X-ray diffaction analysis(XRDA)data of the black or brown patina on the surfaces of eight kinds of bronze mirror samples show 4 or 5 broad diffuse peaks which corresponding to almost the same 20 angle, while their mat...X-ray diffaction analysis(XRDA)data of the black or brown patina on the surfaces of eight kinds of bronze mirror samples show 4 or 5 broad diffuse peaks which corresponding to almost the same 20 angle, while their matixes does not.These results indicate that those diffuse peaks were produced by the SnO2, microcrystals of 3 ￣5 nm size contained in the black or brown patina.The matrix of unearthed black patina bronze mirror numbered 223, gives strong XRDA diffraction peaks, indicating that there are a large amounts of non-oxidized bronze alloy particles surrounded by SnO2,which shows that the black patinas are not wholly metallic oxides (mainly SnO2),there are also a lot of original alloys of different sizes in grain in the patina.The bright-field image of the black patina sample gives the same result.展开更多
Copper patinas are generally regarded as aesthetically pleasing and are supposed to protect copper against further corrosion. The preparation of artificial sulphate patina on bronzes has been realized by immersing the...Copper patinas are generally regarded as aesthetically pleasing and are supposed to protect copper against further corrosion. The preparation of artificial sulphate patina on bronzes has been realized by immersing the bronze into CuSO4 solution. The effect of immersion time on the formation of the patina has been investigated. The sulphate patina obtained with immersion time of 500 h in CuSO4 solution consists of fiat area and crystals. The flat area in the patina is mainly made of cuprite, whereas the crystals are mainly composed of brochantite. The electrochemical measurement of sulphate patina in simulated acid rain with pH 3.1 shows that the protective effectiveness of patina decreases with time and the dissolution of patina is the key factor leading to the degradation of patina. The investigation of the formation mechanism of sulphate patina shows that the cuprite layer forms on the surface of bronze in the initial patination. Then, crystal brochantite grows on the surface of cuprite by the oxidation of cuprite and the incorporation of CuSO4 solution.展开更多
Hot solution of hydroquinone is oxidized by air forming quinone and quinhydrone, both of which have weak oxidizeability, enabling to oxidize metals on the surface of bronze mirror samples forming black and brilliant p...Hot solution of hydroquinone is oxidized by air forming quinone and quinhydrone, both of which have weak oxidizeability, enabling to oxidize metals on the surface of bronze mirror samples forming black and brilliant patina. SEM and electron micro probe analysis show that Cu content is lower than that of the original alloy due to Cu loss; Sn content is higher than the original alloy in patina. This indicates that humic acid is not the substance resulting in making black patina on the bronze mirror surface, but the black patina which produced from hydroquinone solution absence of Si, Al and Mg.展开更多
The formation of black patina caused by soil humic acid under different conditions has been studied,and the black, grey and brown shiny surfaces prepared in laboratory have been analysed. The formation of tin-rich shi...The formation of black patina caused by soil humic acid under different conditions has been studied,and the black, grey and brown shiny surfaces prepared in laboratory have been analysed. The formation of tin-rich shiny black surface on mirrors was the product of the soil corrosion of the bronze mirrors. It is formed by reaction between the alloy and the humic acid in soil, and leaching of copper and lead oxides through a long period of time when the mirrors were buried under the ground. A dense cormsion-resistallt layer on the bronze mirrors consisted predominantly of stannic oxide.展开更多
The formation of the black patina induced by soil humic asid under different conditions was studied, theblack, grey and brown colored shiny surfaces prepared in laboratory were analyzed. As a result the formation ofti...The formation of the black patina induced by soil humic asid under different conditions was studied, theblack, grey and brown colored shiny surfaces prepared in laboratory were analyzed. As a result the formation oftin-rich shiny black surface on bronze mirrors is the product of soil corrosion of the bronze mirrors. The patina isformed by reection between the alloy and the humic acid in soil, and leaching of copper and lead oxides through along period time when the mirrors were buried under the ground leaving a dense compact corrosion-resistant layerconsisted predominantly of stannic oxide microcrystal.展开更多
The modern field of Forensic Engineering evaluates the origin, cause, and duration of failed building components. As many failed components are subject to insurance claims and legal probes, a scientific methodology fo...The modern field of Forensic Engineering evaluates the origin, cause, and duration of failed building components. As many failed components are subject to insurance claims and legal probes, a scientific methodology for evaluating such events is inherently valuable. Due to the potential for widespread interior finish damage, failed plumbing supply components are commonly encountered during forensic evaluations. Plumbing pipes?themselves and properly soldered fittings rarely fail. Consequently, many failures correspond to mechanical fittings which form connections from pipes to plumbing fixtures.?The results of this study provide a scientific methodology to evaluate the duration of connection leaks by quantifying the extent of corrosion, patina, and accumulated deposits on various components?by creating and evaluating slow plumbing supply component connection leaks.展开更多
The last 15 years of research related to atmospheric corrosion and the release of copper to the environment are shortly summarized. Brown and green patinas with high barrier properties for corrosion are gradually evol...The last 15 years of research related to atmospheric corrosion and the release of copper to the environment are shortly summarized. Brown and green patinas with high barrier properties for corrosion are gradually evolved on copper at atmospheric conditions. The corrosion process and repeated dry and wet cycles results in a partial dissolution of corrosion products within the patina. Dissolved copper can be released and dispersed into the environment via the action of rainwater, however the major part is rearranged within the patina during drying cycles. The majority of corrosion products formed have a poor solubility, very different from water soluble copper salts. The release process is very slow and takes place independent of patina color. Its extent has only a marginal effect on the adherent patina. Released copper rapidly interacts with organic matter and in contact with different surfaces already in the close vicinity of the building, such as drainage systems, storm water pipes, pavements, stone materials and soil systems. These surfaces all have high capacities to retain copper in the runoff water and to reduce its concentration and chemical form to non-available and non-toxic levels for aquatic organisms.展开更多
The corrosion kinetics and patina(corrosion products) layer evolution of galvanized steel submitted to wet/dry cyclic corrosion test in a simulated coastal-industrial atmosphere was investigated. The results show that...The corrosion kinetics and patina(corrosion products) layer evolution of galvanized steel submitted to wet/dry cyclic corrosion test in a simulated coastal-industrial atmosphere was investigated. The results show that zinc coating has a greater corrosion rate during the initial period and a lower corrosion rate during the subsequent period, and the patina composition and structure can greatly affect the corrosion kinetics evolution of zinc coating. Moreover, Zn5(OH)6(CO3)2 and Zn4(OH)6 SO4 are identified as the main stable composition and exhibit an increasing relative amount;while Zn12(OH)15Cl3(SO4)3 cannot stably exist and diminish in the patina layer as the corrosion develops.展开更多
文摘X-ray diffaction analysis(XRDA)data of the black or brown patina on the surfaces of eight kinds of bronze mirror samples show 4 or 5 broad diffuse peaks which corresponding to almost the same 20 angle, while their matixes does not.These results indicate that those diffuse peaks were produced by the SnO2, microcrystals of 3 ￣5 nm size contained in the black or brown patina.The matrix of unearthed black patina bronze mirror numbered 223, gives strong XRDA diffraction peaks, indicating that there are a large amounts of non-oxidized bronze alloy particles surrounded by SnO2,which shows that the black patinas are not wholly metallic oxides (mainly SnO2),there are also a lot of original alloys of different sizes in grain in the patina.The bright-field image of the black patina sample gives the same result.
基金Funded by the Special Fund for Talent of Wuhan Instituteof Technologythe Fellowship for Junior Researchers fromPolitecnico di Torino and Regione Piemonte,Italy
文摘Copper patinas are generally regarded as aesthetically pleasing and are supposed to protect copper against further corrosion. The preparation of artificial sulphate patina on bronzes has been realized by immersing the bronze into CuSO4 solution. The effect of immersion time on the formation of the patina has been investigated. The sulphate patina obtained with immersion time of 500 h in CuSO4 solution consists of fiat area and crystals. The flat area in the patina is mainly made of cuprite, whereas the crystals are mainly composed of brochantite. The electrochemical measurement of sulphate patina in simulated acid rain with pH 3.1 shows that the protective effectiveness of patina decreases with time and the dissolution of patina is the key factor leading to the degradation of patina. The investigation of the formation mechanism of sulphate patina shows that the cuprite layer forms on the surface of bronze in the initial patination. Then, crystal brochantite grows on the surface of cuprite by the oxidation of cuprite and the incorporation of CuSO4 solution.
文摘Hot solution of hydroquinone is oxidized by air forming quinone and quinhydrone, both of which have weak oxidizeability, enabling to oxidize metals on the surface of bronze mirror samples forming black and brilliant patina. SEM and electron micro probe analysis show that Cu content is lower than that of the original alloy due to Cu loss; Sn content is higher than the original alloy in patina. This indicates that humic acid is not the substance resulting in making black patina on the bronze mirror surface, but the black patina which produced from hydroquinone solution absence of Si, Al and Mg.
文摘The formation of black patina caused by soil humic acid under different conditions has been studied,and the black, grey and brown shiny surfaces prepared in laboratory have been analysed. The formation of tin-rich shiny black surface on mirrors was the product of the soil corrosion of the bronze mirrors. It is formed by reaction between the alloy and the humic acid in soil, and leaching of copper and lead oxides through a long period of time when the mirrors were buried under the ground. A dense cormsion-resistallt layer on the bronze mirrors consisted predominantly of stannic oxide.
文摘The formation of the black patina induced by soil humic asid under different conditions was studied, theblack, grey and brown colored shiny surfaces prepared in laboratory were analyzed. As a result the formation oftin-rich shiny black surface on bronze mirrors is the product of soil corrosion of the bronze mirrors. The patina isformed by reection between the alloy and the humic acid in soil, and leaching of copper and lead oxides through along period time when the mirrors were buried under the ground leaving a dense compact corrosion-resistant layerconsisted predominantly of stannic oxide microcrystal.
文摘The modern field of Forensic Engineering evaluates the origin, cause, and duration of failed building components. As many failed components are subject to insurance claims and legal probes, a scientific methodology for evaluating such events is inherently valuable. Due to the potential for widespread interior finish damage, failed plumbing supply components are commonly encountered during forensic evaluations. Plumbing pipes?themselves and properly soldered fittings rarely fail. Consequently, many failures correspond to mechanical fittings which form connections from pipes to plumbing fixtures.?The results of this study provide a scientific methodology to evaluate the duration of connection leaks by quantifying the extent of corrosion, patina, and accumulated deposits on various components?by creating and evaluating slow plumbing supply component connection leaks.
文摘The last 15 years of research related to atmospheric corrosion and the release of copper to the environment are shortly summarized. Brown and green patinas with high barrier properties for corrosion are gradually evolved on copper at atmospheric conditions. The corrosion process and repeated dry and wet cycles results in a partial dissolution of corrosion products within the patina. Dissolved copper can be released and dispersed into the environment via the action of rainwater, however the major part is rearranged within the patina during drying cycles. The majority of corrosion products formed have a poor solubility, very different from water soluble copper salts. The release process is very slow and takes place independent of patina color. Its extent has only a marginal effect on the adherent patina. Released copper rapidly interacts with organic matter and in contact with different surfaces already in the close vicinity of the building, such as drainage systems, storm water pipes, pavements, stone materials and soil systems. These surfaces all have high capacities to retain copper in the runoff water and to reduce its concentration and chemical form to non-available and non-toxic levels for aquatic organisms.
基金supported by the National Natural Science Fundation of China (Nos. 51501204 and 51671200)the Research Program of Corrosion Distribution and Anti-corrosion Measures of Power Transmission in Complex Atmospheric Environment of Large Coastal Cities (No. GZM2014-2-0004)the Science and Technology Department of Henan Province (No. 172102310726)
文摘The corrosion kinetics and patina(corrosion products) layer evolution of galvanized steel submitted to wet/dry cyclic corrosion test in a simulated coastal-industrial atmosphere was investigated. The results show that zinc coating has a greater corrosion rate during the initial period and a lower corrosion rate during the subsequent period, and the patina composition and structure can greatly affect the corrosion kinetics evolution of zinc coating. Moreover, Zn5(OH)6(CO3)2 and Zn4(OH)6 SO4 are identified as the main stable composition and exhibit an increasing relative amount;while Zn12(OH)15Cl3(SO4)3 cannot stably exist and diminish in the patina layer as the corrosion develops.
