The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic expo...The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.展开更多
Tibet Plateau has uplifted greatly in the Late Cenozoic era (Li Jijun et al., 1979; Sun Honglie, 1996; Shi Yafeng et al., 1998). The uplift will unquestionably influence the environment and climate of the plateau in t...Tibet Plateau has uplifted greatly in the Late Cenozoic era (Li Jijun et al., 1979; Sun Honglie, 1996; Shi Yafeng et al., 1998). The uplift will unquestionably influence the environment and climate of the plateau in the same time (such as resulting in the decrease of temperature) and leave some footprint on the contemporary sediments on or around the plateau. So, there must be some persistence component in the environmental and climatic evolution reflected by the geochemical information in the contemporary sediments. TS95, namely Tianshuihai Lake core is at the south frank of West Kunlun Mountain of Tibet Plateau and is suitable for the investigation of the persistence component. Using R/S analysis, Zhou Houyun et al. (1999) have previously calculated the Hurst index H of the three ferric indexes, FeO, Fe\-2O\-3 and ratio of FeO/ Fe\-2O\-3, from TS95. It is found that all these indexes satisfy Hurst law and they all are greater than 0 5, which means that there are some long run dependencies\|persistence component in the climatic and environmental evolution around Tianshuihai Lake area. This is in accordance with previous work by Yu Suhua et al. (1996). In this paper, the authors use the same method to do some R/S analysis on the other two climatic proxies of TS95, δ 13 C and δ 18 O, which are more suitable than the three ferric indexes to be climatic and environmental proxies. It is found that both the δ 13 C and δ 18 O satisfy Hurst law very well with H δ 13 C =0 875 and H δ 18 O =894, which suggests stronger persistence than the three ferric indexes.展开更多
基金the National Natural Science Foundation of China(No.20274023)key project foundation of National Ministry of Education(No.02114)Guangdong Province Natural Science Foundation of China(No.021241)for supporting this work.
文摘The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.
文摘Tibet Plateau has uplifted greatly in the Late Cenozoic era (Li Jijun et al., 1979; Sun Honglie, 1996; Shi Yafeng et al., 1998). The uplift will unquestionably influence the environment and climate of the plateau in the same time (such as resulting in the decrease of temperature) and leave some footprint on the contemporary sediments on or around the plateau. So, there must be some persistence component in the environmental and climatic evolution reflected by the geochemical information in the contemporary sediments. TS95, namely Tianshuihai Lake core is at the south frank of West Kunlun Mountain of Tibet Plateau and is suitable for the investigation of the persistence component. Using R/S analysis, Zhou Houyun et al. (1999) have previously calculated the Hurst index H of the three ferric indexes, FeO, Fe\-2O\-3 and ratio of FeO/ Fe\-2O\-3, from TS95. It is found that all these indexes satisfy Hurst law and they all are greater than 0 5, which means that there are some long run dependencies\|persistence component in the climatic and environmental evolution around Tianshuihai Lake area. This is in accordance with previous work by Yu Suhua et al. (1996). In this paper, the authors use the same method to do some R/S analysis on the other two climatic proxies of TS95, δ 13 C and δ 18 O, which are more suitable than the three ferric indexes to be climatic and environmental proxies. It is found that both the δ 13 C and δ 18 O satisfy Hurst law very well with H δ 13 C =0 875 and H δ 18 O =894, which suggests stronger persistence than the three ferric indexes.
文摘将经过多级破碎分选所得的废线路板粉末过60目筛,以2 mol/L HCl溶液、超纯水洗涤,并用丙酮脱水。将预处理后的滤渣、滤纸填入萃取池,或者用新滤纸包裹后置于索氏提取管内,添加5μL内标物,分别用加速溶剂萃取法(ASE)或索氏提取(SE)法进行萃取,依次采用多层硅胶柱和活性炭柱对萃取提取物进行净化、洗脱,得到二噁英测试样品。用同位素稀释-高分辨气相色谱-质谱联用仪分析样品中二噁英的含量。考察两种提取方法及不同氯代数对15种^(13)C-2,3,7,8-PCDD/Fs回收率的影响,比较两种方法的准确度和精密度。结果表明,ASE和SE对15种^(13)C-2,3,7,8-PCDD/Fs的回收率分别为54.3%~113.0%和28.3%~77.7%,实测废线路板中二噁英毒性当量(Toxic equivalent quangtity,TEQ)分别为0.075 ng TEQ/kg和0.266 ng TEQ/kg。在方法精密度允许范围内,ASE相对具有简单快速、溶剂用量少和准确的优势。
