Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasi...Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasing side product yield with the higher Re have been reported.This study investigated the mixing uniformity in microreactors with in-line UV-vis spectroscopy to clarify the relationship between reaction selectivity and chaotic mixing with the higher Re.A colorization experiment of thymolphthalein in an acidic solution was conducted with an excess acid amount to the base to indicate a non-uniformly mixed region.Non-uniformity significantly increased with Re.At the same time,the degree of mixing,which was measured by a usual decolorization experiment,showed that the mixing rate increased with Re.The in-line analysis of the Villermaux-Dushman reaction during the mixing clarified that side product yield significantly increased with Re at around 300 and then decreased at around 1100.These results suggest the compensation effect between the mixing uniformity and mixing rate on the selectivity of the mixing-sensitive reactions.Faster mixing,characterized by a larger Re,can disturb mixing uniformity and,in some cases,decrease reaction selectivity.展开更多
During the excavation of deep coal and rock mass, the radial stress of the free face changes from three-dimensional compression state to two-dimensional stress, bearing the combined action of dynamic disturbance and s...During the excavation of deep coal and rock mass, the radial stress of the free face changes from three-dimensional compression state to two-dimensional stress, bearing the combined action of dynamic disturbance and static load at the same time. With that, many mines suffer from dynamic disasters, such as coal and gas outburst, rock burst and rock caving during deep mining excavation, which is often accompanied by plate crack, spalling and other disasters, seriously affecting the stability of stope and roadway. Taking thin rectangular coal and rock mass as the research object, the dual equation of the free vibration was derived and the exact solution model of the free vibration was established with the use of Hamilton dual system. Based on the action characteristics of the uniform impact load, the effective mode of the forced vibration was obtained by using the Duhamel integral principle and the orthogonality of the mode function. Based on the third strength theory and the numerical simulation results, the dynamic damage process and development trend of coal and rock mass were analyzed under uniform impact load. It was concluded that the starting position of dynamic damage can be judged by the first order main mode, and the development direction and trend of the damage can be judged by the fifth and sixth order main modes. It was concluded that the vibration mode functions of coal and rock mass with four side fixed (C-C-C-C), the two sides fixed and simply supported on the other (S-C-S-C) are mainly composed of three modes that are the first order (dominant frequency), the fifth order and the sixth order, from which the dynamic damage mechanism is preliminarily studied.展开更多
This study used a three-dimensional numerical model of a proton exchange membrane fuel cell with five types of channels:a smooth channel(Case 1);eight rectangular baffles were arranged in the upstream(Case 2),midstrea...This study used a three-dimensional numerical model of a proton exchange membrane fuel cell with five types of channels:a smooth channel(Case 1);eight rectangular baffles were arranged in the upstream(Case 2),midstream(Case 3),downstream(Case 4),and the entire cathode flow channel(Case 5)to study the effects of baffle position on mass transport,power density,net power,etc.Moreover,the effects of back pressure and humidity on the voltage were investigated.Results showed that compared to smooth channels,the oxygen and water transport facilitation at the diffusion layer-channel interface were added 11.53%-20.60%and 7.81%-9.80%at 1.68 A·cm^(-2)by adding baffles.The closer the baffles were to upstream,the higher the total oxygen flux,but the lower the flux uniformity the worse the water removal.The oxygen flux of upstream baffles was 8.14%higher than that of downstream baffles,but oxygen flux uniformity decreased by 18.96%at 1.68 A·cm^(-2).The order of water removal and voltage improvement was Case 4>Case 5>Case 3>Case 2>Case 1.Net power of Case 4 was 9.87%higher than that of the smooth channel.To the Case 4,when the cell worked under low back pressure or high humidity,the voltage increments were higher.The potential increment for the back pressure of 0 atm was 0.9%higher than that of 2 atm(1 atm=101.325 kPa).The potential increment for the humidity of 100%was 7.89%higher than that of 50%.展开更多
Improving radiation use efficiency （RUE） of the canopy is necessary to increase wheat （Triticum aesfivum） production. Tridimensional uniform sowing （U） technology has previously been used to construct a uniforml...Improving radiation use efficiency （RUE） of the canopy is necessary to increase wheat （Triticum aesfivum） production. Tridimensional uniform sowing （U） technology has previously been used to construct a uniformly distributed population structure that increases RUE. In this study, we used tridimensional uniform sowing to create a wheat canopy within which light was spread evenly to increase RUE. This study was done during 2014-2016 in the Shunyi District, Beijing, China. The soil type was sandy loam. Wheat was grown in two sowing patterns： （1） tridimensional uniform sowing （U）; （2） conventional drilling （D）. Four planting densities were used： 1.8, 2.7, 3.6, and 4.5 million plants ha-1. Several indices were measured to compare the wheat canopies： photosynthetic active radiation intercepted by the canopy （IPAR）, leaf area index （LAI）, leaf mass per unit area （LMA）, canopy extinction coefficient （K）, and RUE. In two sowing patterns, the K values decreased with increasing planting density, but the K values of U were lower than that of D. LMA and IPAR were higher for U than for D, whereas LAI was nearly the same for both sowing patterns. IPAR and LAI increased with increasing density under the same sowing pattern. However, the difference in IPAR and LAI between the 3.6 and 4.5 million plants ha-1 treatments was not significant for both sowing patterns. Therefore, LAI within the same planting density was not affected by sowing pattern. RUE was the largest for the U mode with a planting density of 3.6 million plants ha-1 treatment. For the D sowing pattern, the lowest planting density （1.8 million plants ha-1） resulted in the highest yield. Light radiation interception was minimal for the D mode with a planting density of 1.8 million plants ha-1 treatment, but the highest RUE and highest yield were observed under this condition. For the U sowing pattern, IPAR increased with increasing planting density, but yield and RUE were the highest with a planting density of 3.6 million plants ha-1. These results indicated that the optimal planting density for improving the canopy light environment differed between the sowing patterns. The effect of sowing patternxplanting density interaction on grain yield, yield components, RUE, IPAR, and LMA was significant （P〈0.05）. Correlation analysis indicated that there is a positive significant correlation between grain yield and RUE （t=0.880, P〈0.01）, LMA （r=0.613, P〈0.05）, andspike number （t=0.624, P〈0.05）. These results demonstrated that the tridimensional uniform sowing technique, particularly at a planting density of 3.6 million plants ha-0, can effectively increase light interception and utilization and unit leaf area. This leads to the production of more photosynthetic products that in turn lead to significantly increased spike number （P〈0.05）, kernel number, grain weight, and an overall increase in yield.展开更多
The aim of this work is to study the effect of non-uniform single and double slot suction/injection into a steady mixed convection boundary layer flow over a vertical cone, while the axis of the cone is inline with th...The aim of this work is to study the effect of non-uniform single and double slot suction/injection into a steady mixed convection boundary layer flow over a vertical cone, while the axis of the cone is inline with the flow. The governing boundary layer equations are transformed into a non-dimensional form by a group of non-similar trans- formations. The resulting coupled non-linear partial differential equations are solved nu- merically by employing the quasi-linearization technique and an implicit finite-difference scheme. Numerical computations are performed for different values of the dimensionless parameters to display the velocity and temperature profiles graphically. Also, numerical results are presented for the skin friction and heat transfer coefficients. Results indicate that the skin friction and heat transfer coefficients increase with non-uniform slot suction, but the effect of non-uniform slot injection is just opposite.展开更多
基金the support of JSPS KAKENHI(21H05083)the Cooperative Research Program of the Network Joint Research Center for Materials and Devices,which was supported by the Ministry of Education,Culture,Sports,Science,and Technology(MEXT),JapanAUN/SEED-Net(BUU REd-UC 2301)for Research and Education Grant for the University Consortium(consortium name:CES-CHEM)。
文摘Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasing side product yield with the higher Re have been reported.This study investigated the mixing uniformity in microreactors with in-line UV-vis spectroscopy to clarify the relationship between reaction selectivity and chaotic mixing with the higher Re.A colorization experiment of thymolphthalein in an acidic solution was conducted with an excess acid amount to the base to indicate a non-uniformly mixed region.Non-uniformity significantly increased with Re.At the same time,the degree of mixing,which was measured by a usual decolorization experiment,showed that the mixing rate increased with Re.The in-line analysis of the Villermaux-Dushman reaction during the mixing clarified that side product yield significantly increased with Re at around 300 and then decreased at around 1100.These results suggest the compensation effect between the mixing uniformity and mixing rate on the selectivity of the mixing-sensitive reactions.Faster mixing,characterized by a larger Re,can disturb mixing uniformity and,in some cases,decrease reaction selectivity.
文摘During the excavation of deep coal and rock mass, the radial stress of the free face changes from three-dimensional compression state to two-dimensional stress, bearing the combined action of dynamic disturbance and static load at the same time. With that, many mines suffer from dynamic disasters, such as coal and gas outburst, rock burst and rock caving during deep mining excavation, which is often accompanied by plate crack, spalling and other disasters, seriously affecting the stability of stope and roadway. Taking thin rectangular coal and rock mass as the research object, the dual equation of the free vibration was derived and the exact solution model of the free vibration was established with the use of Hamilton dual system. Based on the action characteristics of the uniform impact load, the effective mode of the forced vibration was obtained by using the Duhamel integral principle and the orthogonality of the mode function. Based on the third strength theory and the numerical simulation results, the dynamic damage process and development trend of coal and rock mass were analyzed under uniform impact load. It was concluded that the starting position of dynamic damage can be judged by the first order main mode, and the development direction and trend of the damage can be judged by the fifth and sixth order main modes. It was concluded that the vibration mode functions of coal and rock mass with four side fixed (C-C-C-C), the two sides fixed and simply supported on the other (S-C-S-C) are mainly composed of three modes that are the first order (dominant frequency), the fifth order and the sixth order, from which the dynamic damage mechanism is preliminarily studied.
基金financially supported by the Science&Technology Project of Beijing Education Committee(KM202210005013)National Natural Science Foundation of China(52306180)。
文摘This study used a three-dimensional numerical model of a proton exchange membrane fuel cell with five types of channels:a smooth channel(Case 1);eight rectangular baffles were arranged in the upstream(Case 2),midstream(Case 3),downstream(Case 4),and the entire cathode flow channel(Case 5)to study the effects of baffle position on mass transport,power density,net power,etc.Moreover,the effects of back pressure and humidity on the voltage were investigated.Results showed that compared to smooth channels,the oxygen and water transport facilitation at the diffusion layer-channel interface were added 11.53%-20.60%and 7.81%-9.80%at 1.68 A·cm^(-2)by adding baffles.The closer the baffles were to upstream,the higher the total oxygen flux,but the lower the flux uniformity the worse the water removal.The oxygen flux of upstream baffles was 8.14%higher than that of downstream baffles,but oxygen flux uniformity decreased by 18.96%at 1.68 A·cm^(-2).The order of water removal and voltage improvement was Case 4>Case 5>Case 3>Case 2>Case 1.Net power of Case 4 was 9.87%higher than that of the smooth channel.To the Case 4,when the cell worked under low back pressure or high humidity,the voltage increments were higher.The potential increment for the back pressure of 0 atm was 0.9%higher than that of 2 atm(1 atm=101.325 kPa).The potential increment for the humidity of 100%was 7.89%higher than that of 50%.
基金supported by the National Key Research and Development Program of China (2016YFD0300407)the earmarked fund for China Agriculture Research System (CARS-03)
文摘Improving radiation use efficiency （RUE） of the canopy is necessary to increase wheat （Triticum aesfivum） production. Tridimensional uniform sowing （U） technology has previously been used to construct a uniformly distributed population structure that increases RUE. In this study, we used tridimensional uniform sowing to create a wheat canopy within which light was spread evenly to increase RUE. This study was done during 2014-2016 in the Shunyi District, Beijing, China. The soil type was sandy loam. Wheat was grown in two sowing patterns： （1） tridimensional uniform sowing （U）; （2） conventional drilling （D）. Four planting densities were used： 1.8, 2.7, 3.6, and 4.5 million plants ha-1. Several indices were measured to compare the wheat canopies： photosynthetic active radiation intercepted by the canopy （IPAR）, leaf area index （LAI）, leaf mass per unit area （LMA）, canopy extinction coefficient （K）, and RUE. In two sowing patterns, the K values decreased with increasing planting density, but the K values of U were lower than that of D. LMA and IPAR were higher for U than for D, whereas LAI was nearly the same for both sowing patterns. IPAR and LAI increased with increasing density under the same sowing pattern. However, the difference in IPAR and LAI between the 3.6 and 4.5 million plants ha-1 treatments was not significant for both sowing patterns. Therefore, LAI within the same planting density was not affected by sowing pattern. RUE was the largest for the U mode with a planting density of 3.6 million plants ha-1 treatment. For the D sowing pattern, the lowest planting density （1.8 million plants ha-1） resulted in the highest yield. Light radiation interception was minimal for the D mode with a planting density of 1.8 million plants ha-1 treatment, but the highest RUE and highest yield were observed under this condition. For the U sowing pattern, IPAR increased with increasing planting density, but yield and RUE were the highest with a planting density of 3.6 million plants ha-1. These results indicated that the optimal planting density for improving the canopy light environment differed between the sowing patterns. The effect of sowing patternxplanting density interaction on grain yield, yield components, RUE, IPAR, and LMA was significant （P〈0.05）. Correlation analysis indicated that there is a positive significant correlation between grain yield and RUE （t=0.880, P〈0.01）, LMA （r=0.613, P〈0.05）, andspike number （t=0.624, P〈0.05）. These results demonstrated that the tridimensional uniform sowing technique, particularly at a planting density of 3.6 million plants ha-0, can effectively increase light interception and utilization and unit leaf area. This leads to the production of more photosynthetic products that in turn lead to significantly increased spike number （P〈0.05）, kernel number, grain weight, and an overall increase in yield.
文摘The aim of this work is to study the effect of non-uniform single and double slot suction/injection into a steady mixed convection boundary layer flow over a vertical cone, while the axis of the cone is inline with the flow. The governing boundary layer equations are transformed into a non-dimensional form by a group of non-similar trans- formations. The resulting coupled non-linear partial differential equations are solved nu- merically by employing the quasi-linearization technique and an implicit finite-difference scheme. Numerical computations are performed for different values of the dimensionless parameters to display the velocity and temperature profiles graphically. Also, numerical results are presented for the skin friction and heat transfer coefficients. Results indicate that the skin friction and heat transfer coefficients increase with non-uniform slot suction, but the effect of non-uniform slot injection is just opposite.
