The modification of activated carbon with persimmon tannin and its application for the removal of Pb（II） ions were carried out by batch method. The effects of solution pH, contact time, temperature and initial conce...The modification of activated carbon with persimmon tannin and its application for the removal of Pb（II） ions were carried out by batch method. The effects of solution pH, contact time, temperature and initial concentration on the immobilization of persimmon tannin were studied. The experimental results showed that the experimental data of persimmon tannin and Pb（II） fitted better by Langrnuir adsorption isotherm model and pseudo-second order model. The adsorption capacities of adsorbents for persimmon tannin and Pb（II） were calculated from the Langmuir isotherm model, and found to be 42.97 and 12.40 mg/g at optimum pH, respectively. It was noted that the adsorbent exhibited the best adsorption property for Pb（lI） when 1.0 g activated carbon was modified by 17.32 mg persimmon tannin. The modified activated carbon is more effective than the plain activated carbon, and it is expected to be an economic and effective adsorbent for the disposal of wastewater containing Pb（II） ions.展开更多
In order to recover much amount of gold, gold removal-recovery cycle was examined using immobilized persimmon gel, which could remove much amount of gold (III) from the tetrachloroaurate solution at 30<span style=&...In order to recover much amount of gold, gold removal-recovery cycle was examined using immobilized persimmon gel, which could remove much amount of gold (III) from the tetrachloroaurate solution at 30<span style="font-family:Verdana;"><span style="white-space:nowrap;">°</span>C. Removal of gold has proceeded different 2 mechanisms stages. At first, gold (III) was adsorbed rapidly on the surface of the persimmon gels until 2 hours and reached adsorption equilibrium. After that, the amount of gold removed was re-increased slowly and also reached equilibrium until 48</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">hours. The amount of gold removed was affected by the pH of the solution. The amount of Au removed was the highest at pH 5, which was decreased with decreasing or increasing the pH of the solution. The amount of gold removed (mol/g-dry wt. gels) was increased with increasing the gold concentration in the solution, whereas gold removed ratio was decreased. Gold removed ratio was increased with increasing the amount of persimmon gel used, whereas the amount of removed Au (mol/g-dry wt. gels) was decreased</span><i><span style="font-family:Verdana;">. </span></i><span style="font-family:Verdana;">Gold removal-recovery cycles were also examined in detail.</span></span>展开更多
This study herein was investigated the removal of chromium(VI) from an aqueous solution using persimmon tannin gel and its subsequent recovery as chromium(III). At pH 2, Cr(VI) was effectively adsorbed (~80% adsorptio...This study herein was investigated the removal of chromium(VI) from an aqueous solution using persimmon tannin gel and its subsequent recovery as chromium(III). At pH 2, Cr(VI) was effectively adsorbed (~80% adsorption) and ppm solution was reduced to Cr(III) on the persimmon gel within 10 min. Although desorption of the Cr(III) species was challenging at 30°, it was increased upon increasing the temperature and was quantitatively desorbed in the presence of 1 M hydrochloric acid under reflux. In addition, although the quantity of retained Cr(VI) on the tannin gel increased upon increasing the chromium concentration of the original aqueous solution, all the desorbed chromium was successfully reduced to Cr(III). Finally, Cr(VI) removal and recovery as Cr(III) was repeated effectively 8 times using the same persimmon tannin gel sample, thus demonstrating the recyclability of this system.展开更多
Rare earth elements(REEs)are used for the developme nt of new energy materials owing to their intrinsic physicochemical property.However,excess REEs in water threaten the safety of animals,plants and humans.An efficie...Rare earth elements(REEs)are used for the developme nt of new energy materials owing to their intrinsic physicochemical property.However,excess REEs in water threaten the safety of animals,plants and humans.An efficient way to separate REEs from the water is therefore needed.In this study,a biosorbent consisting of iron oxide(Fe3 O4),persimmon tannin(PT),and graphene oxide(GO)as Fe3 O4/PT/GO was prepared,and the adsorption of trivalent erbium(Er3+)ions from aqueous solution was investigated.The adsorption process for Er3+ions conforms to pseudo-second order kinetic and the Langmuir isotherm model behavior.Thermodynamic studies indicate that the adsorption process is spontaneous and endothermic.Scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),thermogravimetric analysis(TGA).Fourier-transform infrared(FT-IR)spectroscopy;Brunauer-Emmett-Teller(BET)analysis,and vibrating sample magnetometer(VSM)were used to assess the adsorption mechanism of Er3+ions onto the Fe3 O4/PT/GO biosorbent.A combination of electrostatic interactions,redox reactivity and chelation are responsible for adsorption of Er3+ions on the Fe3 O4/PT/GO biosorbent,The magnetic Fe3 O4/PT/GO biosorbent can be easily separated under the magnetic field for effective recycle of Er3+ions from aqueous solution.Therefore,this new biomass composite holds great promise for wastewater treatment.展开更多
Persimmon （ Diospyros kaki Thunb. ） , a member of Ebenaceae family, is known as ＂woody grain＂ and ＂iron-stem crop＂. However, the epigenetie research has been rarely reported. In this study, tannin content in lat...Persimmon （ Diospyros kaki Thunb. ） , a member of Ebenaceae family, is known as ＂woody grain＂ and ＂iron-stem crop＂. However, the epigenetie research has been rarely reported. In this study, tannin content in late fruit development periods was determined. Moreover, the MSAP （methylation-sensitive amplified polymorphism） method was used to analyze methylation profile, and 13 primer combinations were selected. In total, 5 differential fragments were cloned and sequenced. This research would be helpful for further gene cloning, research on deastringency mechanism, as well as molecular breeding of D. kaki.展开更多
基金Funded by the National Military-funded Projects of China(No.9140A12011108QT6912)
文摘The modification of activated carbon with persimmon tannin and its application for the removal of Pb（II） ions were carried out by batch method. The effects of solution pH, contact time, temperature and initial concentration on the immobilization of persimmon tannin were studied. The experimental results showed that the experimental data of persimmon tannin and Pb（II） fitted better by Langrnuir adsorption isotherm model and pseudo-second order model. The adsorption capacities of adsorbents for persimmon tannin and Pb（II） were calculated from the Langmuir isotherm model, and found to be 42.97 and 12.40 mg/g at optimum pH, respectively. It was noted that the adsorbent exhibited the best adsorption property for Pb（lI） when 1.0 g activated carbon was modified by 17.32 mg persimmon tannin. The modified activated carbon is more effective than the plain activated carbon, and it is expected to be an economic and effective adsorbent for the disposal of wastewater containing Pb（II） ions.
文摘In order to recover much amount of gold, gold removal-recovery cycle was examined using immobilized persimmon gel, which could remove much amount of gold (III) from the tetrachloroaurate solution at 30<span style="font-family:Verdana;"><span style="white-space:nowrap;">°</span>C. Removal of gold has proceeded different 2 mechanisms stages. At first, gold (III) was adsorbed rapidly on the surface of the persimmon gels until 2 hours and reached adsorption equilibrium. After that, the amount of gold removed was re-increased slowly and also reached equilibrium until 48</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">hours. The amount of gold removed was affected by the pH of the solution. The amount of Au removed was the highest at pH 5, which was decreased with decreasing or increasing the pH of the solution. The amount of gold removed (mol/g-dry wt. gels) was increased with increasing the gold concentration in the solution, whereas gold removed ratio was decreased. Gold removed ratio was increased with increasing the amount of persimmon gel used, whereas the amount of removed Au (mol/g-dry wt. gels) was decreased</span><i><span style="font-family:Verdana;">. </span></i><span style="font-family:Verdana;">Gold removal-recovery cycles were also examined in detail.</span></span>
文摘This study herein was investigated the removal of chromium(VI) from an aqueous solution using persimmon tannin gel and its subsequent recovery as chromium(III). At pH 2, Cr(VI) was effectively adsorbed (~80% adsorption) and ppm solution was reduced to Cr(III) on the persimmon gel within 10 min. Although desorption of the Cr(III) species was challenging at 30°, it was increased upon increasing the temperature and was quantitatively desorbed in the presence of 1 M hydrochloric acid under reflux. In addition, although the quantity of retained Cr(VI) on the tannin gel increased upon increasing the chromium concentration of the original aqueous solution, all the desorbed chromium was successfully reduced to Cr(III). Finally, Cr(VI) removal and recovery as Cr(III) was repeated effectively 8 times using the same persimmon tannin gel sample, thus demonstrating the recyclability of this system.
基金Project supported by the National Natural Science Foundation of China(81760534,51961010)Guangxi Key Research and Development Program(Guike2018AB38016,GuikeAB16380278)+1 种基金the Natural Science Foundation of Guangxi Province(2016GXNSFGA380001)the Special Fund of Guangxi Distinguished Experts。
文摘Rare earth elements(REEs)are used for the developme nt of new energy materials owing to their intrinsic physicochemical property.However,excess REEs in water threaten the safety of animals,plants and humans.An efficient way to separate REEs from the water is therefore needed.In this study,a biosorbent consisting of iron oxide(Fe3 O4),persimmon tannin(PT),and graphene oxide(GO)as Fe3 O4/PT/GO was prepared,and the adsorption of trivalent erbium(Er3+)ions from aqueous solution was investigated.The adsorption process for Er3+ions conforms to pseudo-second order kinetic and the Langmuir isotherm model behavior.Thermodynamic studies indicate that the adsorption process is spontaneous and endothermic.Scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),thermogravimetric analysis(TGA).Fourier-transform infrared(FT-IR)spectroscopy;Brunauer-Emmett-Teller(BET)analysis,and vibrating sample magnetometer(VSM)were used to assess the adsorption mechanism of Er3+ions onto the Fe3 O4/PT/GO biosorbent.A combination of electrostatic interactions,redox reactivity and chelation are responsible for adsorption of Er3+ions on the Fe3 O4/PT/GO biosorbent,The magnetic Fe3 O4/PT/GO biosorbent can be easily separated under the magnetic field for effective recycle of Er3+ions from aqueous solution.Therefore,this new biomass composite holds great promise for wastewater treatment.
基金Supported by College Students’Innovation and Entrepreneurship Training Program of Huanggang Normal University(zx201425)Fund of Hubei Collaborative Innovation Center for the Characteristic Resources Exploitation of Dabie Mountains(2015TD07)
文摘Persimmon （ Diospyros kaki Thunb. ） , a member of Ebenaceae family, is known as ＂woody grain＂ and ＂iron-stem crop＂. However, the epigenetie research has been rarely reported. In this study, tannin content in late fruit development periods was determined. Moreover, the MSAP （methylation-sensitive amplified polymorphism） method was used to analyze methylation profile, and 13 primer combinations were selected. In total, 5 differential fragments were cloned and sequenced. This research would be helpful for further gene cloning, research on deastringency mechanism, as well as molecular breeding of D. kaki.
