To realize high-efficiency and sustainable exploration of the Jiyang depression at the stage of high exploration degree, a hydrocarbon accumulation-geological evaluation method is developed on the basis of current geo...To realize high-efficiency and sustainable exploration of the Jiyang depression at the stage of high exploration degree, a hydrocarbon accumulation-geological evaluation method is developed on the basis of current geologic knowledge and extent of fine exploration. The concept of "layer exploration unit" is proposed in the study, and it is defined as an exploration geological unit that has a relatively complete and unified tectonic system, sedimentary system and hydrocarbon migration & accumulation system in a tectonic layer or tectonic sublayer within a fault basin. Then, an approach to dividing and evaluating the "layer exploration unit" is developed. With this approach, the Jiyang depression is divided into 305 layer exploration units, thus helping realize precise and stereoscopic geological understanding and exploration deployment. Fine splitting of remaining resources and benefit evaluation of exploration targets are conducted by "layer exploration units". As a result, 66 efficient "layer exploration units" in four major areas(i.e. Paleogene upper Es4-Dongying Formation, Neogene Minghuazhen Formation-Guantao Formation, Paleozoic buried-hill, and Paleogene Kongdian Formation-lower Es4) are determined as the targets for obtaining more reserves and breakthroughs in the short and medium term.展开更多
Based on the productivity equation of coalbed methane (CBM) well, considering the impact of coal reservoir reformability on gas well productivity, the main production layer optimization index in the “three-step metho...Based on the productivity equation of coalbed methane (CBM) well, considering the impact of coal reservoir reformability on gas well productivity, the main production layer optimization index in the “three-step method” of optimal combination of production layers is corrected, and then the CBM production layer potential index is introduced to evaluate favorable areas for commingled multi-coal seam production. Through analysis of the key parameters of coal reservoirs affecting the CBM productivity index, a development unit division method for areas with multi-coal seams is established, and a quantitative grading index system is proposed. On this basis, the evaluation process of CBM development favorable area is developed: the mature 3-D modeling technology is used to characterize the reservoir physical properties of multi-coal seams in full-scale;the production layer potential index of each grid is calculated, and the production layer potential index contour under single-layer or commingled multi-layer production are plotted;according to the distribution of the contour of production layer potential index, the quantitative index of CBM development unit is adopted to outline the grade I, II, III coal reservoir distribution areas, and thus to pick out the favorable development areas. The practical application in the Yuwang block of Laochang in Yunnan proved that the favorable area evaluation process proposed can effectively overcome the defects of selecting favorable development areas only relying on evaluation results of a major coal seam pay, and enhance the accuracy of the evaluation results, meeting the requirements of selecting favorable areas for multi-coal seam commingled CBM production.展开更多
New structural and petrological data unveil a very complicated ductile deformation history of the Xiongdian-Suhe HP metamorphic unit, north-western Dabie Shan, central China. The fine-grained symplectic amphibolite-fa...New structural and petrological data unveil a very complicated ductile deformation history of the Xiongdian-Suhe HP metamorphic unit, north-western Dabie Shan, central China. The fine-grained symplectic amphibolite-facies assemblage and coronal structure enveloping eclogite-facies garnet, omphacite and phengite etc., representing strain-free decompression and retrogressive metamorphism, are considered as the main criteria to distinguish between the early-stage deformation under HP metamorphic conditions related to the continental deep subduction and collision, and the late-stage deformation under amphibolite to greenschist-facies conditions occurred in the post-eclogite exhumation processes. Two late-stages of widely developed, sequential ductile deformations D 3 and D 4, are recognized on the basis of penetrative fabrics and mineral aggregates in the Xiongdian-Suhe HP metamorphic unit, which shows clear, regionally, consistent overprinting relationships. D 3 fabrics are best preserved in the Suhe tract of low post-D 3 deformation intensity and characterized by steeply dipping layered mylonitic amphibolites associated with doubly vergent folds. They are attributed to a phase of tectonism linked to the initial exhumation of the HP rocks and involved crustal shortening with the development of upright structures and the widespread emplacement of garnet-bearing granites and felsic dikes. D 4 structures are attributed to the main episode of ductile extension (D 1 4) with a gently dipping foliation to the north and common intrafolial, recumbent folds in the Xiongdian tract, followed by normal sense top-to-the north ductile shearing (D 2 4) along an important tectonic boundary, the so-called Majiawa-Hexiwan fault (MHF), the westward continuation of the Balifan-Mozitan-Xiaotian fault (BMXF) of the northern Dabie Shan. It is indicated that the two stages of ductile deformation observed in the Xiongdian-Suhe HP metamorphic unit, reflecting the post-eclogite compressional or extrusion wedge formation, the subhorizontal ductile extension and crustal thinning as well as the top-to-the north shearing along the high-angle ductile shear zones responsible for exhumation of the HP unit as a coherent slab, are consistent with those recognized in the Dabie-Sulu UHP and HP metamorphic belts, suggesting that they were closely associated in time and space. The Xiongdian-Suhe HP metamorphic unit thus forms part of the Triassic (250-230 Ma) collision orogenic belt, and can not connect with the South Altun-North Qaidam-North Qinling UHP metamorphic belt formed during the Early Paleozoic (500-400 Ma).展开更多
采用成核-晶化隔离法制备LiAl-CO_(3)-LDHs晶核,在LDHs晶核晶化的过程中引入葡萄糖分子作为碳源,构筑组成和结构可调的LDHs/C型杂化复合前体。通过高温处理,实现前体的结构拓扑转变及无定形碳组分的去除,得到高比表面积的LiAl复合金属...采用成核-晶化隔离法制备LiAl-CO_(3)-LDHs晶核,在LDHs晶核晶化的过程中引入葡萄糖分子作为碳源,构筑组成和结构可调的LDHs/C型杂化复合前体。通过高温处理,实现前体的结构拓扑转变及无定形碳组分的去除,得到高比表面积的LiAl复合金属氧化物型固体碱催化剂。采用XRD、FT-IR、BET、TEM、SEM、CO_(2)-TPD等表征手段对催化剂的组成、结构、织构性能、表面碱性进行了详细研究,并以苯甲醛和氰基乙酸乙酯间的Knoevenagel缩合反应为探针反应系统地研究了催化剂的碱催化性能。研究结果表明,LDHs/C杂化前体制备过程中葡萄糖与金属离子的摩尔比、水热晶化温度以及焙烧温度是影响催化剂活性的主要因素,晶化温度和焙烧温度的提升不利于碱性位的充分暴露。在150℃的水热晶化温度下,葡萄糖与Al 3+的摩尔比为3时的杂化复合前体经500℃焙烧得到的LiAl-MMO-150-3-500固体催化剂比表面积高达229 m 2·g^(-1),苯酚吸附测得催化剂的总碱量为855μmol·g^(-1),对苯甲醛的转化率高达88.21%。展开更多
基金Supported by the China National Science and Technology Major Project(2016ZX05006-003)
文摘To realize high-efficiency and sustainable exploration of the Jiyang depression at the stage of high exploration degree, a hydrocarbon accumulation-geological evaluation method is developed on the basis of current geologic knowledge and extent of fine exploration. The concept of "layer exploration unit" is proposed in the study, and it is defined as an exploration geological unit that has a relatively complete and unified tectonic system, sedimentary system and hydrocarbon migration & accumulation system in a tectonic layer or tectonic sublayer within a fault basin. Then, an approach to dividing and evaluating the "layer exploration unit" is developed. With this approach, the Jiyang depression is divided into 305 layer exploration units, thus helping realize precise and stereoscopic geological understanding and exploration deployment. Fine splitting of remaining resources and benefit evaluation of exploration targets are conducted by "layer exploration units". As a result, 66 efficient "layer exploration units" in four major areas(i.e. Paleogene upper Es4-Dongying Formation, Neogene Minghuazhen Formation-Guantao Formation, Paleozoic buried-hill, and Paleogene Kongdian Formation-lower Es4) are determined as the targets for obtaining more reserves and breakthroughs in the short and medium term.
基金Supported by the National Natural Science Foundation of China(No.41772155)the National Science and Technology Major Project of China(No.2016ZX05044-002)the Fundamental Research Funds for the Central Universities of China(No.2015XKZD07)
文摘Based on the productivity equation of coalbed methane (CBM) well, considering the impact of coal reservoir reformability on gas well productivity, the main production layer optimization index in the “three-step method” of optimal combination of production layers is corrected, and then the CBM production layer potential index is introduced to evaluate favorable areas for commingled multi-coal seam production. Through analysis of the key parameters of coal reservoirs affecting the CBM productivity index, a development unit division method for areas with multi-coal seams is established, and a quantitative grading index system is proposed. On this basis, the evaluation process of CBM development favorable area is developed: the mature 3-D modeling technology is used to characterize the reservoir physical properties of multi-coal seams in full-scale;the production layer potential index of each grid is calculated, and the production layer potential index contour under single-layer or commingled multi-layer production are plotted;according to the distribution of the contour of production layer potential index, the quantitative index of CBM development unit is adopted to outline the grade I, II, III coal reservoir distribution areas, and thus to pick out the favorable development areas. The practical application in the Yuwang block of Laochang in Yunnan proved that the favorable area evaluation process proposed can effectively overcome the defects of selecting favorable development areas only relying on evaluation results of a major coal seam pay, and enhance the accuracy of the evaluation results, meeting the requirements of selecting favorable areas for multi-coal seam commingled CBM production.
文摘New structural and petrological data unveil a very complicated ductile deformation history of the Xiongdian-Suhe HP metamorphic unit, north-western Dabie Shan, central China. The fine-grained symplectic amphibolite-facies assemblage and coronal structure enveloping eclogite-facies garnet, omphacite and phengite etc., representing strain-free decompression and retrogressive metamorphism, are considered as the main criteria to distinguish between the early-stage deformation under HP metamorphic conditions related to the continental deep subduction and collision, and the late-stage deformation under amphibolite to greenschist-facies conditions occurred in the post-eclogite exhumation processes. Two late-stages of widely developed, sequential ductile deformations D 3 and D 4, are recognized on the basis of penetrative fabrics and mineral aggregates in the Xiongdian-Suhe HP metamorphic unit, which shows clear, regionally, consistent overprinting relationships. D 3 fabrics are best preserved in the Suhe tract of low post-D 3 deformation intensity and characterized by steeply dipping layered mylonitic amphibolites associated with doubly vergent folds. They are attributed to a phase of tectonism linked to the initial exhumation of the HP rocks and involved crustal shortening with the development of upright structures and the widespread emplacement of garnet-bearing granites and felsic dikes. D 4 structures are attributed to the main episode of ductile extension (D 1 4) with a gently dipping foliation to the north and common intrafolial, recumbent folds in the Xiongdian tract, followed by normal sense top-to-the north ductile shearing (D 2 4) along an important tectonic boundary, the so-called Majiawa-Hexiwan fault (MHF), the westward continuation of the Balifan-Mozitan-Xiaotian fault (BMXF) of the northern Dabie Shan. It is indicated that the two stages of ductile deformation observed in the Xiongdian-Suhe HP metamorphic unit, reflecting the post-eclogite compressional or extrusion wedge formation, the subhorizontal ductile extension and crustal thinning as well as the top-to-the north shearing along the high-angle ductile shear zones responsible for exhumation of the HP unit as a coherent slab, are consistent with those recognized in the Dabie-Sulu UHP and HP metamorphic belts, suggesting that they were closely associated in time and space. The Xiongdian-Suhe HP metamorphic unit thus forms part of the Triassic (250-230 Ma) collision orogenic belt, and can not connect with the South Altun-North Qaidam-North Qinling UHP metamorphic belt formed during the Early Paleozoic (500-400 Ma).
文摘采用成核-晶化隔离法制备LiAl-CO_(3)-LDHs晶核,在LDHs晶核晶化的过程中引入葡萄糖分子作为碳源,构筑组成和结构可调的LDHs/C型杂化复合前体。通过高温处理,实现前体的结构拓扑转变及无定形碳组分的去除,得到高比表面积的LiAl复合金属氧化物型固体碱催化剂。采用XRD、FT-IR、BET、TEM、SEM、CO_(2)-TPD等表征手段对催化剂的组成、结构、织构性能、表面碱性进行了详细研究,并以苯甲醛和氰基乙酸乙酯间的Knoevenagel缩合反应为探针反应系统地研究了催化剂的碱催化性能。研究结果表明,LDHs/C杂化前体制备过程中葡萄糖与金属离子的摩尔比、水热晶化温度以及焙烧温度是影响催化剂活性的主要因素,晶化温度和焙烧温度的提升不利于碱性位的充分暴露。在150℃的水热晶化温度下,葡萄糖与Al 3+的摩尔比为3时的杂化复合前体经500℃焙烧得到的LiAl-MMO-150-3-500固体催化剂比表面积高达229 m 2·g^(-1),苯酚吸附测得催化剂的总碱量为855μmol·g^(-1),对苯甲醛的转化率高达88.21%。