be able to quantitatively characterise ENPs in the environment and subsequently to assist the risk assessment of the ENPs. This study hence explored the application of nanoparticle tracking system（NTA） to quantitatively describe the behaviour of the ENPs in natural sediment-water systems. The NTA allows the measurement of both particle number concentration（PNC） and particle size distribution（PSD） of the ENPs. The developed NTA method was applied to a range of gold and magnetite ENPs with a selection of surface properties. The results showed that the positively-charged ENPs interacted more strongly with the sediment than neutral and negatively-charged ENPs. It was also found that the citrate coated Au ENPs had a higher distribution percentage（53%） than 11-mercaptoundecanoic acid coated Au ENPs（20%） and citrate coated magnetite ENPs（21%）. The principles of the electrostatic interactions between hard（and soft） acids and bases（HSAB） are used to explain such behaviours; the hard base coating（i.e. citrate ions） will interact more strongly with hard acid（i.e. magnetite） than soft acid（i.e. gold）.The results indicate that NTA is a complementary method to existing approaches to characterise the fate and behaviour of ENPs in natural sediment.

Technical challenges in tackling regulatory concerns for urban atmospheric nanoparticles

Recent Euro 5 and Euro 6 vehicle emission standards are the first ever initiative to control particles on a number basis at the source. Related standards are also desirable for ambient nanoparticles （taken in this article to be those below 300 rim） to protect against possible adverse effects on public health and the environment. However, there are a number of technical challenges that need to be tackled before developing a regulatory framework for atmospheric nanoparticles. Some of the challenges derive from a lack of standardisation of the key measurement parameters, including sampling, necessary for robust evaluation of particle number concentrations, especially in the context of insufficient knowledge of the physicochemical characteristics of emerging sources （i.e. bio-fuel derived and manufactured nanoparti- cles）. Ideally, ambient concentrations of primary particles could be linked to primary particle emissions by use of nanoparticle dispersion models, and secondary nanoparticles using photochemical modeling tools. The limitations in these areas are discussed. Although there is inadequate information on the exact biological mechanism through which these particles cause harm, it is argued that this should not in itself delay the introduction of regulation. This article reviews the missing links between the existing knowledge of nanoparticle number concentrations and the advances required to tackle the technical challenges implied in developing regulations.